CN109265241A - A kind of gardens slow release fertilizer and preparation method thereof - Google Patents
A kind of gardens slow release fertilizer and preparation method thereof Download PDFInfo
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- CN109265241A CN109265241A CN201811208606.9A CN201811208606A CN109265241A CN 109265241 A CN109265241 A CN 109265241A CN 201811208606 A CN201811208606 A CN 201811208606A CN 109265241 A CN109265241 A CN 109265241A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/22—Improving land use; Improving water use or availability; Controlling erosion
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of gardens slow release fertilizers, including composite chemical fertilizer particle, inhibitor layer, microelement layer, the organic fertilizer bed of material is gentle to release packaging material layer, the composite chemical fertilizer particle is compound fertilizer made of a variety of fertilizer, the inhibitor layer is made of urease inhibitor and nitrification inhibitor, the microelement layer is by industrial residue, mine tailings and attapulgite are constituted, the sustained release packaging material is by ammonium magnesium phosphate, calcium carboxymethylcellulose is constituted, the slow release fertilizer includes following component according to parts by weight: 20-25 parts of urea, 10-15 parts of ammonium phosphate, 10-15 parts of potassium dihydrogen phosphate, 15-20 parts of ammonium dihydrogen phosphate, 5-10 parts of charcoal, 5-10 parts of plant ash, 0.06-3 parts of inhibitor, 15-25 parts of microelement, 15-25 parts of organic fertilizer, packaging material 3-9 parts of sustained release , 2-6 parts of adhesive.The slow release fertilizer contains N P and K necessary to plant, also contains microelement, guarantees that the quality and yield of plant rises, effectively inhibits the loss of nitrogen, provide tilth to a soil, slow-release capability and water holding capacity are strong, do not destroy soil texture.
Description
Technical field
The invention belongs to technical field of fertilizers, and in particular to a kind of gardens slow release fertilizer.
Background technique
China soil is vast, and cultivated area accounts for global 7%, but populous so that per capita area of cultivated farmland is seldom,
The population in the world 22% is supported by the arable land for accounting for the world 7%, and as the process of urbanization causes cultivated area to tail off,
Therefore higher and higher, and the agriculture effect increased production dependent on chemical fertilizer is required to the agricultural volume increase of reduction cultivated area increasingly.It passes
System chemistry faces two large problems in agricultural production use process: first is that fertilizer amount is big, utilization rate is low, China's this season fertilizer benefit
It is 30-35%, phosphate fertilizer utilization efficiency 10-25%, potash fertilizer 35%-50% with rate nitrogenous fertilizer;Second is that chemical fertilizer application is unreasonable, at present
The chemical fertilizer application in China is still based on quick action fertilizer by several times application, and utilization rate is low, and the fertilizer efficiency period is short, and at high cost, pollutes ring
Border.Therefore, the effect for how improving utilization rate of fertilizer, giving full play to fertilizer to plant has China's agricultural sustainable development
Major and immediate significance.Slow release fertilizer is also known as slow-release fertilizer or release and release control fertilizer.Compound in its fertilizer containing nutrient is in soil
Middle rate of release is slow or the available a degree of control of nutrient releasing speed is for the utilization of crop constant absorption.At present
Slow release fertilizer is divided into four major class: synthesis class slightly soluble slow release fertilizer, carrier slow release fertilizer, matrix composite and be glued slow release fertilizer and
Coating coating type slow release fertilizer, but the country is based on coating coating type slow release fertilizer at present, since its slow release effect is preferably general
All over receiving.
Patent 201410130689.X disclose it is a kind of with isobutene pitch two ureas be coated slow release fertilizer and its preparation side
Method, material quality number are as follows: isobutene pitches two ureas and is coated 5~15 parts of potassium chloride, and 6~18 parts of granular urea, resin is coated
20~45 parts of urea, 15~25 parts of Diammonium phosphate (DAP), 10~20 parts of granule potassium chloride, which is coated compared to resin and sulphur
Coating, will not cause secondary pollution to soil, will not destroy soil texture, preserve the ecological environment.But the slow release fertilizer needs
The nutrient that dish after two ureas are completely dissolved starts release kernel, the in this way plant for needing nutrient early period are pitched in isobutene, it appears
Some effect are insufficient, in addition, the effective component of the slow release fertilizer is traditional N P and K, for microelement additive amount very
It is few, it is also necessary to apply fertilizer again, increase fertilising workload and fertilising cost.
Patent 201610749601.1 discloses a kind of preparation method of ureaformaldehyde slow release fertilizer containing composite bacteria agent, the party
Nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, ureaformaldehyde powder and auxiliary material are added in pelletizing drum according to certain mass ratio and are granulated by method, drying, cold
But and after screening, ureaformaldehyde slow release fertilizer is obtained, in pack roller, package oil and composite bacteria agent are injected to ureaformaldehyde slow release fertilizer
Surface, obtains the ureaformaldehyde slow release fertilizer containing composite bacteria agent, the slow release fertilizer using composite bacteria agent good water solubility and be easy to plant
Object is absorbed and utilized, and the growth regulating and induction resistance mechanism that can participate in plant promote the growth of plant, improves plant to bad
The resistance of environment and pest and disease damage.But the slow release fertilizer of the composite bacteria agent in the higher soil for putting into saline and alkaline degree when,
It is easy to cause composite bacteria agent not adapt to environment and mortality, in addition, the package oil of the slow release fertilizer is easily by water-soluble and micro- life
Object decomposes, and on the one hand causes the slow releasing function of ureaformaldehyde slow release fertilizer to reduce, on the other hand leads to composite bacteria agent and ureaformaldehyde slow-release fertilizer
Material directly contact keeps composite bacteria agent dead, so that the slow release fertilizer effect reduces, plant regular period nutritional ingredient is caused to be supplied
Deficiency needs to apply fertilizer again.
Patent 201410656449.3 discloses a kind of preparation method of dedicated carbon-base slow release fertilizer of wheat, including following step
It is rapid: by 50~65 parts of polyethylene wax, 5~10 parts of organic acid, 5~12 parts of starch, 5~10 parts of sodium bicarbonate, alcohols solvent 20~
30 parts of obtained carbon microspheres, by 20~30 parts of carbon microspheres and urea, 10~20 parts of ammonium phosphate, 10~20 parts of ammonium sulfate, water 100~
150 parts of obtained fertilizer matrixes, by 5~7 parts of cashew nut oil, 10~12 parts of hexa, 4~8 parts of polyalcohol and polyisocyanic acid
Coating agent is wrapped on fertilizer matrix and carbon-base slow release fertilizer is made by 2~3 parts of obtained coating agents of ester.The slow release fertilizer improves
The slow release effect of fertilizer has achieved the effect that volume increase.But it is done in the slow release fertilizer using hexa and polyisocyanates
Coating membrane, hexa have corrosivity, cause dermatitis after contacting human body and surprise is itched, and is inflammable, toxic by thermally decomposing
Nitrogen oxide flue gas, polyisocyanates volatility, irritation and toxicity are all bigger, in process of production not only to human injury
It is larger, it is higher for production safety requirement, and also the influence after fertilising for root system of plant is also very big, coating membrane volatilization degradation
Afterwards, it so that slow-release capability reduces, causes effective component release rapidly, the effect that plant constant absorption utilizes is not achieved.
Therefore it develops and application slow release fertilizer, reduces the solution rate of fertilizer, make the fertilizer be successively in slow course of dissolution
Crop provides effective component, injures crop seed, seedling or leaf of burning etc. because local concentration is excessively high when preventing from largely applying
Adverse consequences, to reduce the fertilising period, reduces cost, reaches eco-friendly and guarantor to reach raising chemical fertilizer utilization ratio
Demonstrate,prove the purpose of crop yield.
Summary of the invention
The purpose of the present invention is to provide a kind of gardens slow release fertilizers.
