CN102471433A - 制备具有良好长期使用性能的阻燃聚氨酯泡沫的方法 - Google Patents
制备具有良好长期使用性能的阻燃聚氨酯泡沫的方法 Download PDFInfo
- Publication number
- CN102471433A CN102471433A CN2010800308760A CN201080030876A CN102471433A CN 102471433 A CN102471433 A CN 102471433A CN 2010800308760 A CN2010800308760 A CN 2010800308760A CN 201080030876 A CN201080030876 A CN 201080030876A CN 102471433 A CN102471433 A CN 102471433A
- Authority
- CN
- China
- Prior art keywords
- component
- filler
- ability
- polyether glycol
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 28
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 28
- 239000003063 flame retardant Substances 0.000 title claims abstract description 16
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 7
- 238000004519 manufacturing process Methods 0.000 title abstract description 3
- 230000007774 longterm Effects 0.000 title description 4
- 239000000945 filler Substances 0.000 claims abstract description 34
- 229920000570 polyether Polymers 0.000 claims abstract description 30
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 29
- 150000001875 compounds Chemical class 0.000 claims abstract description 25
- 239000000654 additive Substances 0.000 claims abstract description 18
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000012948 isocyanate Substances 0.000 claims abstract description 10
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 9
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 9
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 9
- 229920005862 polyol Polymers 0.000 claims abstract description 9
- 150000003077 polyols Chemical class 0.000 claims abstract description 9
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 8
- 239000000975 dye Substances 0.000 claims abstract description 5
- 239000000049 pigment Substances 0.000 claims abstract description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 54
- 238000000034 method Methods 0.000 claims description 32
- 150000002148 esters Chemical class 0.000 claims description 27
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 27
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 claims description 18
- 230000000996 additive effect Effects 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 238000002485 combustion reaction Methods 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 4
- 241000233866 Fungi Species 0.000 claims description 4
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims description 4
- 206010000269 abscess Diseases 0.000 claims description 4
- 230000003712 anti-aging effect Effects 0.000 claims description 4
- 230000000721 bacterilogical effect Effects 0.000 claims description 4
- 150000004985 diamines Chemical class 0.000 claims description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- 239000003340 retarding agent Substances 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 229920002396 Polyurea Polymers 0.000 claims description 2
- 229920003054 adipate polyester Polymers 0.000 claims description 2
- 229920005906 polyester polyol Polymers 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 241001425800 Pipa Species 0.000 claims 1
- 150000002513 isocyanates Chemical class 0.000 abstract description 6
- 229920001228 polyisocyanate Polymers 0.000 abstract description 4
- 239000005056 polyisocyanate Substances 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 239000003381 stabilizer Substances 0.000 abstract description 3
