CN101346400B - 使乙烯基单体自由基聚合的方法 - Google Patents

使乙烯基单体自由基聚合的方法 Download PDF

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Publication number
CN101346400B
CN101346400B CN2006800494151A CN200680049415A CN101346400B CN 101346400 B CN101346400 B CN 101346400B CN 2006800494151 A CN2006800494151 A CN 2006800494151A CN 200680049415 A CN200680049415 A CN 200680049415A CN 101346400 B CN101346400 B CN 101346400B
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mixture
reaction
grams
acrylate
initiator
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Expired - Fee Related
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CN2006800494151A
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English (en)
Chinese (zh)
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CN101346400A (zh
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马克·F·埃利斯
彼得·A·斯塔克
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F226/10—N-Vinyl-pyrrolidone
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
CN2006800494151A 2005-12-28 2006-12-26 使乙烯基单体自由基聚合的方法 Expired - Fee Related CN101346400B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/275,370 2005-12-28
US11/275,370 US7968661B2 (en) 2005-12-28 2005-12-28 Method of free radically polymerizing vinyl monomers
PCT/US2006/049284 WO2007079080A1 (en) 2005-12-28 2006-12-26 Method of free radically polymerizing vinyl monomers

Publications (2)

Publication Number Publication Date
CN101346400A CN101346400A (zh) 2009-01-14
CN101346400B true CN101346400B (zh) 2012-09-26

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CN2006800494151A Expired - Fee Related CN101346400B (zh) 2005-12-28 2006-12-26 使乙烯基单体自由基聚合的方法

Country Status (8)

Country Link
US (1) US7968661B2 (https=)
EP (1) EP1966249B1 (https=)
JP (1) JP5243266B2 (https=)
KR (1) KR101359775B1 (https=)
CN (1) CN101346400B (https=)
AT (1) ATE536377T1 (https=)
BR (1) BRPI0620711B1 (https=)
WO (1) WO2007079080A1 (https=)

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US7989573B2 (en) * 2005-12-16 2011-08-02 3M Innovative Properties Company Method of free radically polymerizing vinyl monomers
KR101125594B1 (ko) * 2009-08-31 2012-03-22 주식회사 엘지화학 단열 조건을 이용한 발포 폴리스티렌의 제조방법
CN102985467B (zh) 2010-06-29 2014-11-19 3M创新有限公司 由含有氮丙啶基的化合物形成的接枝化合物
CN102985449B (zh) 2010-06-29 2015-08-12 3M创新有限公司 含氮丙啶基的化合物
JP5190097B2 (ja) * 2010-10-21 2013-04-24 住友化学株式会社 重合反応装置及びそれを用いたメタクリル系重合体の製造方法
WO2016133669A1 (en) 2015-02-18 2016-08-25 3M Innovative Properties Company Acrylic adhesive composition from protected photocrosslinking agents
EP3344720B1 (en) 2015-08-31 2020-10-14 3M Innovative Properties Company Articles comprising (meth)acrylate pressure-sensitive adhesive with enhanced adhesion to wet surfaces
WO2017040074A1 (en) 2015-08-31 2017-03-09 3M Innovative Properties Company Negative pressure wound therapy dressings comprising (meth)acrylate pressure-sensitive adhesive with enhanced adhesion to wet surfaces
EP3168237A1 (en) * 2015-11-10 2017-05-17 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
TWI668285B (zh) * 2015-12-31 2019-08-11 長興材料工業股份有限公司 可熱聚合之組合物、由此形成之組成液及其用途
WO2017155644A1 (en) 2016-03-10 2017-09-14 3M Innovative Properties Company Oil resistant adhesive
EP3694946B1 (de) 2017-10-11 2021-11-10 Basf Se Gegen weichmachermigration resistenter, uv-härtbarer schmelzklebstoff für graphikfolien und etiketten aus weich-pvc
CN107815289A (zh) * 2017-11-07 2018-03-20 苏州甫众塑胶有限公司 物流标签纸用胶及其制备方法
JP7063667B2 (ja) * 2018-03-22 2022-05-09 スリーエム イノベイティブ プロパティズ カンパニー 装飾シート
EP3775086B1 (en) 2018-04-05 2022-09-14 3M Innovative Properties Company Gel adhesive comprising crosslinked blend of polydiorganosiloxane and acrylic polymer
WO2021220200A1 (en) 2020-04-29 2021-11-04 3M Innovative Properties Company Hot melt processable adhesive with ionic crosslinkers
CN121532467A (zh) 2023-06-22 2026-02-13 3M创新有限公司 包括可固化粘合剂膜和固体活化剂组合物的粘合剂体系以及相关套件和方法
CN117021643A (zh) * 2023-08-10 2023-11-10 沈阳东阳聚氨酯有限公司 一种复合双层橡胶胶辊的制备方法
DE102024124847A1 (de) * 2024-08-30 2026-03-05 Tesa Se Poly(meth)acrylate, Haftklebmassen und deren Herstellungsverfahren

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CN1209140A (zh) * 1995-12-14 1999-02-24 美国3M公司 使用间歇式反应器进行本体自由基聚合反应
US6479073B1 (en) * 1996-10-07 2002-11-12 3M Innovative Properties Company Pressure sensitive adhesive articles and methods for preparing same
CN1402768A (zh) * 1999-06-09 2003-03-12 3M创新有限公司 有热熔性的压敏导电粘合剂和使用它的生物医学电极

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Publication number Priority date Publication date Assignee Title
CN1209140A (zh) * 1995-12-14 1999-02-24 美国3M公司 使用间歇式反应器进行本体自由基聚合反应
US6479073B1 (en) * 1996-10-07 2002-11-12 3M Innovative Properties Company Pressure sensitive adhesive articles and methods for preparing same
CN1402768A (zh) * 1999-06-09 2003-03-12 3M创新有限公司 有热熔性的压敏导电粘合剂和使用它的生物医学电极

Also Published As

Publication number Publication date
US7968661B2 (en) 2011-06-28
EP1966249A4 (en) 2009-07-29
BRPI0620711A2 (pt) 2011-11-22
BRPI0620711B1 (pt) 2018-10-16
EP1966249B1 (en) 2011-12-07
ATE536377T1 (de) 2011-12-15
JP5243266B2 (ja) 2013-07-24
WO2007079080A1 (en) 2007-07-12
JP2009522411A (ja) 2009-06-11
CN101346400A (zh) 2009-01-14
KR101359775B1 (ko) 2014-02-06
US20070149698A1 (en) 2007-06-28
EP1966249A1 (en) 2008-09-10
KR20080087829A (ko) 2008-10-01

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