CN100546963C - 双酚的合成方法 - Google Patents
双酚的合成方法 Download PDFInfo
- Publication number
- CN100546963C CN100546963C CNB2003801091046A CN200380109104A CN100546963C CN 100546963 C CN100546963 C CN 100546963C CN B2003801091046 A CNB2003801091046 A CN B2003801091046A CN 200380109104 A CN200380109104 A CN 200380109104A CN 100546963 C CN100546963 C CN 100546963C
- Authority
- CN
- China
- Prior art keywords
- phenol
- described method
- ketone
- resin
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0218—Sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
- B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
- B01J2231/347—1,2-additions, e.g. aldol or Knoevenagel condensations via cationic intermediates, e.g. bisphenol A type processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/248,028 | 2002-12-12 | ||
| US10/248,028 US7112702B2 (en) | 2002-12-12 | 2002-12-12 | Process for the synthesis of bisphenol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1741979A CN1741979A (zh) | 2006-03-01 |
| CN100546963C true CN100546963C (zh) | 2009-10-07 |
Family
ID=32505716
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2003801091046A Expired - Fee Related CN100546963C (zh) | 2002-12-12 | 2003-12-04 | 双酚的合成方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7112702B2 (enExample) |
| EP (1) | EP1572611B1 (enExample) |
| JP (1) | JP4579694B2 (enExample) |
| CN (1) | CN100546963C (enExample) |
| AU (1) | AU2003293363A1 (enExample) |
| DE (1) | DE60328522D1 (enExample) |
| WO (1) | WO2004054949A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4640313A1 (en) | 2024-04-22 | 2025-10-29 | Tianjin University | Pretreatment process of resin catalyst for synthesizing bisphenol a |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1683779A4 (en) * | 2003-11-13 | 2007-08-29 | Mitsubishi Chem Corp | PROCESS FOR PREPARING BISPHENOL A |
| DE102004005724A1 (de) * | 2004-02-05 | 2005-08-25 | Bayer Materialscience Ag | Herstellung von Bisphenol A mit verringerter Isomerenbildung |
| US20090209491A1 (en) * | 2004-02-23 | 2009-08-20 | Trustees Of Tufts College | Lactams as conformationally constrained peptidomimetic inhibitors |
| JP4861128B2 (ja) * | 2006-11-08 | 2012-01-25 | 大阪瓦斯株式会社 | 9,9−ビス(4−ヒドロキシフェニル)フルオレン類の連続製造方法 |
| US8735634B2 (en) | 2011-05-02 | 2014-05-27 | Sabic Innovative Plastics Ip B.V. | Promoter catalyst system with solvent purification |
| US20120283485A1 (en) * | 2011-05-02 | 2012-11-08 | Umesh Krishna Hasyagar | Robust promoter catalyst system |
| US9290618B2 (en) | 2011-08-05 | 2016-03-22 | Sabic Global Technologies B.V. | Polycarbonate compositions having enhanced optical properties, methods of making and articles comprising the polycarbonate compositions |
| CN104205376B (zh) | 2012-02-03 | 2018-04-27 | 沙特基础全球技术有限公司 | 发光二极管器件及用于生产其的包括转换材料化学的方法 |
| WO2013130610A1 (en) | 2012-02-29 | 2013-09-06 | Sabic Innovative Plastics Ip B.V. | Polycarbonate compositions containing conversions material chemistry and having enhanced optical properties, methods of making and articles comprising the same |
| WO2013130606A2 (en) | 2012-02-29 | 2013-09-06 | Sabic Innovative Plastics Ip B.V. | Polycarbonate made from low sulfur bisphenol a and containing converions material chemistry, and articles made therefrom |
| US9346949B2 (en) | 2013-02-12 | 2016-05-24 | Sabic Global Technologies B.V. | High reflectance polycarbonate |
| US9821523B2 (en) | 2012-10-25 | 2017-11-21 | Sabic Global Technologies B.V. | Light emitting diode devices, method of manufacture, uses thereof |
