CN100532400C - 用于烯烃聚合的催化剂体系 - Google Patents

用于烯烃聚合的催化剂体系 Download PDF

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Publication number
CN100532400C
CN100532400C CNB038162067A CN03816206A CN100532400C CN 100532400 C CN100532400 C CN 100532400C CN B038162067 A CNB038162067 A CN B038162067A CN 03816206 A CN03816206 A CN 03816206A CN 100532400 C CN100532400 C CN 100532400C
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China
Prior art keywords
formula
contain
atom
alkyl
ring
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Expired - Fee Related
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CNB038162067A
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English (en)
Chinese (zh)
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CN1832970A (zh
Inventor
L·雷斯科尼
F·福坎特
I·卡穆拉蒂
S·吉多蒂
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Basell Polyolefine GmbH
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Basell Polyolefine GmbH
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Publication of CN1832970A publication Critical patent/CN1832970A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/027—Organoboranes and organoborohydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CNB038162067A 2002-07-09 2003-07-09 用于烯烃聚合的催化剂体系 Expired - Fee Related CN100532400C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US39461402P 2002-07-09 2002-07-09
US60/394,614 2002-07-09

Publications (2)

Publication Number Publication Date
CN1832970A CN1832970A (zh) 2006-09-13
CN100532400C true CN100532400C (zh) 2009-08-26

Family

ID=30115746

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB038162067A Expired - Fee Related CN100532400C (zh) 2002-07-09 2003-07-09 用于烯烃聚合的催化剂体系

Country Status (7)

Country Link
US (1) US7314903B2 (enExample)
EP (1) EP1611167A2 (enExample)
JP (1) JP2006508903A (enExample)
CN (1) CN100532400C (enExample)
AU (1) AU2003257448A1 (enExample)
BR (1) BR0305627A (enExample)
WO (1) WO2004005360A2 (enExample)

