CN102405529A - 结构化硅晶片的方法、用于它的处理液及其应用 - Google Patents

结构化硅晶片的方法、用于它的处理液及其应用 Download PDF

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CN102405529A
CN102405529A CN2010800104778A CN201080010477A CN102405529A CN 102405529 A CN102405529 A CN 102405529A CN 2010800104778 A CN2010800104778 A CN 2010800104778A CN 201080010477 A CN201080010477 A CN 201080010477A CN 102405529 A CN102405529 A CN 102405529A
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treatment fluid
silicon wafer
additive
silicon wafers
treatment liquid
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I·马赫尔
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Gebrueder Schmid GmbH and Co
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0236Special surface textures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0236Special surface textures
    • H01L31/02363Special surface textures of the semiconductor body itself, e.g. textured active layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1804Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic Table
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Computer Hardware Design (AREA)
  • Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Photovoltaic Devices (AREA)
  • Weting (AREA)
  • Cleaning Or Drying Semiconductors (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

对在太阳能电池生产中的硅晶片处理的方法中,为了将其结构化的目的,将处理液施加于硅晶片的表面。所述处理液包含含量为0.5%-3%重量百分比的乙基正己醇或环己醇作为添加剂。

Description

结构化硅晶片的方法、用于它的处理液及其应用
应用领域和现有技术
本发明涉及根据权利要求1前序部分的对太阳能电池生产中的硅晶片的处理方法以及适用于该目的的处理液。另外,本发明涉及本发明用于实施所述方法的处理液的应用。
例如,DE 102007026081 A1公开了在太阳能电池生产中硅晶片的结构化。为此,处理液被施加于硅晶片表面上,从而在硅晶片表面形成角锥形突起。这些促进光耦合进入硅晶片及随后进入太阳能电池并伴随改进它们的能量输出。所述的处理液可包含异丙醇作为添加的蚀刻抑制剂。
目的及其效果
本发明的目标是提供如上述的方法和适用于该目的的处理液,借此可消除现有技术遇到的问题并且,特别是,可实现更快和更好的处理,即结构化。
该目标是通过具有权利要求1所限定特征的方法,具有权利要求5所限定特征的处理液,以及具有权利要求8所限定特征的应用来实现的。本发明有利以及优选的实施方式是其他权利要求的主题,并且在下文中对其进行更详细的说明。权利要求的措辞明确提及说明书的内容。
所述的处理液,其有利的是碱性的处理液,包含添加剂。所述添加剂可以是添加的蚀刻抑制剂,并且根据本发明来说是乙基正己醇或环己醇。这两种添加剂可有利地相互择一使用,但是在有些情况下它们可被同时使用。在处理液中这些具体的添加剂的益处是基于这样的事实:在本发明的另一个实施方式中,由于它们更高的沸点使得在温度超过其他可能的情况下实施所述方法成为可能。
由于乙基正己醇的沸点是182℃以及环己醇的沸点是161℃这一事实,在实施结构化时,混合了它们的处理液明显可以在更高的温度下使用。由于以往的添加剂异丙醇的低沸点为82℃,这要求要么持续的进行补充异丙醇,以免得到不满意的结构化结构,要么必须将所述温度保持在80℃或者更低,这种情况下为了实施处理,即结构化处理,所涉及的程序花费长得多的时间,其也可被认为非常有害。使用本发明的添加剂,因此可能在80℃或者更高的温度下实施结构化,例如在大约90℃。这样处理时间可为10至15分钟,且优选地约11分钟。接着硅晶片可以从包含处理液的浴中移走并随后清洗和干燥并进行接下来的处理。
在本发明的另一个实施方式中,硅晶片可以在处理液中被搅动,这同样地改善或加速结构化。这种情况下也可以提供硅晶片和处理液之间发生相对运动,也就是说,为了使得处理液保持运动或者显示出内部液体流。
本发明的目标还是通过使用本发明的所述方法实现的,特别是对在太阳能电池生产中的硅晶片实施处理。
本发明的处理液除了乙基正己醇和环己醇形式的添加剂之外,还包含水作为另外的组份。添加剂的量可以为0.3%-4%,以重量计,特别优选地为0.5%-3%,以重量计。
在本发明的另一实施方式中,处理液可以进一步包含KOH。其含量可以为1.5%-5%,以体积计,优选含量为2%-3%,以体积计。
本发明的另一个独立方面是本发明的用以实施方法的处理液的应用,更特别是应用于实施上面所述的方法。
权利要求中公开了这些和其他特征,其中各个特征可以单独地实现,或者在本发明的任一实施方式中或在其它领域中以次级结合(subcombinations)的方式组合起来,并且可固有地形成有益的和可专利的实施方式,这些实施方式在此要求保护。
至于本发明的执行,同时参考DE 102007026081 A1,其相关的主题内容通过引用包含在本说明书中。在所述的引用中,图1和图2示出了可如何实施该方法,以及因此利用此处示出的所述处理参数和数量可同样好地实施所述方法。

