CN100551948C - 透明和高热聚碳酸酯-聚硅氧烷共聚物和含有聚碳酸酯的透明共混物及其制造过程 - Google Patents
透明和高热聚碳酸酯-聚硅氧烷共聚物和含有聚碳酸酯的透明共混物及其制造过程 Download PDFInfo
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- CN100551948C CN100551948C CNB2004800105845A CN200480010584A CN100551948C CN 100551948 C CN100551948 C CN 100551948C CN B2004800105845 A CNB2004800105845 A CN B2004800105845A CN 200480010584 A CN200480010584 A CN 200480010584A CN 100551948 C CN100551948 C CN 100551948C
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- Prior art keywords
- polycarbonate
- polysiloxane copolymer
- blend
- value
- hydroxyaryl
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 112
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 74
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 48
- 229920001296 polysiloxane Polymers 0.000 title claims description 105
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 106
- -1 siloxanes Chemical class 0.000 claims abstract description 78
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 82
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 78
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- 238000006243 chemical reaction Methods 0.000 claims description 57
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- 150000001875 compounds Chemical class 0.000 claims description 47
- 125000005027 hydroxyaryl group Chemical group 0.000 claims description 41
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
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- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 7
- CJWNFAKWHDOUKL-UHFFFAOYSA-N 2-(2-phenylpropan-2-yl)phenol Chemical compound C=1C=CC=C(O)C=1C(C)(C)C1=CC=CC=C1 CJWNFAKWHDOUKL-UHFFFAOYSA-N 0.000 description 6
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- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
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- GCXUHGZBBGZTII-UHFFFAOYSA-N a828071 Chemical compound ClC(Cl)=O.ClC(Cl)=O GCXUHGZBBGZTII-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- OKQPRBCJOFEFQV-UHFFFAOYSA-N butylbenzene phenol Chemical compound C1(=CC=CC=C1)O.C(CCC)C1=CC=CC=C1 OKQPRBCJOFEFQV-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
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- 230000001351 cycling effect Effects 0.000 description 1
- NNSXQVFLSINZGU-UHFFFAOYSA-N cyclododecanone;phenol Chemical compound OC1=CC=CC=C1.OC1=CC=CC=C1.O=C1CCCCCCCCCCC1 NNSXQVFLSINZGU-UHFFFAOYSA-N 0.000 description 1
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical compound OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
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- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
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- 230000032050 esterification Effects 0.000 description 1
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- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
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- 230000005764 inhibitory process Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