A kind of gardens slow release fertilizer, from inside to outside successively include composite chemical fertilizer particle, inhibitor layer, microelement layer,
The organic fertilizer bed of material, sustained release packaging material layer;The composite chemical fertilizer particle is compound fertilizer made of a variety of fertilizer, the composite chemical fertilizer particle
Partial size be 0.1mm-7mm, the inhibitor layer is made of urease inhibitor and nitrification inhibitor, and the microelement layer is by work
Industry waste residue, mine tailings and attapulgite are constituted, and the sustained release packaging material is made of ammonium magnesium phosphate, calcium carboxymethylcellulose;It is described slow
Release fertilizer includes following component according to parts by weight: 20-25 parts of urea, 10-15 parts of ammonium phosphate, 10-15 parts of potassium dihydrogen phosphate, phosphorus
15-20 parts of acid dihydride ammonium, 5-10 parts of charcoal, 5-10 parts of plant ash, it is 0.06-3 parts of inhibitor, 15-25 parts of microelement, organic
15-25 parts of fertilizer, it is sustained packaging material 3-9 parts, 2-6 parts of adhesive.
The mass ratio of urease inhibitor and nitrification inhibitor is 1:2 in the inhibitor layer, and the urease inhibitor is N-
One or more kinds of in butylthiophosphoric triamide, diphenylphosphoryl diamines, the nitrification inhibitor is by the chloro- 6- trichloromethyl of 2-
It is pyridine, dicyandiamide, one or more kinds of in 3,4- dimethyl pyrazole phosphate.
The mass ratio of industrial residue, mine tailings and attapulgite is 2:2:1, the industrial residue in the microelement layer
For one of scum, copper ashes, molybdenum slag, manganese slag, cadmia, molybdenum slag, waste plaster, blast furnace slag or more than one, the mine tailings
For it is a kind of in boron stone mine tailings, magnesium, iron and silicon hydrochlorate mine tailings, calcium aluminium silicate mine tailings, calcareous carbonate tailings slag or it is a kind of with
On.
The organic fertilizer includes following component according to parts by weight: 2-4 parts of ammoniated peat, 2-4 parts of weathered coal, mud coal 3-
5 parts, 3-5 parts of seaweed, 5-7 parts 5-7 parts of leguminous plant stalk.
The mass ratio of ammonium magnesium phosphate and calcium carboxymethylcellulose is 1:2 in the sustained release packaging material layer, and adhesive is polyethylene
Alcoholic solution.
Preferably, the raw material of the composite chemical fertilizer particle further includes Ba4K2Zn5(B3O6)3(B9O19) 5-10 parts of powder.
Preferably, the raw material of the composite chemical fertilizer particle further includes 5-10 parts of polyhydroxyalkanoates powder.
Preferably, the raw material of the composite chemical fertilizer particle further includes 5-10 parts of lamprophyre mountain flour.
The preparation method of above-mentioned gardens slow release fertilizer carries out in accordance with the following steps:
(1) composite chemical fertilizer is granulated: according to parts by weight, by 20-25 parts of urea, 10-15 parts of ammonium phosphate, potassium dihydrogen phosphate
10-15 parts, 15-20 parts of ammonium dihydrogen phosphate, 5-10 parts of charcoal, 5-10 parts of plant ash, are put into ball mill the 30min that dry grinds, obtain
Mixed dry material is added 2-8 times of water and is sufficiently mixed 30min with high-speed mixer with the stirring rate of 800r/min and mixing is made
Mixed slurry is squeezed into nozzle with high-pressure pump with the pressure of 12-18 megapascal by slurry, is made using pressurization Self-spraying atomizing type
Grain, grain diameter 0.1mm-7mm obtain composite chemical fertilizer particle;
(2) inhibitor layer is wrapped up: according to parts by weight, by 0.02-1 parts of urease inhibitor, 0.04-2 parts of nitrification inhibitor
It is put into ball mill the 1-3h that dry grinds, obtains mixed dry material, mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (1) institute
Compound fertilizer granule mixing is stated, under 10-60 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization
0.5-1.5 parts of poly-vinyl alcohol solution, inhibitor is wrapped in the composite chemical fertilizer particle surface, importing 70-85 DEG C of hot wind makes water
Divide continuous evaporation, obtains intermediate product fertilizer A;
(3) microelement layer is wrapped up: according to parts by weight, by 6-10 parts of industrial residue, 6-10 parts of mine tailings, attapulgite
3-5 parts are put into ball mill the 1-3h that dry grinds, and obtain mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step
(2) the intermediate product fertilizer A mixing, under 10-60 DEG C, the speed conditions of revolving speed 1000r/min, is sprayed by air atomization spray gun
Microelement is wrapped in the surface of intermediate product fertilizer A by poly-vinyl alcohol solution 0.5-1.5 parts of atomization, and importing 70-85 DEG C of hot wind makes
Moisture continuous evaporation obtains intermediate product fertilizer B;
(4) organic matter layer is wrapped up: according to parts by weight, by 2-4 parts of ammoniated peat, 2-4 parts of weathered coal, 3-5 parts of mud coal, sea
3-5 parts of algae, 5-7 parts of leguminous plant stalk be put into ball mill the 1-3h that dry grinds, obtain mixed dry material, by mixed dry material put into disk drum-type
Seed-coating machine or fluidized bed and step (3) the intermediate product fertilizer B are mixed, at 10-60 DEG C, the speed conditions of revolving speed 1000r/min
Under, by 0.5-1.5 parts of air atomization spray gun atomization poly-vinyl alcohol solution, organic matter is wrapped in the table of intermediate product fertilizer B
Face, importing 70-85 DEG C of hot wind makes moisture continuous evaporation, obtains intermediate product fertilizer C.
(5) bundled slow-releasing packaging material layer: according to parts by weight, 1-3 parts of ammonium magnesium phosphate, 2-6 parts of calcium carboxymethylcellulose are put
Enter the 2h that dry grinds in ball mill, mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (3) described centre by mixed dry material
Product fertilizer C mixing, under 10-60 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization polyethylene
0.5-1.5 parts of alcoholic solution, organic matter is wrapped in the surface of intermediate product fertilizer C, importing 70-85 DEG C of hot wind makes moisture continuous steaming
Hair, obtains slow release fertilizer
Preferably, Ba is additionally added in the step (1)4K2Zn5(B3O6)3(B9O19) 5-10 parts of powder or polyhydroxyalkanoates powder
5-10 parts or 5-10 parts of lamprophyre mountain flour.
Beneficial effects of the present invention:
Charcoal and plant ash is added using composite chemical fertilizer particle as kernel in gardens slow release fertilizer prepared by the present invention
Effective fixed fertilizer component, necessary nitrogenous fertilizer, phosphate fertilizer and potash fertilizer needed for adding plant guarantee needed for plant;Pressed down using urase
Preparation and nitrification inhibitor make urease inhibitor inhibit the work of urase in soil as inhibitor layer, and suitably to match
Property, effectively inhibit over a period to come and amidonitrogen is prevented to be converted into ammonium hydroxide and ammonia, nitrification inhibitor can be effective
Inhibit nitrification/denitrifying bacteria activity in soil, reduce ammonium nitrogen and be converted into nitrite nitrogen and nitrate nitrogen, extends ammonium nitrogen and exist
Retention time in soil, to increase the validity period of slow release fertilizer;Microelement layer is with industrial residue, the Industry Wastes such as mine tailings
Material is used as raw material, and waste utilization reduces material cost, attapulgite is furthermore added, and utilizes the chain layer structure of attapulgite
Effective locking microelement and slow release are the lasting release of trace elements of plant, guarantee that plant quality and yield rise;
The organic matters such as ammoniated peat, weathered coal are added in organic matter layer to make, are rich in humic acid, it can be by the direct ammonification of organic matter, furthermore
Seaweed is added and leguminous plant stalk is also greatly improved for soil tilth in addition to having the advantages that organic nitrogenous fertilizer;With phosphorus
Sour magnesium ammonium and calcium carboxymethylcellulose are sustained release packaging material, and slow-release material dissolubility is slow, and slow-release capability and water holding capacity are strong, will not
Secondary pollution is caused to soil, the structure of soil is not destroyed, preserves the ecological environment.
