CN101415640B - 锂二次电池正极材料的锂金属磷酸盐的纳米粒子的合成 - Google Patents
锂二次电池正极材料的锂金属磷酸盐的纳米粒子的合成 Download PDFInfo
- Publication number
- CN101415640B CN101415640B CN200680054126.0A CN200680054126A CN101415640B CN 101415640 B CN101415640 B CN 101415640B CN 200680054126 A CN200680054126 A CN 200680054126A CN 101415640 B CN101415640 B CN 101415640B
- Authority
- CN
- China
- Prior art keywords
- lithium
- polyol
- phosphate
- solution
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/45—Phosphates containing plural metal, or metal and ammonium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/IB2006/051061 WO2007113624A1 (en) | 2006-04-06 | 2006-04-06 | Synthesis of nanoparticles of lithium metal phosphate positive material for lithium secondary battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101415640A CN101415640A (zh) | 2009-04-22 |
| CN101415640B true CN101415640B (zh) | 2015-08-12 |
Family
ID=37441613
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200680054126.0A Expired - Fee Related CN101415640B (zh) | 2006-04-06 | 2006-04-06 | 锂二次电池正极材料的锂金属磷酸盐的纳米粒子的合成 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8313863B2 (enExample) |
| EP (1) | EP2004548A1 (enExample) |
| JP (1) | JP5174803B2 (enExample) |
| KR (1) | KR101331457B1 (enExample) |
| CN (1) | CN101415640B (enExample) |
| WO (1) | WO2007113624A1 (enExample) |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1889314A2 (en) * | 2005-06-06 | 2008-02-20 | High Power Lithium S.A. | Lithium rechargeable electrochemical cell |
| KR20070096063A (ko) * | 2005-11-21 | 2007-10-02 | 김재국 | 폴리올 프로세스를 이용한 전극재료 및 그 합성방법 |
| EP1989747B1 (en) * | 2006-02-14 | 2017-04-12 | Dow Global Technologies LLC | Lithium manganese phosphate positive material for lithium secondary battery |
| US8491861B2 (en) * | 2006-05-26 | 2013-07-23 | Eltron Research, Inc. | Synthetic process for preparation of high surface area electroactive compounds for battery applications |
| EP1901388A1 (en) * | 2006-09-14 | 2008-03-19 | High Power Lithium S.A. | Overcharge and overdischarge protection in lithium-ion batteries |
| FR2913680B1 (fr) * | 2007-03-14 | 2009-07-03 | Commissariat Energie Atomique | Synthese d'un compose limpo4 et utilisation comme materiau d'electrode dans un accumulateur au lithium |
| US20080305256A1 (en) * | 2007-06-08 | 2008-12-11 | Conocophillips Company | Method for producing lithium vanadium polyanion powders for batteries |
| EP2015382A1 (en) | 2007-07-13 | 2009-01-14 | High Power Lithium S.A. | Carbon coated lithium manganese phosphate cathode material |
| US20090212267A1 (en) * | 2007-12-22 | 2009-08-27 | Primet Precision Materials, Inc. | Small particle electrode material compositions and methods of forming the same |
| CA2623407A1 (en) * | 2008-02-28 | 2009-08-28 | Hydro-Quebec | Composite electrode material |
| WO2009127901A1 (en) | 2008-04-14 | 2009-10-22 | High Power Lithium S.A. | Lithium metal phosphate/carbon nanocomposites as cathode active materials for secondary lithium batteries |
| US8435677B2 (en) | 2008-08-05 | 2013-05-07 | Dow Global Technologies Llc | Lithium metal phosphate/carbon nanocomposites as cathode active materials for rechargeable lithium batteries |
| US8821763B2 (en) | 2008-09-30 | 2014-09-02 | Tdk Corporation | Active material and method of manufacturing active material |
