CN102311638B - 一种耐水解耐醇解玻纤增强ppa材料及其制备方法 - Google Patents
一种耐水解耐醇解玻纤增强ppa材料及其制备方法 Download PDFInfo
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- CN102311638B CN102311638B CN2010105985872A CN201010598587A CN102311638B CN 102311638 B CN102311638 B CN 102311638B CN 2010105985872 A CN2010105985872 A CN 2010105985872A CN 201010598587 A CN201010598587 A CN 201010598587A CN 102311638 B CN102311638 B CN 102311638B
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- alcoholysis
- hydrolysis
- resistance
- ppa
- glass
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- 239000000463 material Substances 0.000 title claims abstract description 94
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- DLNKOYKMWOXYQA-UHFFFAOYSA-N dl-pseudophenylpropanolamine Natural products CC(N)C(O)C1=CC=CC=C1 DLNKOYKMWOXYQA-UHFFFAOYSA-N 0.000 title abstract 9
- DLNKOYKMWOXYQA-APPZFPTMSA-N phenylpropanolamine Chemical compound C[C@@H](N)[C@H](O)C1=CC=CC=C1 DLNKOYKMWOXYQA-APPZFPTMSA-N 0.000 title abstract 9
- 229960000395 phenylpropanolamine Drugs 0.000 title abstract 9
- 239000003365 glass fiber Substances 0.000 title abstract 7
- 229920006375 polyphtalamide Polymers 0.000 claims abstract description 50
- 239000004954 Polyphthalamide Substances 0.000 claims abstract description 42
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 230000007062 hydrolysis Effects 0.000 claims description 54
- 238000006460 hydrolysis reaction Methods 0.000 claims description 54
- 238000006136 alcoholysis reaction Methods 0.000 claims description 52
- 239000011521 glass Substances 0.000 claims description 51
- 230000001681 protective effect Effects 0.000 claims description 39
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 23
- 239000001993 wax Substances 0.000 claims description 22
- 239000003381 stabilizer Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 10
- -1 fatty acid salt Chemical class 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 5
- 150000001448 anilines Chemical class 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000011068 loading method Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000003223 protective agent Substances 0.000 abstract 2
- 239000004595 color masterbatch Substances 0.000 abstract 1
- 239000012760 heat stabilizer Substances 0.000 abstract 1
- 239000002667 nucleating agent Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 11
- 238000002156 mixing Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 238000005453 pelletization Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 101100501135 Escherichia coli O157:H7 ehaG gene Proteins 0.000 description 4
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 229920006012 semi-aromatic polyamide Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
-
- B29C47/92—
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
组成 | 实施例1 | 实施例2 | 实施例3 | 对比例1 | 对比例2 | 对比例3 |
PPA(%) | 76.8 | 61.8 | 46.8 | 62 | 62.1 | 61.8 |
玻璃纤维HP3610(%) | 20 | 35 | 50 | 35 | 35 | / |
玻璃纤维HP3540(%) | / | / | / | / | / | 35 |
热稳定剂H161(%) | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 |
耐醇解保护剂(%) | 0.3 | 0.3 | 0.3 | 0.3 | / | 0.3 |
耐水解保护剂(%) | 0.2 | 0.2 | 0.2 | / | 0.2 | 0.2 |
OP蜡(%) | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 |
成核剂CAV102(%) | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
黑色母N54(%) | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
拉伸强度(MPa) | 135 | 220 | 260 | 218 | 225 | 215 |
弯曲强度(MPa) | 205 | 330 | 380 | 325 | 332 | 318 |
弯曲模量(MPa) | 6200 | 9500 | 15500 | 9250 | 9600 | 9550 |
Claims (8)
Priority Applications (1)
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CN2010105985872A CN102311638B (zh) | 2010-12-21 | 2010-12-21 | 一种耐水解耐醇解玻纤增强ppa材料及其制备方法 |
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CN2010105985872A CN102311638B (zh) | 2010-12-21 | 2010-12-21 | 一种耐水解耐醇解玻纤增强ppa材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN102311638A CN102311638A (zh) | 2012-01-11 |