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- 230000000266 injurious effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
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- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
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- 230000007935 neutral effect Effects 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- QVLTXCYWHPZMCA-UHFFFAOYSA-N po4-po4 Chemical compound OP(O)(O)=O.OP(O)(O)=O QVLTXCYWHPZMCA-UHFFFAOYSA-N 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- GGRIQDPLLHVRDU-UHFFFAOYSA-M potassium;2-(benzenesulfonyl)benzenesulfonate Chemical compound [K+].[O-]S(=O)(=O)C1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1 GGRIQDPLLHVRDU-UHFFFAOYSA-M 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000013849 propane Nutrition 0.000 description 1
- AQHHHDLHHXJYJD-UHFFFAOYSA-N propranolol Chemical compound C1=CC=C2C(OCC(O)CNC(C)C)=CC=CC2=C1 AQHHHDLHHXJYJD-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
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- 239000005060 rubber Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229940024463 silicone emollient and protective product Drugs 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
Images
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-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/18—Block or graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/445—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
- C08G77/448—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences containing polycarbonate sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Silicon Polymers (AREA)
Abstract
Description
测量 | 单位 | 5%D-50高Mw | 5%D-50中Mw | 5%D-50低Mw | 5%D-50/PC共混物 | 现有技术<sup>*</sup>5%D-50/PC共混物 |
Mn | - | 9793 | 8463 | 6598 | 10405 | - |
Mw | - | 25504 | 21374 | 17854 | 25298 | - |
Disp.(Mw/Mn) | - | 2.60 | 2.53 | 2.71 | 2.43 | 10405 |
Tg | ℃ | 148.4 | 144.2 | 140.6 | - | |
黄度指数 | - | 8.7 | 8.1 | 7.6 | - | |
透过率 | % | 86.9 | 87.1 | 87.5 | - | 75.0 |
浊度 | % | 4.2 | 6.5 | 10.4 | 1.6 | 27.8 |
成分 | 说明 |
PC/PDMS1 | 第一聚碳酸酯/聚二甲基硅氧烷共聚物,具有基于总聚合物重量的20wt%硅氧烷,和小于25的光透过率和104的浊度。 |
PC/PDMS2 | 第二聚碳酸酯/聚二甲基硅氧烷共聚物,具有基于总聚合物重量的5wt%硅氧烷,84的光透过率和2的浊度。 |
PC | 双酚A聚碳酸酯,用界面过程方法制备,具有约每摩尔30500克的绝对重均分子量,从GE塑料公司得到。 |
实施例 | PC/PDMS2 | PC/PDMS1 | PC | 添加剂 | 总硅氧烷 |
1<sup>*</sup> | - | - | 99.65 | 0.35 | 0 |
2<sup>*</sup> | - | 6.23 | 93.42 | 0.35 | 1.2 |
3<sup>*</sup> | - | 12.46 | 87.19 | 0.35 | 2.5 |
4<sup>*</sup> | - | 18.68 | 80.97 | 0.35 | 3.7 |
5<sup>*</sup> | - | 24.91 | 74.47 | 0.35 | 5.0 |
6<sup>*</sup> | 99.65 | - | - | 0.35 | 5.0 |
7 | 74.74 | 6.23 | 18.68 | 0.35 | 5.0 |
8 | 49.83 | 12.46 | 37.37 | 0.35 | 5.0 |
9 | 24.92 | 18.68 | 56.05 | 0.35 | 5.0 |
实施 | 透过 | 浊度 | 卫氏 | NI23 | NI10 | NI0 | NI-10 | NI-20 | NI-30 | NI-40 | D/B |
例 | 率 | 软化温度 | 温度 | ||||||||
1<sup>*</sup> | 91 | 1 | 149.3 | 75 | 17 | 14 | 12 | 12 | 11 | 10 | <23 |
