CN102775545B - 一种热膨胀性微球及减少其中残余单体的方法 - Google Patents
一种热膨胀性微球及减少其中残余单体的方法 Download PDFInfo
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- CN102775545B CN102775545B CN201210241564.5A CN201210241564A CN102775545B CN 102775545 B CN102775545 B CN 102775545B CN 201210241564 A CN201210241564 A CN 201210241564A CN 102775545 B CN102775545 B CN 102775545B
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Abstract
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CN103665419B (zh) * | 2013-12-06 | 2016-08-24 | 上海金狮化工有限公司 | 中低温热膨胀微球的合成方法及其应用方法 |
CN104403049A (zh) * | 2014-11-10 | 2015-03-11 | 华东理工大学 | 一种通过悬浮聚合制备相变微胶囊的方法 |
CN104558393A (zh) * | 2014-11-10 | 2015-04-29 | 华东理工大学 | 一种正十四醇相变微胶囊及其制备方法 |
CN108219182B (zh) * | 2016-12-15 | 2020-11-24 | 上海略发化工科技有限公司 | 一种热膨胀性微球的制备方法 |
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CN116903923B (zh) * | 2023-09-12 | 2023-11-21 | 潍坊裕凯化工有限公司 | 一种热膨胀发泡剂的合成方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4147845A (en) * | 1976-12-10 | 1979-04-03 | Kemanobel Ab | Reducing the monomer content in expandable thermoplastic beads |
CN101981102A (zh) * | 2008-03-27 | 2011-02-23 | 阿肯马法国公司 | 制备可膨胀聚苯乙烯的方法 |
-
2012
- 2012-07-12 CN CN201210241564.5A patent/CN102775545B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4147845A (en) * | 1976-12-10 | 1979-04-03 | Kemanobel Ab | Reducing the monomer content in expandable thermoplastic beads |
CN101981102A (zh) * | 2008-03-27 | 2011-02-23 | 阿肯马法国公司 | 制备可膨胀聚苯乙烯的方法 |
Non-Patent Citations (1)
Title |
---|
肖超渤等.高分子化学.《高分子化学》.1998,135-136. * |
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