CN101137437B - 碱性离子液体 - Google Patents

碱性离子液体 Download PDF

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CN101137437B
CN101137437B CN2006800056706A CN200680005670A CN101137437B CN 101137437 B CN101137437 B CN 101137437B CN 2006800056706 A CN2006800056706 A CN 2006800056706A CN 200680005670 A CN200680005670 A CN 200680005670A CN 101137437 B CN101137437 B CN 101137437B
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aryl
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ionic liquid
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CN101137437A (zh
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马丁·约翰·厄尔
肯尼斯·理查德·塞登
斯图尔特·福赛思
乌特·弗勒利希
尼马尔·古纳拉特尼
苏哈斯·卡特戴尔
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Queens University of Belfast
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Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7687513B1 (en) 2004-10-21 2010-03-30 University Of Notre Dame Du Lac Aminopyridinium ionic liquids
GB0500028D0 (en) * 2005-01-04 2005-02-09 Univ Belfast Base stable ionic liquids
JP2006206457A (ja) * 2005-01-25 2006-08-10 Toyota Motor Corp 環状アンモニウム溶融塩およびその利用
WO2007138307A2 (en) * 2006-05-25 2007-12-06 The Queen's University Of Belfast Process for removing sulfur-containing acids from crude oil
EP1911829A1 (en) * 2006-10-10 2008-04-16 The Queen's University of Belfast Process for deacidifying crude oil
BRPI0714555A2 (pt) 2006-07-24 2013-05-07 Procter & Gamble processo para epimerizar ciclohexenil cetonas e sua aplicaÇço no processo de condensaÇço aldol
US7674608B2 (en) 2007-02-23 2010-03-09 The University Of Toledo Saccharifying cellulose
CN104232704A (zh) 2007-03-14 2014-12-24 托莱多大学 生物质预处理
US7772293B2 (en) * 2007-07-31 2010-08-10 Invista North America S.A.R.L. Ionic liquid solvents and a process for the depolymerization of polyamides
KR101072896B1 (ko) * 2007-10-09 2011-10-17 한미홀딩스 주식회사 이온성 액체 매개체를 이용한 몬테루카스트산의 제조 방법
JP5009736B2 (ja) * 2007-10-15 2012-08-22 日本曹達株式会社 環状アミノエーテルを用いたマンニッヒ反応
US7999355B2 (en) * 2008-07-11 2011-08-16 Air Products And Chemicals, Inc. Aminosilanes for shallow trench isolation films
EP2350251B1 (en) * 2008-09-01 2013-05-29 Expelliere International Ltd. Compositions and methods for the removal of chewing gum residues from substrates
GB0905896D0 (en) 2009-04-06 2009-05-20 Univ Belfast Process for removing metals from hydrocarbons
GB0908986D0 (en) 2009-05-26 2009-07-01 Univ Belfast Process for removing organic acids from crude oil and crude oil distillates
JP5490613B2 (ja) * 2010-05-31 2014-05-14 三洋化成工業株式会社 アルミニウム電解コンデンサ用電解液、およびそれを用いたアルミニウム電解コンデンサ
GB2547364B8 (en) 2010-10-05 2017-11-29 The Queen's Univ Of Belfast Process for removing metals from hydrocarbons
CN102001925B (zh) * 2010-11-12 2013-04-24 淮阴师范学院 一种2-戊叉基环戊酮的生产方法
FR2967904B1 (fr) * 2010-11-25 2013-06-14 Oreal Composition pour traiter des fibres keratiniques comprenant un tensioactif cationique quinuclidinium
JP2012116802A (ja) * 2010-12-02 2012-06-21 Nitto Boseki Co Ltd イオン液体及びその製造方法
CN102140063B (zh) * 2011-03-09 2016-07-06 中国科学院上海有机化学研究所 一种合成三氟甲基丙烯酸衍生物的方法
CN103517747B (zh) 2011-05-02 2015-11-25 英派尔科技开发有限公司 空气净化
CN102786436B (zh) * 2011-05-19 2015-09-16 浙江久而久化学有限公司 一种合成氰乙酸酯的方法
EP2721686B1 (en) * 2011-06-17 2018-11-28 NantEnergy, Inc. Ionic liquid containing sulfonate ions
GB2496898B (en) * 2011-11-25 2020-10-28 Petroliam Nasional Berhad Petronas Corrosion inhibition
JP5323221B2 (ja) * 2011-11-28 2013-10-23 日本乳化剤株式会社 イオン性液体並びにこれを含む帯電防止剤、防曇剤、分散剤または乳化剤、潤滑剤、電解液、およびセルロース溶解剤
