CN101423443A - Water soluble effervescence composition and method of making the same - Google Patents
Water soluble effervescence composition and method of making the same Download PDFInfo
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- CN101423443A CN101423443A CNA2008102173796A CN200810217379A CN101423443A CN 101423443 A CN101423443 A CN 101423443A CN A2008102173796 A CNA2008102173796 A CN A2008102173796A CN 200810217379 A CN200810217379 A CN 200810217379A CN 101423443 A CN101423443 A CN 101423443A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D7/00—Fertilisers producing carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/40—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting fertiliser dosage or release rate; for affecting solubility
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/40—Fertilisers incorporated into a matrix
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Abstract
The invention relates to an effervescent composition of a water-soluble fertilizer and a preparation method thereof. The effervescent composition contains one or a plurality of plant nutrient substances and one or a plurality of compounds which are contacted with water to generate gas. The effervescent composition comprises an optimized proposal that the plant nutrient substance is monopotassium phosphate. The effervescent composition can be also added with acid, a plant growth conditioner, a surfactant, a filler, a disintegrating agent, an adhesive, dye, a lube and the like. The preparation method comprises the following steps: ingredients are weighed, mixed, pulverized, pelletized and dried to obtain the effervescence composition. The effervescent composition can be manufactured through a routine production process, has rapid disintegrating and dissolving (diffusing) speed in the water, does not block a spray head or drip a pipeline, is uneasy to absorb dampness, has high content of effective compositions, low packaging, storage, metering and using cost and high utilization rate of the effective compositions, reduces waste and pollution to environment, is widely applied to economic crops, gardening, lawns and urban landscaping and has wide market application prospect.
Description
Technical field
The invention belongs to novel water-soluble fertilizer, relate to a kind of water soluble effervescence composition and preparation method thereof.
Background technology
The object of the present invention is to provide a kind of efficient, water soluble effervescence agent of dissolving (dispersion) fast.Another object of the present invention is to provide the preparation method of water soluble effervescence agent.
According to the regulation of China's fertilizer management method of registration, be " water-soluble fertilizer " with common name standards such as dissolved fertilizer, foliar nutrients, foliar nutrient is not re-used as the versatility title.Water-soluble fertilizer specifically comprises: macroelement water-soluble fertilizer, trace element water-soluble fertilizer, moderate-element water-soluble fertilizer, contain the amino acid water-soluble fertilizer, contain humic acid water-soluble fertilizer, organic water-soluble fertilizer etc.Water-soluble fertilizer is the important supplement part of solid chemical fertilizer, composite fertilizer etc., is requisite integral part in the modern agriculture fertilising.
Water-soluble fertilizer product major part is the form of pressed powder or liquid on the domestic market at present, active constituent content is low, the plant utilization rate is low, easily environment is polluted, packing, transportation, storage, metering, use very inconvenient, portioned product is made particulate state by granulation process, owing to be common granulation only, only added anti-hard caking agent, lubricant etc., still exist dissolving (dispersion) slow, easily lump, easily the moisture absorption is decomposed, and insolubles is many, stop up shower nozzle and drip irrigation pipeline, incompatibility modern agriculture easily, gardening, lawn and urban afforestation are to the requirement of high-quality water soluble fertilizer.
The present invention makes effervescent with water-soluble fertilizer, the problems referred to above have been solved well, water soluble effervescence composition disintegration rate in water is fast, dissolving (dispersion) is complete, do not stop up shower nozzle and drip irrigation pipeline, be difficult for the moisture absorption, active constituent content height, packing, storing, metering, use cost is low, owing to added wetting dispersing agent, solution after the preparation has good wettability, and perviousness and plate-out ability have improved the utilization ratio of effective constituent, reduced waste and to the pollution of environment, has tangible performance, cost and environment-friendly advantage are widely used in cash crop, gardening, lawn and urban afforestation, its market application foreground is very wide.
Summary of the invention
The objective of the invention is to be achieved through the following technical solutions:
Water soluble effervescence composition of the present invention contains one or more plant nutrient substances and one or more contact the compound that produces gas with water.The present invention accelerates disintegration, dissolving (refer to water-soluble good water-soluble fertilizer), the dispersion of water-soluble fertilizer in water by effervescent in the mode that contacts generation gas in back with water and (refers to contain the water-soluble fertilizer of water-soluble relatively poor effective constituent, realize quick dispersion by adding auxiliary agents such as dispersion agent), reach the purpose that solves traditional water-soluble fertilizer product shortcoming with this.For the common water-soluble fertilizer that does not contain the effervesce composition, in fact effective constituent be difficult to obtain dissolving rapidly or disperse.
