CN101597353B - 卤代聚合物的自由基聚合制备工艺和卤代聚合物 - Google Patents

卤代聚合物的自由基聚合制备工艺和卤代聚合物 Download PDF

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Publication number
CN101597353B
CN101597353B CN200910145956XA CN200910145956A CN101597353B CN 101597353 B CN101597353 B CN 101597353B CN 200910145956X A CN200910145956X A CN 200910145956XA CN 200910145956 A CN200910145956 A CN 200910145956A CN 101597353 B CN101597353 B CN 101597353B
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China
Prior art keywords
reactor
free radical
ethylene linkage
linkage unsaturated
stage
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Expired - Fee Related
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CN200910145956XA
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English (en)
Chinese (zh)
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CN101597353A (zh
Inventor
P·拉克鲁瓦-德斯马泽斯
R·塞维拉克
B·布特文
V·博达特
V·库罗夫斯基
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Solvay SA
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Solvay SA
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/186Monomers containing fluorine with non-fluorinated comonomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/18Introducing halogen atoms or halogen-containing groups
    • C08F8/20Halogenation
    • C08F8/22Halogenation by reaction with free halogens
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
CN200910145956XA 2002-05-17 2003-05-16 卤代聚合物的自由基聚合制备工艺和卤代聚合物 Expired - Fee Related CN101597353B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0206246 2002-05-17
FR0206246A FR2839724B1 (fr) 2002-05-17 2002-05-17 Procedes de polymerisation radicalaire pour preparer des polymeres halogenes et polymeres halogenes

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CNB038167018A Division CN100519593C (zh) 2002-05-17 2003-05-16 卤代聚合物的自由基聚合制备工艺和卤代聚合物

Publications (2)

Publication Number Publication Date
CN101597353A CN101597353A (zh) 2009-12-09
CN101597353B true CN101597353B (zh) 2011-06-08

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Family Applications (3)

Application Number Title Priority Date Filing Date
CN200910145956XA Expired - Fee Related CN101597353B (zh) 2002-05-17 2003-05-16 卤代聚合物的自由基聚合制备工艺和卤代聚合物
CNB038167018A Expired - Fee Related CN100519593C (zh) 2002-05-17 2003-05-16 卤代聚合物的自由基聚合制备工艺和卤代聚合物
CN2009101459555A Expired - Fee Related CN101597362B (zh) 2002-05-17 2003-05-16 卤代聚合物的自由基聚合制备工艺和卤代聚合物

Family Applications After (2)

Application Number Title Priority Date Filing Date
CNB038167018A Expired - Fee Related CN100519593C (zh) 2002-05-17 2003-05-16 卤代聚合物的自由基聚合制备工艺和卤代聚合物
CN2009101459555A Expired - Fee Related CN101597362B (zh) 2002-05-17 2003-05-16 卤代聚合物的自由基聚合制备工艺和卤代聚合物

Country Status (12)

Country Link
US (3) US7078473B2 (https=)
EP (3) EP2045271B1 (https=)
JP (3) JP4357415B2 (https=)
CN (3) CN101597353B (https=)
AT (3) ATE422206T1 (https=)
AU (1) AU2003232808A1 (https=)
DE (2) DE60336359D1 (https=)
ES (1) ES2321926T3 (https=)
FR (1) FR2839724B1 (https=)
PT (1) PT1507807E (https=)
RU (3) RU2325402C2 (https=)
WO (1) WO2003097704A1 (https=)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2839724B1 (fr) 2002-05-17 2005-08-05 Solvay Procedes de polymerisation radicalaire pour preparer des polymeres halogenes et polymeres halogenes
US7741524B2 (en) * 2003-04-22 2010-06-22 Solvay (Societe Anonyme) Iodinated organic substances of low molecular mass and process for preparing them
JP5078353B2 (ja) * 2003-09-23 2012-11-21 ソルヴェイ(ソシエテ アノニム) ポリマー組成物
US20100311920A1 (en) * 2005-08-26 2010-12-09 Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers
US8357759B2 (en) * 2005-08-26 2013-01-22 CID Centro de Investigación y Desarrollo Tecnológico S.A. de C.V. Reactive block copolymers
KR100899985B1 (ko) * 2006-06-12 2009-05-28 주식회사 엘지화학 현탁 중합에 의한 염화 비닐계 중합체의 제조 방법
FR2903409A1 (fr) * 2006-07-04 2008-01-11 Solvay Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
US20100311849A1 (en) * 2006-08-23 2010-12-09 Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers
BRPI0808594A2 (pt) * 2007-04-02 2014-08-05 Akzo Nobel Nv "solução aceleradora, resina insaturada ou resina de acrilato e uso da solução aceleradora"
US20100256299A1 (en) 2007-06-21 2010-10-07 Tijs Nabuurs Process for obtaining low free monomer levels in a block copolymer emulsion prepared with (reverse) iodine transfer polymerisation
US8366980B2 (en) * 2007-07-31 2013-02-05 Stella Chemifa Corporation Method for producing hollow structual body
JP2013018953A (ja) * 2011-06-15 2013-01-31 Canon Inc 高分子粒子の製造方法
BR112014014967B1 (pt) * 2011-12-21 2020-12-15 Centre National De La Recherche Scientifique Processo para a preparação de um polímero de cloreto de vinilideno
EP2809698B1 (fr) * 2012-01-31 2016-01-27 Rhodia Operations Polymérisation en phase dispersée de monomères vinyliques halogénés en présence de stabilisants réactifs vivants
JP2014084411A (ja) * 2012-10-24 2014-05-12 Canon Inc 高分子粒子の製造方法
MX2021008506A (es) 2019-02-11 2021-08-19 Dow Global Technologies Llc Metodo de polimerizacion por transferencia inversa de yodo y composiciones de este.
MX2021008508A (es) 2019-02-11 2021-08-19 Dow Global Technologies Llc Metodo de polimerizacion por transferencia de yodo y composiciones a partir del mismo.
US11945890B2 (en) 2022-03-23 2024-04-02 Mexichem Specialty Resins Inc. Fluorinated PVC copolymer compositions for increased ultraviolet protection

