CN105152781A - Biological semi-organic fertilizer containing amino acid and making method thereof - Google Patents
Biological semi-organic fertilizer containing amino acid and making method thereof Download PDFInfo
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Abstract
The invention belongs to the technical field of fertilizer production and relates to biological semi-organic fertilizer containing amino acid and a making method thereof. Urea, monoammonium phosphate, potassium sulphate and bentonite are matched reasonably, amino acid mother liquor granules are adopted to form granulation master batch, aminated humic acid, medium trace element compositions, decomposed coal and amino acid mother liquor are blended to form a coating sizing agent used for primary coating of the granulation master batch, then a dusting powder agent is formed by microorganism bacterial liquid and calcium carbonate powder, a coating agent is formed by white oil, molasses and a mixture, and secondary coating is conducted in a coating machine to generate the biological semi-organic fertilizer containing amino acid. The biological semi-organic fertilizer containing amino acid has the efficiency of humic acid, amino acid, biological agents and the like and also has a slow-releasing function, effective constituents can be released slowly and orderly, fertilizer efficiency is remarkable, and production organization is facilitated.
Description
Technical field
The invention belongs to technical field of fertilizer production, relate to a kind of containing amino acid whose biological organic and inorganic fertilizer material and manufacture method thereof.
Background technology
On agricultural planting, form a large amount of use chemical fertilizer for a long time and only paid attention to nitrogen, phosphorus, potassium, think little of organic matter, the fertilising custom of medium trace element, cause chemical fertilizer available nutrient utilization ratio low, fertilized soil soil fertility declines, nutrient imbalance, Soil degradation, constrain the further performance of farm output, occur that waste resource and high investment low yield go out phenomenon, even some areas also cause earth's surface eutrophication, in underground water and vegetables, nitrate nitrogen content exceeds standard, environmental pollution and the food-safety problems such as the increase of nitrous oxide emission amount, certain harm is brought to agriculture production.
On the one hand, humic acid is the main component in weathered coal, brown coal, the peat composed of rotten mosses, it is elementary composition that its composition mainly contains carbon, hydrogen, oxygen, nitrogen, sulphur etc., it is the high molecular polymerization organism aggregate of the heterogeneous uneven structure of a class that plant and animal residues is formed through microbial decomposition and synthesis, for wetting ability reversible colloid, there is loose " spongy " structure, its huge specific surface area and surface energy, form physical adsorption stress basis.Because active group contained in humic acid molecular structure can carry out ion-exchange, complexing or chelatropic reaction with metal ion, the absorption of crop to nutritive element can be activated, stimulate plant physiology metabolism, change chemical fertilizer characteristic, improvement Soil structure produces one of ideal raw material of organic and inorganic fertilizer at present.
Although there is the organic-inorganic complex fertilizer adopting humic acid to produce at present on the market, most of humic acid, without activation treatment, directly uses, poor activity, do not become the humate of free state, usually can not absorbed by cropsly utilize, do not reach due effect.
On the other hand, amino acid is the smallest molecule forming protein in process of crop growth, it not only has promotion crop to the absorption of nutritive substance, stimulates and regulating crop growth, improves crop photosynthesis, accelerate plant growth breeding, promote that crop root is flourishing, impel plant growth healthy and strong, strengthen crop anti-adversity, reduce pesticide residue, improve the functions such as crop quality; And it is also rich in organic matter, there is improvement soil physical property, improve soil aggregate, chessom, reduce the comprehensive action of soil compaction; Simultaneously amino acid or the sequestrant of medium trace element, can prevent medium trace element from using together with compound fertilizer or be fixed in soil, be degenerated to as indissoluble salt.
Current amino acid mostly on the market is and extracts hair waste liquid, and be that product is reclaimed in environmental protection, although its price is low, moisture is large, adopts traditional compound fertilizer production method, as extruder grain, disc granulation, the granulation of rotary drum cylinder are difficult to carry out process for processing.Often occur with the form of liquid fertilizer, fertilizer efficiency is short for action time, is difficult to play slowly-releasing effect.
