CN101384541B - 在催化剂存在下通过单乙二醇和氨的氢化胺化生产亚乙基胺和乙醇胺的方法 - Google Patents

在催化剂存在下通过单乙二醇和氨的氢化胺化生产亚乙基胺和乙醇胺的方法 Download PDF

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CN101384541B
CN101384541B CN2007800054620A CN200780005462A CN101384541B CN 101384541 B CN101384541 B CN 101384541B CN 2007800054620 A CN2007800054620 A CN 2007800054620A CN 200780005462 A CN200780005462 A CN 200780005462A CN 101384541 B CN101384541 B CN 101384541B
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catalyst
reactor
weight
ruthenium
cobalt
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CN101384541A (zh
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G·V·考文贝格
J-P·梅尔德
B·W·霍费尔
T·克鲁格
K·皮肯纳克
F-F·帕佩
E·施瓦布
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
CN2007800054620A 2006-02-14 2007-02-08 在催化剂存在下通过单乙二醇和氨的氢化胺化生产亚乙基胺和乙醇胺的方法 Expired - Fee Related CN101384541B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06101642.4 2006-02-14
EP06101642 2006-02-14
PCT/EP2007/051210 WO2007093552A1 (de) 2006-02-14 2007-02-08 Verfahren zur herstellung von ethylenaminen und ethanolaminen durch hydrierende aminierung von monoethylenglykol und ammoniak in gegenwart eines katalysators

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CN101384541A CN101384541A (zh) 2009-03-11
CN101384541B true CN101384541B (zh) 2012-06-13

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CN2007800054620A Expired - Fee Related CN101384541B (zh) 2006-02-14 2007-02-08 在催化剂存在下通过单乙二醇和氨的氢化胺化生产亚乙基胺和乙醇胺的方法

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US (1) US7635790B2 (enExample)
EP (1) EP1986990B1 (enExample)
JP (1) JP5124486B2 (enExample)
CN (1) CN101384541B (enExample)
WO (1) WO2007093552A1 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005047458A1 (de) * 2005-09-30 2007-04-12 Basf Ag Verfahren zur Herstellung von Aminodiglykol (ADG) und Morpholin
ATE448192T1 (de) 2005-09-30 2009-11-15 Basf Se Verfahren zur herstellung von ethylenaminen
US7696384B2 (en) * 2005-09-30 2010-04-13 Basf Se Process for producing ethyleneamines
JP5656840B2 (ja) * 2008-09-19 2015-01-21 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ アルミニウム−銅触媒を用いた、アミンの連続的な製造方法
DE102011003595B4 (de) 2011-02-03 2014-04-17 Evonik Degussa Gmbh Herstellung von in ihrer Hauptkette linearen primären Diaminen für Polyamidsynthesen
EP3320971A1 (de) * 2016-11-15 2018-05-16 Basf Se Mechanisch stabiler katalysator zur hydrierung von carbonylverbindungen und verfahren zu dessen herstellung
JP6850659B2 (ja) * 2017-03-31 2021-03-31 ルネサスエレクトロニクス株式会社 半導体装置の製造方法
CN111295367B (zh) * 2017-10-27 2024-03-12 巴斯夫欧洲公司 制备亚乙基胺的方法
WO2019081283A1 (de) 2017-10-27 2019-05-02 Basf Se Verfahren zur herstellung von ethylenaminen
CN107857704B (zh) * 2017-11-21 2020-04-10 万华化学集团股份有限公司 一种制备3-氨甲基-3,5,5-三甲基环己胺的方法及用于该方法的催化剂
CN108772074B (zh) * 2018-05-31 2021-01-05 西安近代化学研究所 一种乙二胺加氢制二乙烯三胺的催化剂及其制备方法
WO2020098937A1 (en) * 2018-11-14 2020-05-22 Rhodia Operations Method for producing an amine
CN111116386B (zh) * 2019-12-19 2022-11-08 山东国邦药业有限公司 一种羟乙基乙二胺的合成方法
JP2025503342A (ja) 2022-01-14 2025-02-03 ビーエーエスエフ ソシエタス・ヨーロピア アルカノールアミンの製造又は変換方法
CN119486997A (zh) 2022-06-29 2025-02-18 巴斯夫欧洲公司 用于制造亚乙基胺的方法
CN119451938A (zh) 2022-06-29 2025-02-14 巴斯夫欧洲公司 用于制造亚乙基胺的方法
WO2025216986A1 (en) * 2024-04-09 2025-10-16 Dow Global Technologies Llc Morpholine production
CN119751278B (zh) * 2025-03-04 2025-06-10 中国石油大学(华东) 一种乙醇胺的制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4855505A (en) * 1983-09-09 1989-08-08 Berol Kemi Ab Promoted nickel and/or cobalt catalyst, its use, and process performed in its presence
CN1185995A (zh) * 1996-10-31 1998-07-01 巴斯福股份公司 烯化氧类、醇、醛和酮类胺化用的催化剂