Preferred version of the present invention is: contacts the compound that produces gas with water and is selected from carbonate or supercarbonate, or the mixture of the two, described carbonate and supercarbonate include but not limited to Li
2CO
3, Na
2CO
3, K
2CO
3, (NH
4)
2CO
3, MgCO
3, CaCO
3, LiHCO
3, NaHCO
3, KHCO
3And NH
4HCO
3
Special preferred version of the present invention is NaHCO
3
The present invention can also comprise at least a or multiple acid, includes but not limited to formic acid, acetate, propionic acid, butyric acid, valeric acid, caproic acid, propanedioic acid, phosphoric acid, condensed phosphoric acid, tetra-sodium, tartrate, fumaric acid, oxysuccinic acid, grape acid, toxilic acid, boric acid, Succinic Acid, hexanodioic acid, amino acid, humic acids, butene dioic acid, xitix, Citric Acid (citric acid) and subsalt.
Preferred version of the present invention is: described plant nutrient substance is a potassium primary phosphate.
Water soluble effervescence composition of the present invention also can comprise one or more growth regulators, include but not limited to indolepopionic acid (IPA), indolebutyric acid, naphthylacetic acid (NAA), Nafusaku, 2,4-drips (2,4-D), " production increasing agent " (4-iodobenzene fluoroacetic acid), " drop-proof agent " (4-chlorophenoxyacetic acid), GA3, GA4, GA12, zeatin (ZT), kinetin (KT), 6-benzyl (base) VITAMIN B4 (6-BA), ethrel, dormin (ABA), choline dichloride (CCC), maleic hydrazide (MH), Triiodobenzoic acid (11BA), paclobutrazol, uniconazole, thidiazuron, the first piperazine, forchlorfenuron, maleic hydrazide, flumetralim, triacontanol price quote, brassinolide, alar-85 (B9), Sodium p-nitrophenoxide, p-NP potassium, the p-nitrophenyl cabisan, sodium onitrophenol, o-NP potassium, the ortho-nitrophenyl cabisan, 2,2, 4-dinitrophenol sodium, 2,2, 4-dinitrophenol potassium, 2, the 2, 4-dinitrophenol ammonium, 5-nitro hydroxyanisole sodium, 5-nitro hydroxyanisole potassium, 5-nitro hydroxyanisole ammonium, diethylamino ethanol caproate (DA-6), rich pyridine alcohol, Nucleotide, regulate peace, choline chloride 60, Psoralen, the citric acid titanium, sintofen, DCPTA (DCPTA) etc.
The present invention can satisfy the multiple demand that agricultural goes up crop by adding the additive of one or more growth regulators, and applied once reaches multiple purpose, reduces peasant's use cost, further enlarges use range of the present invention.And, can produce synergistic function between the growth regulator of no-float and the plant nutrient substance, play the effect that reduces cost, improves effect.Many products that contain growth regulator are just arranged in the water-soluble fertilizer product of China Ministry of Agriculture registration management.
Different qualities and different purposes at plant nutrient substance, water soluble effervescence composition of the present invention can also comprise one or more additives such as wetting dispersing agent, disintegrating agent, tamanori, filler, dyestuff, lubricant, its consumption is respectively wetting dispersing agent: 0-50%, disintegrating agent: 0-80%, tamanori: 0-15%, filler: 0-90%, dyestuff: 0-5%, lubricant: 0-10%.
Add wetting dispersing agent and be in order to make the fast and effective constituent of effervescent disintegration dissolve (dispersion) Yu Shuizhong fast, adapt to the requirement of modernized high-efficiency agriculture, and at water-soluble relatively poor effective constituent, make effective constituent in hard water, still keep good dispersion state, make solution have good wettability, perviousness and plate-out ability simultaneously, increase the contact of solution, improved the utilization ratio of effective constituent, reduced waste and the pollution of environment to crop surface.Wetting dispersing agent can use anion surfactant or nonionogenic tenside.