Again on the one hand, people are more and more familiar with bio-bacterial manure in recent years, because of its not only can increase soil fertility (can increase the sources of nitrogen in soil as vinelandii, the phosphorus of insoluble in soil, potassium can be dissolved out by molten phosphorus, potassium solubilizing bacteria, increase Soil Phosphorus, potassium element); And also there is in being manured into soil the diseases prevention of antagonism pathogenic bacteria strengthen bacterium effect, can secrete phytokinin and promote plant growth, improve quality of agricultural product, the standard that agricultural-food indices reaches green food can be met; Simultaneously bio-bacterial manure also has and strengthens crop water suction, water conservation, and improves crop drought resistance, the various crop anti-adversity such as cold-resistant.
There is multiple biologic organic, inorganic compound (conjunction) fertilizer on the market at present, some bacteria agents or bacterium liquid are that material process in process of production adds, due to large by nitrogen, phosphorus, potassium nutrition material concentration or in drying course because its temperature is high, thus have impact on the survival rate of probiotics, reduce bacteria agent or the due effect of bacterial manure.
Summary of the invention
The object of this invention is to provide one and there is the multiple fertilizer efficiency such as humic acid, amino acid, bacteria agent, have slow-release function concurrently, effective constituent slowly, in order can be discharged, what remarkable, the convenient tissue of fertilizer efficiency was produced contains amino acid whose biological organic and inorganic fertilizer material and manufacture method thereof.
For achieving the above object, the present invention adopts following technical scheme:
One of the present invention, containing amino acid whose biological organic and inorganic fertilizer material, is made up of the composition of following weight proportion:
Weathered coal 100-150
Bicarbonate of ammonia 10-15
Urea 160-250
Monoammonium phosphate 180-250
Potassium sulfate 180-250
Wilkinite 30-50
Span amino acid mother liquor 250-300
Microbial inoculum 5
Molasses 2
White oil 8
Calcium carbonate 1;
Described molasses are the concentrated molasses fermented liquid in sugar production process, containing xanthohumic acid 20%, and N P and K total content 8%, amino acid 5%, crude protein 10%, mineral element 20%.
In addition, also contain by the medium trace element composition of following weight proportion in said ratio:
Magnesium sulfate 7, zinc sulfate 3, ferrous sulfate 7, borax 3.
As mentioned above containing a manufacture method for amino acid whose biological organic and inorganic fertilizer material, comprise the steps:
Steps A) preparation of span amino acid mother liquor;
By the animal hair after degreasing and the hydrochloric acid ratio mix and blend according to weight ratio 1:2, the concentration of described hydrochloric acid is 25%-30%, control temperature, at 114-118 DEG C, is hydrolyzed 10-12 hour, then Temperature fall, when temperature is down to 80 ± 5 DEG C, filtered while hot, except de-black detritus, adding concentration is hydrochloric acid in the potassium hydroxide aqueous solution of 10% and residual, obtain being hydrolyzed filtrate, the consumption of described potassium hydroxide aqueous solution is 0.6-1.0 times of animal hair weight;---stop the injection of liquefied ammonia when 5.0, continue stirring 30---60 minutes, then leaves standstill 10-12 hour, obtains span amino acid mother liquor to pass into liquefied ammonia subsequently in hydrolysis filtrate, simultaneously turn on agitator, until the pH value of hydrolysis filtrate reaches 4.8;
Step B) preparation of masterbatch pellet;
Urea, monoammonium phosphate, potassium sulfate, wilkinite to be carried out respectively pulverizing by proportioning, measure, mix, be transported in granulating disc and utilize span amino acid mother liquor to carry out humidification granule, the granule materials after granulation enters in dryer dries, and obtains masterbatch pellet.
Step C) be once coated with and secondary drying;
Weathered coal is mixed with the weight proportion of bicarbonate of ammonia according to 1:1, seals 48-72 hour up for safekeeping, obtain ammonification humic acid, ammonification humic acid and remaining weathered coal and remaining span amino acid mother liquor are fully mixed to get a coating sizing-agent; Masterbatch pellet and a coating sizing-agent are sent into spray granulating machine and carries out slurryspraying granulation process, carry out secondary drying after slurryspraying granulation, be cooled to normal temperature subsequently, obtain coated particle;
Step D) secondary coating;
In mixing machine, microbial inoculum and calcium carbonate are carried out metering mixing, preparation becomes applying medicinal powder; In Drug coating groove, white oil, molasses carried out measuring, stir, mix, carry out being heated to 58 DEG C-62 DEG C, preparation becomes Drug coating simultaneously; Applying medicinal powder and Drug coating are sent in coating machine, dressing, face powder process is carried out to the coated particle that step C produces, obtains described containing amino acid whose biological organic and inorganic fertilizer material.