Claims (8)

1.一种对用于太阳能电池生产的硅晶片处理的方法,其中:
为了将其结构化的目的,在硅晶片的表面施加处理液,所述处理液包含添加剂,其特征在于,所述处理液中包含乙基正己醇或环己醇作为添加剂。
2.如权利要求1所述的方法,其特征在于,所述的方法在比太阳能电池生产中用于硅晶片的结构化的传统方法更高的温度下实施,所述的更高的温度的范围为80℃-95℃,更特别为约90℃。
3.如权利要求1或2所述的方法,其特征在于,所述的处理液施加于硅晶片的时间为8-20分钟,更特别所述时间范围为10-13分钟。
4.如以上权利要求任一项所述的方法,其特征在于,所述硅晶片在所述处理液中被搅动,即在其中相对运动。
5.一种用于实施以上权利要求任一项所述方法的处理液,其特征在于,其除了水外,还包含有乙基正己醇和环己醇作为添加剂。
6.如权利要求5所述的处理液,其特征在于,所述添加剂的含量的重量百分比为0.3%-4%,优选重量百分比为0.5%-3%。
7.如权利要求5或6所述的处理液,其特征在于,其进一步包括KOH,所述的KOH的含量的体积百分比优选地为1.5%-5%,且其更特别地体积百分比为2%-3%。
8.用于实施如权利要求1-4任一项所述方法的如权利要求5-7任一项定义的处理液的应用。
CN2010800104778A 2009-03-03 2010-03-03 结构化硅晶片的方法、用于它的处理液及其应用 Pending CN102405529A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102009012827A DE102009012827A1 (de) 2009-03-03 2009-03-03 Verfahren zur Texturierung von Siliziumwafern für Solarzellen und Behandlungsflüssigkeit dafür
DE102009012827.1 2009-03-03
PCT/EP2010/052677 WO2010100185A1 (de) 2009-03-03 2010-03-03 Verfahren zur texturierung von siliziumwafern, behandlungsflüssigkeit dafür und verwendung

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US (1) US8383523B2 (zh)
EP (1) EP2404325B1 (zh)
JP (1) JP5667092B2 (zh)
KR (1) KR101643307B1 (zh)
CN (1) CN102405529A (zh)
AU (1) AU2010220289B2 (zh)
CA (1) CA2754380A1 (zh)
DE (1) DE102009012827A1 (zh)
ES (1) ES2528632T3 (zh)
IL (1) IL214936A0 (zh)
MX (1) MX2011009243A (zh)
MY (1) MY157459A (zh)
SG (1) SG174226A1 (zh)
WO (1) WO2010100185A1 (zh)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009012827A1 (de) * 2009-03-03 2010-10-07 Gebr. Schmid Gmbh & Co. Verfahren zur Texturierung von Siliziumwafern für Solarzellen und Behandlungsflüssigkeit dafür
CN102544206B (zh) * 2011-12-26 2014-02-26 霞浦吉阳新能源有限公司 一种用于晶体硅制绒的混醇工艺方法
CN102634851B (zh) * 2012-03-26 2016-03-02 北京吉阳技术股份有限公司 一种用于太阳电池制造的制绒方法
CN106119977B (zh) * 2016-08-29 2018-10-16 常州时创能源科技有限公司 单晶硅片制绒添加剂及应用