Can add an amount of wetting dispersing agent among the present invention.Preferred version of the present invention is:
Wherein wetting dispersing agent is selected from ethanol; saponin; lignosulfite; the hydrolyzate of animal waste; alkyl-sulphate; alkylsulfonate; alkylbenzene sulfonate; alkylphosphonic; alkene sulfonate; alkylsulphonic acid an alkali metal salt and ammonium salt; alkylphenol-polyethenoxy base vitriol; alkylphenol polyoxyethylene succinate sulfonate; the alkylphenol polyoxyethylene formaldehyde condensation products; Succinic Acid half ester sulfonate fatty amide; the N methyl taurine sodium salt; polyoxyethylenated alcohol sodium sulfate; sulfonated lignin; NNO; alkylphenol polyoxyethylene vitriol; sulfonated alkyl naphathalene; petroleum sodium sulfonate; the alkyl biphenyl sodium naphthalene sulfonate; sulfonaphthol formaldehyde condensation products sodium salt; fatty alcohol-polyoxyethylene ether; the alkylnaphthalene formaldehyde condensation products; polycarboxylate; dibutyl naphthalenesulfonate, or above two or more mixture.
Disintegrating agent makes water become swelling action to infiltrate in the effervescent by wicking, accelerates the disintegration of effervescent.Among the present invention, according to the character of effervescent effective constituent, some need add disintegrating agent.Preferred version of the present invention is: wherein disintegrating agent is selected from sulphur ammonium, calcium chloride, Lalgine, salt, magnesium chloride, urea, wilkinite, aluminum chloride, sodium sulfate, attapulgite, white carbon black, Povidone, hydroxypropylcellulose, Microcrystalline Cellulose, starch, modified starch, Explotab, carboxymethylstach sodium, crosslinked carboxymethylstach sodium, super carboxymethylstach sodium, or above two or more mixture.
Tamanori is for effective constituent and auxiliary agent are bonded together, and the intensity of finished product avoids broken in transporting procedures after making things convenient for granulation and guaranteeing granulation, and among the present invention, according to the character of effervescent effective constituent, some need add tamanori.Preferred version of the present invention is: wherein tamanori is selected from CMC, PVA, EVA, starch, dextrin, sucrose, syrup, maltose, glucose, polyvinylpyrrolidone (PVP), gum arabic, soybean protein, the arm protein, gelatine, gelatin, water glass, gypsum, shellac, pitch, paraffin, wood is fragrant, polyvinyl acetate (PVA), polyvinyl alcohol, rosin, denaturated sodium polyacrylate, polyoxyethylene glycol, xylogen, methylcellulose gum, ethyl cellulose, polyacrylamide, hydroxypropylcellulose, Vltra tears, polyethylene azoxy ketone, Hydroxypropylcelliloxe, low-substituted hydroxypropyl cellulose, Xylo-Mucine, or above two or more mixture.
Filler mainly is in order to adsorb the physical behavior of effective constituent and maintenance effervescent, and as intensity, water absorbability etc., the present invention can add different fillers according to the character and the service requirements of effective constituent, and some can not add filler.Preferred version of the present invention is: wherein filler is selected from kaolin, corncob cellulose, soybean, tobacco, rice husk, sulphur, acorn, light calcium carbonate, wilkinite, atlapulgite, diatomite, white carbon black, Attapulgite, clay, montmorillonite, float stone, potter's clay, unslaked lime, magnesian lime, phosphorus lime, agalmatolite, calcite, rhombspar, gypsum, sepiolite, silica, mica, talcum, mud coal, silica gel, starch, dextrin, glucose, N.F,USP MANNITOL, lactose, sucrose, calcium sulfate, or above two or more mixture.
Water soluble effervescence composition of the present invention can be processed into shades of colour, and the purpose that adds dyestuff is in order to change the appearance color of product, to increase the commodity of products energy, and is little to other performance impact of product.Preferred version of the present invention is: wherein dyestuff is selected from direct red brown, direct light yellow, turmeric yellow, acid yellowish-brown, EX-SF DISPERSE BLUE EX-SF 300, Reactive blue, reactive scarlet, or above two or more mixture.
Water soluble effervescence composition of the present invention can be processed into arbitrary polygon tablet, sphere, ellipse or arbitrary polyhedron granula, does not influence its result of use.
