CN101495226B - 用于低温转化的催化剂和将一氧化碳和水低温转化为二氧化碳和氢的方法 - Google Patents

用于低温转化的催化剂和将一氧化碳和水低温转化为二氧化碳和氢的方法 Download PDF

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Publication number
CN101495226B
CN101495226B CN2007800282877A CN200780028287A CN101495226B CN 101495226 B CN101495226 B CN 101495226B CN 2007800282877 A CN2007800282877 A CN 2007800282877A CN 200780028287 A CN200780028287 A CN 200780028287A CN 101495226 B CN101495226 B CN 101495226B
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catalyst
weight
hydrogen
catalysts
oxide
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CN101495226A (zh
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S·哈特彻
M·黑塞
M·赫尔茨勒
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BASF SE
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0668Removal of carbon monoxide or carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/12Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066Zirconium or hafnium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007Mixed salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1076Copper or zinc-based catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1082Composition of support materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M2008/1095Fuel cells with polymeric electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Carbon And Carbon Compounds (AREA)
CN2007800282877A 2006-07-26 2007-07-19 用于低温转化的催化剂和将一氧化碳和水低温转化为二氧化碳和氢的方法 Expired - Fee Related CN101495226B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06117843.0 2006-07-26
EP06117843 2006-07-26
PCT/EP2007/057450 WO2008012255A2 (de) 2006-07-26 2007-07-19 Katalysator für die tieftemperaturkonvertierung und verfahren zur tieftemperaturkonvertierung von kohlenmonoxid und wasser zu kohlendioxid und wasserstoff

Publications (2)

Publication Number Publication Date
CN101495226A CN101495226A (zh) 2009-07-29
CN101495226B true CN101495226B (zh) 2012-06-20

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CN2007800282877A Expired - Fee Related CN101495226B (zh) 2006-07-26 2007-07-19 用于低温转化的催化剂和将一氧化碳和水低温转化为二氧化碳和氢的方法

Country Status (7)

Country Link
US (1) US9343767B2 (https=)
EP (1) EP2049249B1 (https=)
JP (1) JP5281572B2 (https=)
CN (1) CN101495226B (https=)
CA (1) CA2658453C (https=)
DK (1) DK2049249T3 (https=)
WO (1) WO2008012255A2 (https=)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5477561B2 (ja) * 2009-09-09 2014-04-23 戸田工業株式会社 炭化水素を分解する多孔質触媒体及びその製造方法、炭化水素から水素を含む混合改質ガスを製造する方法、並びに燃料電池システム
CN102946994B (zh) * 2010-04-21 2015-03-18 Sk新技术株式会社 纳米级Cu基催化剂及其制备方法、以及使用该催化剂通过羧酸的直接氢化来制备醇的方法
GB201015605D0 (en) 2010-09-17 2010-10-27 Magnesium Elektron Ltd Inorganic oxides for co2 capture from exhaust systems
JP5871312B2 (ja) * 2011-01-17 2016-03-01 国立研究開発法人産業技術総合研究所 微粒子凝集体の製造方法、水蒸気改質触媒、水蒸気改質触媒の製造方法及び、水素製造方法
CN103466546B (zh) * 2013-09-06 2015-04-15 清华大学 一种将双功能吸附剂应用于吸附增强式水蒸气重整和水气变换反应的中温变压吸附方法
GB201519133D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
GB2546131B (en) 2015-10-29 2019-04-10 Johnson Matthey Plc Water-gas shift catalyst
GB201519139D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
CN105833876B (zh) * 2016-04-15 2019-03-26 西安向阳航天材料股份有限公司 一种高活性铜锌铝低温变换催化剂及其制备方法
EP3254760A1 (en) * 2016-06-07 2017-12-13 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process to synthesize a catalyst performing water-gas shift reaction at a high temperature
CN109621967B (zh) * 2018-12-26 2022-03-11 西安向阳航天材料股份有限公司 一种铜系低温变换催化剂的制备方法
CN114824320A (zh) * 2022-03-07 2022-07-29 国网综合能源服务集团有限公司 一种具有铜包覆氧化锌界面的铜基催化剂的制备方法及其低温催化水煤气变换反应的应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5272017A (en) * 1992-04-03 1993-12-21 General Motors Corporation Membrane-electrode assemblies for electrochemical cells
JP4295406B2 (ja) * 1998-11-16 2009-07-15 中國石油化工集團公司 銅含有触媒およびその製造方法
US20020061277A1 (en) 2000-09-25 2002-05-23 Engelhard Corporation Non-pyrophoric water-gas shift reaction catalysts
US6693057B1 (en) * 2002-03-22 2004-02-17 Sud-Chemie Inc. Water gas shift catalyst
US6627572B1 (en) * 2002-03-22 2003-09-30 Sud-Chemie Inc. Water gas shift catalyst
AU2003301060A1 (en) * 2002-12-20 2004-07-22 Honda Giken Kogyo Kabushiki Kaisha Noble metal-free nickel catalyst formulations for hydrogen generation
US7081144B2 (en) * 2003-04-04 2006-07-25 Texaco Inc. Autothermal reforming in a fuel processor utilizing non-pyrophoric shift catalyst

Also Published As

Publication number Publication date
US9343767B2 (en) 2016-05-17
CN101495226A (zh) 2009-07-29
JP2009544464A (ja) 2009-12-17
WO2008012255A2 (de) 2008-01-31
CA2658453A1 (en) 2008-01-31
EP2049249B1 (de) 2012-05-23
JP5281572B2 (ja) 2013-09-04
US20100012895A1 (en) 2010-01-21
WO2008012255A3 (de) 2008-04-17
CA2658453C (en) 2014-03-04
DK2049249T3 (da) 2012-09-10
EP2049249A2 (de) 2009-04-22

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