- 239000003054 catalyst Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 3
- 239000004604 Blowing Agent Substances 0.000 abstract 1
- 230000003679 aging effect Effects 0.000 abstract 1
- 230000003385 bacteriostatic effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000001408 fungistatic effect Effects 0.000 abstract 1
- 239000006082 mold release agent Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- -1 amino compound Chemical class 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 13
- 239000006260 foam Substances 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 6
- BRWZYZWZBMGMMG-UHFFFAOYSA-J dodecanoate tin(4+) Chemical compound [Sn+4].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O BRWZYZWZBMGMMG-UHFFFAOYSA-J 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical class [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 5
- 150000001721 carbon Chemical group 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920000265 Polyparaphenylene Polymers 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 description 2
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- AXFVIWBTKYFOCY-UHFFFAOYSA-N 1-n,1-n,3-n,3-n-tetramethylbutane-1,3-diamine Chemical compound CN(C)C(C)CCN(C)C AXFVIWBTKYFOCY-UHFFFAOYSA-N 0.000 description 1
- GXVUZYLYWKWJIM-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanamine Chemical class NCCOCCN GXVUZYLYWKWJIM-UHFFFAOYSA-N 0.000 description 1
- YSAANLSYLSUVHB-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]ethanol Chemical compound CN(C)CCOCCO YSAANLSYLSUVHB-UHFFFAOYSA-N 0.000 description 1
- 229940105325 3-dimethylaminopropylamine Drugs 0.000 description 1
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 1
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 1
- GTJVPLGQFHDOAC-UHFFFAOYSA-N C(C(=O)O)(=O)O.C(CCCCCCC)[Sn]CCCCCCCC Chemical compound C(C(=O)O)(=O)O.C(CCCCCCC)[Sn]CCCCCCCC GTJVPLGQFHDOAC-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Natural products CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 238000005684 Liebig rearrangement reaction Methods 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- PSDYQSWHANEKRV-UHFFFAOYSA-N [S]N Chemical compound [S]N PSDYQSWHANEKRV-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- DYDNPESBYVVLBO-UHFFFAOYSA-N formanilide Chemical compound O=CNC1=CC=CC=C1 DYDNPESBYVVLBO-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 235000015220 hamburgers Nutrition 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- JMOLZNNXZPAGBH-UHFFFAOYSA-N hexyldecanoic acid Chemical compound CCCCCCCCC(C(O)=O)CCCCCC JMOLZNNXZPAGBH-UHFFFAOYSA-N 0.000 description 1
- 229950004531 hexyldecanoic acid Drugs 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JWIXXKMOAUUTIQ-UHFFFAOYSA-N n',n'-dimethylpropane-1,3-diamine;urea Chemical compound NC(N)=O.CN(C)CCCN JWIXXKMOAUUTIQ-UHFFFAOYSA-N 0.000 description 1
- SBOJXQVPLKSXOG-UHFFFAOYSA-N o-amino-hydroxylamine Chemical compound NON SBOJXQVPLKSXOG-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- UDKSLGIUCGAZTK-UHFFFAOYSA-N phenyl pentadecane-1-sulfonate Chemical group CCCCCCCCCCCCCCCS(=O)(=O)OC1=CC=CC=C1 UDKSLGIUCGAZTK-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000582 polyisocyanurate Polymers 0.000 description 1