Water soluble effervescence composition of the present invention can also add lubricant, it mainly is the situation that is processed as tablet at needs, its purpose is to make particle lubricated, the convenient punch die hole that flows into, effervescent tablet is easily dished out from mould, reduce with the friction and the adhesion of punch die and make the accurate measurement of effervescent tablet, light attractive in appearance.Preferred version of the present invention is: wherein lubricant is selected from stearic acid, stearate, hydrogenated vegetable oil, polyoxyl 40 stearate, light mineral oil, polyoxyethylene glycol, boric acid, sodium-chlor, Sodium Benzoate, sodium-acetate, sodium oleate, sodium laurylsulfate, magnesium laurylsulfate, polyoxyethylene lauryl alcohol sodium sulfate, hexanodioic acid, fumaric acid, glycerine triacetate, sodium starch glycolate, talcum powder, or above two or more mixture.
More than all additives all are known substances, also be material commonly used and that know in the processing of agricultural chemicals, pharmaceutical preparation.
Preparation method of the present invention is:
The preparation method of water soluble effervescence composition of the present invention is characterised in that and comprises following processing step and processing method: with formulation material weighing, mixing, pulverizing, granulation, be drying to obtain product.
The known device of widely applying on the market is all used in the preparation of water soluble effervescence composition of the present invention, and granulation adopts conventional granulation process to realize that these technologies include but not limited to extruder grain, cylinder granulation, fluidized bed granulation, fluidized bed prilling etc.
Advantage of the present invention is as follows:
This water soluble effervescence agent is easy to use except having, cost is low, also has the following advantages:
1, the particulate disintegration rate is fast;
2, dissolve (dispersion) property fast, uniformly;
3, there is not macrobead after the dissolving (dispersion), not blocking sprayer and drip irrigation facility;
4, excellent storage stability;
5, good fluidity, the packing, the storing cost low;
6, there is not dust, environmentally friendly;
7, Pei Zhi liquid has good wettability, and perviousness and plate-out ability have improved the utilization ratio of effective constituent, has reduced waste and to the pollution of environment.
Concrete embodiment
In order to understand the present invention better, describe the technology contents of invention below in detail with example, but embodiment of the present invention are not limited to these examples.
Embodiment 1
Take by weighing each component raw material according to following proportioning
Saltpetre 70 grams
Ammonium chloride 10 grams
Plant hormones regulators,gibberellins GA
31 gram
KHCO
37 grams
Xitix 5 grams
Succinic Acid half ester sulfonate fatty amide 4 grams
Sodium dodecylbenzene sulfonate 3 grams
Earlier with Plant hormones regulators,gibberellins GA
3More than superfine grinding to 250 order, with other component mixing, prepare female powder through coarse reduction, with mixing of female powder and an amount of alcoholic solution, carry out extruder grain then, drying, screening, analytical study warehouse-in obtain saltpetre Plant hormones regulators,gibberellins effervescent.
Embodiment 2
Take by weighing each component raw material according to following proportioning
Saltpetre 70 grams
Sulphur ammonium 9 grams
Naphthylacetic acid 1 gram
NH
4HCO
35 grams
Fumaric acid 5 grams
NNO 4 grams
Fatty alcohol-polyoxyethylene ether 3 grams
Talcum powder 2 grams
Gum arabic 1 gram
Earlier with naphthylacetic acid more than superfine grinding to 250 order, with other component mixing, prepare female powder through coarse reduction, with mixing of the tamanori gum arabic alcoholic solution of female powder and 3%, carry out fluidized bed prilling then, drying, compressing tablet, analytical study warehouse-in obtain saltpetre naphthylacetic acid effervescent tablet.
Embodiment 3
Take by weighing each component raw material according to following proportioning
Boric acid 65 grams
Microcrystalline Cellulose 10 grams
KHCO
36 grams
Tartrate 4 grams
Sodium lignosulfonate 5 grams
Sodium dodecylbenzene sulfonate 5 grams
Magnesium Stearate 2 grams
Polyvinylpyrrolidone 3 grams
With the said components mixing, through pulverizing the female powder of preparation,, carry out the cylinder granulation then with mixing of the tamanori polyvinylpyrrolidone alcoholic solution of female powder and 3%, drying, compressing tablet, analytical study are put in storage and are obtained the boric acid effervescent tablet.
