CN102936478B - 一种双组份常温固化弹性环氧树脂胶粘剂及其制备方法 - Google Patents
一种双组份常温固化弹性环氧树脂胶粘剂及其制备方法 Download PDFInfo
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- CN102936478B CN102936478B CN201210513453.5A CN201210513453A CN102936478B CN 102936478 B CN102936478 B CN 102936478B CN 201210513453 A CN201210513453 A CN 201210513453A CN 102936478 B CN102936478 B CN 102936478B
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 19
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- WTFAGPBUAGFMQX-UHFFFAOYSA-N 1-[2-[2-(2-aminopropoxy)propoxy]propoxy]propan-2-amine Chemical compound CC(N)COCC(C)OCC(C)OCC(C)N WTFAGPBUAGFMQX-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 13
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- HPILSDOMLLYBQF-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)butoxymethyl]oxirane Chemical compound C1OC1COC(CCC)OCC1CO1 HPILSDOMLLYBQF-UHFFFAOYSA-N 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 claims description 4
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
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- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 claims description 2
- KUAUJXBLDYVELT-UHFFFAOYSA-N 2-[[2,2-dimethyl-3-(oxiran-2-ylmethoxy)propoxy]methyl]oxirane Chemical compound C1OC1COCC(C)(C)COCC1CO1 KUAUJXBLDYVELT-UHFFFAOYSA-N 0.000 claims description 2
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 2
- DLYLVPHSKJVGLG-UHFFFAOYSA-N 4-(cyclohexylmethyl)cyclohexane-1,1-diamine Chemical group C1CC(N)(N)CCC1CC1CCCCC1 DLYLVPHSKJVGLG-UHFFFAOYSA-N 0.000 claims description 2
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- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 3
- SEFYJVFBMNOLBK-UHFFFAOYSA-N 2-[2-[2-(oxiran-2-ylmethoxy)ethoxy]ethoxymethyl]oxirane Chemical compound C1OC1COCCOCCOCC1CO1 SEFYJVFBMNOLBK-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
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- 125000003700 epoxy group Chemical group 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920003987 resole Polymers 0.000 description 2
- 239000000565 sealant Substances 0.000 description 2
- HSDVRWZKEDRBAG-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)hexoxymethyl]oxirane Chemical compound C1OC1COC(CCCCC)OCC1CO1 HSDVRWZKEDRBAG-UHFFFAOYSA-N 0.000 description 1
- HJOVHMDZYOCNQW-UHFFFAOYSA-N Isophorone Natural products CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 1
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- Adhesives Or Adhesive Processes (AREA)
- Epoxy Resins (AREA)
Abstract
Description
性能项目 | 实施例1 | 实施例2 | 实施例3 |
拉伸剪切强度(MPa) | 9.7 | 11.2 | 10.5 |
胶体抗拉强度(MPa) | 21.7 | 25.3 | 20.1 |
伸长率(%) | 132.2 | 115.0 | 150.1 |
拉伸弹性模量(MPa) | 269.1 | 312.0 | 221.7 |
Claims (10)
