CN102413931B - 氟化醇的烷氧基化 - Google Patents

氟化醇的烷氧基化 Download PDF

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Publication number
CN102413931B
CN102413931B CN201080019123.XA CN201080019123A CN102413931B CN 102413931 B CN102413931 B CN 102413931B CN 201080019123 A CN201080019123 A CN 201080019123A CN 102413931 B CN102413931 B CN 102413931B
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CN
China
Prior art keywords
quaternary salt
formula
catalyst system
alkali metal
halogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201080019123.XA
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English (en)
Chinese (zh)
Other versions
CN102413931A (zh
Inventor
K·J·斯维特曼
S·A·贝克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
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Publication of CN102413931A publication Critical patent/CN102413931A/zh
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Expired - Fee Related legal-status Critical Current
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B01J31/0268—Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/121—Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/02—Preparation of ethers from oxiranes
    • C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/10—Saturated ethers of polyhydroxy compounds
    • C07C43/11—Polyethers containing —O—(C—C—O—)n units with ≤ 2 n≤ 10

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201080019123.XA 2009-04-30 2010-04-30 氟化醇的烷氧基化 Expired - Fee Related CN102413931B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/432825 2009-04-30
US12/432,825 US8053606B2 (en) 2009-04-30 2009-04-30 Alkoxylation of fluorinated alcohols
PCT/US2010/033130 WO2010127221A1 (en) 2009-04-30 2010-04-30 Alkoxylation of fluorinated alcohols

Publications (2)

Publication Number Publication Date
CN102413931A CN102413931A (zh) 2012-04-11
CN102413931B true CN102413931B (zh) 2014-05-07

Family

ID=42371364

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080019123.XA Expired - Fee Related CN102413931B (zh) 2009-04-30 2010-04-30 氟化醇的烷氧基化

Country Status (8)

Country Link
US (1) US8053606B2 (enExample)
EP (1) EP2424662A1 (enExample)
JP (1) JP2012525438A (enExample)
KR (1) KR20120017057A (enExample)
CN (1) CN102413931B (enExample)
AU (1) AU2010242860A1 (enExample)
CA (1) CA2754444A1 (enExample)
WO (1) WO2010127221A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8039677B2 (en) * 2009-04-30 2011-10-18 E.I. Du Pont De Nemours And Company Fluoroalkylalkoxylates
US20120255651A1 (en) * 2011-04-07 2012-10-11 E.I. Du Pont De Nemours And Company Fluoroalkylalkoxylates
WO2014090649A1 (en) 2012-12-11 2014-06-19 Solvay Specialty Polymers Italy S.P.A. Process for the alkoxylation of (per)fluoropolyether alcohols
CN116354830A (zh) * 2017-05-19 2023-06-30 埃特纳科技有限公司 官能化氟化单体的制备方法、氟化单体及用于制备其的组合物

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4533759A (en) * 1982-04-09 1985-08-06 National Distillers And Chemical Corporation Process for the production of fragrance quality ethylene glycol monoaryl ethers
CN1151153A (zh) * 1994-06-21 1997-06-04 纳幕尔杜邦公司 具有增强水溶性的氟代烷基乙氧基化物
CN1419561A (zh) * 2000-03-24 2003-05-21 纳幕尔杜邦公司 氟化润滑剂添加剂