Embodiment 4
Take by weighing each component raw material according to following proportioning
Potassium primary phosphate 84 grams
NaHCO
39 grams
CMC 2 grams
Lalgine 5 grams
With the said components mixing, prepare female powder through superfine grinding, with mixing of the tamanori CMC alcoholic solution of female powder and 1%, carry out extruder grain then, drying, screening, analytical study are put in storage and are obtained the potassium primary phosphate effervescent granule.
Embodiment 5
Take by weighing each component raw material according to following proportioning
Nitric acid ammonia calcium 70 grams
Magnesium sulfate heptahydrate 8.6 grams
Sodium p-nitrophenoxide 1 gram
Sodium onitrophenol 1.2 grams
5-nitro hydroxyanisole sodium 0.2 gram
CaCO
35 grams
Xitix 5 grams
N methyl taurine sodium salt 8 grams
Hydroxypropylcellulose 1 gram
Earlier with Sodium p-nitrophenoxide, sodium onitrophenol, 5-nitro hydroxyanisole sodium and CaCO
3More than superfine grinding to 250 order, with other component mixing, prepare female powder through coarse reduction, with mixing of the tamanori hydroxypropylcellulose alcoholic solution of female powder and 3%, carry out extruder grain then, drying, screening, analytical study warehouse-in obtain column sodium nitrophenolate effervescent granule.
Embodiment 6
Take by weighing each component raw material according to following proportioning
Potassium primary phosphate 33.95 grams
Borax 7 grams
Ammonium molybdate 10 grams
Zinc Sulphate Monohydrate 8 grams
Anhydrous cupric sulfate 6 grams
Sulfuric acid monohydrate iron 3 grams
Manganese sulfate monohydrate 4 grams
Paclobutrazol 10 grams
KHCO
38 grams
Xitix 8 grams
Dextrin 2 grams
Direct light yellow 0.05 gram
Will be except that the said components mixing dextrin, the direct light yellow, prepare female powder through coarse reduction, dextrin is configured to 3% tamanori dextrin alcoholic solution, direct light yellow adds in the dextrin alcoholic solution again, with female powder with contain mixing of dye well dextrin alcoholic solution, carry out extruder grain then, drying, screening, analytical study warehouse-in obtain the agent of yellow micro-paclobutrazol composite effervescent cylindrical particle.
Embodiment 7
Take by weighing each component raw material according to following proportioning
Aminoacids complex 75 grams
Urea 8 grams
NH
4HCO
38 grams
NNO 4 grams
Fatty alcohol-polyoxyethylene ether 3 grams
Gum arabic 2 grams
With the said components mixing, prepare female powder through coarse reduction, with mixing of the tamanori gum arabic alcoholic solution of female powder and 3%, carry out fluidized bed prilling then, drying, screening, analytical study are put in storage and are obtained the agent of aminoacids complex effervesce spheroidal particle.
Embodiment 8
Take by weighing each component raw material according to following proportioning
Humic acid 77 grams
Sulphur ammonium 9 grams
NaHCO
36 grams
Polycarboxylate 4 grams
Succinic Acid half ester sulfonate fatty amide 3 grams
Low-substituted hydroxypropyl cellulose 1 gram
Earlier with humic acid more than superfine grinding to 250 order, with other component mixing, prepare female powder through coarse reduction, with mixing of the tamanori gelatin alcoholic solution of female powder and 3%, carry out fluidized bed prilling then, drying, screening, analytical study warehouse-in obtain the agent of humic acid effervesce spheroidal particle.
Embodiment 9
Present embodiment is the slaking of the foregoing description, dispersed experiment.Because the water soluble effervescence agent is an innovative product, there is not sophisticated product standard, therefore check with reference to national pesticide water dispersible granules standard, for effective constituent is water miscible product, no longer carry out the mensuration of dispersing property, the sample that the foregoing description is made has carried out following detection, and concrete detection method is as follows:
Dispersed and redispersibility is measured: adopt the graduated cylinder hybrid system to carry out, its step is as follows: (1) adds 98ml deionized water (100ml scale) in tool plug graduated cylinder; (2) claim the 2g sample to add graduated cylinder; (3) turn upside down and leave standstill behind the graduated cylinder 10 times, each 2 seconds, the precipitation capacity when record 30,60min; (4) put upside down graduated cylinder behind the 24h, write down the number of times that makes the settling redispersion and put upside down, the number of reversals is lower than 10 persons and thinks qualified.