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CN201210513453.5A CN102936478B (zh) | 2012-12-05 | 2012-12-05 | 一种双组份常温固化弹性环氧树脂胶粘剂及其制备方法 |
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CN201210513453.5A CN102936478B (zh) | 2012-12-05 | 2012-12-05 | 一种双组份常温固化弹性环氧树脂胶粘剂及其制备方法 |
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CN102936478B true CN102936478B (zh) | 2014-03-05 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110133819A (zh) * | 2019-05-15 | 2019-08-16 | 瑞镭激光技术(深圳)有限公司 | 一种低面型畸变的振镜反射镜及其粘接固定方法 |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2014058527A1 (en) * | 2012-10-10 | 2014-04-17 | Huntsman Advanced Materials Americas Llc | Uv resistant epoxy structural adhesive |
CN103224611A (zh) * | 2013-05-15 | 2013-07-31 | 程梦喜 | 一种改性脂环胺固化剂及其制备方法 |
CN103409090B (zh) * | 2013-06-05 | 2015-01-14 | 武汉市科达云石护理材料有限公司 | 在潮湿环境下使用的环氧嵌缝胶 |
CN103897643A (zh) * | 2014-03-12 | 2014-07-02 | 南京艾布纳密封技术有限公司 | 室温固化耐高热环氧胶粘剂 |
CN104984704B (zh) * | 2014-12-17 | 2017-08-25 | 江西腾德实业有限公司 | 一种变电设备双组分浇注料同步制备系统及方法 |
CN105199639B (zh) * | 2015-09-16 | 2018-05-18 | 上海回天新材料有限公司 | 一种柔性胶粘剂及其制备方法和应用 |
CN105336564B (zh) * | 2015-11-04 | 2017-08-11 | 清华大学 | 电子学真空穿通件 |
CN105256975A (zh) * | 2015-11-06 | 2016-01-20 | 周翠华 | 一种蜂窝式弹性锁扣木地板及其制造方法 |
CN105331049A (zh) * | 2015-11-24 | 2016-02-17 | 苏州盖德精细材料有限公司 | 一种高弹性环氧树脂灌封材料及其制备方法 |
CN106085321A (zh) * | 2016-06-20 | 2016-11-09 | 济南庆达丰成工程技术有限公司 | 一种用于粘结碳板的环氧结构胶粘剂及其制备方法 |
CN107163888A (zh) * | 2017-07-07 | 2017-09-15 | 东莞市德聚胶接技术有限公司 | 环氧树脂灌封胶及其制备方法 |
CN108611037A (zh) * | 2018-05-25 | 2018-10-02 | 合肥昂诺新材料有限公司 | 一种弹性和韧性提升的环氧树脂胶 |
CN109439256A (zh) * | 2018-11-10 | 2019-03-08 | 湖南神力铃胶粘剂制造有限公司 | 一种石材断裂修复用环氧胶粘剂及其制备方法 |
CN109988539B (zh) * | 2019-04-11 | 2022-01-11 | 福建省优泥墙体工程服务有限公司 | 一种切块砖粘结胶 |
CN110041869A (zh) * | 2019-04-22 | 2019-07-23 | 苏州市姑苏新型建材有限公司 | 一种改性环氧注射式植筋胶及其制备方法 |
CN110939378B (zh) * | 2019-11-16 | 2021-10-22 | 河北金河电力器具有限公司 | 一种胶合式全绝缘梯及专用胶水 |
CN114262593A (zh) * | 2021-12-29 | 2022-04-01 | 东莞市亚聚电子材料有限公司 | 一种mini显示屏用环氧AB胶及测试方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101475788A (zh) * | 2009-01-15 | 2009-07-08 | 湖南神力实业有限公司 | 一种高强度聚氨酯改性环氧建筑结构胶及其制造方法 |
CN101948667A (zh) * | 2010-10-13 | 2011-01-19 | 湖南神力铃胶粘剂制造有限公司 | 一种饰面大理石薄板与基材复合的胶粘剂及其制备方法 |
CN102675886A (zh) * | 2012-05-07 | 2012-09-19 | 湖北大学 | 一种纤维增强的环氧沥青材料及制备方法 |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101475788A (zh) * | 2009-01-15 | 2009-07-08 | 湖南神力实业有限公司 | 一种高强度聚氨酯改性环氧建筑结构胶及其制造方法 |
CN101948667A (zh) * | 2010-10-13 | 2011-01-19 | 湖南神力铃胶粘剂制造有限公司 | 一种饰面大理石薄板与基材复合的胶粘剂及其制备方法 |
CN102675886A (zh) * | 2012-05-07 | 2012-09-19 | 湖北大学 | 一种纤维增强的环氧沥青材料及制备方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110133819A (zh) * | 2019-05-15 | 2019-08-16 | 瑞镭激光技术(深圳)有限公司 | 一种低面型畸变的振镜反射镜及其粘接固定方法 |
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