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DE60202524T2 (de) * 2001-05-21 2005-06-30 Basell Polyolefine Gmbh Katalysatorsystem für die polymerisierung von olefinen
EP1539843B1 (en) 2002-09-06 2009-10-14 Basell Polyolefine GmbH Process for the copolymerization of ethylene
EP1549688A2 (en) * 2002-10-10 2005-07-06 Basell Polyolefine GmbH Process for the copolymerization of ethylene
US7741417B2 (en) 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
EP1753792B1 (en) * 2004-05-04 2009-10-14 Basell Polyolefine GmbH Process for the preparation of atactic 1-butene polymers
EP1794197A4 (en) 2004-09-16 2009-07-01 Lg Chemical Ltd CATALYST SYSTEM FOR POLYMERIZATION OF CYCLIC OLEFIN HAVING POLAR FUNCTIONAL GROUP, POLYMERIZATION METHOD USING THE CATALYST SYSTEM, OLEFIN POLYMER PRODUCED THEREBY, AND OPTICAL ANISOTROPIC FILM COMPRISING THE OLEFIN POLYMER
CA2584395A1 (en) 2004-10-18 2006-04-27 Basell Poliolefine Italia S.R.L. Butene-1 (co)polymers having low isotacticity
WO2006045687A1 (en) 2004-10-21 2006-05-04 Basell Polyolefine Gmbh 1-butene polymer and process for the preparation thereof
EP1655314A1 (en) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
JP2008520793A (ja) * 2004-11-22 2008-06-19 バーゼル・ポリオレフィン・ゲーエムベーハー プロピレンベースのターポリマー
EP1825036A1 (en) * 2004-12-13 2007-08-29 Basell Poliolefine Italia S.r.l. Polyolefin composition, fibres and nonwoven fabrics
ATE502080T1 (de) * 2005-02-03 2011-04-15 Basell Polyolefine Gmbh Verfahren zur herstellung von warmgeformten artikeln
US7842764B2 (en) 2005-03-18 2010-11-30 Basell Poliolefine Italia S.R.L. Metallocene compounds
WO2006097500A1 (en) * 2005-03-18 2006-09-21 Basell Polyolefine Gmbh Metallocene compounds
JP5294842B2 (ja) 2005-03-23 2013-09-18 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィンの重合プロセス
JP2008534705A (ja) 2005-03-23 2008-08-28 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン類の重合法
JP2008540714A (ja) * 2005-05-03 2008-11-20 バーゼル・ポリオレフィン・ゲーエムベーハー α−オレフィンの重合方法
JP2008540752A (ja) 2005-05-11 2008-11-20 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ポリオレフィンブレンドを製造するための重合方法
US8051611B2 (en) * 2005-06-24 2011-11-08 Dryvit Systems, Inc. Exterior insulation and finish system and method and tool for installing same
JP5379480B2 (ja) * 2005-10-21 2013-12-25 バーゼル・ポリオレフィン・ゲーエムベーハー プロピレンポリマー
JP5379479B2 (ja) 2005-10-21 2013-12-25 バーゼル・ポリオレフィン・ゲーエムベーハー 射出成形用のポリプロピレン
JP5584416B2 (ja) * 2005-10-21 2014-09-03 バーゼル・ポリオレフィン・ゲーエムベーハー 射出成形及びメルトブロー用途のための高いメルトフローレートを有するポリプロピレンランダムコポリマー
US20090156391A1 (en) * 2005-12-06 2009-06-18 Basell Poliolefine Italia S.R.L. Catalyst Components for the Polymerization of Olefins
CA2641818C (en) * 2006-02-02 2012-04-10 Basell Polyolefine Gmbh Propylene homopolymer melt blown resins
ATE461244T1 (de) * 2006-02-23 2010-04-15 Basell Poliolefine Srl Propylenpolymere für spritzgiessanwendungen
JP5295098B2 (ja) * 2006-04-21 2013-09-18 バーゼル・ポリオレフィン・ゲーエムベーハー エチレンコポリマーの製造方法
US8785575B2 (en) * 2006-04-21 2014-07-22 Basell Polyolefine Gmbh Process for the preparation of ethylene propylene copolymers
US8022005B2 (en) * 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US7799879B2 (en) 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
CN102112499B (zh) 2008-08-01 2014-02-05 埃克森美孚化学专利公司 催化剂体系和用于烯烃聚合的方法
CN103857706B (zh) 2011-09-30 2016-09-28 埃克森美孚化学专利公司 金属茂催化剂的动力学调制
EP3022233B1 (en) 2013-07-17 2019-05-01 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
CN105377904B (zh) 2013-07-17 2018-07-10 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
JP2016531978A (ja) 2013-07-17 2016-10-13 エクソンモービル ケミカル パテンツ インコーポレイテッド 置換メタロセン触媒
CN105358589B (zh) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
WO2015009480A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US10570219B2 (en) 2015-06-05 2020-02-25 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
WO2016196334A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
WO2017204830A1 (en) 2016-05-27 2017-11-30 Exxonmobil Chemical Patents, Inc. Metallocene catalyst compositions and polymerization process therewith
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
EP4476275A1 (en) 2022-02-07 2024-12-18 ExxonMobil Chemical Patents Inc. C1 symmetric 5-ome-6-alkyl substituted metallocenes

Citations (3)

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CN88103902A (zh) * 1987-05-13 1988-12-14 三井石油化学工业株式会社 烯烃聚合的固体催化剂
CN1034548A (zh) * 1987-11-20 1989-08-09 中国石油化工总公司 烯烃聚合的载体催化剂体系的制法
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CN88103902A (zh) * 1987-05-13 1988-12-14 三井石油化学工业株式会社 烯烃聚合的固体催化剂
CN1034548A (zh) * 1987-11-20 1989-08-09 中国石油化工总公司 烯烃聚合的载体催化剂体系的制法
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Also Published As

Publication number Publication date
JP2006508903A (ja) 2006-03-16
WO2004005360A3 (en) 2005-11-10
AU2003257448A8 (en) 2004-01-23
CN1832970A (zh) 2006-09-13
WO2004005360A2 (en) 2004-01-15
US7314903B2 (en) 2008-01-01
AU2003257448A1 (en) 2004-01-23
BR0305627A (pt) 2004-09-08
EP1611167A2 (en) 2006-01-04
US20060094840A1 (en) 2006-05-04

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