| US9553244B2 (en) | 2013-05-16 | 2017-01-24 | Sabic Global Technologies B.V. | Branched polycarbonate compositions having conversion material chemistry and articles thereof |
| EP3004234B1 (en) | 2013-05-29 | 2021-08-18 | SABIC Global Technologies B.V. | Illuminating devices with color stable thermoplastic light-transmitting articles |
| CN103819313A (zh) * | 2014-02-20 | 2014-05-28 | 常州市正锋光电新材料有限公司 | 一种双酚芴的制备方法 |
| US10851230B2 (en) * | 2015-12-09 | 2020-12-01 | Ptt Global Chemical Public Company Limited | Ion exchange resin for producing bisphenol, and a method for producing bisphenol using said ion exchange resin |
| RU2626005C1 (ru) * | 2016-06-15 | 2017-07-21 | Федеральное государственное унитарное предприятие "Российский научный центр "Прикладная химия" | Способ получения бисфенолов |
| CN109414687A (zh) * | 2016-06-24 | 2019-03-01 | 沙特基础工业全球技术有限公司 | 交联聚苯乙烯催化剂、制备方法及其用途 |
| JP6829135B2 (ja) * | 2017-03-30 | 2021-02-10 | 大阪ガスケミカル株式会社 | フルオレン誘導体の製造方法 |
| CN107876089B (zh) * | 2017-11-24 | 2020-08-25 | 北京濮源新材料技术研究院(普通合伙) | 用于双酚a合成的离子液体催化剂体系及其制备方法 |
| EP4087898A1 (en) * | 2020-01-09 | 2022-11-16 | Sumitomo Chemical Advanced Technologies, LLC, D.B.A. Sumika Electronic Materials | Phloroglucinolic resins, methods of making, and uses in rubber compositions |
| US20240294452A1 (en) * | 2021-02-23 | 2024-09-05 | Covestro Deutschland Ag | Process for preparing bisphenol a (bpa) in the presence of cumene |
| JP2024508774A (ja) * | 2021-02-23 | 2024-02-28 | コベストロ、ドイチュラント、アクチエンゲゼルシャフト | ベンゼンの存在下でビスフェノールa(bpa)を作製するプロセス |
| US12486354B2 (en) | 2023-02-28 | 2025-12-02 | Westlake Epoxy Inc. | Processes for forming bisphenols, epoxy resin compositions |
| CN117446763B (zh) * | 2023-10-11 | 2025-09-19 | 浙江锦华新材料股份有限公司 | 一种环己酮肟催化水解制备羟胺水溶液的方法 |
| CN117486692A (zh) * | 2023-11-02 | 2024-02-02 | 世名(辽宁)新材料有限公司 | 一种利用微通道反应制备双醚芴的方法 |
Citations (4)
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|---|---|---|---|---|
| EP0045959A1 (en) * | 1980-08-07 | 1982-02-17 | Mitsubishi Kasei Corporation | Process for preparing bisphenols |
| US4400555A (en) * | 1981-10-06 | 1983-08-23 | General Electric Company | Ion exchange catalyzed bisphenol synethesis |
| US5284981A (en) * | 1986-06-10 | 1994-02-08 | Bayer Aktiengesellschaft | Ion exchangers modified with mercapto amines |
| WO2002070443A1 (en) * | 2001-03-01 | 2002-09-12 | Idemitsu Petrochemical Co., Ltd. | Process for producing bisphenol a |
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- 2002-12-12 US US10/248,028 patent/US7112702B2/en not_active Expired - Fee Related
-
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- 2003-12-04 JP JP2004560357A patent/JP4579694B2/ja not_active Expired - Fee Related
- 2003-12-04 WO PCT/US2003/038487 patent/WO2004054949A1/en not_active Ceased
- 2003-12-04 DE DE60328522T patent/DE60328522D1/de not_active Expired - Lifetime
- 2003-12-04 CN CNB2003801091046A patent/CN100546963C/zh not_active Expired - Fee Related
- 2003-12-04 AU AU2003293363A patent/AU2003293363A1/en not_active Abandoned
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4640313A1 (en) | 2024-04-22 | 2025-10-29 | Tianjin University | Pretreatment process of resin catalyst for synthesizing bisphenol a |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1741979A (zh) | 2006-03-01 |
| EP1572611A1 (en) | 2005-09-14 |
| EP1572611B1 (en) | 2009-07-22 |
| US20040116751A1 (en) | 2004-06-17 |
| US7112702B2 (en) | 2006-09-26 |
| JP4579694B2 (ja) | 2010-11-10 |
| WO2004054949A1 (en) | 2004-07-01 |
| JP2006509818A (ja) | 2006-03-23 |
| DE60328522D1 (de) | 2009-09-03 |
| AU2003293363A1 (en) | 2004-07-09 |
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