CN101933189B - 用于薄膜电池的薄膜电解质 - Google Patents

用于薄膜电池的薄膜电解质 Download PDF

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Publication number
CN101933189B
CN101933189B CN200980103184.1A CN200980103184A CN101933189B CN 101933189 B CN101933189 B CN 101933189B CN 200980103184 A CN200980103184 A CN 200980103184A CN 101933189 B CN101933189 B CN 101933189B
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electrolyte
deposition
chemical composition
lithium
temperature
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CN101933189A (zh
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B·J·纽德克尔
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Saplast Research LLC
Phonex Corp
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Infinite Power Solutions Inc
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/447—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on phosphates, e.g. hydroxyapatite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/122—Ionic conductors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
    • C04B2235/3203—Lithium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C—CHEMISTRY; METALLURGY
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3227—Lanthanum oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
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    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • Ceramic Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Secondary Cells (AREA)
  • Conductive Materials (AREA)
CN200980103184.1A 2008-01-23 2009-01-23 用于薄膜电池的薄膜电解质 Active CN101933189B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US2290408P 2008-01-23 2008-01-23
US61/022,904 2008-01-23
PCT/US2009/031815 WO2009094524A1 (en) 2008-01-23 2009-01-23 Thin film electrolyte for thin film batteries

Publications (2)

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CN101933189A CN101933189A (zh) 2010-12-29
CN101933189B true CN101933189B (zh) 2014-06-25

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Country Link
EP (1) EP2235782B1 (enExample)
JP (1) JP5816434B2 (enExample)
KR (1) KR101608546B1 (enExample)
CN (1) CN101933189B (enExample)
WO (1) WO2009094524A1 (enExample)

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US9356316B2 (en) * 2012-04-18 2016-05-31 Applied Materials, Inc. Pinhole-free solid state electrolytes with high ionic conductivity
JP6165546B2 (ja) * 2013-08-09 2017-07-19 株式会社日立製作所 固体電解質および全固体リチウムイオン二次電池
KR102368632B1 (ko) 2013-10-07 2022-02-28 퀀텀스케이프 배터리, 인코포레이티드 Li 이차 전지용 가넷 물질
FR3023302B1 (fr) * 2014-07-01 2016-07-15 I-Ten Batterie entierement solide comprenant un electrolyte solide a base de phosphate lithie, stable au contact de l'anode
JP5873533B2 (ja) 2014-07-16 2016-03-01 三井金属鉱業株式会社 リチウムイオン電池用硫化物系固体電解質
US12294050B2 (en) 2014-12-02 2025-05-06 Polyplus Battery Company Lithium ion conducting sulfide glass fabrication
US12454478B2 (en) 2022-09-09 2025-10-28 Polyplus Battery Company Ionically conductive glass preform
US10164289B2 (en) * 2014-12-02 2018-12-25 Polyplus Battery Company Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods
US20190173128A1 (en) 2014-12-02 2019-06-06 Polyplus Battery Company Making and inspecting a web of vitreous lithium sulfide separator sheet and lithium electrode assemblies and battery cells
WO2016125230A1 (ja) 2015-02-02 2016-08-11 富士通株式会社 固体電解質、及び全固体電池
KR20240059640A (ko) 2015-04-16 2024-05-07 퀀텀스케이프 배터리, 인코포레이티드 고체 전해질 제조를 위한 리튬 함유 가넷 세터 플레이트
WO2017015511A1 (en) 2015-07-21 2017-01-26 Quantumscape Corporation Processes and materials for casting and sintering green garnet thin films
FR3040241A1 (fr) * 2016-01-27 2017-02-24 Commissariat Energie Atomique Batterie electrochimique au lithium comprenant un electrolyte solide specifique
US12482827B2 (en) 2021-04-13 2025-11-25 Polyplus Battery Company Binary phosphorus nitride protective solid electrolyte intermediary structures for electrode assemblies
JP6667141B2 (ja) * 2016-07-04 2020-03-18 パナソニックIpマネジメント株式会社 酸窒化物を含む固体電解質、及びそれを用いた二次電池
CN107579275B (zh) 2016-07-04 2022-02-11 松下知识产权经营株式会社 含有氧氮化物的固体电解质和使用它的二次电池
EP3494613A4 (en) 2016-08-05 2020-03-11 QuantumScape Corporation TRANSPARENT AND TRANSPARENT SEPARATORS
EP4369453A3 (en) 2017-06-23 2024-10-02 QuantumScape Battery, Inc. Lithium-stuffed garnet electrolytes with secondary phase inclusions
CN107863533A (zh) * 2017-09-30 2018-03-30 中国科学院青岛生物能源与过程研究所 一种玻璃态的氧化物电解质材料
FR3080957B1 (fr) 2018-05-07 2020-07-10 I-Ten Electrodes mesoporeuses pour dispositifs electrochimiques en couches minces
FR3091036B1 (fr) 2018-12-24 2024-04-19 I Ten Procede de fabrication de batteries, et batterie obtenue par ce procede
US12021238B2 (en) 2020-08-04 2024-06-25 Polyplus Battery Company Glassy embedded solid-state electrode assemblies, solid-state batteries and methods of making electrode assemblies and solid-state batteries
US12021187B2 (en) 2020-08-04 2024-06-25 Polyplus Battery Company Surface treatment of a sulfide glass solid electrolyte layer
US12034116B2 (en) 2020-08-04 2024-07-09 Polyplus Battery Company Glass solid electrolyte layer, methods of making glass solid electrolyte layer and electrodes and battery cells thereof
CN113151790B (zh) * 2021-02-05 2022-06-07 电子科技大学 离子/电子共导体薄膜及其制备方法、固态电池及电动车
CN121204607B (zh) * 2025-11-26 2026-03-20 河北大学 一种LiPON固态电解质薄膜及其制备方法

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CN1795577A (zh) * 2003-06-27 2006-06-28 松下电器产业株式会社 固体电解质和使用该固体电解质的全固态电池
CN1828987A (zh) * 2006-01-23 2006-09-06 浙江大学 全固态微型锂电池电解质的制备方法

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Publication number Publication date
WO2009094524A1 (en) 2009-07-30
EP2235782B1 (en) 2018-06-13
JP2011511399A (ja) 2011-04-07
EP2235782A4 (en) 2014-11-05
CN101933189A (zh) 2010-12-29
KR101608546B1 (ko) 2016-04-01
KR20100120165A (ko) 2010-11-12
JP5816434B2 (ja) 2015-11-18
EP2235782A1 (en) 2010-10-06

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