- 239000011495 polyisocyanurate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/409—Dispersions of polymers of C08G in organic compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0871—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic
- C08G18/0876—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic the dispersing or dispersed phase being a polyol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/016—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
1(比较) | 2 | 3 | 4 | 5 | 6(比较) | 7(比较) | ||
A1-1 | 100 | 100 | 100 | 100 | 100 | |||
A1-2 | 100 | 100 | ||||||
A2 | 1.2 | 1.2 | 1.2 | 1.2 | 1.2 | 1.2 | 1.2 | |
A3 (使用的水) | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.5 | 2.5 | |
A3 (总的水) | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | |
A4 | 5.0 | 5.0 | 5.0 | 5.0 | 5.0 | 5.0 | ||
A5-1 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 | |
A5-2 | 0.18 | 0.18 | 0.18 | 0.18 | 0.20 | 0.20 | 0.20 | |
A5-3 | 0.35 | 0.35 | 0.35 | 0.35 | 0.35 | 0.40 | 0.40 | |
A5-4 | 5.0 | 5.0 | ||||||
A5-5 | 5.0 | 5.0 | 5.0 | |||||
B | 33.98 | 34.65 | 34.65 | 34.65 | 34.70 | 34.50 | 35.10 | |
指数 | 108 | 108 | 108 | 108 | 108 | 108 | 108 | |
性能 | ||||||||
容积密度 | [kg/m3] | 35 | 35.3 | 37.1 | 38.2 | 38.1 | 33.7 | 35.7 |
拉伸强度 | [kPa] | 145 | 123 | 128 | 103 | 114 | 129 | 126 |
断裂伸长率 | [%] | 120 | 122 | 116 | 104 | 94 | 128 | 113 |
抗拉强度 | [kPa] | 3.19 | 3.09 | 3.43 | 3.41 | 4.41 | 4.54 | 4.15 |
DVR 90% | [%] | 5.5 | 6.8 | 6.1 | 12.6 | 21.1 | 9.4 | 39.7 |
Crib 5 | 通过 | 否 | 是 | 是 | 是 | 是 | 否 | 否 |
8(比较) | 9(比较) | ||
A1-1 | 100 | 100 | |
A2 | 1.2 | 1.2 | |
A3 (使用的水) | 2.0 | 2.0 | |
A3 (总的水) | 2.5 | 2.5 | |
A4 | 5.0 | 5.0 | |
A5-1 | 0.25 | 0.25 | |
A5-2 | 0.25 | 0.25 | |
A5-3 | 0.4 | 0.4 | |
A5-6 | 5.0 | 5.0 | |
A5-7 | 1.0 | ||
B | 34.65 | 34.65 | |
指数 | 108 | 108 | |
性能 | 1) | ||
容积密度 | [kg/m3] | 37.2 | |
拉伸强度 | [kPa] | 111 | |
断裂伸长率 | [%] | 103 | |
压缩负荷变形 | [kPa] | 3.88 | |
DVR 90% | [%] | 20.1 | |
Crib 5 | 通过 | 否 |
Claims (10)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009032415 | 2009-07-09 | ||
DE102009032415.1 | 2009-07-09 | ||
PCT/EP2010/004110 WO2011003590A2 (de) | 2009-07-09 | 2010-07-06 | Verfahren zur herstellung von flammgeschützten polyurethanschaumstoffen mit guten dauergebrauchseigenschaften |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102471433A true CN102471433A (zh) | 2012-05-23 |
CN102471433B CN102471433B (zh) | 2014-07-09 |
Family
ID=43402083
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201080030876.0A Expired - Fee Related CN102471433B (zh) | 2009-07-09 | 2010-07-06 | 制备具有良好长期使用性能的阻燃聚氨酯泡沫的方法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US20120108690A1 (zh) |
EP (1) | EP2451856B1 (zh) |
JP (1) | JP2012532237A (zh) |
CN (1) | CN102471433B (zh) |
CA (1) | CA2767469C (zh) |
ES (1) | ES2443834T3 (zh) |
MX (1) | MX2012000213A (zh) |
PL (1) | PL2451856T3 (zh) |
RU (1) | RU2540950C2 (zh) |
WO (1) | WO2011003590A2 (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109963900A (zh) * | 2016-09-29 | 2019-07-02 | 陶氏环球技术有限责任公司 | 可燃性降低的柔性聚氨酯泡沫 |
CN110183609A (zh) * | 2019-04-23 | 2019-08-30 | 合肥科天水性科技有限责任公司 | 一种无溶剂聚氨酯树脂及其应用 |
CN110809666A (zh) * | 2017-07-07 | 2020-02-18 | 科思创德国股份有限公司 | 用于内燃机的阻燃隔绝材料 |
CN111417665A (zh) * | 2017-12-18 | 2020-07-14 | 科思创德国股份有限公司 | 阻燃硬质聚氨酯泡沫 |
CN114127149A (zh) * | 2019-07-22 | 2022-03-01 | 巴斯夫欧洲公司 | 低tvoc的阻燃聚氨酯喷涂泡沫体系 |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX2010005069A (es) * | 2009-05-27 | 2010-11-26 | Bayer Materialscience Ag | Procedimiento para la fabricacion de espumas blandas de poliuretano con emision reducida. |