CN102311638B true CN102311638B (zh) | 2012-12-19 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103436010A (zh) * | 2013-06-03 | 2013-12-11 | 安徽科聚新材料有限公司 | 一种高强度耐腐蚀pa66材料及其制备方法和应用 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103044903A (zh) * | 2012-12-26 | 2013-04-17 | 安徽科聚新材料有限公司 | 一种耐水解尼龙复合材料及其制备方法 |
CN103450671B (zh) * | 2013-08-28 | 2016-08-31 | 宁波伊德尔新材料有限公司 | 热稳定耐水醇解尼龙母粒及其制备方法 |
CN105062046A (zh) * | 2015-09-01 | 2015-11-18 | 惠州市华聚塑化科技有限公司 | 一种ppa复合材料 |
CN106675009A (zh) * | 2015-11-05 | 2017-05-17 | 株洲时代新材料科技股份有限公司 | 一种轨道扣件用高强高韧尼龙复合材料及其制备方法 |
CN105273389B (zh) * | 2015-11-30 | 2017-08-22 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | 一种耐水醇解ppe/玻纤母粒的加工方法 |
CN109071941A (zh) * | 2016-05-04 | 2018-12-21 | Ems专利股份公司 | 聚酰胺模塑组合物和由此制成的模塑品 |
CN107236293A (zh) * | 2017-04-26 | 2017-10-10 | 木林森股份有限公司 | 一种改性ppa复合材料及其制备方法和应用 |
CN108587151A (zh) * | 2017-12-27 | 2018-09-28 | 浙江普利特新材料有限公司 | 一种应用在汽车冷却系统耐醇解尼龙材料及其制备方法 |
CN110066509A (zh) * | 2019-04-13 | 2019-07-30 | 苏州旭光聚合物有限公司 | 一种耐水解、醇解玻纤增强改性尼龙 |
CN111117231A (zh) * | 2019-12-31 | 2020-05-08 | 会通新材料(上海)有限公司 | 一种不含卤素的耐热空气长期老化的聚酰胺56组合物及其应用 |
CN114181522B (zh) * | 2021-11-03 | 2024-08-09 | 横店集团得邦工程塑料有限公司 | 一种耐醇解热稳定型ppa复合材料及其制备方法 |
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EP1424361A1 (de) * | 2002-11-26 | 2004-06-02 | Bayer Aktiengesellschaft | Verwendung von Polykondensatmischungen zur Herstellung von Formteilen mit verbesserter Hydrolysebeständigkeit |
WO2008022910A1 (de) * | 2006-08-23 | 2008-02-28 | Basf Se | Polyamidformmassen mit verbesserter wärmealterungs- und hydrolysebeständigkeit |
KR20090062763A (ko) * | 2007-12-13 | 2009-06-17 | 현대자동차주식회사 | 폴리아미드 수지 조성물 |
CN101508842A (zh) * | 2008-12-23 | 2009-08-19 | 深圳市科聚新材料有限公司 | 一种聚酰胺/聚酯合金及其制备方法 |
CN101613527A (zh) * | 2009-07-29 | 2009-12-30 | 东莞市意普万工程塑料有限公司 | 一种耐醇解尼龙复合材料及其制备方法 |
CN101918482A (zh) * | 2007-03-19 | 2010-12-15 | 纳幕尔杜邦公司 | 聚酰胺树脂组合物 |
Family Cites Families (1)
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KR100844728B1 (ko) * | 2006-12-12 | 2008-07-07 | 현대자동차주식회사 | 자동차 라디에이터용 폴리아미드 수지 조성물 |
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- 2010-12-21 CN CN2010105985872A patent/CN102311638B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1424361A1 (de) * | 2002-11-26 | 2004-06-02 | Bayer Aktiengesellschaft | Verwendung von Polykondensatmischungen zur Herstellung von Formteilen mit verbesserter Hydrolysebeständigkeit |
WO2008022910A1 (de) * | 2006-08-23 | 2008-02-28 | Basf Se | Polyamidformmassen mit verbesserter wärmealterungs- und hydrolysebeständigkeit |
CN101918482A (zh) * | 2007-03-19 | 2010-12-15 | 纳幕尔杜邦公司 | 聚酰胺树脂组合物 |
KR20090062763A (ko) * | 2007-12-13 | 2009-06-17 | 현대자동차주식회사 | 폴리아미드 수지 조성물 |
CN101508842A (zh) * | 2008-12-23 | 2009-08-19 | 深圳市科聚新材料有限公司 | 一种聚酰胺/聚酯合金及其制备方法 |
CN101613527A (zh) * | 2009-07-29 | 2009-12-30 | 东莞市意普万工程塑料有限公司 | 一种耐醇解尼龙复合材料及其制备方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103436010A (zh) * | 2013-06-03 | 2013-12-11 | 安徽科聚新材料有限公司 | 一种高强度耐腐蚀pa66材料及其制备方法和应用 |
CN103436010B (zh) * | 2013-06-03 | 2015-12-02 | 安徽科聚新材料有限公司 | 一种高强度耐腐蚀pa66材料及其制备方法和应用 |
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Denomination of invention: Hydrolysis-resistance alcoholysis-resistance glass fiber reinforced PPA (phenyl-propanolamine) material and preparation method thereof Effective date of registration: 20150817 Granted publication date: 20121219 Pledgee: China Everbright Bank Shenzhen branch Pledgor: Xu Dong Registration number: 2015990000680 |
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Denomination of invention: Hydrolysis-resistance alcoholysis-resistance glass fiber reinforced PPA (phenyl-propanolamine) material and preparation method thereof Effective date of registration: 20170106 Granted publication date: 20121219 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Anhui science and Technology Co., Ltd.|Shenzhen branch poly new materials Co., Ltd.|Xu Dong Registration number: 2016990001133 |
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