CA2658453C - Catalyst for low-temperature conversion and process for the low-temperature conversion of carbon monoxide and water into carbon dioxide and hydrogen - Google Patents

Catalyst for low-temperature conversion and process for the low-temperature conversion of carbon monoxide and water into carbon dioxide and hydrogen Download PDF

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Publication number
CA2658453C
CA2658453C CA2658453A CA2658453A CA2658453C CA 2658453 C CA2658453 C CA 2658453C CA 2658453 A CA2658453 A CA 2658453A CA 2658453 A CA2658453 A CA 2658453A CA 2658453 C CA2658453 C CA 2658453C
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CA
Canada
Prior art keywords
catalyst
weight
oxide
hydrogen
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2658453A
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English (en)
French (fr)
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CA2658453A1 (en
Inventor
Stephan Hatscher
Michael Hesse
Markus Hoelzle
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BASF SE
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BASF SE
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Publication of CA2658453A1 publication Critical patent/CA2658453A1/en
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Publication of CA2658453C publication Critical patent/CA2658453C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0668—Removal of carbon monoxide or carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/12—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Carbon And Carbon Compounds (AREA)
CA2658453A 2006-07-26 2007-07-19 Catalyst for low-temperature conversion and process for the low-temperature conversion of carbon monoxide and water into carbon dioxide and hydrogen Expired - Fee Related CA2658453C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06117843.0 2006-07-26
EP06117843 2006-07-26
PCT/EP2007/057450 WO2008012255A2 (de) 2006-07-26 2007-07-19 Katalysator für die tieftemperaturkonvertierung und verfahren zur tieftemperaturkonvertierung von kohlenmonoxid und wasser zu kohlendioxid und wasserstoff

Publications (2)

Publication Number Publication Date
CA2658453A1 CA2658453A1 (en) 2008-01-31
CA2658453C true CA2658453C (en) 2014-03-04

Family

ID=38634636

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2658453A Expired - Fee Related CA2658453C (en) 2006-07-26 2007-07-19 Catalyst for low-temperature conversion and process for the low-temperature conversion of carbon monoxide and water into carbon dioxide and hydrogen

Country Status (7)

Country Link
US (1) US9343767B2 (https=)
EP (1) EP2049249B1 (https=)
JP (1) JP5281572B2 (https=)
CN (1) CN101495226B (https=)
CA (1) CA2658453C (https=)
DK (1) DK2049249T3 (https=)
WO (1) WO2008012255A2 (https=)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5477561B2 (ja) * 2009-09-09 2014-04-23 戸田工業株式会社 炭化水素を分解する多孔質触媒体及びその製造方法、炭化水素から水素を含む混合改質ガスを製造する方法、並びに燃料電池システム
CN102946994B (zh) * 2010-04-21 2015-03-18 Sk新技术株式会社 纳米级Cu基催化剂及其制备方法、以及使用该催化剂通过羧酸的直接氢化来制备醇的方法
GB201015605D0 (en) 2010-09-17 2010-10-27 Magnesium Elektron Ltd Inorganic oxides for co2 capture from exhaust systems
JP5871312B2 (ja) * 2011-01-17 2016-03-01 国立研究開発法人産業技術総合研究所 微粒子凝集体の製造方法、水蒸気改質触媒、水蒸気改質触媒の製造方法及び、水素製造方法
CN103466546B (zh) * 2013-09-06 2015-04-15 清华大学 一种将双功能吸附剂应用于吸附增强式水蒸气重整和水气变换反应的中温变压吸附方法
GB201519133D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
GB2546131B (en) 2015-10-29 2019-04-10 Johnson Matthey Plc Water-gas shift catalyst
GB201519139D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
CN105833876B (zh) * 2016-04-15 2019-03-26 西安向阳航天材料股份有限公司 一种高活性铜锌铝低温变换催化剂及其制备方法
EP3254760A1 (en) * 2016-06-07 2017-12-13 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process to synthesize a catalyst performing water-gas shift reaction at a high temperature
CN109621967B (zh) * 2018-12-26 2022-03-11 西安向阳航天材料股份有限公司 一种铜系低温变换催化剂的制备方法
CN114824320A (zh) * 2022-03-07 2022-07-29 国网综合能源服务集团有限公司 一种具有铜包覆氧化锌界面的铜基催化剂的制备方法及其低温催化水煤气变换反应的应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5272017A (en) * 1992-04-03 1993-12-21 General Motors Corporation Membrane-electrode assemblies for electrochemical cells
JP4295406B2 (ja) * 1998-11-16 2009-07-15 中國石油化工集團公司 銅含有触媒およびその製造方法
US20020061277A1 (en) 2000-09-25 2002-05-23 Engelhard Corporation Non-pyrophoric water-gas shift reaction catalysts
US6693057B1 (en) * 2002-03-22 2004-02-17 Sud-Chemie Inc. Water gas shift catalyst
US6627572B1 (en) * 2002-03-22 2003-09-30 Sud-Chemie Inc. Water gas shift catalyst
AU2003301060A1 (en) * 2002-12-20 2004-07-22 Honda Giken Kogyo Kabushiki Kaisha Noble metal-free nickel catalyst formulations for hydrogen generation
US7081144B2 (en) * 2003-04-04 2006-07-25 Texaco Inc. Autothermal reforming in a fuel processor utilizing non-pyrophoric shift catalyst

Also Published As

Publication number Publication date
US9343767B2 (en) 2016-05-17
CN101495226A (zh) 2009-07-29
JP2009544464A (ja) 2009-12-17
WO2008012255A2 (de) 2008-01-31
CA2658453A1 (en) 2008-01-31
EP2049249B1 (de) 2012-05-23
JP5281572B2 (ja) 2013-09-04
US20100012895A1 (en) 2010-01-21
WO2008012255A3 (de) 2008-04-17
CN101495226B (zh) 2012-06-20
DK2049249T3 (da) 2012-09-10
EP2049249A2 (de) 2009-04-22

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Effective date: 20180719