CN101657394A - 无铅压电陶瓷组合物,其制备方法以及含该材料的压电构件 - Google Patents
无铅压电陶瓷组合物,其制备方法以及含该材料的压电构件 Download PDFInfo
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- CN101657394A CN101657394A CN200880011297.4A CN200880011297A CN101657394A CN 101657394 A CN101657394 A CN 101657394A CN 200880011297 A CN200880011297 A CN 200880011297A CN 101657394 A CN101657394 A CN 101657394A
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- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 239000000919 ceramic Substances 0.000 title claims abstract description 31
- 239000000463 material Substances 0.000 title claims description 16
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000013078 crystal Substances 0.000 claims abstract description 41
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 150000001768 cations Chemical class 0.000 claims abstract description 7
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 6
- 229910052691 Erbium Inorganic materials 0.000 claims abstract description 6
- 229910052693 Europium Inorganic materials 0.000 claims abstract description 6
- 229910052688 Gadolinium Inorganic materials 0.000 claims abstract description 6
- 229910052779 Neodymium Inorganic materials 0.000 claims abstract description 6
- 229910052777 Praseodymium Inorganic materials 0.000 claims abstract description 6
- 229910052772 Samarium Inorganic materials 0.000 claims abstract description 6
- 229910052769 Ytterbium Inorganic materials 0.000 claims abstract description 6
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 6
- 229910052738 indium Inorganic materials 0.000 claims abstract description 6
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 6
- 229910052706 scandium Inorganic materials 0.000 claims abstract description 6
- 229910052716 thallium Inorganic materials 0.000 claims abstract description 6
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 6
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 19
- 238000002360 preparation method Methods 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000001354 calcination Methods 0.000 claims description 9
- 239000004615 ingredient Substances 0.000 claims description 9
- -1 oxyhydroxide Chemical compound 0.000 claims description 9
- 150000002500 ions Chemical class 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 6
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 3
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- PMVSDNDAUGGCCE-TYYBGVCCSA-L Ferrous fumarate Chemical compound [Fe+2].[O-]C(=O)\C=C\C([O-])=O PMVSDNDAUGGCCE-TYYBGVCCSA-L 0.000 abstract 1
- 150000002506 iron compounds Chemical class 0.000 abstract 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 58
- 238000005245 sintering Methods 0.000 description 18
- 229910052742 iron Inorganic materials 0.000 description 13
- 239000010955 niobium Substances 0.000 description 9
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 241000894007 species Species 0.000 description 5
- 150000001340 alkali metals Chemical class 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910052728 basic metal Inorganic materials 0.000 description 3
- 150000003818 basic metals Chemical class 0.000 description 3
- 238000010316 high energy milling Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- LDHMAVIPBRSVRG-UHFFFAOYSA-O 1-methylnicotinamide Chemical compound C[N+]1=CC=CC(C(N)=O)=C1 LDHMAVIPBRSVRG-UHFFFAOYSA-O 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 229910013641 LiNbO 3 Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- UTBYQPSPFXHANA-UHFFFAOYSA-N [K].[Na].[Li] Chemical compound [K].[Na].[Li] UTBYQPSPFXHANA-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical group O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- PSVBHJWAIYBPRO-UHFFFAOYSA-N lithium;niobium(5+);oxygen(2-) Chemical compound [Li+].[O-2].[O-2].[O-2].[Nb+5] PSVBHJWAIYBPRO-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002822 niobium compounds Chemical class 0.000 description 1
