CN102307659A - 氢化催化剂及其制备和用途 - Google Patents

氢化催化剂及其制备和用途 Download PDF

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Publication number
CN102307659A
CN102307659A CN2010800069346A CN201080006934A CN102307659A CN 102307659 A CN102307659 A CN 102307659A CN 2010800069346 A CN2010800069346 A CN 2010800069346A CN 201080006934 A CN201080006934 A CN 201080006934A CN 102307659 A CN102307659 A CN 102307659A
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catalyst
elements
weight
monolithic
earth metals
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Chinese (zh)
Inventor
C·W·维格博斯
J·施泰纳
M·恩斯特
B·W·霍费尔
E·施瓦布
J-P·梅尔德
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BASF SE
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1817—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with copper, silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0234—Impregnation and coating simultaneously
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2010800069346A 2009-02-09 2010-02-04 氢化催化剂及其制备和用途 Pending CN102307659A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09152400.9 2009-02-09
EP09152400 2009-02-09
PCT/EP2010/051355 WO2010089346A2 (de) 2009-02-09 2010-02-04 Verfahren zur verbesserung der katalytischen aktivität von monolithischen katalysatoren

Publications (1)

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CN102307659A true CN102307659A (zh) 2012-01-04

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US (1) US20110313188A1 (enExample)
EP (1) EP2393592A2 (enExample)
JP (1) JP2012517333A (enExample)
CN (1) CN102307659A (enExample)
WO (1) WO2010089346A2 (enExample)

Cited By (7)

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WO2014086039A1 (zh) * 2012-12-07 2014-06-12 烟台万华聚氨酯股份有限公司 3-氨甲基-3,5,5-三甲基环己胺的制备方法
CN104001516A (zh) * 2014-05-29 2014-08-27 中国天辰工程有限公司 一种己二腈加氢合成己二胺的催化剂的制备方法
CN104326927A (zh) * 2014-10-28 2015-02-04 齐鲁天和惠世制药有限公司 一种1-[2-氨基-1-(4-甲氧基苯基)乙基]环己醇硫酸盐的制备方法
CN108276291A (zh) * 2018-03-04 2018-07-13 兰州大学 一种用于苯甲腈直接常压加氢催化剂的制备方法
CN108484410A (zh) * 2018-03-04 2018-09-04 兰州大学 一种苯甲腈直接常压加氢制备苯甲胺的方法
CN110152642A (zh) * 2019-05-24 2019-08-23 常州大学 一种用于制备间苯二甲胺的催化剂及应用
CN111644196A (zh) * 2020-06-17 2020-09-11 山东达民化工股份有限公司 一种采用复合催化体系的甲基戊二胺高选择性制备方法

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TWI490034B (zh) * 2009-11-17 2015-07-01 Basf Se 製備具有增強氫化活性之經承載氫化觸媒之方法
US8455693B2 (en) 2010-05-21 2013-06-04 Basf Se Process for preparing 2-(2-tert-butylaminoethoxy)ethanol (tert-butylaminodiglycol, TBADG)
US8637668B2 (en) 2010-06-15 2014-01-28 Basf Se Process for preparing a cyclic tertiary methylamine
CN101879448B (zh) * 2010-06-24 2012-05-23 天津大学 用于草酸酯加氢制乙二醇的规整结构催化剂及其制备方法
US8933223B2 (en) 2010-10-14 2015-01-13 Basf Se Process for preparing a cyclic tertiary amine
EP2478958A1 (de) 2011-01-19 2012-07-25 Euro Support Catalyst Group B.V. Katalytisch aktives Material für die Hydrierungsbehandlung von Kohlenwasserstoffen
US8884015B2 (en) 2012-06-01 2014-11-11 Basf Se Process for the preparation of a mono-N-alkypiperazine
JP6242878B2 (ja) 2012-06-01 2017-12-06 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ モノ−ｎ−アルキル−ピペラジンの製造方法
US8981093B2 (en) 2012-06-06 2015-03-17 Basf Se Process for preparing piperazine
US20150001156A1 (en) * 2013-06-26 2015-01-01 Corning Incorporated Methods and apparatus for treatment of liquids containing contaminants using zero valent nanoparticles
US9461324B2 (en) * 2014-04-02 2016-10-04 H&Power, Inc. Autothermal reforming catalyst for monolithic fuel cell
BR112017003878A2 (pt) * 2014-08-28 2018-01-23 Basf Se processo para produzir aminas primárias.
JP2019530570A (ja) * 2016-09-23 2019-10-24 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ドープされた構造化触媒成形体を含む触媒固定床を提供する方法
JP7421177B2 (ja) * 2019-01-30 2024-01-24 国立大学法人大阪大学 水素化触媒およびこれを用いた水素化有機化合物の製造方法
CN114835588B (zh) * 2022-05-06 2023-05-26 万华化学集团股份有限公司 一种双氰乙基脂环胺加氢制备双氨丙基脂环胺的方法
CN116870912A (zh) * 2023-07-07 2023-10-13 山东海科创新研究院有限公司 一种负载型加氢催化剂的制备方法及应用

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WO2014086039A1 (zh) * 2012-12-07 2014-06-12 烟台万华聚氨酯股份有限公司 3-氨甲基-3,5,5-三甲基环己胺的制备方法
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CN104001516A (zh) * 2014-05-29 2014-08-27 中国天辰工程有限公司 一种己二腈加氢合成己二胺的催化剂的制备方法
CN104326927A (zh) * 2014-10-28 2015-02-04 齐鲁天和惠世制药有限公司 一种1-[2-氨基-1-(4-甲氧基苯基)乙基]环己醇硫酸盐的制备方法
CN104326927B (zh) * 2014-10-28 2016-06-15 齐鲁天和惠世制药有限公司 一种1-[2-氨基-1-(4-甲氧基苯基)乙基]环己醇硫酸盐的制备方法
CN108276291A (zh) * 2018-03-04 2018-07-13 兰州大学 一种用于苯甲腈直接常压加氢催化剂的制备方法
CN108484410A (zh) * 2018-03-04 2018-09-04 兰州大学 一种苯甲腈直接常压加氢制备苯甲胺的方法
CN108484410B (zh) * 2018-03-04 2020-12-29 兰州大学 一种苯甲腈直接常压加氢制备苯甲胺的方法
CN110152642A (zh) * 2019-05-24 2019-08-23 常州大学 一种用于制备间苯二甲胺的催化剂及应用
CN111644196A (zh) * 2020-06-17 2020-09-11 山东达民化工股份有限公司 一种采用复合催化体系的甲基戊二胺高选择性制备方法
CN111644196B (zh) * 2020-06-17 2021-02-09 山东达民化工股份有限公司 一种采用复合催化体系的甲基戊二胺高选择性制备方法

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US20110313188A1 (en) 2011-12-22
WO2010089346A3 (de) 2011-01-20
WO2010089346A2 (de) 2010-08-12
EP2393592A2 (de) 2011-12-14
JP2012517333A (ja) 2012-08-02

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Application publication date: 20120104