Slaking is measured: represent to measure disintegration time length, general provision is qualified less than 3min, method is as follows: to the 100ml tool plug graduated cylinder that fills 90ml distilled water (the high 22.5cm of tube, internal diameter 28mm) adds sample particle 0.5g down in 25 ℃ in, clamp the graduated cylinder middle part, at the uniform velocity rotate along the center with 8r/min speed, up to sample in water fully till the disintegration, writing time.This time is disintegration time.
Result such as following table:
Table 2: the assay of embodiment 1-6
The result shows, the water soluble effervescence agent that the present invention makes, and excellent performances such as the slaking of product, dispersiveness have been realized purpose of the present invention.
Claims (10)
1, a kind of water soluble effervescence composition is characterized in that: contain one or more plant nutrient substances and one or more and contact the compound that produces gas with water.
2, according to the described effervescence combination of claim 1, it is characterized in that: described plant nutrient substance is a potassium primary phosphate.
3, according to the described effervescence combination of claim 1, it is characterized in that: contact the compound that produces gas with water and be selected from carbonate or supercarbonate, or the mixture of the two, described carbonate and supercarbonate include but not limited to Li
2CO
3, Na
2CO
3, K
2CO
3, (NH
4)
2CO
3, MgCO
3, CaCO
3, LiHCO
3, NaHCO
3, KHCO
3And NH
4HCO
3
4, according to the described effervescence combination of claim 3, it is characterized in that: described supercarbonate is NaHCO
3
5, according to the described effervescence combination of claim 1, it is characterized in that: also comprise at least a or multiple acid, include but not limited to formic acid, acetate, propionic acid, butyric acid, valeric acid, caproic acid, propanedioic acid, phosphoric acid, condensed phosphoric acid, tetra-sodium, tartrate, fumaric acid, oxysuccinic acid, grape acid, toxilic acid, boric acid, Succinic Acid, hexanodioic acid, amino acid, humic acids, butene dioic acid, xitix, Citric Acid (citric acid) and subsalt.
6, described effervescence combination according to claim 1, it is characterized in that: also comprise one or more growth regulators, include but not limited to indolepopionic acid (IPA), indolebutyric acid, naphthylacetic acid (NAA), Nafusaku, 2,4-drips (2,4-D), " production increasing agent " (4-iodobenzene fluoroacetic acid), " drop-proof agent " (4-chlorophenoxyacetic acid), GA3, GA4, GA12, zeatin (ZT), kinetin (KT), 6-benzyl (base) VITAMIN B4 (6-BA), ethrel, dormin (ABA), choline dichloride (CCC), maleic hydrazide (MH), Triiodobenzoic acid (11BA), paclobutrazol, uniconazole, thidiazuron, the first piperazine, forchlorfenuron, maleic hydrazide, flumetralim, triacontanol price quote, brassinolide, alar-85 (B9), Sodium p-nitrophenoxide, p-NP potassium, the p-nitrophenyl cabisan, sodium onitrophenol, o-NP potassium, the ortho-nitrophenyl cabisan, 2,2, 4-dinitrophenol sodium, 2,2, 4-dinitrophenol potassium, 2, the 2, 4-dinitrophenol ammonium, 5-nitro hydroxyanisole sodium, 5-nitro hydroxyanisole potassium, 5-nitro hydroxyanisole ammonium, diethylamino ethanol caproate (DA-6), rich pyridine alcohol, Nucleotide, regulate peace, choline chloride 60, Psoralen, the citric acid titanium, sintofen, DCPTA (DCPTA) etc.
7, according to the described effervescence combination of claim 1, it is characterized in that: can also comprise one or more additives such as wetting dispersing agent, disintegrating agent, tamanori, filler, dyestuff, lubricant, its consumption is respectively wetting dispersing agent: 0-50%, disintegrating agent: 0-80%, tamanori: 0-15%, filler: 0-90%, dyestuff: 0-5%, lubricant: 0-10%.