When containing medium trace element composition time, its manufacture method comprises the steps:
Steps A) preparation of span amino acid mother liquor;
By the animal hair after degreasing and the hydrochloric acid ratio mix and blend according to weight ratio 1:2, the concentration of described hydrochloric acid is 25%-30%, control temperature, at 114-118 DEG C, is hydrolyzed 10-12 hour, then Temperature fall, when temperature is down to 80 ± 5 DEG C, filtered while hot, except de-black detritus, adding concentration is hydrochloric acid in the potassium hydroxide aqueous solution of 10% and residual, obtain being hydrolyzed filtrate, the consumption of described potassium hydroxide aqueous solution is 0.6-1.0 times of animal hair weight;---stop the injection of liquefied ammonia when 5.0, continue stirring 30---60 minutes, then leaves standstill 10-12 hour, obtains span amino acid mother liquor to pass into liquefied ammonia subsequently in hydrolysis filtrate, simultaneously turn on agitator, until the pH value of hydrolysis filtrate reaches 4.8;
Step B) preparation of masterbatch pellet;
Urea, monoammonium phosphate, potassium sulfate, wilkinite to be carried out respectively pulverizing by proportioning, measure, mix, be transported in granulating disc and utilize span amino acid mother liquor to carry out humidification granule, the granule materials after granulation enters in dryer dries, and obtains masterbatch pellet.
Step C) be once coated with and secondary drying;
Weathered coal is mixed with the weight proportion of bicarbonate of ammonia according to 1:1, seal 48-72 hour up for safekeeping, obtain ammonification humic acid, ammonification humic acid and medium trace element composition and remaining weathered coal and remaining span amino acid mother liquor are fully mixed to get a coating sizing-agent; Masterbatch pellet and a coating sizing-agent are sent into spray granulating machine and carries out slurryspraying granulation process, carry out secondary drying after slurryspraying granulation, be cooled to normal temperature subsequently, obtain coated particle;
Step D) secondary coating;
In mixing machine, microbial inoculum and calcium carbonate are carried out metering mixing, preparation becomes applying medicinal powder; In Drug coating groove, white oil, molasses carried out measuring, stir, mix, carry out being heated to 58 DEG C-62 DEG C, preparation becomes Drug coating simultaneously; Applying medicinal powder and Drug coating are sent in coating machine, dressing, face powder process is carried out to the coated particle that step C produces, obtains described containing amino acid whose biological organic and inorganic fertilizer material.
Production method of the present invention is for making the upper outside film of double-baging in female fertile basis at amino-acid compound fertilizer: the first tunic is activation humic acid material, and its equilibrium is coated on fertiliser granulates surface and forms nexine film.Second tunic is the activeconstituents containing microbial inoculum.Tool has the following advantages: 1, improve soil.Humic acid in product, amino acid have slightly acidic, wetting ability, adsorptivity and complexing, can interact with urea, phosphorus, medium trace element etc., obvious stimulating activity is had to the growth of crop, also be improved soil physical property simultaneously, increase soil aggregate, thus make loosing soil, reduce soil compaction, be conducive to water conservation, fertilizer conservation, ventilation and promotion root system development, for farm crop provide comfortable growing environment.Product is rich in probiotics, soil beneficial microorganism quantity can be promoted with active, promote that soil aggregate is formed, improve soil water-reataining fertilizer-keeping and nutrient-supply capacity, reduce aluminum ions murder by poisoning or the too high murder by poisoning of salt concentration, prevent moisture and nutrient loss, strengthen soil buffer performance, improvement soil compaction, improves ecological environment of soil.2, Crop yield and quality is improved.Probiotics, humic acids and amino acid can improve the activity of multiple enzyme, strengthen the redox processes done in object, crop is impelled to grow fast, promote the absorption of crop metabolism and various nutrient, promote seed germination, root growth and water suction fertilizer sucting ability, increase plant and divide evil and branch quantity, improve soil to the absorption of sunlight and crop to the utilization of luminous energy, thus stimulate plant growth, improve crop yield and quality.3, chemical fertilizer utilization ratio is improved.Have employed in granulation process and wrapped up inorganics amino acid, humic acid with organism nitrogen-phosphorus-potassium compound fertilizer for core core, slow down the rate of release of K nutrition element, thus improve its available nutrient utilization ratio; Product of the present invention is rich in organic matter and probiotics on the one hand, phosphorus effectuation can be impelled under microbiobacterial agent and humic acid, amino acid whose effect, reduce phosphorus fixation, greatly improve the utilization ratio of phosphorus element, can reach and improve chemical fertilizer utilization ratio, the problem because alleviating the environmental pollution using chemical fertilizer to cause being reached again, also can reduce fertilizer application amount simultaneously, economize on resources, avoid the high investment low yield occurred in agriculture production to go out phenomenon.