| JP5396798B2 (ja) | 2008-09-30 | 2014-01-22 | Tdk株式会社 | 活物質材料、それを用いた正極及びリチウムイオン二次電池 |
| TWI474970B (zh) | 2008-12-29 | 2015-03-01 | Basf Se | 於水熱條件下合成鋰-金屬-磷酸鹽 |
| JP5574143B2 (ja) * | 2009-02-18 | 2014-08-20 | トヨタ自動車株式会社 | 正極活物質の製造方法 |
| JP2012523075A (ja) * | 2009-04-01 | 2012-09-27 | ユニバーシティ オブ ザ ウェスタン ケイプ | カーボン複合材料の製造方法 |
| US9225022B2 (en) * | 2009-06-24 | 2015-12-29 | Gs Yuasa International Ltd. | Positive active material for lithium secondary battery and lithium secondary battery |
| US9431649B2 (en) * | 2009-11-23 | 2016-08-30 | Uchicago Argonne, Llc | Coated electroactive materials |
| KR101134474B1 (ko) * | 2009-12-03 | 2012-04-13 | 전남대학교산학협력단 | 급속 충방전이 가능한 리튬 이차전지용 고용량 음극소재 및 그 제조 방법 |
| JP5729802B2 (ja) * | 2009-12-25 | 2015-06-03 | 三菱マテリアル株式会社 | Liイオン電池用正極活物質、およびその製造方法 |
| EP2355214B1 (fr) * | 2010-01-28 | 2013-12-25 | Prayon | Accumulateurs au lithium à base de phosphate de fer lithié et de carbone |
| JP5820566B2 (ja) * | 2010-02-17 | 2015-11-24 | 株式会社Gsユアサ | 正極材料の製造方法 |
| US10170764B2 (en) * | 2010-06-30 | 2019-01-01 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing ultra small particle, positive electrode active material of second battery using the method for manufacturing ultra small particle and method for manufacturing the same, and secondary battery using the positive electrode active material and method for manufacturing the same |
| CN103098273B (zh) * | 2010-09-09 | 2016-03-02 | Sk新技术株式会社 | 锂二次电池的正电极活性材料、其生产方法和包含其的锂二次电池 |
| US8980126B2 (en) * | 2010-10-08 | 2015-03-17 | Semiconductor Energy Laboratory Co., Ltd. | Electrode material and method for manufacturing power storage device |
| US20120088151A1 (en) * | 2010-10-08 | 2012-04-12 | Semiconductor Energy Laboratory Co., Ltd. | Positive-electrode active material and power storage device |
| EP2457588A1 (en) * | 2010-11-05 | 2012-05-30 | UMC Utrecht Holding B.V. | Microsphere comprising a lanthanide metal complex |
| WO2012087916A1 (en) * | 2010-12-21 | 2012-06-28 | Physical Sciences, Inc | Method of forming a metal phosphate coated cathode for improved cathode material safety |
| US9160001B2 (en) * | 2010-12-23 | 2015-10-13 | Wildcat Discovery Technologies, Inc. | Lithium-ion battery materials with improved properties |
| JP5673275B2 (ja) | 2011-03-23 | 2015-02-18 | 住友大阪セメント株式会社 | リチウムイオン電池用正極活物質とその製造方法及びリチウムイオン電池用電極並びにリチウムイオン電池 |
| JP5673274B2 (ja) | 2011-03-23 | 2015-02-18 | 住友大阪セメント株式会社 | リチウムイオン電池用正極活物質とその製造方法及びリチウムイオン電池用電極並びにリチウムイオン電池 |
| JP5664404B2 (ja) * | 2011-03-29 | 2015-02-04 | 東レ株式会社 | 金属化合物−導電剤複合体およびそれを用いてなるリチウム二次電池、および金属化合物−導電剤複合体の製造方法 |
| KR101181323B1 (ko) * | 2011-04-05 | 2012-09-11 | 전남대학교산학협력단 | 폴리올 프로세스를 이용한 리튬화된 전극재료제조방법, 그 방법으로 제조된 리튬화된 전극재료 및 상기 전극재료를 포함하는 2차전지 |
| US9385367B2 (en) | 2011-06-27 | 2016-07-05 | National University Of Singapore | Approach for manufacturing efficient mesoporous nano-composite positive electrode LiMn1-xFexPO4 materials |
| FR2977887B1 (fr) | 2011-07-12 | 2018-01-26 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Phosphate de manganese lithie et materiau composite le comprenant |
| JP5709004B2 (ja) * | 2011-10-14 | 2015-04-30 | トヨタ自動車株式会社 | 二次電池およびその製造方法 |
| CA2876237A1 (en) * | 2012-06-27 | 2014-01-03 | Dow Global Technologies Llc | Low-cost method for making lithium transition metal olivines with high energy density |
