CN100534780C - 用于防火门的复合层板 - Google Patents
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Abstract
本发明涉及一种复合层板,其至少包括:a)一层具有基于碱金属硅酸盐的膨胀组合物的防火层(A),并且该防火层在两侧上被施涂,b)保护层(B和B’),以及c)由木材、纸面石膏板、熟石膏或硅酸钙板、纸张、金属、塑料或另外的防火层组成的底材层(C)。本发明还涉及一种生产复合材料的方法以及该复合材料作为防火门的芯材的用途。
Description
本发明涉及复合层板,其至少包括:
a)具有基于碱金属硅酸盐的膨胀组合物的防火层A,并且该防火层在两侧上被施涂,
b)保护层B和B’,以及
c)由无机或有机结构材料、纸张、金属、塑料或另外的防火层组成的底材层C,以及还涉及它们的生产方法。
在暴露于高温下时会膨胀成为稳定的泡沫层的基于碱金属硅酸盐的绝热防火层例如由DE-B-1169832获知。然而,因为碱金属硅酸盐对暴露于湿气和二氧化碳中敏感,因此它们必须由保护层保护以防暴露于湿气和二氧化碳中。DE-A-1621799描述了由碱金属硅酸盐组成的且具有由环氧树脂组成的保护层的防火板。
防火材料的主要应用领域之一是由木材组成的防火门,其中必须利用钉钉子的方式或粘合方式将阻燃层施用于木材或者碎料纤维板上。为了获得足够的粘合,必须使用昂贵的专门的粘合剂或者必须将填料颗粒嵌入环氧树脂层的表面中(EP-B 0743292)。
因此,本发明目的就是发现可用于木制品工厂中而没有通过专门粘合剂的复杂粘合的防火门用复合层板。进一步目的是发现一种简单而便宜的用于生产复合层板的方法。
相应地已经发现了开始时所述的复合层板。
防火层A优选由基于硅酸钠的膨胀组合物形成。为此,使用水含量约65重量%的市购水玻璃溶液,并且将其与水含量约18重量%的水玻璃粉末混合。对于该混合物的混和时间可以由水玻璃粉末的用量来精确地调节。合适的话,可以将无机填料如金属氢氧化物或金属硫酸盐水合物以0-50重量%的量加入到混合物中,如同可以不超过10重量%的有机材料。为了增强,防火层A一般包含2-20重量%的玻璃纤维。
防火层A的厚度一般为1-5mm,优选1.5-3mm。它的制备描述于例如DE-A-1621799中。
防火层B和B’优选由环氧树脂或聚氨酯树脂组成,且它们的厚度为10-500μm,优选20-100μm。
可使用的底材层C是无机或有机结构材料,例如木材、中密度或高密度纤维板、石膏板或硅酸钙板、纸张、金属或塑料。
然而,使用另外的防火层作为底材层C也是可行的。如同防火层A,另外的防火层可以包含基于碱金属硅酸盐的膨胀组合物或基于可膨胀石墨的膨胀组合物,例如如EP-A 0694574中所描述。这种方法可以生产具有较高厚度或具有平衡防火性能的防火层。
底材层C的厚度可以在大范围内变化且基本上根据所用结构材料和预期应用来决定。底材层C的厚度通常为0.1-500mm,优选1-100mm。
因此,本发明的复合层板有B’-A-B-C的层序。然而,它也可以包含两层或更多层底材层C。在这种情况下,保护层B和保护层B’都作为防火层A和底材层C之间的连接层。优选层序是C-B’-A-B-C或C-B’-A-B-C-B-A-B’-C。
本发明的复合层板可以通过将环氧/硬化剂混合物或聚氨酯树脂粘合剂施用于防火层A并且在完全固化保护层B之前施用底材层C来生产。固化可在压机例如单板压机中进行,压机中的压力在固化期间为0.1-10巴,优选2-5巴。可以将另一保护层B’施用于防火层A的反面,并且在制得复合材料和翻转材料之前或之后固化。
为了形成其它层,上述方法可根据需要重复进行。优选的是,用环氧/硬化剂混合物或聚氨酯树脂粘合剂涂敷防火层A并且用两层或更多层底材层C按所需层序堆叠于防火层A上。然后,固化优选通过在压机中挤压整个复合材料进行。由于防火层A在还没有涂敷时更柔韧,因此这获得较好的挤压和较小的厚度变化。在固化过程中温度基本由环氧/硬化剂混合物或聚氨酯树脂粘合剂的性质和构成决定,并且温度一般在20-100℃范围内。在更高温度下,为了抑制防火层A起泡,选择的挤压时间必须适当缩短。
本发明的复合层板可以在非自动化工厂里通过常规的加工机器、通过锯、切割或冲压容易地加工。具有由中密度或高密度纤维板组成的底材层C的复合层板尤其适合作为防火门的芯材。
实施例
实施例1
利用基于DE-A-1621799的实施例1的方法,将所述出版物中描述的环氧/硬化剂混合物施用于厚度为1.2mm的板的一侧上,使用的单位面积重量为90g/m2,所述板由玻璃纤维增强的硅酸钠组成。然后,施用厚1mm的中密度纤维板,并且在单板压机中于80℃下固化10分钟,压机中压力为4kg/cm2。
实施例2
利用与实施例1类似的方法,将环氧/硬化剂混合物施用于厚度为1.2mm的板的双侧上,使用的单位面积重量为90g/m2,所述板由玻璃纤维增强的硅酸钠组成,并且将厚1mm的中密度纤维板施用于每一侧上。如同实施例1所述将得到的复合材料在单板压机中固化,得到层序为C-B’-A-B-C的复合材料。
Claims (11)
1.一种生产复合层板的方法,其包括将环氧树脂/硬化剂混合物或聚氨酯树脂粘合剂施用于具有基于碱金属硅酸盐的膨胀组合物的防火层A,形成保护层B,在完全固化保护层B之前施用由木材、纤维板、纸张、金属或塑料组成的底材层C,并且在压机中进行固化。
2.如权利要求1所要求的方法,其中固化期间压机内压力为0.1-10巴。
3.如权利要求1或2所要求的方法,其中在施用保护层B和底材层C之前或之后,将另一保护层B’施用于防火层A并且固化。
4.一种复合层板,其至少包括:
a)具有基于碱金属硅酸盐的膨胀组合物的防火层A,并且该防火层在两侧上被施涂,
b)保护层B和B’,该保护层由环氧树脂或聚氨酯树脂组成,并且作为防火层A和底材层C之间的连接层,以及
c)由无机或有机结构材料、纸张、金属、塑料组成的底材层C,其中复合层板具有层序B’-A-B-C,且可通过根据权利要求3的方法获得。
5.根据权利要求4所述的复合层板,其中防火层A由纤维增强的含水硅酸钠组成。
6.根据权利要求4所述的复合层板,其中底材层C包含作为无机或有机结构材料的木材、中密度或高密度纤维板、熟石膏或硅酸钙。
7.根据权利要求5所述的复合层板,其中底材层C包含作为无机或有机结构材料的木材、中密度或高密度纤维板、熟石膏或硅酸钙。
8.根据权利要求4-7中任意一项所述的复合层板,其中防火层A的厚度为1-5mm,保护层B和B’各自的厚度为10-500μm,且底材层C的厚度为0.1-100mm。
9.根据权利要求4-7中任意一项所述的复合层板,其组成层序为C-B’-A-B-C。
10.根据权利要求8所述的复合层板,其组成层序为C-B’-A-B-C。