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19811878C2 (de) 1998-03-18 2002-09-19 Siemens Solar Gmbh Verfahren und Ätzlösung zum naßchemischen pyramidalen Texturätzen von Siliziumoberflächen
WO2001099124A1 (fr) * 2000-06-21 2001-12-27 Dai Nippon Printing Co., Ltd. Stratifie et son utilisation
DE10241300A1 (de) * 2002-09-04 2004-03-18 Merck Patent Gmbh Ätzpasten für Siliziumoberflächen und -schichten
JP3740138B2 (ja) * 2003-06-25 2006-02-01 直江津電子工業株式会社 テクスチャー形成用エッチング液
JP4326545B2 (ja) * 2006-02-23 2009-09-09 三洋電機株式会社 凹凸基板の製造方法及び光起電力素子の製造方法
DE102006051952A1 (de) * 2006-11-01 2008-05-08 Merck Patent Gmbh Partikelhaltige Ätzpasten für Siliziumoberflächen und -schichten
DE102007026081A1 (de) 2007-05-25 2008-11-27 Gebr. Schmid Gmbh & Co. Verfahren zur Behandlung von Siliziumwafern, Behandlungsflüssigkeit und Siliziumwafer
TWI393184B (zh) * 2008-09-22 2013-04-11 Taiwan Semiconductor Mfg 半導體裝置之製造方法
JP2010074102A (ja) * 2008-09-22 2010-04-02 Mitsubishi Electric Corp シリコン基板のエッチング方法、シリコン基板のエッチング液、シリコン基板のエッチング装置
JP2010093194A (ja) * 2008-10-10 2010-04-22 Sharp Corp 太陽電池の製造方法
DE102009012827A1 (de) * 2009-03-03 2010-10-07 Gebr. Schmid Gmbh & Co. Verfahren zur Texturierung von Siliziumwafern für Solarzellen und Behandlungsflüssigkeit dafür
US7910393B2 (en) * 2009-06-17 2011-03-22 Innovalight, Inc. Methods for forming a dual-doped emitter on a silicon substrate with a sub-critical shear thinning nanoparticle fluid
SG170691A1 (en) * 2009-10-14 2011-05-30 Rohm & Haas Elect Mat Method of cleaning and micro-etching semiconductor wafers
EP2337089A3 (en) * 2009-12-17 2013-12-11 Rohm and Haas Electronic Materials LLC Improved method of texturing semiconductor substrates

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
KATRIN BIRMANN,ETC: "FAST ALKALINE ETCHING OF MONOCRYSTALLINE WAFERS IN KOH/CHX", 《23RD EUROPEAN PHOTOVOLTAIC SOLAR ENERGY CONFERENCE-CD-ROM EDITION》 *

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JP2012519389A (ja) 2012-08-23
IL214936A0 (en) 2011-11-30
SG174226A1 (en) 2011-10-28
AU2010220289B2 (en) 2015-06-18
MY157459A (en) 2016-06-15
US20120034725A1 (en) 2012-02-09
DE102009012827A1 (de) 2010-10-07
KR20110123756A (ko) 2011-11-15
EP2404325B1 (de) 2014-12-03
WO2010100185A1 (de) 2010-09-10
KR101643307B1 (ko) 2016-07-27
US8383523B2 (en) 2013-02-26
CA2754380A1 (en) 2010-09-10
AU2010220289A1 (en) 2011-09-22
EP2404325A1 (de) 2012-01-11
ES2528632T3 (es) 2015-02-11
JP5667092B2 (ja) 2015-02-12
MX2011009243A (es) 2011-10-24

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Application publication date: 20120404