8, according to the described effervescence combination of claim 7, it is characterized in that:
Wherein wetting dispersing agent is selected from ethanol, saponin, lignosulfite, the hydrolyzate of animal waste, alkyl-sulphate, alkylsulfonate, alkylbenzene sulfonate, alkylphosphonic, alkene sulfonate, alkylsulphonic acid an alkali metal salt and ammonium salt, alkylphenol-polyethenoxy base vitriol, alkylphenol polyoxyethylene succinate sulfonate, the alkylphenol polyoxyethylene formaldehyde condensation products, Succinic Acid half ester sulfonate fatty amide, the N methyl taurine sodium salt, polyoxyethylenated alcohol sodium sulfate, sulfonated lignin, NNO, alkylphenol polyoxyethylene vitriol, sulfonated alkyl naphathalene, petroleum sodium sulfonate, the alkyl biphenyl sodium naphthalene sulfonate, sulfonaphthol formaldehyde condensation products sodium salt, fatty alcohol-polyoxyethylene ether, the alkylnaphthalene formaldehyde condensation products, polycarboxylate, dibutyl naphthalenesulfonate, or above two or more mixture;
Wherein disintegrating agent is selected from sulphur ammonium, calcium chloride, Lalgine, salt, magnesium chloride, urea, wilkinite, aluminum chloride, sodium sulfate, attapulgite, white carbon black, Povidone, hydroxypropylcellulose, Microcrystalline Cellulose, starch, modified starch, Explotab, carboxymethylstach sodium, crosslinked carboxymethylstach sodium, super carboxymethylstach sodium, or above two or more mixture;
Wherein tamanori is selected from CMC, PVA, EVA, starch, dextrin, sucrose, syrup, maltose, glucose, polyvinylpyrrolidone (PVP), gum arabic, soybean protein, the arm protein, gelatine, gelatin, water glass, gypsum, shellac, pitch, paraffin, wood is fragrant, polyvinyl acetate (PVA), polyvinyl alcohol, rosin, denaturated sodium polyacrylate, polyoxyethylene glycol, xylogen, methylcellulose gum, ethyl cellulose, polyacrylamide, hydroxypropylcellulose, Vltra tears, polyethylene azoxy ketone, Hydroxypropylcelliloxe, low-substituted hydroxypropyl cellulose, Xylo-Mucine, or above two or more mixture;
Wherein filler is selected from kaolin, corncob cellulose, soybean, tobacco, rice husk, sulphur, acorn, light calcium carbonate, wilkinite, atlapulgite, diatomite, white carbon black, Attapulgite, clay, montmorillonite, float stone, potter's clay, unslaked lime, magnesian lime, phosphorus lime, agalmatolite, calcite, rhombspar, gypsum, sepiolite, silica, mica, talcum, mud coal, silica gel, starch, dextrin, glucose, N.F,USP MANNITOL, lactose, sucrose, calcium sulfate, or above two or more mixture;
Wherein dyestuff is selected from direct red brown, direct light yellow, turmeric yellow, acid yellowish-brown, EX-SF DISPERSE BLUE EX-SF 300, Reactive blue, reactive scarlet, or above two or more mixture;
Wherein lubricant is selected from stearic acid, stearate, hydrogenated vegetable oil, polyoxyl 40 stearate, light mineral oil, polyoxyethylene glycol, boric acid, sodium-chlor, Sodium Benzoate, sodium-acetate, sodium oleate, sodium laurylsulfate, magnesium laurylsulfate, polyoxyethylene lauryl alcohol sodium sulfate, hexanodioic acid, fumaric acid, glycerine triacetate, sodium starch glycolate, talcum powder, or above two or more mixture.
9, according to the arbitrary described effervescence combination of claim 1-8, it is characterized in that: effervescence combination can be processed into arbitrary polygon tablet, sphere, ellipse or arbitrary polyhedron granula.
10, according to the preparation method of the arbitrary described effervesce effervescence composition of claim 1-9, it is characterized in that comprising following processing step and processing method: with formulation material weighing, mixing, pulverizing, granulation, be drying to obtain.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102173796A CN101423443A (en) | 2008-11-21 | 2008-11-21 | Water soluble effervescence composition and method of making the same |
| PCT/CN2009/070228 WO2010057372A1 (en) | 2008-11-21 | 2009-01-20 | Plant nutriment effervescent composition and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CNA2008102173796A CN101423443A (en) | 2008-11-21 | 2008-11-21 | Water soluble effervescence composition and method of making the same |
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| CN112062636A (en) * | 2020-09-19 | 2020-12-11 | 河南黑色生态科技有限公司 | Instant potassium fulvate tablet and preparation method and application thereof |
| CN112425442A (en) * | 2020-11-30 | 2021-03-02 | 句容市乡土树种研究所 | Pruning and trimming method for grape facility cultivation |
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