CN102046604B - 包括光亚硝化步骤然后贝克曼重排作用步骤的制备内酰胺的方法 - Google Patents

包括光亚硝化步骤然后贝克曼重排作用步骤的制备内酰胺的方法 Download PDF

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Publication number
CN102046604B
CN102046604B CN200980119112.6A CN200980119112A CN102046604B CN 102046604 B CN102046604 B CN 102046604B CN 200980119112 A CN200980119112 A CN 200980119112A CN 102046604 B CN102046604 B CN 102046604B
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China
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photonitrosation
microreactor
reactor
beckmann rearrangement
dechlorination
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CN200980119112.6A
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Chinese (zh)
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CN102046604A (zh
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T·奥贝尔
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Arkema France SA
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Arkema France SA
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02—Preparation of lactams
    • C07D201/10—Preparation of lactams from cycloaliphatic compounds by simultaneous nitrosylation and rearrangement
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
    • C07C249/06—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes by nitrosation of hydrocarbons or substituted hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02—Preparation of lactams
    • C07D201/04—Preparation of lactams from or via oximes by Beckmann rearrangement
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D225/00—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom
    • C07D225/02—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D227/00—Heterocyclic compounds containing rings having one nitrogen atom as the only ring hetero atom, according to more than one of groups C07D203/00 - C07D225/00
    • C07D227/02—Heterocyclic compounds containing rings having one nitrogen atom as the only ring hetero atom, according to more than one of groups C07D203/00 - C07D225/00 with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D227/06—Heterocyclic compounds containing rings having one nitrogen atom as the only ring hetero atom, according to more than one of groups C07D203/00 - C07D225/00 with only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D227/08—Oxygen atoms
    • C07D227/087—One doubly-bound oxygen atom in position 2, e.g. lactams
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
CN200980119112.6A 2008-05-26 2009-05-14 包括光亚硝化步骤然后贝克曼重排作用步骤的制备内酰胺的方法 Active CN102046604B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310505599.XA CN103588706B (zh) 2008-05-26 2009-05-14 包括光亚硝化步骤然后贝克曼重排作用步骤的制备内酰胺的方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR08.53419 2008-05-26
FR0853419A FR2931478B1 (fr) 2008-05-26 2008-05-26 Prodece de preparation de lactames comprenant une etape de photonitrosation suivie d'une etape de transposition de beckmann
PCT/FR2009/050886 WO2009153470A1 (fr) 2008-05-26 2009-05-14 Procede de preparation de lactames comprenant une etape de photonitrosation suivie d'une etape de transposition de beckmann

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CN102046604A CN102046604A (zh) 2011-05-04
CN102046604B true CN102046604B (zh) 2015-02-25

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CN201310505599.XA Active CN103588706B (zh) 2008-05-26 2009-05-14 包括光亚硝化步骤然后贝克曼重排作用步骤的制备内酰胺的方法

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US (2) US20110137027A1 (enExample)
EP (2) EP2291357B1 (enExample)
JP (5) JP6235769B2 (enExample)
CN (2) CN102046604B (enExample)
FR (1) FR2931478B1 (enExample)
PL (2) PL2291357T3 (enExample)
WO (1) WO2009153470A1 (enExample)

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FR2931478B1 (fr) * 2008-05-26 2012-08-03 Arkema France Prodece de preparation de lactames comprenant une etape de photonitrosation suivie d'une etape de transposition de beckmann
JP5359064B2 (ja) * 2008-06-30 2013-12-04 東レ株式会社 シクロアルカノンオキシムの製造方法および光化学反応装置
JP5359063B2 (ja) * 2008-06-30 2013-12-04 東レ株式会社 シクロアルカノンオキシムの製造方法
JP5821623B2 (ja) * 2010-12-28 2015-11-24 東レ株式会社 シクロアルカノンオキシムの製造方法およびラクタムを製造する方法
ES2526796T3 (es) 2012-06-26 2015-01-15 Toray Industries, Inc. Método de producción de oxima de cicloalcanona
US9932296B2 (en) 2012-06-27 2018-04-03 Toray Industries, Inc. Method of producing cycloalkanone oxime
CN107073433B (zh) * 2014-10-09 2020-01-31 东丽株式会社 光化学反应装置、使用该装置的光化学反应方法
EP3277664B1 (en) 2015-04-02 2019-08-07 Anthea Aromatics Private Limited An efficient process for the synthesis of cyclic amides
US10618873B2 (en) 2016-02-01 2020-04-14 Basf Se Method for producing C4-C15 lactams
CN108409646B (zh) * 2018-01-19 2020-05-19 南京红太阳生物化学有限责任公司 一种烟酰胺的合成方法
FR3107612B1 (fr) 2020-02-20 2022-03-04 Arkema France Lampe pour réacteur photochimique à base de diodes électroluminescentes
CN115260073B (zh) * 2022-08-31 2024-09-20 中国天辰工程有限公司 一种无硫酸铵副产重排工艺制备月桂精内酰胺的方法
CN119258936B (zh) * 2023-07-07 2025-11-11 中国石油化工股份有限公司 一种微反应设备脱除原油中有机氯的方法
EP4733296A1 (en) 2024-10-22 2026-04-29 Basf Se Process for the preparation of 2-c3-c4 alkanone oximes