11.一种防火门,其包括根据权利要求4-10中任意一项所述的复合层板。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102004049632.3 | 2004-10-11 | ||
DE200410049632 DE102004049632B4 (de) | 2004-10-11 | 2004-10-11 | Verbundschichtplatte für Brandschutztüren |
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CN101039799A CN101039799A (zh) | 2007-09-19 |
CN100534780C true CN100534780C (zh) | 2009-09-02 |
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CNB2005800345491A Expired - Fee Related CN100534780C (zh) | 2004-10-11 | 2005-10-08 | 用于防火门的复合层板 |
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US (1) | US20080138585A1 (zh) |
EP (1) | EP1802454B1 (zh) |
JP (1) | JP2008516112A (zh) |
KR (1) | KR20070063035A (zh) |
CN (1) | CN100534780C (zh) |
BR (1) | BRPI0516844A (zh) |
CA (1) | CA2581344A1 (zh) |
DE (1) | DE102004049632B4 (zh) |
ES (1) | ES2383606T3 (zh) |
NO (1) | NO20071543L (zh) |
PL (1) | PL1802454T3 (zh) |
RU (1) | RU2373062C2 (zh) |
UA (1) | UA85907C2 (zh) |
WO (1) | WO2006040097A1 (zh) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102007049727A1 (de) | 2007-10-16 | 2009-04-23 | Basf Se | Brand-Schall-Schutztür |
BE1017821A5 (nl) * | 2007-10-19 | 2009-08-04 | Flooring Ind Ltd Sarl | Plaat, werkwijzen voor het vervaardigen van platen en paneel dat dergelijk plaatmateriaal bevat. |
JP5382416B2 (ja) * | 2009-01-21 | 2014-01-08 | 清水建設株式会社 | 建具及び耐火被覆材 |
FR2943699B1 (fr) * | 2009-03-31 | 2012-06-29 | Vincent Damour | Panneau sandwich resistant au feu,avec une ame a base de silicate renforce. |
RU2013144410A (ru) | 2011-03-04 | 2015-04-10 | Басф Се | Композитные элементы |
US9126386B2 (en) | 2011-03-04 | 2015-09-08 | Basf Se | Composite elements |
ITMI20112399A1 (it) * | 2011-12-28 | 2013-06-29 | Silcart S P A | Pannello isolante da costruzione e relativo metodo di fabbricazione |
WO2013102208A1 (en) * | 2011-12-29 | 2013-07-04 | Firestone Building Products Co., LLC | Roofing membranes with expandable graphite as flame retardant |
ES2425140B1 (es) * | 2013-08-28 | 2014-08-05 | Oatek, S.L. | Cerramiento cortafuegos |
FR3016188B1 (fr) * | 2014-01-09 | 2016-01-01 | Snecma | Protection contre le feu d'une piece en materiau composite tisse tridimensionnel |
DE202014105591U1 (de) * | 2014-11-20 | 2016-02-23 | Holzbau Schmid Gmbh & Co. Kg | Nicht brennbare Baustofftür |
CN104831825A (zh) * | 2015-06-03 | 2015-08-12 | 安徽五信新材料有限公司 | 一种抗冲击金属复合防火板 |
CN108099309A (zh) * | 2017-12-22 | 2018-06-01 | 衢州听语信息科技有限公司 | 一种防火层压板 |
CN108277944A (zh) * | 2018-03-28 | 2018-07-13 | 浙江省建材集团建筑产业化有限公司 | 一种透气纸板建材 |
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DE1169832B (de) * | 1960-08-27 | 1964-05-06 | Basf Ag | Verfahren zur Herstellung von thermisch isolierenden Flammschutzschichten |
US3106500A (en) * | 1960-11-01 | 1963-10-08 | Thomas M Turner | Wood veneered gypsum board panel and process for making same |