Specific embodiment
The present invention will be further described combined with specific embodiments below.
Embodiment 1
A kind of gardens slow release fertilizer, the raw material including following parts by weight: urea 22.5kg, ammonium phosphate 12.5kg, phosphorus
Acid dihydride potassium 12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, N- butylthiophosphoric triamide
0.5kg, N-serve 1kg, manganese slag 8kg, boron stone mine tailings 8kg, attapulgite 4kg, ammoniated peat 3kg, wind
Change coal 3kg, mud coal 4kg, seaweed 4kg, leguminous plant stalk 6kg, ammonium magnesium phosphate 2kg, calcium carboxymethylcellulose 4kg, polyethylene
Alcoholic solution 4kg.
The preparation method of above-mentioned gardens slow release fertilizer carries out in accordance with the following steps:
(1) composite chemical fertilizer is granulated: according to parts by weight, by urea 22.5kg, ammonium phosphate 12.5kg, potassium dihydrogen phosphate
12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, are put into ball mill the 30min that dry grinds, and must mix
Siccative is added 5 times of water and is sufficiently mixed 30min with high-speed mixer with the stirring rate of 800r/min and mixed slurry is made,
Mixed slurry is squeezed into nozzle with the pressure of 15 megapascal with high-pressure pump, is granulated using pressurization Self-spraying atomizing type, particle
Partial size is 0.1mm-7mm, obtains composite chemical fertilizer particle;
(2) it wraps up inhibitor layer: according to parts by weight, urease inhibitor 0.5kg, nitrification inhibitor 1kg being put into ball milling
Dry grind 2h in machine, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (1) described compound fertilizer
Particle mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Inhibitor is wrapped in the composite chemical fertilizer particle surface by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product fertilizer
Expect A;
(3) wrap up microelement layer: according to parts by weight, by manganese slag 8kg, boron stone mine tailings 8kg, attapulgite 4kg are put
Enter the 2h that dry grinds in ball mill, obtain mixed dry material, by mixed dry material put into disk drum-type seed-coating machine or fluidized bed and step (2) it is described in
Between product fertilizer A mix, under 35 DEG C, the speed conditions of revolving speed 1000r/min, pass through air atomization spray gun atomization polyvinyl alcohol
Microelement is wrapped in the surface of intermediate product fertilizer A by solution 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product
Fertilizer B;
(4) wrap up organic matter layer: according to parts by weight, by ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg,
Leguminous plant stalk 6kg, is put into ball mill the 2h that dry grinds, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or stream
Change bed and step (3) the intermediate product fertilizer B is mixed, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air mist
Change gun spraying poly-vinyl alcohol solution 1kg, organic matter is wrapped in the surface of intermediate product fertilizer B, importing 78 DEG C of hot winds makes water
Divide continuous evaporation, obtains intermediate product fertilizer C;
(5) bundled slow-releasing packaging material layer: according to parts by weight, ammonium magnesium phosphate 2kg, calcium carboxymethylcellulose 4kg are put into ball
Dry grind 2h in grinding machine, mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (3) the intermediate product fertilizer
Expect C mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Organic matter is wrapped in the surface of intermediate product fertilizer C by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains slow release fertilizer.
Embodiment 2
A kind of gardens slow release fertilizer, the raw material including following parts by weight: urea 20kg, ammonium phosphate 10kg, di(2-ethylhexyl)phosphate
Hydrogen potassium 10kg, ammonium dihydrogen phosphate 15kg, charcoal 5kg, the chloro- 6- of plant ash 5kg, N- butylthiophosphoric triamide 0.02kg, 2-
Trichloromethyl pyridine 0.04kg, cadmia 6kg, magnesium, iron and silicon hydrochlorate mine tailings 6kg, attapulgite 3kg, ammoniated peat 2kg, weathered coal
2kg, mud coal 3kg, seaweed 3kg, leguminous plant stalk 5kg, ammonium magnesium phosphate 1kg, calcium carboxymethylcellulose 2kg, polyvinyl alcohol are molten
Liquid 2kg.
The preparation method of above-mentioned gardens slow release fertilizer carries out in accordance with the following steps:
(1) composite chemical fertilizer is granulated: according to parts by weight, urea 20kg, ammonium phosphate 10kg, potassium dihydrogen phosphate 10kg, phosphoric acid
Ammonium dihydrogen 15kg, charcoal 5kg, plant ash 5kg, are put into ball mill the 30min that dry grinds, and obtain mixed dry material, and 2 times of water is added,
It with high-speed mixer with the stirring rate of 800r/min, is sufficiently mixed 30min and mixed slurry is made, with high-pressure pump by mixed slurry
Nozzle is squeezed into the pressure of 12 megapascal, is granulated using pressurization Self-spraying atomizing type, grain diameter 0.1mm-7mm is obtained
Composite chemical fertilizer particle;
(2) inhibitor layer is wrapped up: according to parts by weight, the chloro- 6- trichloromethyl of N- butylthiophosphoric triamide 0.02kg, 2-
Pyridine 0.04kg, is put into ball mill the 1h that dry grinds, and obtains mixed dry material, by mixed dry material put into disk drum-type seed-coating machine or fluidized bed with
Step (1) the compound fertilizer granule mixing, under 10 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun
Inhibitor is wrapped in the composite chemical fertilizer particle surface by atomization poly-vinyl alcohol solution 0.5kg, and importing 70 DEG C of hot winds makes moisture
Continuous evaporation obtains intermediate product fertilizer A;
(3) microelement layer is wrapped up: according to parts by weight, by cadmia 6kg, magnesium, iron and silicon hydrochlorate mine tailings 6kg, attapulgite
3kg is put into ball mill the 1h that dry grinds, and obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (2)
The intermediate product fertilizer A mixing, it is poly- by air atomization spray gun atomization under 10 DEG C, the speed conditions of revolving speed 1000r/min
Microelement is wrapped in the surface of intermediate product fertilizer A by glycohol solution 0.5kg, and importing 70 DEG C of hot winds makes moisture continuous evaporation,
Obtain intermediate product fertilizer B;
(4) wrap up organic matter layer: according to parts by weight, by ammoniated peat 2kg, weathered coal 2kg, mud coal 3kg, seaweed 3kg,
Leguminous plant stalk 5kg, is put into ball mill the 1h that dry grinds, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or stream
Change bed and step (3) the intermediate product fertilizer B is mixed, under 10 DEG C, the speed conditions of revolving speed 1000r/min, passes through air mist
Change gun spraying poly-vinyl alcohol solution 0.5kg, organic matter is wrapped in the surface of intermediate product fertilizer B, importing 70 DEG C of hot winds makes
Moisture continuous evaporation obtains intermediate product fertilizer C;
(5) bundled slow-releasing packaging material layer: according to parts by weight, ammonium magnesium phosphate 1kg, calcium carboxymethylcellulose 2kg are put into ball
Dry grind 2h in grinding machine, mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (3) the intermediate product fertilizer
Expect C mixing, under 10 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Organic matter is wrapped in the surface of intermediate product fertilizer C by 0.5kg, and importing 70 DEG C of hot winds makes moisture continuous evaporation, obtains slow release fertilizer.