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1172268B (de) * 1962-02-21 1964-06-18 Basf Ag Verfahren zur Herstellung von Diaminen
SE345122B (enExample) * 1966-12-30 1972-05-15 Mo Och Domsjoe Ab
BE757840A (fr) 1969-10-23 1971-04-22 Basf Ag Procede de preparation d'amines a partir d'alcools
US4014933A (en) 1969-10-23 1977-03-29 Basf Aktiengesellschaft Production of amines from alcohols
DE2439275B2 (de) 1974-08-16 1978-09-21 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Diäthylentriamin und Triäthylentetramin aus Äthylendiamin
US4234730A (en) * 1979-09-24 1980-11-18 Texaco Development Corp. Process of preparing selective mixtures of piperazine and ethylenediamine
US4645834A (en) 1980-03-17 1987-02-24 Air Products And Chemicals, Inc. Synthesis of heterocyclic amines via the reaction of dialkylene glycol and ammonia
CA1151646A (en) 1980-03-17 1983-08-09 Randall J. Daughenbaugh Synthesis of heterocyclic amines via the reaction of dialkylene glycol and ammonia
US4647663A (en) 1982-05-25 1987-03-03 Air Products And Chemicals, Inc. Synthesis of morpholine
JPS59115746A (ja) 1982-12-23 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd モルホリン製造用触媒およびその製造法
US4568746A (en) * 1982-12-29 1986-02-04 Union Carbide Corporation Catalytic preparation of diethylenetriamine
US4863890A (en) * 1983-09-09 1989-09-05 Berol Kemi Ab Process for preparing a ruthenium-promoted, halogen-containing nickel and/or cobalt catalyst and a catalyst prepared by the process
CA1300144C (en) * 1985-04-04 1992-05-05 Arthur R. Doumaux, Jr. Conversion of oxygen-containing polyamines
CA1293255C (en) * 1985-04-04 1991-12-17 Arthur Roy Doumaux, Jr. Water addition to enchance phosphoric acid salt catalytic activity
DE3903367A1 (de) 1989-02-04 1990-08-16 Basf Ag Katalysator und verfahren zur hydrierenden aminierung von alkoholen
US5410086A (en) 1989-06-27 1995-04-25 Burgess; Lloyd M. Selective preparation of diethylenetriamine
DE4010227A1 (de) * 1990-03-30 1991-10-02 Basf Ag Verfahren zur herstellung von 3-aminomethyl-3,5,5-trimethyl-cyclohexylamin
US5817593A (en) 1995-06-02 1998-10-06 The Dow Chemical Company Catalyst and process for producing amines
DE19644107A1 (de) * 1996-10-31 1998-05-07 Basf Ag Katalysatoren für die Aminierung von Alkylenoxiden, Alkoholen, Aldehyden und Ketonen
JP3948798B2 (ja) * 1997-10-27 2007-07-25 株式会社日本触媒 アクリル酸の製造方法
DE19826396A1 (de) 1998-06-12 1999-12-16 Basf Ag Verfahren zur Herstellung von Aminen
DE19859776B4 (de) 1998-12-23 2008-06-19 Basf Se Verfahren zur Herstellung von Aminen
DE50007278D1 (de) 1999-12-06 2004-09-09 Basf Ag Verfahren zur Herstellung von Aminen
SE524126C2 (sv) 2001-07-24 2004-06-29 Akzo Nobel Nv Förfarande för framställning av dietylentriamin och högre polyetylenpolyaminer genom transaminering av etylendiamin
DE10211101A1 (de) 2002-03-14 2003-09-25 Basf Ag Katalysatoren und Verfahren zur Herstellung von Aminen
DE10335991A1 (de) * 2003-08-01 2005-02-24 Basf Ag Verfahren zur Herstellung von Ethylenaminen
US7393978B2 (en) 2003-08-01 2008-07-01 Basf Aktiengesellschaft Method for producing ethylene-amines
EP1660539B1 (en) 2003-08-07 2010-06-02 Enkam Pharmaceuticals A/S Compounds comprising lpa
DE10349059A1 (de) 2003-10-17 2005-05-19 Basf Ag Verfahren zur destillativen Auftrennung von Gemischen enthaltend Ethylenamine
DE10359811A1 (de) 2003-12-19 2005-07-21 Basf Ag Verfahren zur Erhöhung der Raum-Zeit-Ausbeute (RZA) in einem Verfahren zur Herstellung eines symmetrischen sekundären Amins
DE102005019373A1 (de) 2005-04-26 2006-11-02 Basf Ag Verfahren zur Herstellung von Ethylenaminen
US7696384B2 (en) 2005-09-30 2010-04-13 Basf Se Process for producing ethyleneamines
DE102005047458A1 (de) 2005-09-30 2007-04-12 Basf Ag Verfahren zur Herstellung von Aminodiglykol (ADG) und Morpholin
ATE448192T1 (de) 2005-09-30 2009-11-15 Basf Se Verfahren zur herstellung von ethylenaminen
DE102005047464A1 (de) 2005-09-30 2007-04-05 Basf Ag Verfahren zur Herstellung von Ethylenaminen

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4855505A (en) * 1983-09-09 1989-08-08 Berol Kemi Ab Promoted nickel and/or cobalt catalyst, its use, and process performed in its presence
CN1185995A (zh) * 1996-10-31 1998-07-01 巴斯福股份公司 烯化氧类、醇、醛和酮类胺化用的催化剂

Also Published As

Publication number Publication date
CN101384541A (zh) 2009-03-11
WO2007093552A1 (de) 2007-08-23
JP2009526810A (ja) 2009-07-23
EP1986990B1 (de) 2013-08-14
EP1986990A1 (de) 2008-11-05
US20090030237A1 (en) 2009-01-29
JP5124486B2 (ja) 2013-01-23
US7635790B2 (en) 2009-12-22

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