US9403961B2 (en) * | 2010-11-18 | 2016-08-02 | Dow Global Technologies Llc | Flame resistant flexible polyurethane foam |
WO2013003027A2 (en) * | 2011-06-29 | 2013-01-03 | Dow Global Technologies Llc | Thermally stable flame resistant flexible polyurethane foam |
EP2690118A1 (de) * | 2012-07-27 | 2014-01-29 | Basf Se | Polyurethane enthaltend Phosphorverbindungen |
CN103103795B (zh) * | 2013-01-17 | 2014-09-17 | 杭州电子科技大学 | 一种聚醚型聚氨酯乳液皮革涂饰剂的制备方法 |
CN103073987B (zh) * | 2013-01-17 | 2015-01-07 | 杭州电子科技大学 | 有机硅改性聚酯型聚氨酯乳液皮革涂饰剂的制备方法 |
CN103073988B (zh) * | 2013-01-17 | 2015-01-07 | 杭州电子科技大学 | 环氧树脂改性聚氨酯乳液皮革涂饰剂的制备方法 |
MX2016000554A (es) | 2013-07-25 | 2016-04-18 | Dow Global Technologies Llc | Espuma de poliuretano flexible resistente a las llamas. |
JP6364807B2 (ja) * | 2014-02-19 | 2018-08-01 | 東ソー株式会社 | ポリオール組成物 |
US11014998B2 (en) | 2016-11-28 | 2021-05-25 | Univation Technologies, Llc | Producing a polyethylene polymer |
KR20190109742A (ko) * | 2017-01-31 | 2019-09-26 | 바스프 에스이 | Hfo 함유 pu 제제 |
EP3425187A1 (de) | 2017-07-07 | 2019-01-09 | Covestro Deutschland AG | Flammgeschütze isolierung für verbrennungsmotoren |
EP4023692A4 (en) * | 2019-08-28 | 2023-09-20 | Sekisui Chemical Co., Ltd. | POLYOL CONTAINING COMPOSITION, FOAMABLE POLYURETHANE COMPOSITION AND POLYURETHANE FOAM |
CN117656343B (zh) * | 2023-12-08 | 2024-06-14 | 绍兴市辰星聚氨酯有限公司 | 一种层状硬质聚氨酯泡沫及加工方法 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6034146A (en) * | 1996-10-12 | 2000-03-07 | Basf Aktiengesellschaft | Preparation of a stable dispersion of melamine in polyol components |
WO2003016373A1 (en) * | 2001-08-15 | 2003-02-27 | Dow Global Technologies Inc. | Process to manufacture polyurethane products using polymer polyols in which the carrier polyol is a tertiary amone based polyol |
WO2004060956A1 (en) * | 2002-12-17 | 2004-07-22 | Dow Global Technologies Inc. | Amine-epoxy autocatalytic polymers and polyurethane products made therefrom |
WO2004081075A1 (en) * | 2003-03-11 | 2004-09-23 | Dow Global Technologies, Inc. | Low amine emission polyutethane foam |
US20050020707A1 (en) * | 2000-02-10 | 2005-01-27 | Simon Waddington | Low emission polyurethane polymers made with autocatalytic polyols |
CN1898287A (zh) * | 2003-12-23 | 2007-01-17 | 陶氏环球技术公司 | 含有亚胺键和叔胺的非短效催化剂以及用其制备的聚氨酯产品 |
CN101039974A (zh) * | 2004-10-15 | 2007-09-19 | 亨茨曼国际有限公司 | 制备pipa-多元醇的方法 |
CN101351484A (zh) * | 2005-11-14 | 2009-01-21 | 陶氏环球技术公司 | 导热性增强的硬质聚氨酯泡沫的模制法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2764565A (en) | 1951-12-24 | 1956-09-25 | Bayer Ag | Process and apparatus for the manufacture of polyurethane plastics |
US3178490A (en) | 1961-10-06 | 1965-04-13 | Thiokol Chemical Corp | Process for producing a foamed plastic article having a dense skin |
US3182104A (en) | 1962-02-14 | 1965-05-04 | Glidden Co | Process for making thick-skinned articles comprising polyurethane foam |
DE1694142C3 (de) | 1967-03-25 | 1975-10-23 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Schaumstoffen |
DE1720768A1 (de) | 1968-01-02 | 1971-07-15 | Bayer Ag | Kunststoffe auf Isocyanatbasis und Verfahren zu ihrer Herstellung |
DE2051304A1 (de) * | 1970-10-20 | 1972-04-27 | Bayer | Verfahren zur Herstellung von Isocyanuratgruppen aufweisenden Schaum stoffen |
DE2121670C3 (de) | 1971-05-03 | 1979-11-15 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Schaumstoffen |