Citations (3)

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US3553091A (en) * 1966-08-17 1971-01-05 Fumio Nishikawa Method of photonitrosation of cycloalkanes
CN1252404A (zh) * 1998-09-21 2000-05-10 埃勒夫阿托化学有限公司 制备ω－十二碳内酰胺的方法
JP2003529578A (ja) * 2000-03-31 2003-10-07 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング 有機オキシムのベックマン転位のための方法

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US3652552A (en) * 1966-12-16 1972-03-28 Stamicarbon Preparation of lactams from cycloalkanes
FR2417501A1 (fr) * 1978-02-17 1979-09-14 Ato Chimie Procede de preparation de lactames par isomerisation d'oximes en milieu sulfurique
BE893651A (fr) * 1982-06-25 1982-12-27 Desaar Rene Nez poreux pour le bullage d'acier
CN1109671C (zh) * 1997-07-02 2003-05-28 埃勒夫阿托化学有限公司 在一种基本无水的介质氯仿中的环十二烷的光亚硝化
JP2000164931A (ja) 1998-11-27 2000-06-16 Sumitomo Electric Ind Ltd 白色光源
JP2001002636A (ja) * 1999-06-15 2001-01-09 Toray Ind Inc ラクタムの製造方法
US6871982B2 (en) * 2003-01-24 2005-03-29 Digital Optics International Corporation High-density illumination system
EP1775875A1 (en) 2004-08-04 2007-04-18 Matsushita Electric Industrial Co., Ltd. Radio communication device, radio communication system, and radio communication method
DE102005003966A1 (de) * 2005-01-27 2006-08-10 Ehrfeld Mikrotechnik Bts Gmbh Vorrichtung zur kontinuierlichen Durchführung photochemischer Prozesse mit geringen optischen Schichtdicken, enger Verweilzeitverteilung und hohen Durchsätzen
FR2887250B1 (fr) * 2005-06-21 2009-10-02 Arkema Sa Procede de synthese du lauryllactame (l12) par rearrangement catalytique en phase gazeuse de la cyclododecanone oxime
JP5110779B2 (ja) * 2005-07-21 2012-12-26 日東電工株式会社 光反応生成物シート類の製造方法及び装置
JP5083205B2 (ja) 2006-03-10 2012-11-28 日亜化学工業株式会社 発光装置
KR20090019871A (ko) * 2006-05-31 2009-02-25 크리 엘이디 라이팅 솔루션즈, 인크. 조명 장치 및 조명 방법
JP5030222B2 (ja) 2006-09-08 2012-09-19 国立大学法人東京工業大学 光触媒系マイクロ反応装置
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FR2931478B1 (fr) * 2008-05-26 2012-08-03 Arkema France Prodece de preparation de lactames comprenant une etape de photonitrosation suivie d'une etape de transposition de beckmann
JP5359063B2 (ja) * 2008-06-30 2013-12-04 東レ株式会社 シクロアルカノンオキシムの製造方法
JP5359064B2 (ja) * 2008-06-30 2013-12-04 東レ株式会社 シクロアルカノンオキシムの製造方法および光化学反応装置

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3553091A (en) * 1966-08-17 1971-01-05 Fumio Nishikawa Method of photonitrosation of cycloalkanes
CN1252404A (zh) * 1998-09-21 2000-05-10 埃勒夫阿托化学有限公司 制备ω－十二碳内酰胺的方法
JP2003529578A (ja) * 2000-03-31 2003-10-07 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング 有機オキシムのベックマン転位のための方法

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Quantum Yield of Photonitrosation of Cyclohexane in Homogeneous System;Hajime Miyama, et al.;《The Journal of Physical Chemistry》;19691231;第73卷(第12期);4345-4347 *

Also Published As

Publication number Publication date
US9499481B2 (en) 2016-11-22
US20110137027A1 (en) 2011-06-09
JP6235769B2 (ja) 2017-11-22
CN103588706A (zh) 2014-02-19
FR2931478A1 (fr) 2009-11-27
JP2019055999A (ja) 2019-04-11
EP2291357B1 (fr) 2016-07-13
JP2015157871A (ja) 2015-09-03
JP6567332B2 (ja) 2019-08-28
US20140246303A1 (en) 2014-09-04
JP2017132797A (ja) 2017-08-03
PL2291357T3 (pl) 2016-12-30
CN102046604A (zh) 2011-05-04
EP2291357A1 (fr) 2011-03-09
JP2011521004A (ja) 2011-07-21
FR2931478B1 (fr) 2012-08-03
PL3101011T3 (pl) 2018-09-28
JP2017081987A (ja) 2017-05-18
CN103588706B (zh) 2016-08-24
WO2009153470A1 (fr) 2009-12-23
EP3101011B1 (fr) 2018-06-20
EP3101011A1 (fr) 2016-12-07

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