CN102947358B - 低乙烯基苯乙烯-丁二烯聚合物及其制造方法 - Google Patents

低乙烯基苯乙烯-丁二烯聚合物及其制造方法 Download PDF

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Publication number
CN102947358B
CN102947358B CN201180028897.3A CN201180028897A CN102947358B CN 102947358 B CN102947358 B CN 102947358B CN 201180028897 A CN201180028897 A CN 201180028897A CN 102947358 B CN102947358 B CN 102947358B
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polymer
styrene
butadiene
reactor
polymerization
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Expired - Fee Related
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CN201180028897.3A
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Chinese (zh)
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CN102947358A (zh
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S·瓦伦蒂
E·哈曼
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Contain European Of Auspiciousness Austria LLC
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Styron Europe GmbH
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
CN201180028897.3A 2010-06-15 2011-06-15 低乙烯基苯乙烯-丁二烯聚合物及其制造方法 Expired - Fee Related CN102947358B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US35495110P 2010-06-15 2010-06-15
US61/354,951 2010-06-15
PCT/EP2011/059918 WO2011157742A1 (en) 2010-06-15 2011-06-15 Low vinyl styrene-butadiene polymers and methods of making the same

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CN102947358A CN102947358A (zh) 2013-02-27
CN102947358B true CN102947358B (zh) 2015-04-15

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US (2) US9243099B2 (enExample)
EP (1) EP2582735A1 (enExample)
JP (1) JP2013528686A (enExample)
KR (1) KR20130109003A (enExample)
CN (1) CN102947358B (enExample)
BR (1) BR112012032000A2 (enExample)
MX (1) MX2012014834A (enExample)
RU (1) RU2562458C2 (enExample)
SG (2) SG185707A1 (enExample)
TW (1) TW201211083A (enExample)
WO (1) WO2011157742A1 (enExample)

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ES2709631T3 (es) 2013-04-30 2019-04-17 Borealis Ag Catalizadores de Ziegler-Natta soportados modificados con donador
TWI531605B (zh) * 2014-12-30 2016-05-01 奇美實業股份有限公司 共軛二烯-乙烯基芳香烴共聚物及橡膠組成物
FR3037586A1 (fr) * 2015-06-17 2016-12-23 Michelin & Cie Procede de polymerisation continu d'elastomere dienique
MX2018013578A (es) * 2016-09-09 2019-08-01 Dynasol Elastomeros Sa De Cv Sistemas de modificadores polares para la copolimerizacion en bloques con alto contenido de vinilo.
WO2018081799A1 (en) * 2016-10-31 2018-05-03 Bridgestone Corporation Methods for producing polydienes
CN108017866B (zh) * 2016-11-01 2021-04-09 中国石油化工股份有限公司 一种聚合物组合物
FR3060580A1 (fr) * 2016-12-21 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de polymerisation continu d'elastomere dienique avec initiateur amidure de lithium
FR3060578A1 (fr) 2016-12-21 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de synthese en continu d'elastomere dienique avec initiateur amidure de lithium
CN110678492A (zh) * 2017-03-29 2020-01-10 西索斯公司 用于具有高乙烯基芳烃含量和低乙烯基含量的乙烯基芳烃单体与共轭二烯单体的共聚物的合成的极性添加剂
KR101893384B1 (ko) * 2017-07-25 2018-08-30 금호석유화학 주식회사 공중합체의 제조방법 및 이를 포함하는 고무 조성물
CN109485791B (zh) * 2017-09-13 2021-10-19 中国石油化工股份有限公司 线形丁苯共聚物及其制备方法和组合物以及芳族乙烯基树脂及其制备方法
CN109627382B (zh) * 2017-10-06 2022-03-18 台橡股份有限公司 共轭二烯聚合物及其组合物及制造方法
RU2733742C1 (ru) * 2019-12-26 2020-10-06 Публичное акционерное общество «СИБУР Холдинг» Способ получения модифицированных сополимеров

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BR112012032000A2 (pt) 2016-11-08
TW201211083A (en) 2012-03-16
SG185707A1 (en) 2012-12-28
MX2012014834A (es) 2013-01-29
US20160096912A1 (en) 2016-04-07
US9243099B2 (en) 2016-01-26
US9567421B2 (en) 2017-02-14
SG10201504708YA (en) 2015-07-30
WO2011157742A1 (en) 2011-12-22
EP2582735A1 (en) 2013-04-24
JP2013528686A (ja) 2013-07-11
US20130090440A1 (en) 2013-04-11
RU2013101615A (ru) 2014-07-20
RU2562458C2 (ru) 2015-09-10
KR20130109003A (ko) 2013-10-07
CN102947358A (zh) 2013-02-27

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