Embodiment
Embodiment 1:
A kind of containing amino acid whose biological organic and inorganic fertilizer material, it is characterized in that being made up of the composition of following weight proportion:
Weathered coal 100-150
Bicarbonate of ammonia 10-15
Urea 160-250
Monoammonium phosphate 180-250
Potassium sulfate 180-250
Wilkinite 30-50
Span amino acid mother liquor 250-300
Microbial inoculum 5
Molasses 2
White oil 8
Calcium carbonate 1;
Above-mentioned weathered coal is powdery mud coal or brown coal, and containing organic 65%, moisture is less than 20%; Calcium carbonate adopts superfine light calcium carbonate.Microbial inoculum adopts the mixture being of value to the multi-cultur es such as the genus bacillus of plant-growth, rhizopus, streptomycete, colloid bacillus cereus, silicate bacteria and photosynthetic bacteria, milk-acid bacteria, yeast, and its proportioning can be allocated as required flexibly.
Described molasses are the concentrated molasses fermented liquid in sugar production process, containing xanthohumic acid 20%, and N P and K total content 8%, amino acid 5%, crude protein 10%, mineral element 20%.
Above-mentioned a kind of manufacture method containing amino acid whose biological organic and inorganic fertilizer material, comprises the steps:
Steps A) preparation of span amino acid mother liquor;
By the animal hair after degreasing and the hydrochloric acid ratio mix and blend according to weight ratio 1:2, the concentration of described hydrochloric acid is 25%-30%, control temperature, at 114-118 DEG C, is hydrolyzed 10-12 hour, then Temperature fall, when temperature is down to 80 ± 5 DEG C, filtered while hot, except de-black detritus, adding concentration is hydrochloric acid in the potassium hydroxide aqueous solution of 10% and residual, obtain being hydrolyzed filtrate, the consumption of described potassium hydroxide aqueous solution is 0.6-1.0 times of animal hair weight;---stop the injection of liquefied ammonia when 5.0, continue stirring 30---60 minutes, then leaves standstill 10-12 hour, obtains span amino acid mother liquor to pass into liquefied ammonia subsequently in hydrolysis filtrate, simultaneously turn on agitator, until the pH value of hydrolysis filtrate reaches 4.8; Wherein containing organic 70%, moisture 60%, pH value 5-6, amino acid 33%, N P and K total amount 8%.
Step B) preparation of masterbatch pellet;
Urea, monoammonium phosphate, potassium sulfate, wilkinite to be carried out respectively pulverizing by proportioning, measure, mix, be transported in granulating disc and utilize span amino acid mother liquor to carry out humidification granule, the granule materials after granulation enters in dryer dries, and obtains masterbatch pellet.
Step C) be once coated with and secondary drying;
Weathered coal is mixed with the weight proportion of bicarbonate of ammonia according to 1:1, seals 48-72 hour up for safekeeping, obtain ammonification humic acid, ammonification humic acid and remaining weathered coal and remaining span amino acid mother liquor are fully mixed to get a coating sizing-agent; Masterbatch pellet and a coating sizing-agent are sent into spray granulating machine and carries out slurryspraying granulation process, carry out secondary drying after slurryspraying granulation, be cooled to normal temperature subsequently, obtain coated particle;
Step D) secondary coating;
In mixing machine, microbial inoculum and calcium carbonate are carried out metering mixing, preparation becomes applying medicinal powder; In Drug coating groove, white oil, molasses carried out measuring, stir, mix, carry out being heated to 58 DEG C-62 DEG C, preparation becomes Drug coating simultaneously; Applying medicinal powder and Drug coating are sent in coating machine, dressing, face powder process is carried out to the coated particle that step C produces, obtains described containing amino acid whose biological organic and inorganic fertilizer material.
