CN102947358B - 低乙烯基苯乙烯-丁二烯聚合物及其制造方法 - Google Patents
低乙烯基苯乙烯-丁二烯聚合物及其制造方法 Download PDFInfo
- Publication number
- CN102947358B CN102947358B CN201180028897.3A CN201180028897A CN102947358B CN 102947358 B CN102947358 B CN 102947358B CN 201180028897 A CN201180028897 A CN 201180028897A CN 102947358 B CN102947358 B CN 102947358B
- Authority
- CN
- China
- Prior art keywords
- polymer
- styrene
- butadiene
- reactor
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 0 CCI(C)(C1NCCC1)C1C=*CCC1 Chemical compound CCI(C)(C1NCCC1)C1C=*CCC1 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
- C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US35495110P | 2010-06-15 | 2010-06-15 | |
| US61/354,951 | 2010-06-15 | ||
| PCT/EP2011/059918 WO2011157742A1 (en) | 2010-06-15 | 2011-06-15 | Low vinyl styrene-butadiene polymers and methods of making the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102947358A CN102947358A (zh) | 2013-02-27 |
| CN102947358B true CN102947358B (zh) | 2015-04-15 |
Family
ID=44215835
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180028897.3A Expired - Fee Related CN102947358B (zh) | 2010-06-15 | 2011-06-15 | 低乙烯基苯乙烯-丁二烯聚合物及其制造方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US9243099B2 (enExample) |
| EP (1) | EP2582735A1 (enExample) |
| JP (1) | JP2013528686A (enExample) |
| KR (1) | KR20130109003A (enExample) |
| CN (1) | CN102947358B (enExample) |
| BR (1) | BR112012032000A2 (enExample) |
| MX (1) | MX2012014834A (enExample) |
| RU (1) | RU2562458C2 (enExample) |
| SG (2) | SG185707A1 (enExample) |
| TW (1) | TW201211083A (enExample) |
| WO (1) | WO2011157742A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2495266A1 (en) * | 2011-03-04 | 2012-09-05 | Styron Deutschland GmbH | High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof |
| HUE031644T2 (en) * | 2012-03-20 | 2017-07-28 | Trinseo Europe Gmbh | Modified polymer preparations |
| EP2746300B1 (en) | 2012-12-21 | 2016-12-07 | Borealis AG | Process for producing a ziegler natta procatalyst for ethylene polymerisation |
| ES2653868T3 (es) | 2012-12-21 | 2018-02-09 | Borealis Ag | Procatalizador de Ziegler Natta soportado para la polimerización de etileno |
| ES2709631T3 (es) | 2013-04-30 | 2019-04-17 | Borealis Ag | Catalizadores de Ziegler-Natta soportados modificados con donador |
| TWI531605B (zh) * | 2014-12-30 | 2016-05-01 | 奇美實業股份有限公司 | 共軛二烯-乙烯基芳香烴共聚物及橡膠組成物 |
| FR3037586A1 (fr) * | 2015-06-17 | 2016-12-23 | Michelin & Cie | Procede de polymerisation continu d'elastomere dienique |
| MX2018013578A (es) * | 2016-09-09 | 2019-08-01 | Dynasol Elastomeros Sa De Cv | Sistemas de modificadores polares para la copolimerizacion en bloques con alto contenido de vinilo. |
| WO2018081799A1 (en) * | 2016-10-31 | 2018-05-03 | Bridgestone Corporation | Methods for producing polydienes |
| CN108017866B (zh) * | 2016-11-01 | 2021-04-09 | 中国石油化工股份有限公司 | 一种聚合物组合物 |
| FR3060580A1 (fr) * | 2016-12-21 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Procede de polymerisation continu d'elastomere dienique avec initiateur amidure de lithium |
| FR3060578A1 (fr) | 2016-12-21 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Procede de synthese en continu d'elastomere dienique avec initiateur amidure de lithium |
| CN110678492A (zh) * | 2017-03-29 | 2020-01-10 | 西索斯公司 | 用于具有高乙烯基芳烃含量和低乙烯基含量的乙烯基芳烃单体与共轭二烯单体的共聚物的合成的极性添加剂 |
| KR101893384B1 (ko) * | 2017-07-25 | 2018-08-30 | 금호석유화학 주식회사 | 공중합체의 제조방법 및 이를 포함하는 고무 조성물 |
| CN109485791B (zh) * | 2017-09-13 | 2021-10-19 | 中国石油化工股份有限公司 | 线形丁苯共聚物及其制备方法和组合物以及芳族乙烯基树脂及其制备方法 |
| CN109627382B (zh) * | 2017-10-06 | 2022-03-18 | 台橡股份有限公司 | 共轭二烯聚合物及其组合物及制造方法 |