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US2537981A (en) 1949-10-28 1951-01-16 American Cyanamid Co Method of producing a glycidyl ester
GB961893A (en) * 1961-06-20 1964-06-24 Metal Hydrides Inc Improvements in solutions of quaternary ammonium borohydrides in liquid hydrocarbons
US3372201A (en) 1966-06-17 1968-03-05 Gen Aniline & Film Corp Alkoxylation of secondary alcohols
SU895492A1 (ru) 1980-03-12 1982-01-07 Предприятие П/Я А-1785 Катализатор дл оксиэтилировани жирных спиртов с @ -с @
JPS60146848A (ja) 1984-01-10 1985-08-02 Daikin Ind Ltd 新規テトラアンモニウム塩およびその用途
US4727199A (en) 1985-07-10 1988-02-23 Union Carbide Corporation Heterogeneous alkoxylation using anion-bound metal oxides
US5136106A (en) 1985-07-10 1992-08-04 Union Carbide Chemicals & Plastics Technology Corporation Heterogeneous alkoxylation using anion-bound metal oxides
US5025094A (en) 1985-07-10 1991-06-18 Union Carbide Chemicals And Plastics Technology Corporation Heterogeneous alkoxylation using anion-bound metal oxides
US4873017A (en) 1985-07-10 1989-10-10 Union Carbide Corporation Heterogeneous alkoxylation using anion-bound metal oxides
GB2198725B (en) 1986-11-05 1991-01-16 Alter Sa Use of a series of quaternary ammonium salts as phase-transfer catalysts
US4754089A (en) * 1986-12-05 1988-06-28 Sepracor Inc. Phase transfer catalysis
JPH01193236A (ja) * 1988-01-29 1989-08-03 Mitsubishi Metal Corp 含フッ素アルコールおよびその製造法
IT1218205B (it) 1988-04-08 1990-04-12 Ausimont Spa Impiego di derivati dei perfluoropolieteri in forma di microemulsione acquosa per la protezione dei materiali lapidei dagli agenti atmosferici
DE3814781A1 (de) 1988-04-30 1989-11-09 Basf Ag Verfahren zur herstellung von 2-hydroxy-4-(2'-hydroxyethoxy)-benzophenonen
JPH02188545A (ja) 1989-01-13 1990-07-24 Nippon Oil & Fats Co Ltd ポリフルオロアルキルポリオキシアルキレン（メタ）アリルエーテル
JPH07165832A (ja) 1993-12-15 1995-06-27 Tokuyama Corp 含フッ素アルキルポリエーテル系モノマーおよびその製法
JPH07233111A (ja) * 1994-02-22 1995-09-05 Kao Corp ポリエーテル化合物の製造法
US5608116A (en) * 1994-06-21 1997-03-04 E. I. Du Pont De Nemours And Company Process for the alkoxylation of fluorinated alcohols
US5491261A (en) 1994-07-01 1996-02-13 Ciba-Geigy Corporation Poly-perfluoroalkyl-substituted alcohols and acids, and derivatives thereof
IT1273685B (it) 1994-07-26 1997-07-09 Ausimont Spa Procedimento per la protezione delle superfici lapidee o di rivestimento
JPH08217714A (ja) * 1995-02-09 1996-08-27 Yotsukaichi Gosei Kk ハロゲン化ビスフェノール類のアルキレンオキシド付加物の製造方法
IT1273609B (it) 1995-04-28 1997-07-08 Ausimont Spa Procedimento per la protezione delle superfici lapidee o di rivestimento
US5633420A (en) 1995-09-22 1997-05-27 Amoco Corporation Olefin oligomerization process
JP3433024B2 (ja) 1996-09-05 2003-08-04 信越化学工業株式会社 撥水撥油剤組成物
US6593500B2 (en) 2001-01-19 2003-07-15 Rhodia, Inc. Process for alkoxylation with a boron-containing catalyst
US6737489B2 (en) 2001-05-21 2004-05-18 3M Innovative Properties Company Polymers containing perfluorovinyl ethers and applications for such polymers
JP4211313B2 (ja) 2002-01-29 2009-01-21 Ｄｉｃ株式会社 フッ素系界面活性剤組成物
EP1762566B1 (en) 2004-05-20 2011-03-23 Daikin Industries, Ltd. Branched surfactant having fluoroalkyl group and hydrocarbon group
US8124699B2 (en) 2005-08-08 2012-02-28 Arkema Inc. Polymerization of fluoropolymers using alkyl phosphonate surfactants
DE102005051939A1 (de) 2005-10-29 2007-05-03 Goldschmidt Gmbh Verfahren zur Herstellung von organisch modifizierten Polyorganosiloxanen
DE102006010034A1 (de) 2006-03-04 2007-09-06 Degussa Ag Stickstoff-haltige Phosphoniumsalze

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4533759A (en) * 1982-04-09 1985-08-06 National Distillers And Chemical Corporation Process for the production of fragrance quality ethylene glycol monoaryl ethers
CN1151153A (zh) * 1994-06-21 1997-06-04 纳幕尔杜邦公司 具有增强水溶性的氟代烷基乙氧基化物
CN1419561A (zh) * 2000-03-24 2003-05-21 纳幕尔杜邦公司 氟化润滑剂添加剂

Also Published As

Publication number Publication date
US8053606B2 (en) 2011-11-08
WO2010127221A1 (en) 2010-11-04
CN102413931A (zh) 2012-04-11
US20100280281A1 (en) 2010-11-04
CA2754444A1 (en) 2010-11-04
KR20120017057A (ko) 2012-02-27
JP2012525438A (ja) 2012-10-22
AU2010242860A1 (en) 2011-09-08
EP2424662A1 (en) 2012-03-07

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