Embodiment 2:
Described one, containing amino acid whose biological organic and inorganic fertilizer material, also contains by the medium trace element composition of following weight proportion:
Magnesium sulfate 7, zinc sulfate 3, ferrous sulfate 7, borax 3.
Its manufacture method comprises the steps:
Steps A) preparation of span amino acid mother liquor;
By the animal hair after degreasing and the hydrochloric acid ratio mix and blend according to weight ratio 1:2, the concentration of described hydrochloric acid is 25%-30%, control temperature, at 114-118 DEG C, is hydrolyzed 10-12 hour, then Temperature fall, when temperature is down to 80 ± 5 DEG C, filtered while hot, except de-black detritus, adding concentration is hydrochloric acid in the potassium hydroxide aqueous solution of 10% and residual, obtain being hydrolyzed filtrate, the consumption of described potassium hydroxide aqueous solution is 0.6-1.0 times of animal hair weight;---stop the injection of liquefied ammonia when 5.0, continue stirring 30---60 minutes, then leaves standstill 10-12 hour, obtains span amino acid mother liquor to pass into liquefied ammonia subsequently in hydrolysis filtrate, simultaneously turn on agitator, until the pH value of hydrolysis filtrate reaches 4.8;
Step B) preparation of masterbatch pellet;
Urea, monoammonium phosphate, potassium sulfate, wilkinite to be carried out respectively pulverizing by proportioning, measure, mix, be transported in granulating disc and utilize span amino acid mother liquor to carry out humidification granule, the granule materials after granulation enters in dryer dries, and obtains masterbatch pellet.
Step C) be once coated with and secondary drying;
Weathered coal is mixed with the weight proportion of bicarbonate of ammonia according to 1:1, seal 48-72 hour up for safekeeping, obtain ammonification humic acid, ammonification humic acid and medium trace element composition and remaining weathered coal and remaining span amino acid mother liquor are fully mixed to get a coating sizing-agent; Masterbatch pellet and a coating sizing-agent are sent into spray granulating machine and carries out slurryspraying granulation process, carry out secondary drying after slurryspraying granulation, be cooled to normal temperature subsequently, obtain coated particle;
Step D) secondary coating;
In mixing machine, microbial inoculum and calcium carbonate are carried out metering mixing, preparation becomes applying medicinal powder; In Drug coating groove, white oil, molasses carried out measuring, stir, mix, carry out being heated to 58 DEG C-62 DEG C, preparation becomes Drug coating simultaneously; Applying medicinal powder and Drug coating are sent in coating machine, dressing, face powder process is carried out to the coated particle that step C produces, obtains described containing amino acid whose biological organic and inorganic fertilizer material.
Claims (4)
1., containing an amino acid whose biological organic and inorganic fertilizer material, it is characterized in that being made up of the composition of following weight proportion:
Weathered coal 100-150
Bicarbonate of ammonia 10-15
Urea 160-250
Monoammonium phosphate 180-250
Potassium sulfate 180-250
Wilkinite 30-50
Span amino acid mother liquor 250-300
Microbial inoculum 5
Molasses 2
White oil 8
Calcium carbonate 1;
Described molasses are the concentrated molasses fermented liquid in sugar production process, containing xanthohumic acid 20%, and N P and K total content 8%, amino acid 5%, crude protein 10%, mineral element 20%.
2. one according to claim 1 is containing amino acid whose biological organic and inorganic fertilizer material, it is characterized in that also containing the medium trace element composition by following weight proportion:
Magnesium sulfate 7, zinc sulfate 3, ferrous sulfate 7, borax 3.