| RU2733742C1 (ru) * | 2019-12-26 | 2020-10-06 | Публичное акционерное общество «СИБУР Холдинг» | Способ получения модифицированных сополимеров |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US3554997A (en) | 1968-10-02 | 1971-01-12 | Dow Chemical Co | Process for preventing gel formation during polymerization tube reactor |
| DE2332796A1 (de) * | 1973-06-28 | 1975-01-16 | Huels Chemische Werke Ag | Verfahren zur herstellung rieselfaehiger, pulverfoermiger kautschuk-fuellstoffmischungen |
| CA1143896A (en) | 1979-05-01 | 1983-03-29 | Richard L. Smith | Continuous solution polymerization process |
| US4525560A (en) * | 1979-05-18 | 1985-06-25 | Smith Richard L | Solution polymerization of conjugated dienes |
| JPS5785809A (en) * | 1980-11-18 | 1982-05-28 | Asahi Chem Ind Co Ltd | Production of conjugated diene polymer |
| JPS57100112A (en) * | 1980-12-16 | 1982-06-22 | Asahi Chem Ind Co Ltd | Perfectly random styrene-butadiene copolymer rubber |
| JPS57117508A (en) * | 1981-01-14 | 1982-07-22 | Asahi Chem Ind Co Ltd | Preparation of conjugated diene polymer |
| JPS58142901A (ja) | 1982-02-19 | 1983-08-25 | Nippon Zeon Co Ltd | ゴムの変性方法 |
| JPS5936144A (ja) | 1982-08-23 | 1984-02-28 | Sumitomo Rubber Ind Ltd | ジエン系ゴム組成物及び該組成物をトレツドに用いたタイヤ |
| US4429091A (en) | 1983-03-09 | 1984-01-31 | The Firestone Tire & Rubber Company | Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators |
| US5164450A (en) * | 1984-05-16 | 1992-11-17 | Japan Synthetic Rubber Co. | Butadiene copolymer rubber composition |
| JPS60240746A (ja) | 1984-05-16 | 1985-11-29 | Japan Synthetic Rubber Co Ltd | ブタジエン系共重合体ゴム組成物 |
| US4616069A (en) | 1984-10-26 | 1986-10-07 | Nippon Zeon Co., Ltd. | Process for making diene polymer rubbers |
| JPH0641488B2 (ja) | 1985-05-09 | 1994-06-01 | 旭化成工業株式会社 | 耐屈曲性に優れたスチレン−ブタジエン共重合ゴムの製造方法 |
| JPS6236437A (ja) * | 1985-08-12 | 1987-02-17 | Bridgestone Corp | タイヤトレツド用ゴム組成物 |
| ZA865707B (en) | 1985-09-03 | 1987-03-25 | Firestone Tire & Rubber Co | Oligomeric oxolanyl alkanes as randomizers for copolymerization |
| US4672097A (en) | 1986-03-25 | 1987-06-09 | The Firestone Tire & Rubber Company | Process and system for preparing random copolymers having low vinyl contents |
| EP0299074B1 (en) | 1987-01-14 | 1992-01-29 | Bridgestone Corporation | Tire |
| US5134199A (en) * | 1987-11-27 | 1992-07-28 | Asahi Kasei Kogyo Kabushiki Kaisha | Diene block polymer and polymer composition |
| CA1338317C (en) | 1988-02-25 | 1996-05-07 | Akio Imai | Modified diene polymer rubbers |
| EP0447066B2 (en) | 1990-03-02 | 2000-08-16 | Bridgestone Corporation | Pneumatic tyres |
| US5066729A (en) | 1990-04-09 | 1991-11-19 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated by reaction with n-alkyl and n-aryl imines |
| US5070150A (en) | 1990-07-02 | 1991-12-03 | The Goodyear Tire & Rubber Company | Process for the solid state (solventless) hydroxylation of vinyl-containing rubbers using a hydroxymercaptan |
| JP3146506B2 (ja) * | 1991-03-18 | 2001-03-19 | 日本ゼオン株式会社 | ジエン系重合体の製造方法およびゴム組成物 |
| US5227431A (en) | 1991-04-12 | 1993-07-13 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers jumped by partial crosslinking and terminated with a substituted imine |
| US5210145A (en) | 1991-12-20 | 1993-05-11 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated by reaction with fused-ring polynuclear aromatic compounds |
| JPH0723417B2 (ja) * | 1992-05-06 | 1995-03-15 | 旭化成工業株式会社 | 完全ランダムスチレン‐ブタジエン共重合ゴムの製造方法 |
| JP3319639B2 (ja) * | 1992-12-24 | 2002-09-03 | 株式会社ブリヂストン | 共役ジエン系重合体の製造方法、スチレン−ブタジエン系重合体及びそのゴム組成物 |
| FR2722503A1 (fr) | 1994-07-15 | 1996-01-19 | Michelin & Cie | Polymeres dieniques fonctionnels, leur procede de preparation et leur utilisation dans des compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques |
| US5679751A (en) | 1996-02-12 | 1997-10-21 | The Goodyear Tire & Rubber Company | Solution polymerization process for synthesis of styrene-butadiene or styrene-isoprene rubber |
| US6127472A (en) * | 1997-11-11 | 2000-10-03 | Jsr Corporation | Rubber composition |
| US6274680B1 (en) | 1998-12-31 | 2001-08-14 | Bridgestone/Firestone Research, Inc. | Sulfenyl halide polymerization terminators |
| US6372863B1 (en) | 1999-08-12 | 2002-04-16 | The Goodyear Tire & Rubber Company | Synthesis of styrene-butadiene rubber |
| EP1205506B1 (en) * | 2000-10-26 | 2004-12-29 | JSR Corporation | Rubber composition and methods for producing the same |
| US6693160B1 (en) * | 2002-08-16 | 2004-02-17 | The Goodyear Tire & Rubber Company | Functionalized monomers for synthesis of rubbery polymers |
| DE602006021727D1 (enExample) * | 2005-03-29 | 2011-06-16 | Asahi Kasei Chemicals Corp | |
| ITMI20060385A1 (it) | 2006-03-03 | 2007-09-04 | Polimeri Europa Spa | Procedimento in continuo per la preparazione di copolimeri randon dieni coniugati-vinil areni |
| RU2377258C2 (ru) * | 2008-01-09 | 2009-12-27 | Открытое акционерное общество "Воронежский синтетический каучук" | Способ получения полимеров бутадиена и сополимеров бутадиена со стиролом |
| CN102159600B (zh) | 2008-04-30 | 2014-06-11 | 斯泰隆欧洲有限责任公司 | 具有苯乙烯梯度的苯乙烯-丁二烯聚合物及其制备方法 |
-
2011
- 2011-06-10 TW TW100120353A patent/TW201211083A/zh unknown
- 2011-06-15 KR KR1020127032559A patent/KR20130109003A/ko not_active Withdrawn
- 2011-06-15 MX MX2012014834A patent/MX2012014834A/es active IP Right Grant
- 2011-06-15 SG SG2012086013A patent/SG185707A1/en unknown
- 2011-06-15 BR BR112012032000A patent/BR112012032000A2/pt not_active IP Right Cessation
- 2011-06-15 US US13/702,685 patent/US9243099B2/en active Active
- 2011-06-15 SG SG10201504708YA patent/SG10201504708YA/en unknown
- 2011-06-15 JP JP2013514697A patent/JP2013528686A/ja active Pending
- 2011-06-15 CN CN201180028897.3A patent/CN102947358B/zh not_active Expired - Fee Related
- 2011-06-15 RU RU2013101615/04A patent/RU2562458C2/ru not_active IP Right Cessation
- 2011-06-15 WO PCT/EP2011/059918 patent/WO2011157742A1/en not_active Ceased
- 2011-06-15 EP EP11725449.0A patent/EP2582735A1/en not_active Withdrawn
-
2015
- 2015-12-11 US US14/966,856 patent/US9567421B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BR112012032000A2 (pt) | 2016-11-08 |
| TW201211083A (en) | 2012-03-16 |
| SG185707A1 (en) | 2012-12-28 |
| MX2012014834A (es) | 2013-01-29 |
| US20160096912A1 (en) | 2016-04-07 |
| US9243099B2 (en) | 2016-01-26 |
| US9567421B2 (en) | 2017-02-14 |
| SG10201504708YA (en) | 2015-07-30 |
| WO2011157742A1 (en) | 2011-12-22 |
| EP2582735A1 (en) | 2013-04-24 |
| JP2013528686A (ja) | 2013-07-11 |
| US20130090440A1 (en) | 2013-04-11 |
| RU2013101615A (ru) | 2014-07-20 |
| RU2562458C2 (ru) | 2015-09-10 |
| KR20130109003A (ko) | 2013-10-07 |
| CN102947358A (zh) | 2013-02-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: Horgen Switzerland Applicant after: Styron Europe GmbH Address before: Horgen Switzerland Applicant before: Styron Europe GmbH |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Horgen Switzerland Patentee after: STYRON EUROPE GMBH Address before: Horgen Switzerland Patentee before: Styron Europe GmbH |
|
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Horgen Switzerland Patentee after: Contain European limited liability company of auspiciousness Austria Address before: Horgen Switzerland Patentee before: STYRON EUROPE GMBH |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150415 Termination date: 20160615 |