Embodiment 3
A kind of gardens slow release fertilizer, the raw material including following parts by weight: urea 25kg, ammonium phosphate 15kg, di(2-ethylhexyl)phosphate
Hydrogen potassium 15kg, ammonium dihydrogen phosphate 20kg, charcoal 10kg, the chloro- 6- tri- of plant ash 10kg, N- butylthiophosphoric triamide 1kg, 2-
Chloromethylpyridine 2kg, cadmia 10kg, magnesium, iron and silicon hydrochlorate mine tailings 10kg, attapulgite 5kg, ammoniated peat 4kg, weathered coal
4kg, mud coal 5kg, seaweed 5kg, leguminous plant stalk 7kg, ammonium magnesium phosphate 3kg, calcium carboxymethylcellulose 6kg, polyvinyl alcohol are molten
Liquid 6kg.
The preparation method of above-mentioned gardens slow release fertilizer carries out in accordance with the following steps:
(1) composite chemical fertilizer is granulated: according to parts by weight, urea 25kg, ammonium phosphate 15kg, potassium dihydrogen phosphate 15kg, phosphoric acid
Ammonium dihydrogen 20kg, charcoal 10kg, plant ash 10kg, are put into ball mill the 30min that dry grinds, and obtain mixed dry material, are added 8 times
Water is sufficiently mixed 30min and mixed slurry is made with high-speed mixer with the stirring rate of 800r/min, will be mixed with high-pressure pump
Slurry squeezes into nozzle with the pressure of 18 megapascal, is granulated using pressurization Self-spraying atomizing type, grain diameter 0.1mm-
7mm obtains composite chemical fertilizer particle;
(2) inhibitor layer is wrapped up: according to parts by weight, the chloro- 6- trichloromethyl pyrrole of N- butylthiophosphoric triamide 1kg, 2-
Pyridine 2kg, is put into ball mill the 3h that dry grinds, and obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step
(1) the compound fertilizer granule mixing, it is spraying by air atomization spray gun under 60 DEG C, the speed conditions of revolving speed 1000r/min
Change poly-vinyl alcohol solution 1.5kg, inhibitor is wrapped in the composite chemical fertilizer particle surface, importing 85 DEG C of hot winds keeps moisture continuous
Evaporation, obtains intermediate product fertilizer A;
(3) microelement layer is wrapped up: according to parts by weight, by cadmia 10kg, magnesium, iron and silicon hydrochlorate mine tailings 10kg, concave convex rod
Native 6kg, is put into ball mill the 3h that dry grinds, and obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step
(2) the intermediate product fertilizer A mixing, it is spraying by air atomization spray gun under 60 DEG C, the speed conditions of revolving speed 1000r/min
Change poly-vinyl alcohol solution 1.5kg, microelement is wrapped in the surface of intermediate product fertilizer A, importing 85 DEG C of hot winds keeps moisture continuous
Evaporation, obtains intermediate product fertilizer B;
(4) wrap up organic matter layer: according to parts by weight, by ammoniated peat 4kg, weathered coal 4kg, mud coal 5kg, seaweed 5kg,
Leguminous plant stalk 7kg, is put into ball mill the 3h that dry grinds, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or stream
Change bed and step (3) the intermediate product fertilizer B is mixed, under 60 DEG C, the speed conditions of revolving speed 1000r/min, passes through air mist
Change gun spraying poly-vinyl alcohol solution 1.5kg, organic matter is wrapped in the surface of intermediate product fertilizer B, importing 85 DEG C of hot winds makes
Moisture continuous evaporation obtains intermediate product fertilizer C;
(5) bundled slow-releasing packaging material layer: according to parts by weight, ammonium magnesium phosphate 3kg, calcium carboxymethylcellulose 6kg are put into ball
Dry grind 2h in grinding machine, mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (3) the intermediate product fertilizer
Expect C mixing, under 60 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Organic matter is wrapped in the surface of intermediate product fertilizer C by 1.5kg, and importing 85 DEG C of hot winds makes moisture continuous evaporation, obtains slow release fertilizer.
Embodiment 4
A kind of gardens slow release fertilizer, the raw material including following parts by weight: urea 22.5kg, ammonium phosphate 12.5kg, phosphorus
Acid dihydride potassium 12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, Ba4K2Zn5(B3O6)3(B9O19) powder
7.5kg, N- butylthiophosphoric triamide 0.5kg, N-serve 1kg, manganese slag 8kg, boron stone mine tailings 8kg are recessed
Convex stick soil 4kg, ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg, leguminous plant stalk 6kg, ammonium magnesium phosphate 2kg,
Calcium carboxymethylcellulose 4kg, poly-vinyl alcohol solution 4kg.
The preparation method of above-mentioned gardens slow release fertilizer carries out in accordance with the following steps:
(1) composite chemical fertilizer is granulated: according to parts by weight, by urea 22.5kg, ammonium phosphate 12.5kg, potassium dihydrogen phosphate
12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, Ba4K2Zn5(B3O6)3(B9O19) powder 7.5kg, it puts
Enter the 30min that dry grinds in ball mill, obtain mixed dry material, 5 times of water is added, with high-speed mixer with the stirring rate of 800r/min,
It is sufficiently mixed 30min and mixed slurry is made, mixed slurry is squeezed into nozzle with the pressure of 15 megapascal with high-pressure pump, certainly using pressurization
Spray formula atomizing type is granulated, and grain diameter 0.1mm-7mm obtains composite chemical fertilizer particle;
(2) it wraps up inhibitor layer: according to parts by weight, urease inhibitor 0.5kg, nitrification inhibitor 1kg being put into ball milling
Dry grind 2h in machine, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (1) described compound fertilizer
Particle mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Inhibitor is wrapped in the composite chemical fertilizer particle surface by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product fertilizer
Expect A;
(3) wrap up microelement layer: according to parts by weight, by manganese slag 8kg, boron stone mine tailings 8kg, attapulgite 4kg are put
Enter the 2h that dry grinds in ball mill, obtain mixed dry material, by mixed dry material put into disk drum-type seed-coating machine or fluidized bed and step (2) it is described in
Between product fertilizer A mix, under 35 DEG C, the speed conditions of revolving speed 1000r/min, pass through air atomization spray gun atomization polyvinyl alcohol
Microelement is wrapped in the surface of intermediate product fertilizer A by solution 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product
Fertilizer B;
(4) wrap up organic matter layer: according to parts by weight, by ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg,
Leguminous plant stalk 6kg, is put into ball mill the 2h that dry grinds, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or stream
Change bed and step (3) the intermediate product fertilizer B is mixed, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air mist
Change gun spraying poly-vinyl alcohol solution 1kg, organic matter is wrapped in the surface of intermediate product fertilizer B, importing 78 DEG C of hot winds makes water
Divide continuous evaporation, obtains intermediate product fertilizer C;
(5) bundled slow-releasing packaging material layer: according to parts by weight, ammonium magnesium phosphate 2kg, calcium carboxymethylcellulose 4kg are put into ball
Dry grind 2h in grinding machine, mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (3) the intermediate product fertilizer
Expect C mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Organic matter is wrapped in the surface of intermediate product fertilizer C by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains slow release fertilizer.
Embodiment 5
A kind of gardens slow release fertilizer, the raw material including following parts by weight: urea 22.5kg, ammonium phosphate 12.5kg, phosphorus
Acid dihydride potassium 12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, polyhydroxyalkanoates powder 7.5kg,
N- butylthiophosphoric triamide 0.5kg, N-serve 1kg, manganese slag 8kg, boron stone mine tailings 8kg, attapulgite
4kg, ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg, leguminous plant stalk 6kg, ammonium magnesium phosphate 2kg, carboxymethyl
Cellulose calcium 4kg, poly-vinyl alcohol solution 4kg.