US8946471B2 (en) * 2011-12-29 2015-02-03 Uop Llc Process for oxidizing an alkyl-aromatic compound
CN102850314B (zh) * 2012-07-12 2014-08-13 盐城师范学院 双功能碱性离子液体水相催化苯并氧杂蒽衍生物的合成
CN103012202B (zh) * 2012-12-04 2014-10-08 山东鑫泉医药有限公司 沙坦联苯的制备方法
CN103204845B (zh) * 2013-03-12 2014-12-24 西北大学 咪唑基离子液体及其合成方法和应用
KR101415844B1 (ko) * 2013-03-29 2014-07-09 한국과학기술연구원 소수성 이온성 액체 기반 이산화황 및 아황산 흡수제
CN103896952B (zh) * 2014-04-09 2016-03-30 中国科学院化学研究所 离子液体催化剂及其制备方法与应用
CN104016973B (zh) * 2014-05-28 2016-11-02 台州学院 一种制备二芳香环取代烯烃的方法
GB2538760A (en) * 2015-05-27 2016-11-30 The Queen's Univ Of Belfast Removal of free fatty acids from glyceride oils
EP3098293A1 (en) 2015-05-27 2016-11-30 Evonik Degussa GmbH A process for removing metal from a metal-containing glyceride oil comprising a basic quaternary ammonium salt treatment
GB2538758A (en) 2015-05-27 2016-11-30 Green Lizard Tech Ltd Process for removing chloropropanols and/or glycidol
EP3098292A1 (en) 2015-05-27 2016-11-30 Evonik Degussa GmbH A process for refining glyceride oil comprising a basic quaternary ammonium salt treatment
DE102015212749A1 (de) 2015-07-08 2017-01-12 Evonik Degussa Gmbh Verfahren zur Entfeuchtung von feuchten Gasgemischen
JP6685039B2 (ja) * 2015-08-26 2020-04-22 国立大学法人東北大学 化合物、イオン液体、白金族元素の抽出剤、白金族元素の抽出方法
EP3257568B1 (de) 2016-06-14 2019-09-18 Evonik Degussa GmbH Verfahren zur entfeuchtung von feuchten gasgemischen mit ionischen flüssigkeiten
DE102016210484A1 (de) 2016-06-14 2017-12-14 Evonik Degussa Gmbh Verfahren zur Entfeuchtung von feuchten Gasgemischen
DE102016210478A1 (de) 2016-06-14 2017-12-14 Evonik Degussa Gmbh Verfahren zur Entfeuchtung von feuchten Gasgemischen
CN106632522B (zh) * 2016-09-20 2019-07-12 华南理工大学 一种碱性离子液体催化葡萄糖异构制备果糖的方法
CN107243642B (zh) * 2017-06-20 2019-02-22 太原理工大学 利用离子液辅助制备锑烯的方法
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EP3483237A1 (de) 2017-11-10 2019-05-15 Evonik Degussa GmbH Verfahren zur extraktion von fettsäuren aus triglyceridölen
US11655402B2 (en) * 2017-11-21 2023-05-23 Nitto Denko Corporation Basic ionic liquids compositions and elements including the same
WO2019113513A1 (en) 2017-12-08 2019-06-13 Baker Hughes, A Ge Company, Llc Ionic liquid based well asphaltene inhibitors and methods of using the same
EA202091413A1 (ru) 2018-07-11 2020-09-24 Бейкер Хьюз Холдингз Ллк Скважинные ингибиторы асфальтенов на основе ионной жидкости и способы их применения
AR116635A1 (es) * 2018-10-15 2021-05-26 Servier Lab Proceso para la síntesis de derivados de piperazinil-etoxi-bromofenilo y su aplicación en la producción de compuestos que los contienen
CN110713462A (zh) * 2019-09-03 2020-01-21 沈阳化工大学 用于环己烷-乙醇体系分离1-癸基-3-甲基咪唑磷酸盐离子液体方法
US11235283B2 (en) * 2019-12-30 2022-02-01 Industrial Technology Research Institute Ionic liquid and forward osmosis process employing the same
CN114426458B (zh) * 2020-10-13 2024-01-09 中国石油化工股份有限公司 一种环氧烷烃催化水合制二元醇的方法
CN112808306A (zh) * 2021-01-13 2021-05-18 华东理工大学 一种有机酸稳定的金属氧簇催化剂的制备方法及其应用
CN113620787A (zh) * 2021-07-12 2021-11-09 浙江诺亚氟化工有限公司 一种含氟芳香醚的合成方法
CN114522723B (zh) * 2022-03-08 2023-04-18 福州大学 一种轻质烷烃低温异构化催化剂及其制备方法和应用
CN116332854B (zh) * 2023-03-21 2024-09-24 浙江昂利泰制药有限公司 一种亚苄基海因的制备方法
CN117024365B (zh) * 2023-08-24 2025-06-24 山西师范大学 一种吡唑类离子液体及利用其催化Mannich反应的方法
CN117024364B (zh) * 2023-08-24 2025-06-20 山西师范大学 一种吡唑类离子液体及利用其催化Betti反应的方法
CN117326959A (zh) * 2023-09-25 2024-01-02 华东理工大学 一种氨基醚类化合物及其合成方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040035293A1 (en) * 2002-04-05 2004-02-26 Davis James Hillard Functionalized ionic liquids, and methods of use thereof