2<sup>*</sup> | 40 | 98 | 148.9 | 81 | 72 | 72 | 52 | 25 | 19 | 15 | <-10 |
3<sup>*</sup> | 32 | 104 | 148.2 | 79 | 74 | 72 | 69 | 67 | 60 | 29 | <-30 |
4<sup>*</sup> | 25 | 104 | 147.9 | 74 | 75 | 74 | 70 | 67 | 62 | 58 | <-40 |
5<sup>*</sup> | 23 | 104 | 147.4 | 73 | 70 | 68 | 65 | 64 | 60 | 56 | <-40 |
6<sup>*</sup> | 84 | 2 | 141.6 | 55 | 54 | 50 | 45 | 39 | 20 | 17 | <-20 |
7 | 60 | 28 | 142.5 | 67 | 65 | 61 | 60 | 59 | 51 | 34 | <-30 |
8 | 36 | 94 | 144.4 | 71 | 71 | 67 | 65 | 62 | 57 | 52 | <-40 |
9 | 29 | 103 | 146.3 | 73 | 71 | 67 | 66 | 63 | 60 | 56 | <-40 |
实施例 | PC/PDMS2 | PC/PDMS1 | PC | BPADP | TSAN | 添加剂 | 总硅氧烷量 |
10 | 89.65 | - | - | 10 | 0 | 0.35 | 4.5 |
11 | 67.24 | 5.6 | 16.81 | 10 | 0 | 0.35 | 4.5 |
12 | 44.83 | 11.21 | 33.62 | 10 | 0 | 0.35 | 4.5 |
13 | 22.41 | 16.81 | 50.43 | 10 | 0 | 0.35 | 4.5 |
14 | - | 22.41 | 67.24 | 10 | 0 | 0.35 | 4.5 |
15 | 89.45 | - | - | 10 | 0.2 | 0.35 | 4.5 |
16 | 44.73 | 11.18 | 33.54 | 10 | 0.2 | 0.35 | 4.5 |
17 | 22.36 | 67.09 | 10 | 0.2 | 0.35 | 4.5 |
实施例 | 透过率 | 浊度 | 维卡软化点 | NI23 | NI10 | NI0 | NI-10 | NI-20 | NI-30 | NI-40 | D/B | UL94在1.2毫米 | UL945VB在2毫米 |
10 | 84.9 | 1.4 | 110.5 | 6.7 | 6.3 | 6.5 | 6.4 | 6.6 | 6.6 | 6.6 | >23 | V2 | 不合格 |
11 | 66.4 | 18.5 | 111.1 | 8.9 | 7.2 | 7.1 | 7.8 | 7.2 | 7.5 | 7.6 | >23 | V2 | 不合格 |
12 | 41.5 | 77.2 | 111.5 | 10.0 | 9.8 | 10.1 | 9.8 | 9.8 | 9.7 | 9.4 | >23 | V0 | 不合格 |
13 | 30.8 | 102.0 | 113.8 | 62.1 | 53.1 | 40.0 | 13.9 | 12.8 | 12.3 | 12.0 | 0.0 | V0 | 不合格 |
14 | 23.9 | 104.0 | 114.1 | 72.1 | 65.5 | 57.5 | 46.0 | 15.8 | 14.5 | 13.1 | -10.0 | V0 | 不合格 |
15 | 70.7 | 38.8 | 108.7 | 6.4 | 6.0 | 6.1 | 5.2 | 6.2 | 6.1 | 6.4 | >23 | V0 | 不合格 |
16 | 38.8 | 88.5 | 111.2 | 15.9 | 10.3 | 9.6 | 9.9 | 9.8 | 9.6 | 9.4 | 23.0 | V0 | 合格 |
17 | 24.3 | 104.0 | 112.7 | 64.4 | 55.8 | 45.6 | 13.8 | 13.1 | 12.3 | 12.1 | 0.0 | V0 | 合格 |
实施例 | PC/PDMS2 | PC/PDMS1 | PC | BPADP | TSAN | 添加剂 | 总硅氧烷量 |
18 | 67.09 | 22.36 | - | 10 | 0.2 | 0.35 | 7.8 |
19 | 74.74 | 24.91 | - | 0 | 0 | 0.35 | 8.7 |
实施例 | 透过率 | 浊度 | 维卡软化点 | NI23 | NI10 | NI0 | NI-10 | NI-20 | NI-30 | NI-40 | D/B温度 | UL94分级在1.2毫米 | UL945VB在2毫米 |
18 | 35.5 | 92.2 | 10.8.5 | 26.9 | 25.3 | 23.7 | 14.7 | 11.8 | 11.3 | 11.0 | <0 | V0 | 合格 |
19 | 32.1 | 97.4 | 140.9 | 62.3 | 59.1 | 55.8 | 53.4 | 52.1 | 50.6 | 47.6 | <-40 |
Claims (72)
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CN201110005646.5A CN102161753B (zh) | 2003-02-21 | 2004-02-23 | 透明和高热聚碳酸酯-聚硅氧烷共聚物和含有聚碳酸酯的透明共混物及其制造过程 |
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US44881503P | 2003-02-21 | 2003-02-21 | |
US60/448,815 | 2003-02-21 | ||
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CNA2007101383684A Division CN101121789A (zh) | 2003-02-21 | 2004-02-23 | 透明和高热聚碳酸酯-聚硅氧烷共聚物和含有聚碳酸酯的透明共混物及其制造过程 |
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CNB2004800105845A Expired - Lifetime CN100551948C (zh) | 2003-02-21 | 2004-02-23 | 透明和高热聚碳酸酯-聚硅氧烷共聚物和含有聚碳酸酯的透明共混物及其制造过程 |
CNA2007101383684A Pending CN101121789A (zh) | 2003-02-21 | 2004-02-23 | 透明和高热聚碳酸酯-聚硅氧烷共聚物和含有聚碳酸酯的透明共混物及其制造过程 |
