CN101230113B - 用于质子传导性电解质的接枝有磺酰基的杂环材料 - Google Patents

用于质子传导性电解质的接枝有磺酰基的杂环材料 Download PDF

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Publication number
CN101230113B
CN101230113B CN2007101800856A CN200710180085A CN101230113B CN 101230113 B CN101230113 B CN 101230113B CN 2007101800856 A CN2007101800856 A CN 2007101800856A CN 200710180085 A CN200710180085 A CN 200710180085A CN 101230113 B CN101230113 B CN 101230113B
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polymer
heterocyclic compound
proton
proton conducting
carbon atoms
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Expired - Fee Related
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CN2007101800856A
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Chinese (zh)
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CN101230113A (zh
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李斯文
周震
张月兰
刘美林
李文
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Toyota Motor Corp
Georgia Tech Research Corp
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Georgia Tech Research Institute
Toyota Engineering and Manufacturing North America Inc
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/10—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aromatic carbon atoms, e.g. polyphenylenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/18—Polybenzimidazoles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/28—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen sulfur-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1037—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having silicon, e.g. sulfonated crosslinked polydimethylsiloxanes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Conductive Materials (AREA)
  • Fuel Cell (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Silicon Polymers (AREA)
  • Polyethers (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Epoxy Resins (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
CN2007101800856A 2006-12-21 2007-12-21 用于质子传导性电解质的接枝有磺酰基的杂环材料 Expired - Fee Related CN101230113B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/614,198 US7964651B2 (en) 2006-12-21 2006-12-21 Sulfonyl grafted heterocycle materials for proton conducting electrolytes
US11/614,198 2006-12-21

Publications (2)

Publication Number Publication Date
CN101230113A CN101230113A (zh) 2008-07-30
CN101230113B true CN101230113B (zh) 2013-05-22

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US (1) US7964651B2 (https=)
JP (1) JP5650403B2 (https=)
CN (1) CN101230113B (https=)
DE (1) DE102007060692B4 (https=)
WO (1) WO2008091475A1 (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8519074B2 (en) * 2010-01-15 2013-08-27 The University of Massachusettes Comb polymers for supramolecular nanoconfinement
JP2014009190A (ja) * 2012-06-29 2014-01-20 Shikoku Chem Corp イミダゾールシラン化合物、合成方法及びその利用
CN103467991A (zh) * 2013-09-23 2013-12-25 上海大学 双草酸硼酸盐离子液体掺杂磺化聚苯硫醚质子交换膜材料及其制备方法
CN107033350B (zh) * 2017-03-31 2019-07-23 上海大学 质子交换膜用膦酸和1,2,3-三唑功能化聚醚砜及其制备方法
CN115850538B (zh) * 2021-09-27 2024-10-22 山东东岳未来氢能材料股份有限公司 一类带有联吡啶侧基的全氟离子聚合物及合成方法与应用
CN119490610A (zh) * 2021-09-27 2025-02-21 山东东岳未来氢能材料股份有限公司 带有吡啶侧基的长寿命质子交换膜及制备方法
CN115873154B (zh) * 2021-09-27 2024-10-22 山东东岳未来氢能材料股份有限公司 带有三联吡啶侧基的全氟离子聚合物及合成方法与应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5283310A (en) * 1991-09-13 1994-02-01 Saint-Gobain Vitrage International Proton conducting polymer, and application thereof as electrolyte in electrochemical devices
US6310110B1 (en) * 1999-07-30 2001-10-30 Michael A. Markowitz Molecularly-imprinted material made by template-directed synthesis
US6531539B2 (en) * 2000-04-08 2003-03-11 Degussa Ag Organosilicon compounds
CN1601793A (zh) * 2003-08-28 2005-03-30 株式会社东芝 质子传导性聚合物、催化剂组合物、燃料电池用电解质膜、以及燃料电池
CN1809606A (zh) * 2003-05-28 2006-07-26 美国丰田技术中心公司 由具有官能团的硅烷形成的传导膜

Family Cites Families (11)

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US3574593A (en) 1967-07-21 1971-04-13 American Cyanamid Co Herbicidal method using substituted alkylsulfonylimidazoles
US5525436A (en) 1994-11-01 1996-06-11 Case Western Reserve University Proton conducting polymers used as membranes
US5827602A (en) 1995-06-30 1998-10-27 Covalent Associates Incorporated Hydrophobic ionic liquids
US6248469B1 (en) 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
US20040122256A1 (en) * 2001-02-01 2004-06-24 Masanori Ikeda Perfluorvinyl ether monomer having sulfonamide group
WO2002062749A1 (fr) * 2001-02-01 2002-08-15 Asahi Kasei Kabushiki Kaisha Monomere d'ether perfluorovinylique ayant un groupe sulfonamide
DE10163518A1 (de) 2001-12-21 2003-07-10 Fraunhofer Ges Forschung Protonenleitfähige Membranen/Schichten und Verfahren zu deren Herstellung
US6987163B2 (en) 2002-08-07 2006-01-17 Research Foundation Of The State University Of New York Modified polybenzimidazole (PBI) membranes for enhanced polymer electrochemical cells
US6878475B2 (en) 2002-11-22 2005-04-12 T/J Technologies, Inc. Membrane for fuel cell, and fuel cell incorporating that membrane
JP3904083B2 (ja) * 2003-07-10 2007-04-11 株式会社豊田中央研究所 高分子電解質組成物
US7576165B2 (en) 2004-01-27 2009-08-18 Georgia Institute Of Technology Heterocycle grafted monomers and related polymers and hybrid inorganic-organic polymer membranes

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5283310A (en) * 1991-09-13 1994-02-01 Saint-Gobain Vitrage International Proton conducting polymer, and application thereof as electrolyte in electrochemical devices
US6310110B1 (en) * 1999-07-30 2001-10-30 Michael A. Markowitz Molecularly-imprinted material made by template-directed synthesis
US6531539B2 (en) * 2000-04-08 2003-03-11 Degussa Ag Organosilicon compounds
CN1809606A (zh) * 2003-05-28 2006-07-26 美国丰田技术中心公司 由具有官能团的硅烷形成的传导膜
CN1601793A (zh) * 2003-08-28 2005-03-30 株式会社东芝 质子传导性聚合物、催化剂组合物、燃料电池用电解质膜、以及燃料电池

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US20080152985A1 (en) 2008-06-26
DE102007060692A1 (de) 2008-09-11
US7964651B2 (en) 2011-06-21
DE102007060692B4 (de) 2021-05-27
JP2011507979A (ja) 2011-03-10
CN101230113A (zh) 2008-07-30
JP5650403B2 (ja) 2015-01-07
WO2008091475A1 (en) 2008-07-31

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