KR101359775B1 - 비닐 단량체의 자유 라디칼 중합 방법 - Google Patents
비닐 단량체의 자유 라디칼 중합 방법 Download PDFInfo
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- KR101359775B1 KR101359775B1 KR1020087017426A KR20087017426A KR101359775B1 KR 101359775 B1 KR101359775 B1 KR 101359775B1 KR 1020087017426 A KR1020087017426 A KR 1020087017426A KR 20087017426 A KR20087017426 A KR 20087017426A KR 101359775 B1 KR101359775 B1 KR 101359775B1
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- 229910052763 palladium Inorganic materials 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
- C08F226/10—N-Vinyl-pyrrolidone
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/275,370 | 2005-12-28 | ||
| US11/275,370 US7968661B2 (en) | 2005-12-28 | 2005-12-28 | Method of free radically polymerizing vinyl monomers |
| PCT/US2006/049284 WO2007079080A1 (en) | 2005-12-28 | 2006-12-26 | Method of free radically polymerizing vinyl monomers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20080087829A KR20080087829A (ko) | 2008-10-01 |
| KR101359775B1 true KR101359775B1 (ko) | 2014-02-06 |
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| KR1020087017426A Active KR101359775B1 (ko) | 2005-12-28 | 2006-12-26 | 비닐 단량체의 자유 라디칼 중합 방법 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7968661B2 (https=) |
| EP (1) | EP1966249B1 (https=) |
| JP (1) | JP5243266B2 (https=) |
| KR (1) | KR101359775B1 (https=) |
| CN (1) | CN101346400B (https=) |
| AT (1) | ATE536377T1 (https=) |
| BR (1) | BRPI0620711B1 (https=) |
| WO (1) | WO2007079080A1 (https=) |
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| US7989573B2 (en) * | 2005-12-16 | 2011-08-02 | 3M Innovative Properties Company | Method of free radically polymerizing vinyl monomers |
| KR101125594B1 (ko) * | 2009-08-31 | 2012-03-22 | 주식회사 엘지화학 | 단열 조건을 이용한 발포 폴리스티렌의 제조방법 |
| CN102985467B (zh) | 2010-06-29 | 2014-11-19 | 3M创新有限公司 | 由含有氮丙啶基的化合物形成的接枝化合物 |
| CN102985449B (zh) | 2010-06-29 | 2015-08-12 | 3M创新有限公司 | 含氮丙啶基的化合物 |
| JP5190097B2 (ja) * | 2010-10-21 | 2013-04-24 | 住友化学株式会社 | 重合反応装置及びそれを用いたメタクリル系重合体の製造方法 |
| WO2016133669A1 (en) | 2015-02-18 | 2016-08-25 | 3M Innovative Properties Company | Acrylic adhesive composition from protected photocrosslinking agents |
| EP3344720B1 (en) | 2015-08-31 | 2020-10-14 | 3M Innovative Properties Company | Articles comprising (meth)acrylate pressure-sensitive adhesive with enhanced adhesion to wet surfaces |
| WO2017040074A1 (en) | 2015-08-31 | 2017-03-09 | 3M Innovative Properties Company | Negative pressure wound therapy dressings comprising (meth)acrylate pressure-sensitive adhesive with enhanced adhesion to wet surfaces |
| EP3168237A1 (en) * | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | High pressure, free radical polymerizations to produce ethylene-based polymers |
| TWI668285B (zh) * | 2015-12-31 | 2019-08-11 | 長興材料工業股份有限公司 | 可熱聚合之組合物、由此形成之組成液及其用途 |
| WO2017155644A1 (en) | 2016-03-10 | 2017-09-14 | 3M Innovative Properties Company | Oil resistant adhesive |
| EP3694946B1 (de) | 2017-10-11 | 2021-11-10 | Basf Se | Gegen weichmachermigration resistenter, uv-härtbarer schmelzklebstoff für graphikfolien und etiketten aus weich-pvc |
| CN107815289A (zh) * | 2017-11-07 | 2018-03-20 | 苏州甫众塑胶有限公司 | 物流标签纸用胶及其制备方法 |
| JP7063667B2 (ja) * | 2018-03-22 | 2022-05-09 | スリーエム イノベイティブ プロパティズ カンパニー | 装飾シート |
| EP3775086B1 (en) | 2018-04-05 | 2022-09-14 | 3M Innovative Properties Company | Gel adhesive comprising crosslinked blend of polydiorganosiloxane and acrylic polymer |
| WO2021220200A1 (en) | 2020-04-29 | 2021-11-04 | 3M Innovative Properties Company | Hot melt processable adhesive with ionic crosslinkers |
| CN121532467A (zh) | 2023-06-22 | 2026-02-13 | 3M创新有限公司 | 包括可固化粘合剂膜和固体活化剂组合物的粘合剂体系以及相关套件和方法 |
| CN117021643A (zh) * | 2023-08-10 | 2023-11-10 | 沈阳东阳聚氨酯有限公司 | 一种复合双层橡胶胶辊的制备方法 |
| DE102024124847A1 (de) * | 2024-08-30 | 2026-03-05 | Tesa Se | Poly(meth)acrylate, Haftklebmassen und deren Herstellungsverfahren |