DE2307589C3 (de) | 1973-02-16 | 1984-11-15 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Schaumstoffen mit vorzüglichen Entformungseigenschaften |
US4089835A (en) | 1975-03-27 | 1978-05-16 | Bayer Aktiengesellschaft | Stable polyurethane dispersions and process for production thereof |
DE2639254A1 (de) | 1976-09-01 | 1978-03-02 | Bayer Ag | Verfahren zur herstellung von stabilen dispersionen |
DE2732292A1 (de) | 1977-07-16 | 1979-02-01 | Bayer Ag | Verfahren zur herstellung von polyurethankunststoffen |
DE2832253A1 (de) | 1978-07-22 | 1980-01-31 | Bayer Ag | Verfahren zur herstellung von formschaumstoffen |
DE3435070A1 (de) | 1984-09-25 | 1986-04-03 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von gegebenenfalls geschaeumten polyurethanen, die mit einem anderen werkstoff verbunden oder konfektioniert worden sind |
JPH10147623A (ja) | 1996-11-20 | 1998-06-02 | Chisso Corp | 難燃性軟質ポリウレタンフォーム用組成物 |
DE19728543A1 (de) * | 1997-07-04 | 1999-01-07 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen mit geringer Wärmeleitfähigkeit |
DE19811472A1 (de) * | 1998-03-17 | 1999-09-23 | Basf Ag | Verfahren zur Herstellung von Polyurethansystemen mit verminderter Eindringtiefe zur Hinterschäumung |
TW568921B (en) * | 1998-08-07 | 2004-01-01 | Huntsman Int Llc | Process for preparing a moulded flexible polyurethane foam |
DE10105560A1 (de) * | 2001-02-06 | 2002-08-08 | Basf Ag | Verfahren zur Herstellung von Polyurethanweichschäumen |
DE102005050701A1 (de) * | 2005-10-22 | 2007-05-03 | Bayer Materialscience Ag | Verfahren zur Herstellung von PIPA-Polyolen |
DE102006060376A1 (de) * | 2006-12-20 | 2008-06-26 | Bayer Materialscience Ag | Verfahren zur Herstellung von PIPA-Polyolen zur Herstellung von hochelastischen Polyurethan-Weichschaumstoffen |
-
2010
- 2010-07-06 RU RU2012104326/04A patent/RU2540950C2/ru not_active IP Right Cessation
- 2010-07-06 PL PL10730725T patent/PL2451856T3/pl unknown
- 2010-07-06 JP JP2012518813A patent/JP2012532237A/ja active Pending
- 2010-07-06 WO PCT/EP2010/004110 patent/WO2011003590A2/de active Application Filing
- 2010-07-06 US US13/382,776 patent/US20120108690A1/en not_active Abandoned
- 2010-07-06 CA CA2767469A patent/CA2767469C/en not_active Expired - Fee Related
- 2010-07-06 CN CN201080030876.0A patent/CN102471433B/zh not_active Expired - Fee Related
- 2010-07-06 MX MX2012000213A patent/MX2012000213A/es active IP Right Grant
- 2010-07-06 ES ES10730725.8T patent/ES2443834T3/es active Active
- 2010-07-06 EP EP10730725.8A patent/EP2451856B1/de not_active Not-in-force
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6034146A (en) * | 1996-10-12 | 2000-03-07 | Basf Aktiengesellschaft | Preparation of a stable dispersion of melamine in polyol components |
US20050020707A1 (en) * | 2000-02-10 | 2005-01-27 | Simon Waddington | Low emission polyurethane polymers made with autocatalytic polyols |
WO2003016373A1 (en) * | 2001-08-15 | 2003-02-27 | Dow Global Technologies Inc. | Process to manufacture polyurethane products using polymer polyols in which the carrier polyol is a tertiary amone based polyol |
WO2004060956A1 (en) * | 2002-12-17 | 2004-07-22 | Dow Global Technologies Inc. | Amine-epoxy autocatalytic polymers and polyurethane products made therefrom |
WO2004081075A1 (en) * | 2003-03-11 | 2004-09-23 | Dow Global Technologies, Inc. | Low amine emission polyutethane foam |