The preparation method of above-mentioned gardens slow release fertilizer carries out in accordance with the following steps:
(1) composite chemical fertilizer is granulated: according to parts by weight, by urea 22.5kg, ammonium phosphate 12.5kg, potassium dihydrogen phosphate
12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, polyhydroxyalkanoates powder 7.5kg, are put into ball milling
Dry grind 30min in machine, obtains mixed dry material, and 5 times of water is added, sufficiently mixed with high-speed mixer with the stirring rate of 800r/min
It closes 30min and mixed slurry is made, mixed slurry is squeezed into nozzle with the pressure of 15 megapascal with high-pressure pump, utilize pressurization Self-spraying mist
Change mode is granulated, and grain diameter 0.1mm-7mm obtains composite chemical fertilizer particle;
(2) it wraps up inhibitor layer: according to parts by weight, urease inhibitor 0.5kg, nitrification inhibitor 1kg being put into ball milling
Dry grind 2h in machine, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (1) described compound fertilizer
Particle mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Inhibitor is wrapped in the composite chemical fertilizer particle surface by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product fertilizer
Expect A;
(3) wrap up microelement layer: according to parts by weight, by manganese slag 8kg, boron stone mine tailings 8kg, attapulgite 4kg are put
Enter the 2h that dry grinds in ball mill, obtain mixed dry material, by mixed dry material put into disk drum-type seed-coating machine or fluidized bed and step (2) it is described in
Between product fertilizer A mix, under 35 DEG C, the speed conditions of revolving speed 1000r/min, pass through air atomization spray gun atomization polyvinyl alcohol
Microelement is wrapped in the surface of intermediate product fertilizer A by solution 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product
Fertilizer B;
(4) wrap up organic matter layer: according to parts by weight, by ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg,
Leguminous plant stalk 6kg, is put into ball mill the 2h that dry grinds, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or stream
Change bed and step (3) the intermediate product fertilizer B is mixed, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air mist
Change gun spraying poly-vinyl alcohol solution 1kg, organic matter is wrapped in the surface of intermediate product fertilizer B, importing 78 DEG C of hot winds makes water
Divide continuous evaporation, obtains intermediate product fertilizer C;
(5) bundled slow-releasing packaging material layer: according to parts by weight, ammonium magnesium phosphate 2kg, calcium carboxymethylcellulose 4kg are put into ball
Dry grind 2h in grinding machine, mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (3) the intermediate product fertilizer
Expect C mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Organic matter is wrapped in the surface of intermediate product fertilizer C by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains slow release fertilizer.
Embodiment 6
A kind of gardens slow release fertilizer, the raw material including following parts by weight: urea 22.5kg, ammonium phosphate 12.5kg, phosphorus
Acid dihydride potassium 12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, lamprophyre mountain flour 7.5kg, N- fourth
Base thiophosphoryl triamide 0.5kg, N-serve 1kg, manganese slag 8kg, boron stone mine tailings 8kg, attapulgite 4kg,
Ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg, leguminous plant stalk 6kg, ammonium magnesium phosphate 2kg, carboxymethyl cellulose
Plain calcium 4kg, poly-vinyl alcohol solution 4kg.
The preparation method of above-mentioned gardens slow release fertilizer carries out in accordance with the following steps:
(1) composite chemical fertilizer is granulated: according to parts by weight, by urea 22.5kg, ammonium phosphate 12.5kg, potassium dihydrogen phosphate
12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, lamprophyre mountain flour 7.5kg, are put into ball mill
Dry grind 30min, obtains mixed dry material, and 5 times of water is added and is sufficiently mixed with high-speed mixer with the stirring rate of 800r/min
Mixed slurry is made in 30min, and mixed slurry is squeezed into nozzle with the pressure of 15 megapascal with high-pressure pump, is atomized using pressurization Self-spraying
Mode is granulated, and grain diameter 0.1mm-7mm obtains composite chemical fertilizer particle;
(2) it wraps up inhibitor layer: according to parts by weight, urease inhibitor 0.5kg, nitrification inhibitor 1kg being put into ball milling
Dry grind 2h in machine, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (1) described compound fertilizer
Particle mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Inhibitor is wrapped in the composite chemical fertilizer particle surface by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product fertilizer
Expect A;
(3) wrap up microelement layer: according to parts by weight, by manganese slag 8kg, boron stone mine tailings 8kg, attapulgite 4kg are put
Enter the 2h that dry grinds in ball mill, obtain mixed dry material, by mixed dry material put into disk drum-type seed-coating machine or fluidized bed and step (2) it is described in
Between product fertilizer A mix, under 35 DEG C, the speed conditions of revolving speed 1000r/min, pass through air atomization spray gun atomization polyvinyl alcohol
Microelement is wrapped in the surface of intermediate product fertilizer A by solution 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product
Fertilizer B;
(4) wrap up organic matter layer: according to parts by weight, by ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg,
Leguminous plant stalk 6kg, is put into ball mill the 2h that dry grinds, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or stream
Change bed and step (3) the intermediate product fertilizer B is mixed, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air mist
Change gun spraying poly-vinyl alcohol solution 1kg, organic matter is wrapped in the surface of intermediate product fertilizer B, importing 78 DEG C of hot winds makes water
Divide continuous evaporation, obtains intermediate product fertilizer C;
(5) bundled slow-releasing packaging material layer: according to parts by weight, ammonium magnesium phosphate 2kg, calcium carboxymethylcellulose 4kg are put into ball
Dry grind 2h in grinding machine, mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (3) the intermediate product fertilizer
Expect C mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Organic matter is wrapped in the surface of intermediate product fertilizer C by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains slow release fertilizer.
Embodiment 7
A kind of gardens slow release fertilizer, the raw material including following parts by weight: urea 22.5kg, ammonium phosphate 12.5kg, phosphorus
Acid dihydride potassium 12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, flesite mountain flour 7.5kg, N- fourth
Base thiophosphoryl triamide 0.5kg, N-serve 1kg, manganese slag 8kg, boron stone mine tailings 8kg, attapulgite 4kg,
Ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg, leguminous plant stalk 6kg, ammonium magnesium phosphate 2kg, carboxymethyl cellulose
Plain calcium 4kg, poly-vinyl alcohol solution 4kg.
The preparation method of above-mentioned gardens slow release fertilizer carries out in accordance with the following steps:
(1) composite chemical fertilizer is granulated: according to parts by weight, by urea 22.5kg, ammonium phosphate 12.5kg, potassium dihydrogen phosphate
12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, flesite mountain flour 7.5kg, are put into ball mill
Dry grind 30min, obtains mixed dry material, and 5 times of water is added and is sufficiently mixed with high-speed mixer with the stirring rate of 800r/min
Mixed slurry is made in 30min, and mixed slurry is squeezed into nozzle with the pressure of 15 megapascal with high-pressure pump, is atomized using pressurization Self-spraying
Mode is granulated, and grain diameter 0.1mm-7mm obtains composite chemical fertilizer particle;
(2) it wraps up inhibitor layer: according to parts by weight, urease inhibitor 0.5kg, nitrification inhibitor 1kg being put into ball milling
Dry grind 2h in machine, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (1) described compound fertilizer
Particle mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Inhibitor is wrapped in the composite chemical fertilizer particle surface by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product fertilizer
Expect A;
(3) wrap up microelement layer: according to parts by weight, by manganese slag 8kg, boron stone mine tailings 8kg, attapulgite 4kg are put
Enter the 2h that dry grinds in ball mill, obtain mixed dry material, by mixed dry material put into disk drum-type seed-coating machine or fluidized bed and step (2) it is described in
Between product fertilizer A mix, under 35 DEG C, the speed conditions of revolving speed 1000r/min, pass through air atomization spray gun atomization polyvinyl alcohol
Microelement is wrapped in the surface of intermediate product fertilizer A by solution 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product
Fertilizer B;
(4) wrap up organic matter layer: according to parts by weight, by ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg,
Leguminous plant stalk 6kg, is put into ball mill the 2h that dry grinds, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or stream
Change bed and step (3) the intermediate product fertilizer B is mixed, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air mist
Change gun spraying poly-vinyl alcohol solution 1kg, organic matter is wrapped in the surface of intermediate product fertilizer B, importing 78 DEG C of hot winds makes water
Divide continuous evaporation, obtains intermediate product fertilizer C;
(5) bundled slow-releasing packaging material layer: according to parts by weight, ammonium magnesium phosphate 2kg, calcium carboxymethylcellulose 4kg are put into ball
Dry grind 2h in grinding machine, mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (3) the intermediate product fertilizer
Expect C mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Organic matter is wrapped in the surface of intermediate product fertilizer C by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains slow release fertilizer.