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0617057A1 (en) * 1993-03-22 1994-09-28 The Geon Company Pseudo-living radical polymerization

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US3467363A (en) * 1967-08-31 1969-09-16 Richard Alan Reichel Noise generator for shaking loose packed material
DE2000501A1 (de) * 1970-01-07 1971-07-15 Basf Ag Verfahren zur Polymerisation von Vinyl- und Vinylidenverbindungen
SU440378A1 (ru) * 1972-12-06 1974-08-25 Предприятие П/Я М-5927 Способ получени блок-сополимеров
JPS5218787A (en) * 1975-08-04 1977-02-12 Kanegafuchi Chem Ind Co Ltd Suspension polymerization process of vinyl chloride
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US4180634A (en) * 1975-07-18 1979-12-25 Shin-Etsu Chemical Co., Ltd. Polymerizing vinyl chloride with lowering of scale formation
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JPH0826087B2 (ja) * 1990-11-29 1996-03-13 ダイキン工業株式会社 ポリマーの新規な製造方法
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JPH1144970A (ja) * 1997-05-28 1999-02-16 Ricoh Co Ltd 静電荷像現像用乾式現像剤
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FR2786178A1 (fr) * 1998-11-25 2000-05-26 Solvay Monomeres trifluorovinyliques fonctionnels et leur copolymerisation avec des olefines fluorees
FR2818580B1 (fr) * 2000-12-22 2003-03-21 Solvay Structures a couches polymeriques multiples
US6838535B2 (en) * 2001-03-23 2005-01-04 University Of Pennsylvania Process for the living radical polymerization of chlorine containing monomers
FR2839724B1 (fr) 2002-05-17 2005-08-05 Solvay Procedes de polymerisation radicalaire pour preparer des polymeres halogenes et polymeres halogenes
US7741524B2 (en) * 2003-04-22 2010-06-22 Solvay (Societe Anonyme) Iodinated organic substances of low molecular mass and process for preparing them

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EP0617057A1 (en) * 1993-03-22 1994-09-28 The Geon Company Pseudo-living radical polymerization

Non-Patent Citations (1)

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Also Published As

Publication number Publication date
US20050171312A1 (en) 2005-08-04
RU2004136996A (ru) 2005-07-10
CN101597362A (zh) 2009-12-09
FR2839724A1 (fr) 2003-11-21
JP2009132941A (ja) 2009-06-18
EP2045271A3 (fr) 2009-07-01
AU2003232808A1 (en) 2003-12-02
RU2419635C2 (ru) 2011-05-27
EP1507807A1 (fr) 2005-02-23
PT1507807E (pt) 2009-05-08
WO2003097704A1 (fr) 2003-11-27
CN100519593C (zh) 2009-07-29
US7285597B2 (en) 2007-10-23
JP5139354B2 (ja) 2013-02-06
ATE501184T1 (de) 2011-03-15
US7208558B2 (en) 2007-04-24
FR2839724B1 (fr) 2005-08-05
RU2007144484A (ru) 2009-06-10
RU2325402C2 (ru) 2008-05-27
JP2005530871A (ja) 2005-10-13
RU2011102762A (ru) 2012-07-27
US7078473B2 (en) 2006-07-18
WO2003097704A8 (fr) 2005-03-17
EP2045271A2 (fr) 2009-04-08
DE60324271D1 (de) 2010-03-18
EP2045277A2 (fr) 2009-04-08
US20060205906A1 (en) 2006-09-14
CN1668655A (zh) 2005-09-14
EP1507807B1 (fr) 2009-02-04
EP2045271B1 (fr) 2011-08-03
ATE422206T1 (de) 2009-02-15
EP2045277B1 (fr) 2011-03-09
CN101597362B (zh) 2012-10-03
JP2009132940A (ja) 2009-06-18
JP4357415B2 (ja) 2009-11-04
DE60336359D1 (de) 2011-04-21
CN101597353A (zh) 2009-12-09
RU2582616C2 (ru) 2016-04-27
US20070155929A1 (en) 2007-07-05
ATE518891T1 (de) 2011-08-15
JP5161818B2 (ja) 2013-03-13
ES2321926T3 (es) 2009-06-15
EP2045277A3 (fr) 2009-07-01

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Termination date: 20180516