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| US5741542A (en) * | 1994-04-28 | 1998-04-21 | Minnesota Mining & Manufacturing Company | Process of making thermal free-radical cure adhesives |
| US5753768A (en) * | 1995-12-14 | 1998-05-19 | Minnesota Mining And Manufacturing Company | Bulk radical polymerization using a batch reactor |
| US5795650A (en) * | 1995-09-27 | 1998-08-18 | Lintec Corporation | Pressure-sensitive adhesive sheet |
| US6624273B1 (en) * | 1999-03-19 | 2003-09-23 | 3M Innovative Properties Company | Plasticized acrylics for pressure sensitive adhesive applications |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3842059A (en) | 1971-02-22 | 1974-10-15 | M Chiang | Acrylate and methacrylate terminated polystyrene macromolecular monomers having a substantially uniform molecular weight distribution |
| US3786116A (en) | 1972-08-21 | 1974-01-15 | Cpc International Inc | Chemically joined,phase separated thermoplastic graft copolymers |
| US4181752A (en) | 1974-09-03 | 1980-01-01 | Minnesota Mining And Manufacturing Company | Acrylic-type pressure sensitive adhesives by means of ultraviolet radiation curing |
| JPS59213783A (ja) * | 1983-05-19 | 1984-12-03 | Nippon Shokubai Kagaku Kogyo Co Ltd | ホツトメルト型感圧接着剤の製造方法 |
| DE3531913A1 (de) * | 1985-09-07 | 1987-03-19 | Roehm Gmbh | Haertbare giessharze |
| US4732808A (en) | 1985-11-14 | 1988-03-22 | Minnesota Mining And Manufacturing Company | Macromer reinforced pressure sensitive skin adhesive sheet material |
| US4737559A (en) | 1986-05-19 | 1988-04-12 | Minnesota Mining And Manufacturing Co. | Pressure-sensitive adhesive crosslinked by copolymerizable aromatic ketone monomers |
| US4737577A (en) * | 1986-12-31 | 1988-04-12 | Minnesota Mining And Manufacturing Company | Method for removing monomer from an acrylate adhesive by reaction with a scavenger monomer |
| US5266402A (en) * | 1990-12-18 | 1993-11-30 | Minnesota Mining And Manufacturing Company | Interpenetrating pressure-sensitive adhesive polymer networks |
| EP0625998B1 (en) | 1992-02-10 | 1996-06-05 | Minnesota Mining And Manufacturing Company | Radiation crosslinked elastomers |
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| JPH1087740A (ja) | 1996-09-11 | 1998-04-07 | Toray Ind Inc | ビニル系重合体の製造方法 |
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- 2005-12-28 US US11/275,370 patent/US7968661B2/en active Active
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2006
- 2006-12-26 BR BRPI0620711A patent/BRPI0620711B1/pt not_active IP Right Cessation
- 2006-12-26 WO PCT/US2006/049284 patent/WO2007079080A1/en not_active Ceased
- 2006-12-26 AT AT06848164T patent/ATE536377T1/de active
- 2006-12-26 EP EP06848164A patent/EP1966249B1/en not_active Not-in-force
- 2006-12-26 CN CN2006800494151A patent/CN101346400B/zh not_active Expired - Fee Related
- 2006-12-26 KR KR1020087017426A patent/KR101359775B1/ko active Active
- 2006-12-26 JP JP2008548679A patent/JP5243266B2/ja not_active Expired - Fee Related
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| US5741542A (en) * | 1994-04-28 | 1998-04-21 | Minnesota Mining & Manufacturing Company | Process of making thermal free-radical cure adhesives |
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| US6624273B1 (en) * | 1999-03-19 | 2003-09-23 | 3M Innovative Properties Company | Plasticized acrylics for pressure sensitive adhesive applications |
Also Published As
| Publication number | Publication date |
|---|---|
| US7968661B2 (en) | 2011-06-28 |
| EP1966249A4 (en) | 2009-07-29 |
| BRPI0620711A2 (pt) | 2011-11-22 |
| BRPI0620711B1 (pt) | 2018-10-16 |
| EP1966249B1 (en) | 2011-12-07 |
| ATE536377T1 (de) | 2011-12-15 |
| JP5243266B2 (ja) | 2013-07-24 |
| WO2007079080A1 (en) | 2007-07-12 |
| JP2009522411A (ja) | 2009-06-11 |
| CN101346400A (zh) | 2009-01-14 |
| US20070149698A1 (en) | 2007-06-28 |
| EP1966249A1 (en) | 2008-09-10 |
| CN101346400B (zh) | 2012-09-26 |
| KR20080087829A (ko) | 2008-10-01 |
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