Embodiment 8
A kind of gardens slow release fertilizer, the raw material including following parts by weight: urea 22.5kg, ammonium phosphate 12.5kg, phosphorus
Acid dihydride potassium 12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, Ca2Na(Ca0.09Na0.41)(B5O8
(OH)2)(CO3) powder 7.5kg, N- butylthiophosphoric triamide 0.5kg, N-serve 1kg, manganese slag 8kg, boron stone
Mine tailings 8kg, attapulgite 4kg, ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg, leguminous plant stalk 6kg,
Ammonium magnesium phosphate 2kg, calcium carboxymethylcellulose 4kg, poly-vinyl alcohol solution 4kg.
The preparation method of above-mentioned gardens slow release fertilizer carries out in accordance with the following steps:
(1) composite chemical fertilizer is granulated: according to parts by weight, by urea 22.5kg, ammonium phosphate 12.5kg, potassium dihydrogen phosphate
12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, Ca2Na(Ca0.09Na0.41)(B5O8(OH)2)
(CO3) powder 7.5kg, it is put into ball mill the 30min that dry grinds, obtains mixed dry material, 5 times of water is added, with high-speed mixer with 800r/
The stirring rate of min is sufficiently mixed 30min and mixed slurry is made, and is squeezed into mixed slurry with the pressure of 15 megapascal with high-pressure pump
Nozzle is granulated using pressurization Self-spraying atomizing type, and grain diameter 0.1mm-7mm obtains composite chemical fertilizer particle;
(2) it wraps up inhibitor layer: according to parts by weight, urease inhibitor 0.5kg, nitrification inhibitor 1kg being put into ball milling
Dry grind 2h in machine, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (1) described compound fertilizer
Particle mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Inhibitor is wrapped in the composite chemical fertilizer particle surface by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product fertilizer
Expect A;
(3) wrap up microelement layer: according to parts by weight, by manganese slag 8kg, boron stone mine tailings 8kg, attapulgite 4kg are put
Enter the 2h that dry grinds in ball mill, obtain mixed dry material, by mixed dry material put into disk drum-type seed-coating machine or fluidized bed and step (2) it is described in
Between product fertilizer A mix, under 35 DEG C, the speed conditions of revolving speed 1000r/min, pass through air atomization spray gun atomization polyvinyl alcohol
Microelement is wrapped in the surface of intermediate product fertilizer A by solution 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains intermediate product
Fertilizer B;
(4) wrap up organic matter layer: according to parts by weight, by ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg,
Leguminous plant stalk 6kg, is put into ball mill the 2h that dry grinds, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or stream
Change bed and step (3) the intermediate product fertilizer B is mixed, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air mist
Change gun spraying poly-vinyl alcohol solution 1kg, organic matter is wrapped in the surface of intermediate product fertilizer B, importing 78 DEG C of hot winds makes water
Divide continuous evaporation, obtains intermediate product fertilizer C;
(5) bundled slow-releasing packaging material layer: according to parts by weight, ammonium magnesium phosphate 2kg, calcium carboxymethylcellulose 4kg are put into ball
Dry grind 2h in grinding machine, mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (3) the intermediate product fertilizer
Expect C mixing, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air atomization spray gun atomization poly-vinyl alcohol solution
Organic matter is wrapped in the surface of intermediate product fertilizer C by 1kg, and importing 78 DEG C of hot winds makes moisture continuous evaporation, obtains slow release fertilizer.
Comparative example:
A kind of gardens slow release fertilizer, the raw material including following parts by weight: urea 22.5kg, ammonium phosphate 12.5kg, phosphorus
Acid dihydride potassium 12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, ammoniated peat 3kg, weathered coal
3kg, mud coal 4kg, seaweed 4kg, leguminous plant stalk 6kg, poly-vinyl alcohol solution 1kg.
The preparation method of above-mentioned gardens slow release fertilizer carries out in accordance with the following steps:
(1) composite chemical fertilizer is granulated: according to parts by weight, by urea 22.5kg, ammonium phosphate 12.5kg, potassium dihydrogen phosphate
12.5kg, ammonium dihydrogen phosphate 17.5kg, charcoal 7.5kg, plant ash 7.5kg, are put into ball mill the 30min that dry grinds, and must mix
Siccative is added 5 times of water and is sufficiently mixed 30min with high-speed mixer with the stirring rate of 800r/min and mixed slurry is made,
Mixed slurry is squeezed into nozzle with the pressure of 15 megapascal with high-pressure pump, is granulated using pressurization Self-spraying atomizing type, particle
Partial size is 0.1mm-7mm, obtains composite chemical fertilizer particle;
(2) wrap up organic matter layer: according to parts by weight, by ammoniated peat 3kg, weathered coal 3kg, mud coal 4kg, seaweed 4kg,
Leguminous plant stalk 6kg, is put into ball mill the 2h that dry grinds, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or stream
Change bed to mix with step (1) described compound fertilizer granule, under 35 DEG C, the speed conditions of revolving speed 1000r/min, passes through air mist
Change gun spraying poly-vinyl alcohol solution 1kg, organic matter is wrapped in the surface of compound fertilizer granule, importing 78 DEG C of hot winds makes water
Divide continuous evaporation, obtains slow release fertilizer.
Experimental example 1:
It is sample according to slow release fertilizer prepared by the preparation method of embodiment 1-8, comparative example, is formulated according to China " slow
Release fertilizer " dissolution experiment of the above sample of national standard (GB/T 23348-2009) measurement at 25 DEG C, as a result referring to table 1.
Experimental procedure is as follows: the slow release fertilizer prepared according to the preparation method of embodiment 1-8, comparative example respectively weighs 100g
Fertilizer is divided into 10 parts, and every part of 10g (claims standard to 0.01g), is respectively put into the pouch that the nylon wire of 150 μm (100 mesh) is made into
In, after sealing, pouch is respectively put into the vial or plastic bottle of 250mL, adds 200mL water, seals, is placed in 25 DEG C
Biochemical constant incubator in, sample time be for 24 hours, 3d, 7d, 14d, 28d, 56d.When sampling, bottle is turned upside down three times, is made
Strength of fluid in bottle is consistent, moves into the volumetric flask of 250mL, scale is settled to after being cooled to room temperature, then to equipped with fertilizer
250mL water is added in pouch, and biochemical constant incubator is put into after sealing and continues to cultivate.