- 229910000484 niobium oxide Inorganic materials 0.000 description 1
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 1
- YPJKMVATUPSWOH-UHFFFAOYSA-N nitrooxidanyl Chemical compound [O][N+]([O-])=O YPJKMVATUPSWOH-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical group [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910001460 tantalum ion Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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- C04B35/495—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on vanadium, niobium, tantalum, molybdenum or tungsten oxides or solid solutions thereof with other oxides, e.g. vanadates, niobates, tantalates, molybdates or tungstates
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DE102007016854.5 | 2007-04-10 | ||
DE102007016854.5A DE102007016854B4 (de) | 2007-04-10 | 2007-04-10 | Piezoelektrische, bleifreie keramische Zusammensetzung, Verfahren zu deren Herstellung sowie ein dieses Material unfassendes piezoelektrisches Bauelement |
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CN (1) | CN101657394A (de) |
DE (1) | DE102007016854B4 (de) |
WO (1) | WO2008122458A1 (de) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102173799A (zh) * | 2011-02-28 | 2011-09-07 | 上海海事大学 | 一种钽酸锂掺杂铌酸钾钠陶瓷的合成方法及设备 |
CN112510171A (zh) * | 2019-09-13 | 2021-03-16 | 株式会社东芝 | 复合氧化物、活性物质复合材料、电极、电池、电池包及车辆 |
CN115028450A (zh) * | 2022-06-09 | 2022-09-09 | 清华大学 | 一种铌酸钠基陶瓷材料及其制备方法 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007046450A1 (de) * | 2007-09-28 | 2009-04-02 | Siemens Ag | Bleifreier piezokeramischer Werkstoff des Kalium-Natrium-Niobat-Systems mit Eisen-Lanthan-Dotierung, Verfahren zum Herstellen eines Bauteils mit dem piezokeramischen Werkstoff und Verwendung des Bauteils |
DE102008008902B3 (de) * | 2008-02-13 | 2009-06-04 | Siemens Aktiengesellschaft | Verfahren zum Herstellen eines bleifreien piezokeramischen Werkstoffs des Kalium-Natrium-Niobat-Systems mit Hilfe von Niobhydroxid und Verwendung eines Bauteils mit dem Werkstoff |
GB2469285A (en) * | 2009-04-06 | 2010-10-13 | Ntnu Technology Transfer As | Ferroelectric niobate materials formed by spray pyrolysis |
CN109336599B (zh) * | 2018-12-18 | 2021-08-31 | 宁波大学 | 无铅铁电上转换发光材料及其制备方法 |
CN113557612B (zh) * | 2019-03-13 | 2024-07-23 | 京瓷株式会社 | 压电陶瓷组合物 |
CN111174950B (zh) * | 2020-01-04 | 2022-04-19 | 湖北大学 | 铌酸钾钠纳米棒阵列生长操作方法及其传感器件制作方法 |
CN113149647A (zh) * | 2021-06-06 | 2021-07-23 | 福州大学 | 一种镱与上转换稀土发光离子双掺杂铌酸钾钠厚膜 |
CN115572165B (zh) * | 2021-06-21 | 2023-08-29 | 四川大学 | 一种高机械品质因数的铌锆酸铋钾钠铜铁无铅压电陶瓷 |
CN116332644B (zh) * | 2023-03-17 | 2024-03-22 | 西安建筑科技大学 | 一种K0.5Na0.5Nb0.7Ta0.3O3基无铅压电陶瓷材料、制备方法及应用 |
Family Cites Families (4)
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TWI228728B (en) * | 2001-05-29 | 2005-03-01 | Murata Manufacturing Co | Piezoelectric ceramic composition, piezoelectric ceramic element and method for producing piezoelectric ceramic composition |
EP1457471B1 (de) * | 2003-03-14 | 2014-02-26 | Denso Corporation | Keramik mit Kristallorientierung und Verfahren zu ihrer Herstellung |
CN100337980C (zh) * | 2003-05-29 | 2007-09-19 | 日本特殊陶业株式会社 | 压电陶瓷组合物以及含该组合物的压电元件 |
JP4513948B2 (ja) | 2003-12-22 | 2010-07-28 | Tdk株式会社 | 圧電磁器およびその製造方法 |
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2007
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2008
- 2008-02-15 CN CN200880011297.4A patent/CN101657394A/zh active Pending
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102173799A (zh) * | 2011-02-28 | 2011-09-07 | 上海海事大学 | 一种钽酸锂掺杂铌酸钾钠陶瓷的合成方法及设备 |
CN112510171A (zh) * | 2019-09-13 | 2021-03-16 | 株式会社东芝 | 复合氧化物、活性物质复合材料、电极、电池、电池包及车辆 |
CN115028450A (zh) * | 2022-06-09 | 2022-09-09 | 清华大学 | 一种铌酸钠基陶瓷材料及其制备方法 |
Also Published As
Publication number | Publication date |
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DE102007016854A1 (de) | 2008-10-16 |
DE102007016854B4 (de) | 2017-02-16 |
WO2008122458A1 (de) | 2008-10-16 |
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