3. a kind of manufacture method containing amino acid whose biological organic and inorganic fertilizer material as claimed in claim 1, is characterized in that comprising the steps:
Steps A) preparation of span amino acid mother liquor;
By the animal hair after degreasing and the hydrochloric acid ratio mix and blend according to weight ratio 1:2, the concentration of described hydrochloric acid is 25%-30%, control temperature, at 114-118 DEG C, is hydrolyzed 10-12 hour, then Temperature fall, when temperature is down to 80 ± 5 DEG C, filtered while hot, except de-black detritus, adding concentration is hydrochloric acid in the potassium hydroxide aqueous solution of 10% and residual, obtain being hydrolyzed filtrate, the consumption of described potassium hydroxide aqueous solution is 0.6-1.0 times of animal hair weight;---stop the injection of liquefied ammonia when 5.0, continue stirring 30---60 minutes, then leaves standstill 10-12 hour, obtains span amino acid mother liquor to pass into liquefied ammonia subsequently in hydrolysis filtrate, simultaneously turn on agitator, until the pH value of hydrolysis filtrate reaches 4.8;
Step B) preparation of masterbatch pellet;
Urea, monoammonium phosphate, potassium sulfate, wilkinite to be carried out respectively pulverizing by proportioning, measure, mix, be transported in granulating disc and utilize span amino acid mother liquor to carry out humidification granule, the granule materials after granulation enters in dryer dries, and obtains masterbatch pellet.
Step C) be once coated with and secondary drying;
Weathered coal is mixed with the weight proportion of bicarbonate of ammonia according to 1:1, seals 48-72 hour up for safekeeping, obtain ammonification humic acid, ammonification humic acid and remaining weathered coal and remaining span amino acid mother liquor are fully mixed to get a coating sizing-agent; Masterbatch pellet and a coating sizing-agent are sent into spray granulating machine and carries out slurryspraying granulation process, carry out secondary drying after slurryspraying granulation, be cooled to normal temperature subsequently, obtain coated particle;
Step D) secondary coating;
In mixing machine, microbial inoculum and calcium carbonate are carried out metering mixing, preparation becomes applying medicinal powder; In Drug coating groove, white oil, molasses carried out measuring, stir, mix, carry out being heated to 58 DEG C-62 DEG C, preparation becomes Drug coating simultaneously; Applying medicinal powder and Drug coating are sent in coating machine, dressing, face powder process is carried out to the coated particle that step C produces, obtains described containing amino acid whose biological organic and inorganic fertilizer material.
4. a kind of manufacture method containing amino acid whose biological organic and inorganic fertilizer material as claimed in claim 2, is characterized in that comprising the steps:
Steps A) preparation of span amino acid mother liquor;
By the animal hair after degreasing and the hydrochloric acid ratio mix and blend according to weight ratio 1:2, the concentration of described hydrochloric acid is 25%-30%, control temperature, at 114-118 DEG C, is hydrolyzed 10-12 hour, then Temperature fall, when temperature is down to 80 ± 5 DEG C, filtered while hot, except de-black detritus, adding concentration is hydrochloric acid in the potassium hydroxide aqueous solution of 10% and residual, obtain being hydrolyzed filtrate, the consumption of described potassium hydroxide aqueous solution is 0.6-1.0 times of animal hair weight;---stop the injection of liquefied ammonia when 5.0, continue stirring 30---60 minutes, then leaves standstill 10-12 hour, obtains span amino acid mother liquor to pass into liquefied ammonia subsequently in hydrolysis filtrate, simultaneously turn on agitator, until the pH value of hydrolysis filtrate reaches 4.8;
Step B) preparation of masterbatch pellet;
Urea, monoammonium phosphate, potassium sulfate, wilkinite to be carried out respectively pulverizing by proportioning, measure, mix, be transported in granulating disc and utilize span amino acid mother liquor to carry out humidification granule, the granule materials after granulation enters in dryer dries, and obtains masterbatch pellet.
Step C) be once coated with and secondary drying;
Weathered coal is mixed with the weight proportion of bicarbonate of ammonia according to 1:1, seal 48-72 hour up for safekeeping, obtain ammonification humic acid, ammonification humic acid and medium trace element composition and remaining weathered coal and remaining span amino acid mother liquor are fully mixed to get a coating sizing-agent; Masterbatch pellet and a coating sizing-agent are sent into spray granulating machine and carries out slurryspraying granulation process, carry out secondary drying after slurryspraying granulation, be cooled to normal temperature subsequently, obtain coated particle;
Step D) secondary coating;
In mixing machine, microbial inoculum and calcium carbonate are carried out metering mixing, preparation becomes applying medicinal powder; In Drug coating groove, white oil, molasses carried out measuring, stir, mix, carry out being heated to 58 DEG C-62 DEG C, preparation becomes Drug coating simultaneously; Applying medicinal powder and Drug coating are sent in coating machine, dressing, face powder process is carried out to the coated particle that step C produces, obtains described containing amino acid whose biological organic and inorganic fertilizer material.
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