Accumulative dissolution rate (%)=(fertilizer nutrient Cumulative release amount/fertilizer nutrient total amount) * 100%
The fertilizer nutrient of each time of table 1 adds up dissolution rate (%) (n=10)
Experimental group | Dissolution rate for 24 hours | 3d dissolution rate | 7d dissolution rate | 14d dissolution rate | 28d dissolution rate | 56d dissolution rate |
Comparative example | 17.2±0.4* | 32.8±0.3* | 53.6±0.4* | 68.6±0.4* | 85.1±0.4* | 99.9±0.1* |
Embodiment 1 | 10.3±0.3 | 20.3±0.2 | 35.8±0.2 | 50.8±0.2 | 65.6±0.3 | 85.3±0.2 |
Embodiment 2 | 9.9±0.2 | 19.9±0.1 | 35.2±0.3 | 49.8±0.1 | 66.2±0.1 | 84.5±0.1 |
Embodiment 3 | 11.0±0.1 | 20.2±0.3 | 36.1±0.4 | 51.1±0.3 | 64.2±0.4 | 86.5±0.3 |
Embodiment 4 | 8.1±0.2* | 17.5±0.4* | 30.5±0.2* | 42.6±0.4* | 55.8±0.2* | 74.5±0.4* |
Embodiment 5 | 8.3±0.3* | 17.0±0.2* | 29.8±0.3* | 41.5±0.3* | 54.6±0.2* | 73.6±0.2* |
Embodiment 6 | 7.9±0.3* | 17.2±0.4* | 31.1±0.2* | 40.8±0.3* | 56.1±0.4* | 75.8±0.5* |
Embodiment 7 | 10.3±0.1 | 21.3±0.5 | 36.0±0.1 | 50.2±0.4 | 65.2±0.1 | 85.5±0.1 |
Embodiment 8 | 8.6±0.3* | 16.8±0.3* | 28.6±0.2* | 39.8±0.5* | 53.8±0.1* | 72.6±0.3* |
Note: * represents P < 0.05 compared with example 1 group
As can be seen from Table 1, embodiment 1-4, embodiment 7 is suitable in the accumulative dissolution rate of fertilizer nutrient of each time, does not have
There were significant differences;The fertilizer nutrient of comparative example adds up dissolution rate and is significantly higher than embodiment 1, illustrate comparative example fertilizer slow release ability compared with
It is weak;Embodiment 4-6, embodiment 8 fertilizer nutrient add up dissolution rate be substantially less than embodiment 1, illustrate slow-release capability be higher than implement
Example 1.In 28d, for the accumulative dissolution rate of embodiment 1-8 less than 80%, fertilizer has slow-release capability.
Experimental example 2:
According to embodiment 1-8, comparative example preparation method prepare slow release fertilizer be sample, select ornamental plant Chinese rose into
Row potted plant experiment.
Experimental procedure is as follows: using potted plant growth Chinese rose, basin bore 40cm, bottom diameter 30cm, the high 40cm of basin, every basin dress soil
10kg respectively weighs 500g fertilizer, is divided into 10 according to slow release fertilizer prepared by the preparation method of embodiment 1-8, comparative example
Part, every part of 50g is discharged in the soil, and seed carries out Sand culture before Chinese rose is sowed, and temperature after planting exists at 5-10 DEG C when sowing
Laminin sand is covered on seed, is then sprinkled profoundly water, is waited Chinese roses flower seedling to grow to 3-5 piece leaf and transplanted, every 1 cave of basin, often
1 seedling of cave pours equivalent amount of water on time, after Chinese rose grows 2 months, acquires Chinese rose plant height, stem thickness, root long, root volume, fresh weight amount, Chinese rose
NO3-N and NO2-N content in strain, as a result referring to table 2.
2 Chinese rose data of table acquire (n=10)
Note: * represents P < 0.05 compared with example 1 group
As can be seen from Table 2, the plant height of comparative example, stem thickness, root long, fresh weight dose rate are substantially less than embodiment 1, illustrate to compare
The nutritional ingredient of example is insufficient, causes plant growth short and small, nitrate content, the content of nitrite of comparative example are significantly higher than implementation
Example 1 illustrates that the nutritional ingredient of comparative example is not slow release, causes nutritional ingredient more in plant interior accumulation;Plant height side
Face: embodiment 1-3, embodiment 5, the plant height of embodiment 7 are suitable, are not significantly different, embodiment 4, embodiment 6, embodiment 8
Plant height is significantly higher than embodiment 1;In terms of stem thickness: embodiment 1-3, embodiment 5, the stem thickness of embodiment 7 are suitable, without significance difference
Different, embodiment 4, embodiment 6, the stem thickness of embodiment 8 are significantly higher than embodiment 1;In terms of root long: embodiment 1-3, embodiment 7
Root long is suitable, is not significantly different, embodiment 4-6, embodiment 8 root long be significantly higher than embodiment 1;In terms of fresh weight amount: implementing
Example 1-3, the fresh weight amount of embodiment 7 is suitable, is not significantly different, embodiment 4-6, embodiment 8 fresh weight amount be significantly higher than implementation
Example 1;In terms of NO3-N and NO2-N: embodiment 1-3, the nitrate content of embodiment 7 and content of nitrite are suitable, do not have
Significant difference, embodiment 4-6, the nitrate content of embodiment 8 and content of nitrite are substantially less than embodiment 1, illustrate to implement
Example 4-6, embodiment 8 nutriment be slow release, be consistent substantially with the nutrient absorption rate of plant, avoid fertilizer
Waste.
Claims (10)
1. a kind of gardens slow release fertilizer, which is characterized in that from inside to outside successively include composite chemical fertilizer particle, inhibitor layer, micro-
Secondary element layer, the organic fertilizer bed of material, sustained release packaging material layer;The composite chemical fertilizer particle is compound fertilizer made of a variety of fertilizer, described multiple
The partial size for closing chemical fertilizer granule is 0.1mm-7mm, and the inhibitor layer is made of urease inhibitor and nitrification inhibitor, described micro
Element layer is made of industrial residue, mine tailings and attapulgite, and the sustained release packaging material is by ammonium magnesium phosphate, calcium carboxymethylcellulose structure
At;The slow release fertilizer includes following component according to parts by weight: 20-25 parts of urea, 10-15 parts of ammonium phosphate, potassium dihydrogen phosphate
10-15 parts, 15-20 parts of ammonium dihydrogen phosphate, 5-10 parts of charcoal, 5-10 parts of plant ash, 0.06-3 parts of inhibitor, microelement
15-25 parts, 15-25 parts of organic fertilizer, it is sustained packaging material 3-9 parts, 2-6 parts of adhesive.
2. gardens slow release fertilizer according to claim 1, which is characterized in that urease inhibitor and nitre in the inhibitor layer
The mass ratio for changing inhibitor is 1:2, the urease inhibitor is N- butylthiophosphoric triamide, it is a kind of in diphenylphosphoryl diamines or
More than one, the nitrification inhibitor is by N-serve, dicyandiamide, 3,4- dimethyl pyrazole phosphate one
Kind or more than one.
3. gardens slow release fertilizer according to claim 1, which is characterized in that industrial residue, tail in the microelement layer
The mass ratio of slag and attapulgite is 2:2:1, and the industrial residue is scum, copper ashes, molybdenum slag, manganese slag, cadmia, molybdenum slag, gives up
Abandon gypsum, one of blast furnace slag or more than one, the mine tailings are boron stone mine tailings, magnesium, iron and silicon hydrochlorate mine tailings, calcium aluminium
It is one or more kinds of in silicate mine tailings, calcareous carbonate tailings slag.
4. gardens slow release fertilizer according to claim 1, which is characterized in that the organic fertilizer includes according to parts by weight
Following component: 2-4 parts of ammoniated peat, 2-4 parts of weathered coal, 3-5 parts of mud coal, 3-5 parts of seaweed, 5-7 parts of leguminous plant stalk.
5. gardens slow release fertilizer according to claim 1, which is characterized in that ammonium magnesium phosphate and carboxylic in the sustained release packaging material layer
The mass ratio of methylcellulose calcium is 1:2, and described adhesive is poly-vinyl alcohol solution.
6. gardens slow release fertilizer according to claim 1, which is characterized in that the raw material of the composite chemical fertilizer particle further includes
Ba4K2Zn5(B3O6)3(B9O19) 5-10 parts of powder.
7. gardens slow release fertilizer according to claim 1, which is characterized in that the raw material of the composite chemical fertilizer particle further includes
5-10 parts of polyhydroxyalkanoates powder.
8. gardens slow release fertilizer according to claim 1, which is characterized in that the raw material of the composite chemical fertilizer particle further includes
5-10 parts of lamprophyre mountain flour.