DE1621799B2 (de) * | 1966-01-18 | 1977-03-10 | Basf Ag, 6700 Ludwigshafen | Verfahren zur erhoehung der dauerbestaendigkeit von formkoerpern aus alkalisilikaten |
GB1477658A (en) * | 1974-10-08 | 1977-06-22 | Ici Ltd | Laminates |
CA1127395A (en) * | 1978-06-14 | 1982-07-13 | Bfg Glassgroup | Fire screening glazing panels and method of manufacturing same |
JPS56130341A (en) * | 1980-03-19 | 1981-10-13 | Takeda Chemical Industries Ltd | Manufacture of refractory heat insulating material |
US4530877A (en) * | 1981-10-22 | 1985-07-23 | Cyclops Corporation | Fire resistant foam insulated building panels |
US4515744A (en) * | 1983-07-28 | 1985-05-07 | The General Tire & Rubber Company | Vinyl chloride polymer laminate |
DE3622897A1 (de) * | 1986-07-08 | 1988-01-21 | Wolman Gmbh Dr | Brand- und schallschutzkassette |
DE3776230D1 (de) * | 1986-08-28 | 1992-03-05 | Ciba Geigy Ag | Mit silikat behandelte bienenwabenstruktur. |
GB2239213B (en) * | 1989-12-23 | 1993-06-16 | Glaverbel | Fire-screening panels |
FR2695159B1 (fr) * | 1992-07-06 | 1995-01-13 | Olivier Sa | Structure sandwich pour éléments de portes et cloisons coupe-feu. |
EP0694574A1 (de) * | 1994-06-24 | 1996-01-31 | Dr. Wolman GmbH | Verfahren zur Herstellung von brandschützenden Verbundwerkstoffen |
EP0822896B1 (en) * | 1995-04-26 | 2001-10-24 | Atévic, Tomislav | Laminated structure with improved fire resistance and procedure for the manufacture of the structure |
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SE513860C2 (sv) * | 1998-01-16 | 2000-11-20 | Glasis Holding Ab | Brandbeständig skiva samt förfarande för framställning därav |
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- 2005-10-08 KR KR1020077010622A patent/KR20070063035A/ko not_active Application Discontinuation
- 2005-10-08 PL PL05793841T patent/PL1802454T3/pl unknown
- 2005-10-08 CN CNB2005800345491A patent/CN100534780C/zh not_active Expired - Fee Related
- 2005-10-08 WO PCT/EP2005/010849 patent/WO2006040097A1/de active Application Filing
- 2005-10-08 RU RU2007117349A patent/RU2373062C2/ru not_active IP Right Cessation
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Also Published As
Publication number | Publication date |
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DE102004049632B4 (de) | 2008-07-31 |
CN101039799A (zh) | 2007-09-19 |
ES2383606T3 (es) | 2012-06-22 |
DE102004049632A1 (de) | 2006-05-11 |
BRPI0516844A (pt) | 2008-09-23 |
EP1802454B1 (de) | 2012-05-16 |
CA2581344A1 (en) | 2006-04-20 |
NO20071543L (no) | 2007-05-08 |
JP2008516112A (ja) | 2008-05-15 |
WO2006040097A1 (de) | 2006-04-20 |
RU2007117349A (ru) | 2008-11-20 |
US20080138585A1 (en) | 2008-06-12 |
PL1802454T3 (pl) | 2012-10-31 |
RU2373062C2 (ru) | 2009-11-20 |
EP1802454A1 (de) | 2007-07-04 |
UA85907C2 (uk) | 2009-03-10 |
KR20070063035A (ko) | 2007-06-18 |
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