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3014039A (en) * 1959-09-29 1961-12-19 Searle & Co 9-[omega-n-(omega-dialkylaminoalkyl)aminoalkyl]-9-pyrid[3, 4-b]-indoles and derivatives
US4883655A (en) * 1986-10-24 1989-11-28 Gaf Corporation Quaternized nitrogen containing polycyclic compounds
DE4405055A1 (de) * 1994-02-17 1995-08-24 Basf Ag Verfahren zur Herstellung von Isocyanuratgruppen aufweisenden Polyisocyanaten und ihre Verwendung
US6307102B1 (en) * 1997-10-15 2001-10-23 Tosoh Corporation Amine catalyst for producing polyurethane and polyisocyanurate
DE69934170T2 (de) * 1998-02-03 2007-09-27 Acep Inc., Montreal Neue als elektrolytische solubilisate geeignete werkstoffe
GB9906829D0 (en) 1999-03-24 1999-05-19 Univ Leicester Ionic liquids
GB9928290D0 (en) 1999-12-01 2000-01-26 Univ Belfast Process for preparing ambient temperature ionic liquids
FR2813305B1 (fr) * 2000-08-23 2004-02-13 Inst Francais Du Petrole Procede ameliore d'hydroformylation mettant en oeuvre un catalyseur a base de cobalt et/ou de rhodium dans un solvant ionique non aqueux
GB0023708D0 (en) 2000-09-27 2000-11-08 Scionix Ltd Hydrated salt mixtures
GB0023706D0 (en) * 2000-09-27 2000-11-08 Scionix Ltd Ionic liquids
JP3541223B2 (ja) * 2001-03-08 2004-07-07 東北大学長 イオン性液体中でのＰｄ／Ｃ触媒を用いたＨｅｃｋ反応
JP2002275118A (ja) * 2001-03-15 2002-09-25 Central Glass Co Ltd アルドール反応生成物の製造方法
GB0112093D0 (en) * 2001-05-18 2001-07-11 Univ Belfast Hydrogenation processes
US6552232B2 (en) 2001-06-26 2003-04-22 Exxonmobil Research And Engineering Company Process for conducting aldol condensation reactions in ionic liquid media
MY138064A (en) 2002-01-24 2009-04-30 Basf Ag Method for the separation of acids from chemical reaction mixtures by means of ionic fluids
JP4239537B2 (ja) 2002-09-18 2009-03-18 株式会社ジーエス・ユアサコーポレーション 常温溶融塩型電解質およびそれを用いた電気化学デバイス
FR2845084B1 (fr) * 2002-09-26 2009-07-17 Centre Nat Rech Scient Compositions contenant des liquides ioniques et leurs utilisations, notamment en synthese organique
DE10247578A1 (de) * 2002-10-13 2004-04-22 Solvent Innovation Gmbh Neuartige, funktionalisierte ionische Flüssigkeiten und Verfahren zu ihrer Herstellung
DE10258671A1 (de) 2002-12-13 2004-06-24 Merck Patent Gmbh Ionische Flüssigkeiten mit [N(CF3)2]-Anionen
PT1660457E (pt) * 2003-08-26 2011-12-13 Ecole Polytech Líquidos iónicos com base em sais de imidazólio, incorporando uma funcionalidade nitrilo
JP2005104845A (ja) * 2003-09-26 2005-04-21 Tosoh Corp ４級アンモニウム系常温溶融塩及び製造法
WO2005072376A2 (en) * 2004-01-26 2005-08-11 University Of South Alabama Anionic-sweetener-based ionic liquids and methods of use thereof
EA009571B1 (ru) * 2004-03-12 2008-02-28 Сэнт-Гобэн Керамикс & Пластикс, Инк. Распылительно высушенный оксид алюминия для носителя катализатора
ES2263346B1 (es) * 2004-08-25 2007-12-16 Consejo Superior De Investigaciones Cientificas Uso de una composicion catalitica en la insercion de dioxido de carbo no en acetales, ortoesteres y epoxidos.
PT1831159E (pt) 2004-12-21 2010-03-03 Hoffmann La Roche Derivados de tetralina e de indano e as suas utilizações
GB0500028D0 (en) * 2005-01-04 2005-02-09 Univ Belfast Base stable ionic liquids

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040035293A1 (en) * 2002-04-05 2004-02-26 Davis James Hillard Functionalized ionic liquids, and methods of use thereof

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