9. the preparation method of gardens slow release fertilizer described in claim 1, which is characterized in that carry out in accordance with the following steps:
(1) composite chemical fertilizer is granulated: according to parts by weight, by 20-25 parts of urea, 10-15 parts of ammonium phosphate, potassium dihydrogen phosphate 10-15
Part, 15-20 parts of ammonium dihydrogen phosphate, 5-10 parts of charcoal, 5-10 parts of plant ash, are put into ball mill the 30min that dry grinds, and must mix dry
Material is added 2-8 times of water and is sufficiently mixed 30min with high-speed mixer with the stirring rate of 800r/min and mixed slurry is made,
Mixed slurry is squeezed into nozzle with the pressure of 12-18 megapascal with high-pressure pump, is granulated using pressurization Self-spraying atomizing type,
Grain partial size is 0.1mm-7mm, obtains composite chemical fertilizer particle;
(2) it wraps up inhibitor layer: according to parts by weight, 0.02-1 parts of urease inhibitor, 0.04-2 parts of nitrification inhibitor being put into
Dry grind 1-3h in ball mill, obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (1) is described multiple
Fertiliser granulates mixing is closed, under 10-60 DEG C, the speed conditions of revolving speed 1000r/min, passes through the poly- second of air atomization spray gun atomization
0.5-1.5 parts of enolate solution, inhibitor is wrapped in the composite chemical fertilizer particle surface, importing 70-85 DEG C of hot wind connects moisture
Continuous evaporation, obtains intermediate product fertilizer A;
(3) microelement layer is wrapped up: according to parts by weight, by 6-10 parts of industrial residue, 6-10 parts of mine tailings, attapulgite 3-5
Part is put into ball mill the 1-3h that dry grinds, and obtains mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (2)
The intermediate product fertilizer A mixing, it is spraying by air atomization spray gun under 10-60 DEG C, the speed conditions of revolving speed 1000r/min
Change poly-vinyl alcohol solution 0.5-1.5 parts, microelement is wrapped in the surface of intermediate product fertilizer A, importing 70-85 DEG C of hot wind makes water
Divide continuous evaporation, obtains intermediate product fertilizer B;
(4) organic matter layer is wrapped up: according to parts by weight, by 2-4 parts of ammoniated peat, 2-4 parts of weathered coal, 3-5 parts of mud coal, seaweed 3-
5 parts, 5-7 parts of leguminous plant stalk are put into ball mill the 1-3h that dry grinds, and obtain mixed dry material, by mixed dry material investment disk drum-type coating
Machine or fluidized bed and step (3) the intermediate product fertilizer B are mixed, and under 10-60 DEG C, the speed conditions of revolving speed 1000r/min, are led to
0.5-1.5 parts of air atomization spray gun atomization poly-vinyl alcohol solution is crossed, organic matter is wrapped in the surface of intermediate product fertilizer B, is led
Entering 70-85 DEG C of hot wind makes moisture continuous evaporation, obtains intermediate product fertilizer C;
(5) bundled slow-releasing packaging material layer: according to parts by weight, 1-3 parts of ammonium magnesium phosphate, 2-6 parts of calcium carboxymethylcellulose are put into ball
Dry grind 2h in grinding machine, mixed dry material, and mixed dry material is put into disk drum-type seed-coating machine or fluidized bed and step (3) the intermediate product fertilizer
Expect C mixing, it is molten by air atomization spray gun atomization polyvinyl alcohol under 10-60 DEG C, the speed conditions of revolving speed 1000r/min
0.5-1.5 parts of liquid, organic matter is wrapped in the surface of intermediate product fertilizer C, importing 70-85 DEG C of hot wind makes moisture continuous evaporation, obtains
Slow release fertilizer.
10. the preparation method of gardens slow release fertilizer according to claim 1, which is characterized in that the step (1) can also add
Enter Ba4K2Zn5(B3O6)3(B9O19) 5-10 parts of 5-10 parts of powder or polyhydroxyalkanoates powder or 5-10 parts of lamprophyre mountain flour.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109761707A (en) * | 2019-03-25 | 2019-05-17 | 成都新柯力化工科技有限公司 | A kind of long-acting sustained-release agent preventing soil acidification and preparation method |
CN111453841A (en) * | 2020-04-29 | 2020-07-28 | 广东亮科环保工程有限公司 | Preparation method of slow-release carbon source hollow rod |
CN114131924A (en) * | 2021-11-08 | 2022-03-04 | 北京卫星制造厂有限公司 | Low-energy-consumption lunar soil solidification simulation forming device and method suitable for lunar surface environment |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB984109A (en) * | 1962-09-28 | 1965-02-24 | Sun Oil Co | Slow release fertilizers |
JP2000178091A (en) * | 1998-12-15 | 2000-06-27 | Daito Hiryo Kk | Slow-release organic liquid compound fertilizer and its production |
CN101343204A (en) * | 2007-07-10 | 2009-01-14 | 南京理工大学 | Environment friendly sulfur coating type sustained-release chemical fertilizer |
CN105777367A (en) * | 2016-03-31 | 2016-07-20 | 太仓市新联粮食生产专业合作社 | Long-acting environment-friendly coated slow release compound fertilizer used for planting oryza sativa and preparation method thereof |
CN105859486A (en) * | 2016-03-31 | 2016-08-17 | 太仓市璜泾新联农机作业专业合作社 | A selenium-rich coated organic compound fertilizer used for strawberry planting and a preparing method thereof |
CN108546198A (en) * | 2018-07-11 | 2018-09-18 | 丽水地乐农业科技合伙企业(普通合伙) | Slow release fertilizer and its preparation method and application |
-
2018
- 2018-10-17 CN CN201811208606.9A patent/CN109265241A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB984109A (en) * | 1962-09-28 | 1965-02-24 | Sun Oil Co | Slow release fertilizers |
JP2000178091A (en) * | 1998-12-15 | 2000-06-27 | Daito Hiryo Kk | Slow-release organic liquid compound fertilizer and its production |
CN101343204A (en) * | 2007-07-10 | 2009-01-14 | 南京理工大学 | Environment friendly sulfur coating type sustained-release chemical fertilizer |
CN105777367A (en) * | 2016-03-31 | 2016-07-20 | 太仓市新联粮食生产专业合作社 | Long-acting environment-friendly coated slow release compound fertilizer used for planting oryza sativa and preparation method thereof |
CN105859486A (en) * | 2016-03-31 | 2016-08-17 | 太仓市璜泾新联农机作业专业合作社 | A selenium-rich coated organic compound fertilizer used for strawberry planting and a preparing method thereof |
CN108546198A (en) * | 2018-07-11 | 2018-09-18 | 丽水地乐农业科技合伙企业(普通合伙) | Slow release fertilizer and its preparation method and application |
Non-Patent Citations (6)
Title |
---|
中华人民共和国科学技术部农村与社会发展司: "《2004中国生物技术发展报告》", 30 September 2005, 中国农业出版社 * |
云南农村干部学院: "《云南农村干部学院系列培训教材 作物营养与合理施肥》", 31 December 2012, 云南人民出版社 * |
冯瑞华等: "《2015年国家执业药师资格考试高分宝典 药学专业知识 1》", 30 June 2015, 中国协和医科大学出版社 * |
宁夏农业综合开发办公室: "《宁夏农业综合开发实用新技术选编》", 31 December 2017, 宁夏人民出版社 * |
张殿印: "《环保知识400问》", 31 December 1988, 冶金工业出版社 * |
杨春平: "《固体废物环境管理丛书 工业固体废物处理与处置》", 30 June 2017, 河南科学技术出版社 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109761707A (en) * | 2019-03-25 | 2019-05-17 | 成都新柯力化工科技有限公司 | A kind of long-acting sustained-release agent preventing soil acidification and preparation method |
CN111453841A (en) * | 2020-04-29 | 2020-07-28 | 广东亮科环保工程有限公司 | Preparation method of slow-release carbon source hollow rod |
CN114131924A (en) * | 2021-11-08 | 2022-03-04 | 北京卫星制造厂有限公司 | Low-energy-consumption lunar soil solidification simulation forming device and method suitable for lunar surface environment |
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