CN1898287A (zh) * | 2003-12-23 | 2007-01-17 | 陶氏环球技术公司 | 含有亚胺键和叔胺的非短效催化剂以及用其制备的聚氨酯产品 |
CN101039974A (zh) * | 2004-10-15 | 2007-09-19 | 亨茨曼国际有限公司 | 制备pipa-多元醇的方法 |
CN101351484A (zh) * | 2005-11-14 | 2009-01-21 | 陶氏环球技术公司 | 导热性增强的硬质聚氨酯泡沫的模制法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109963900A (zh) * | 2016-09-29 | 2019-07-02 | 陶氏环球技术有限责任公司 | 可燃性降低的柔性聚氨酯泡沫 |
CN109963900B (zh) * | 2016-09-29 | 2021-09-03 | 陶氏环球技术有限责任公司 | 可燃性降低的柔性聚氨酯泡沫 |
CN110809666A (zh) * | 2017-07-07 | 2020-02-18 | 科思创德国股份有限公司 | 用于内燃机的阻燃隔绝材料 |
CN111417665A (zh) * | 2017-12-18 | 2020-07-14 | 科思创德国股份有限公司 | 阻燃硬质聚氨酯泡沫 |
CN111417665B (zh) * | 2017-12-18 | 2022-09-27 | 科思创德国股份有限公司 | 阻燃硬质聚氨酯泡沫 |
CN110183609A (zh) * | 2019-04-23 | 2019-08-30 | 合肥科天水性科技有限责任公司 | 一种无溶剂聚氨酯树脂及其应用 |
CN110183609B (zh) * | 2019-04-23 | 2021-12-24 | 合肥科天水性科技有限责任公司 | 一种无溶剂聚氨酯树脂及其应用 |
CN114127149A (zh) * | 2019-07-22 | 2022-03-01 | 巴斯夫欧洲公司 | 低tvoc的阻燃聚氨酯喷涂泡沫体系 |
Also Published As
Publication number | Publication date |
---|---|
ES2443834T3 (es) | 2014-02-20 |
RU2012104326A (ru) | 2013-08-20 |
PL2451856T3 (pl) | 2014-05-30 |
EP2451856A2 (de) | 2012-05-16 |
MX2012000213A (es) | 2012-01-25 |
EP2451856B1 (de) | 2013-12-11 |
WO2011003590A3 (de) | 2011-03-31 |
JP2012532237A (ja) | 2012-12-13 |
WO2011003590A2 (de) | 2011-01-13 |
RU2540950C2 (ru) | 2015-02-10 |
CA2767469C (en) | 2017-10-17 |
CA2767469A1 (en) | 2011-01-13 |
US20120108690A1 (en) | 2012-05-03 |
CN102471433B (zh) | 2014-07-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102471433B (zh) | 制备具有良好长期使用性能的阻燃聚氨酯泡沫的方法 | |
CN100528922C (zh) | 用于具有改进老化特性的低密度聚氨酯泡沫的自催化多元醇的助催化 | |
US9512271B2 (en) | Silicone copolymers with pendant alkyl radicals attached via allyl glycidyl ether and related compounds, and use thereof as stabilizers for production of flexible polyurethane foams | |
WO2012067841A2 (en) | Flame resistant flexible polyurethane foam | |
EP2726543A2 (en) | Thermally stable flame resistant flexible polyurethane foam | |
MX2010005069A (es) | Procedimiento para la fabricacion de espumas blandas de poliuretano con emision reducida. | |
EP0309217A1 (en) | Manufacture of polyurethane foam | |
AU2014318646A1 (en) | PIPA polyol based conventional flexible foam | |
CN106574037A (zh) | 阻热性和阻燃性聚氨酯泡沫体 | |
CN107001575A (zh) | 用于制备粘弹性的聚氨酯泡沫材料的方法 | |
US20240360278A1 (en) | Process for preparing a polyether polyol with a high ethylene oxide content | |
CN102725330B (zh) | 用于吸收声音和振动的低密度聚氨酯泡沫的制造方法 | |
KR20060009322A (ko) | Pipa-폴리올의 제조 방법 | |
AU2017394687B2 (en) | Polyol blends useful for producing viscoelastic foam | |
US8901187B1 (en) | High resilience flexible polyurethane foam using MDI | |
US5885479A (en) | Production of flame-resistant flexible polyurethane foams | |
CN109963900B (zh) | 可燃性降低的柔性聚氨酯泡沫 | |
CN108368230B (zh) | 用于制造聚氨基甲酸酯泡沫的方法 | |
KR102516479B1 (ko) | 폴리우레탄에 관한 개선 | |
JP2003147044A (ja) | 軟質ポリウレタンフォームの製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20160617 Address after: Leverkusen, Germany Patentee after: COVESTRO DEUTSCHLAND AG Address before: German Monheim Patentee before: BAYER INTELLECTUAL PROPERTY GmbH Effective date of registration: 20160617 Address after: German Monheim Patentee after: BAYER INTELLECTUAL PROPERTY GmbH Address before: Germany Leverkusen Patentee before: BAYER MATERIALSCIENCE AG |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140709 Termination date: 20190706 |
|
CF01 | Termination of patent right due to non-payment of annual fee |