| KR101973052B1 (ko) * | 2012-08-10 | 2019-04-26 | 삼성에스디아이 주식회사 | 리튬 금속인산화물의 제조방법 |
| JP2016507452A (ja) * | 2012-12-21 | 2016-03-10 | ダウ グローバル テクノロジーズ エルエルシー | 水/共溶媒混合物を使用してリチウム遷移金属オリビンを作製するための方法 |
| KR101561374B1 (ko) * | 2013-01-10 | 2015-10-19 | 주식회사 엘지화학 | 리튬 인산철 나노분말 제조방법 |
| KR101561378B1 (ko) * | 2013-01-10 | 2015-10-20 | 주식회사 엘지화학 | 탄소 코팅 리튬 인산철 나노분말 제조방법 |
| KR101561376B1 (ko) * | 2013-01-10 | 2015-10-19 | 주식회사 엘지화학 | 리튬 인산철 나노분말 제조방법 |
| CN103123969B (zh) * | 2013-01-22 | 2015-07-29 | 北京大学 | 一种锂离子电池纳米LiMPO4正极材料的制备方法 |
| GB201308654D0 (en) | 2013-05-14 | 2013-06-26 | Faradion Ltd | Metal-containing compounds |
| CN103359701B (zh) * | 2013-06-28 | 2015-10-21 | 清华大学 | 磷酸铁锂的制备方法 |
| KR101580030B1 (ko) * | 2013-07-09 | 2015-12-23 | 주식회사 엘지화학 | 탄소 코팅 리튬 인산철 나노분말의 제조방법 |
| US10340517B2 (en) | 2014-12-05 | 2019-07-02 | Lg Chem, Ltd. | Positive electrode active material, method for preparing the same and lithium secondary battery including the same |
| CN107004841B (zh) * | 2014-12-05 | 2021-08-17 | 株式会社Lg 化学 | 正极活性材料、制备其的方法以及包含其的锂二次电池 |
| CN107428535B (zh) | 2015-03-31 | 2020-12-04 | 东丽株式会社 | 磷酸锰锂纳米颗粒及其制造方法、碳覆盖磷酸锰锂纳米颗粒、碳覆盖磷酸锰锂纳米颗粒造粒体、锂离子电池 |
| US10820588B2 (en) | 2018-08-24 | 2020-11-03 | Wisconsin Alumni Research Foundation | Compositionally and morphologically controlled nanostructures for delivery of micronutrients and suppression of disease in agriculture |
| EP3916842A1 (en) * | 2020-05-29 | 2021-12-01 | Arkema Inc. | Electrode binder composition for lithium ion electrical storage devices |
| CN118420006B (zh) * | 2024-07-05 | 2024-09-17 | 太原工业学院 | 一种多元金属氢氧化物纳米片及其制备方法和应用 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20130038952A (ko) | 2002-06-21 | 2013-04-18 | 상트르 나쇼날 드 라 르세르쒸 시앙티피끄 | 탄소-코팅된 리튬-함유 분말과 이의 제조 방법 |
| DE10353266B4 (de) * | 2003-11-14 | 2013-02-21 | Süd-Chemie Ip Gmbh & Co. Kg | Lithiumeisenphosphat, Verfahren zu seiner Herstellung und seine Verwendung als Elektrodenmaterial |
| KR20070096063A (ko) * | 2005-11-21 | 2007-10-02 | 김재국 | 폴리올 프로세스를 이용한 전극재료 및 그 합성방법 |
| EP1989747B1 (en) * | 2006-02-14 | 2017-04-12 | Dow Global Technologies LLC | Lithium manganese phosphate positive material for lithium secondary battery |
-
2006
- 2006-04-06 JP JP2009503671A patent/JP5174803B2/ja not_active Expired - Fee Related
- 2006-04-06 CN CN200680054126.0A patent/CN101415640B/zh not_active Expired - Fee Related
- 2006-04-06 WO PCT/IB2006/051061 patent/WO2007113624A1/en not_active Ceased
- 2006-04-06 EP EP06727848A patent/EP2004548A1/en not_active Withdrawn
- 2006-04-06 KR KR1020087023271A patent/KR101331457B1/ko not_active Expired - Fee Related
- 2006-04-06 US US12/296,204 patent/US8313863B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
|---|
| Jun Ma, Qi-Zong Qin.Electrochemical performance of nanocrystalline LiMPO4 thin-films prepared by electrostatic spray deposition.《Journal of Power Sources》.2005,第148卷第66-71页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007113624A1 (en) | 2007-10-11 |
| KR101331457B1 (ko) | 2013-11-21 |
| KR20080111019A (ko) | 2008-12-22 |
| US8313863B2 (en) | 2012-11-20 |
| JP2009532323A (ja) | 2009-09-10 |
| CN101415640A (zh) | 2009-04-22 |
| EP2004548A1 (en) | 2008-12-24 |
| JP5174803B2 (ja) | 2013-04-03 |
| US20090186275A1 (en) | 2009-07-23 |
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