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EP (1) | EP1597317B1 (zh) |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US6066700A (en) * | 1997-03-12 | 2000-05-23 | Bayer Aktiengesellschaft | Process for the production of polysiloxane/polycarbonate block co-condensation products |
DE19710081A1 (de) * | 1997-03-12 | 1998-09-17 | Bayer Ag | Verfahren zur Herstellung von Polysiloxan-Polysiloxan-Polycarbonat-Blockcokondensaten |
US6500549B1 (en) * | 1998-10-13 | 2002-12-31 | Gambro Ab | Biocompatible polymer film |
US6625379B1 (en) * | 1999-10-14 | 2003-09-23 | Asahi Kasei Kogyo Kabushiki Kaisha | Light-conducting plate and method of producing the same |
US6730720B2 (en) * | 2000-12-27 | 2004-05-04 | General Electric Company | Method for reducing haze in a fire resistant polycarbonate composition |
US6727302B2 (en) * | 2001-04-03 | 2004-04-27 | General Electric Company | Transparent, fire-resistant polycarbonate |
EP1448687A1 (de) | 2001-11-08 | 2004-08-25 | Albis Plastic GmbH | Metallic-farbene thermoplastische formmasse |
US6676852B2 (en) * | 2002-05-31 | 2004-01-13 | General Electric Company | Phosphorescent thermoplastic composition |
-
2004
- 2004-02-20 EP EP04713352.5A patent/EP1597317B1/en not_active Expired - Lifetime
- 2004-02-20 JP JP2006503935A patent/JP2006523243A/ja active Pending
- 2004-02-20 WO PCT/US2004/005001 patent/WO2004076541A2/en active Application Filing
- 2004-02-20 KR KR1020057015352A patent/KR20050107583A/ko active IP Right Grant
- 2004-02-20 CN CNB2004800047638A patent/CN100469838C/zh not_active Expired - Lifetime
- 2004-02-20 US US10/783,140 patent/US7166687B2/en not_active Expired - Lifetime
- 2004-02-23 CN CNB2004800105845A patent/CN100551948C/zh not_active Expired - Lifetime
- 2004-02-23 CN CNA2007101383684A patent/CN101121789A/zh active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US9994709B2 (en) | 2012-02-29 | 2018-06-12 | Sabic Global Technologies B.V. | Thermoplastic compositions having low smoke, methods of their manufacture, and uses thereof |
CN104870563A (zh) * | 2012-12-21 | 2015-08-26 | 沙特基础全球技术有限公司 | 聚碳酸酯组合物、由其形成的制品以及制造其的方法 |
CN106471043A (zh) * | 2014-07-03 | 2017-03-01 | 莫门蒂夫性能材料股份有限公司 | Uv‑活性的发色团官能化的聚硅氧烷和由其制成的共聚物 |
CN106687506A (zh) * | 2014-07-03 | 2017-05-17 | 莫门蒂夫性能材料股份有限公司 | 酯官能的聚硅氧烷和由其制成的共聚物 |
CN106471043B (zh) * | 2014-07-03 | 2021-01-12 | 莫门蒂夫性能材料股份有限公司 | Uv-活性的发色团官能化的聚硅氧烷和由其制成的共聚物 |
Also Published As
Publication number | Publication date |
---|---|
US7166687B2 (en) | 2007-01-23 |
CN1751096A (zh) | 2006-03-22 |
EP1597317A2 (en) | 2005-11-23 |
CN101121789A (zh) | 2008-02-13 |
US20050187372A1 (en) | 2005-08-25 |
CN100469838C (zh) | 2009-03-18 |
US20060014919A9 (en) | 2006-01-19 |
KR20050107583A (ko) | 2005-11-14 |
JP2006523243A (ja) | 2006-10-12 |
WO2004076541A3 (en) | 2004-11-25 |
EP1597317B1 (en) | 2015-09-09 |
CN1798791A (zh) | 2006-07-05 |
WO2004076541A2 (en) | 2004-09-10 |
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