CN100500754C - 用于农业应用的聚合物组合物和促进植物生长的方法 - Google Patents
用于农业应用的聚合物组合物和促进植物生长的方法 Download PDFInfo
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- CN100500754C CN100500754C CNB2003101138805A CN200310113880A CN100500754C CN 100500754 C CN100500754 C CN 100500754C CN B2003101138805 A CNB2003101138805 A CN B2003101138805A CN 200310113880 A CN200310113880 A CN 200310113880A CN 100500754 C CN100500754 C CN 100500754C
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- alkyl
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- carbon atoms
- carbon atom
- phenyl
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- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 27
- 229920000642 polymer Polymers 0.000 title claims description 43
- -1 dialkylamino benzaldehyde Chemical compound 0.000 claims abstract description 216
- 239000000654 additive Substances 0.000 claims abstract description 46
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- 239000007859 condensation product Substances 0.000 claims abstract description 36
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 22
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 142
- 229910052799 carbon Inorganic materials 0.000 claims description 123
- 125000000217 alkyl group Chemical group 0.000 claims description 104
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 104
- 229910052757 nitrogen Inorganic materials 0.000 claims description 88
- 150000001875 compounds Chemical class 0.000 claims description 80
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 70
- 229910052739 hydrogen Inorganic materials 0.000 claims description 64
- 239000006096 absorbing agent Substances 0.000 claims description 45
- 125000001118 alkylidene group Chemical group 0.000 claims description 44
- 239000001257 hydrogen Substances 0.000 claims description 43
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 38
- 125000003545 alkoxy group Chemical group 0.000 claims description 34
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 34
- 229910052760 oxygen Inorganic materials 0.000 claims description 33
- 239000001301 oxygen Substances 0.000 claims description 31
- 150000001412 amines Chemical class 0.000 claims description 28
- 125000002769 thiazolinyl group Chemical group 0.000 claims description 26
- 229910052736 halogen Inorganic materials 0.000 claims description 23
- 150000002367 halogens Chemical class 0.000 claims description 23
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 22
- 239000000460 chlorine Substances 0.000 claims description 22
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 21
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 18
- 239000012964 benzotriazole Substances 0.000 claims description 18
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 18
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 17
- 229910052801 chlorine Inorganic materials 0.000 claims description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 16
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 16
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 claims description 15
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 15
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 claims description 14
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 11
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- VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical compound OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
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- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 8
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- FNIATMYXUPOJRW-UHFFFAOYSA-N cyclohexylidene Chemical group [C]1CCCCC1 FNIATMYXUPOJRW-UHFFFAOYSA-N 0.000 claims description 7
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- GXFQBBOZTNQHMW-UHFFFAOYSA-N n'-(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound CC1(C)CC(NCCCCCCN)CC(C)(C)N1 GXFQBBOZTNQHMW-UHFFFAOYSA-N 0.000 claims description 7
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 6
- 150000005690 diesters Chemical class 0.000 claims description 6
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 6
- 238000003780 insertion Methods 0.000 claims description 6
- ODGYWRBCQWKSSH-UHFFFAOYSA-N n'-ethylpropane-1,3-diamine Chemical compound CCNCCCN ODGYWRBCQWKSSH-UHFFFAOYSA-N 0.000 claims description 6
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 claims description 6
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- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 5
- 239000012965 benzophenone Substances 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 125000004193 piperazinyl group Chemical group 0.000 claims description 5
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- IYXGSMUGOJNHAZ-UHFFFAOYSA-N Ethyl malonate Chemical compound CCOC(=O)CC(=O)OCC IYXGSMUGOJNHAZ-UHFFFAOYSA-N 0.000 claims description 4
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- 239000003963 antioxidant agent Substances 0.000 claims description 4
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- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- HTSVYUUXJSMGQC-UHFFFAOYSA-N 2-chloro-1,3,5-triazine Chemical compound ClC1=NC=NC=N1 HTSVYUUXJSMGQC-UHFFFAOYSA-N 0.000 claims description 3
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical group C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 3
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000007952 growth promoter Substances 0.000 claims description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 claims description 3
- 229940038384 octadecane Drugs 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- 125000006839 xylylene group Chemical group 0.000 claims description 3
- FBIXXCXCZOZFCO-UHFFFAOYSA-N 3-dodecyl-1-(2,2,6,6-tetramethylpiperidin-4-yl)pyrrolidine-2,5-dione Chemical compound O=C1C(CCCCCCCCCCCC)CC(=O)N1C1CC(C)(C)NC(C)(C)C1 FBIXXCXCZOZFCO-UHFFFAOYSA-N 0.000 claims description 2
- SXGXVOZDLWXVKM-UHFFFAOYSA-N 3-dodecylpyrrolidine-2,5-dione Chemical compound CCCCCCCCCCCCC1CC(=O)NC1=O SXGXVOZDLWXVKM-UHFFFAOYSA-N 0.000 claims description 2
- GHUDTURWNYDCKX-UHFFFAOYSA-N 4-oxo-4-(2,2,6,6-tetramethylpiperidin-4-yl)oxybutanoic acid Chemical compound CC1(C)CC(OC(=O)CCC(O)=O)CC(C)(C)N1 GHUDTURWNYDCKX-UHFFFAOYSA-N 0.000 claims description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 2
- 125000003282 alkyl amino group Chemical group 0.000 claims description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 claims description 2
- 239000007850 fluorescent dye Substances 0.000 claims description 2
- YVYHWOZEQUFKOB-UHFFFAOYSA-N n'-[3-(dimethylamino)propyl]oxamide Chemical compound CN(C)CCCNC(=O)C(N)=O YVYHWOZEQUFKOB-UHFFFAOYSA-N 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 6
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- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 12
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- 238000012544 monitoring process Methods 0.000 description 1
- 125000001802 myricyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- SLYJXPKHTZCZOG-UHFFFAOYSA-N n-tetradecyltetradecan-1-imine oxide Chemical compound CCCCCCCCCCCCCC[N+]([O-])=CCCCCCCCCCCCCC SLYJXPKHTZCZOG-UHFFFAOYSA-N 0.000 description 1
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- 229920003251 poly(α-methylstyrene) Polymers 0.000 description 1
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- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920002480 polybenzimidazole Polymers 0.000 description 1
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- 235000015320 potassium carbonate Nutrition 0.000 description 1
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 1
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- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
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- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
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- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- MGLWZSOBALDPEK-UHFFFAOYSA-N simetryn Chemical compound CCNC1=NC(NCC)=NC(SC)=N1 MGLWZSOBALDPEK-UHFFFAOYSA-N 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000004307 sodium orthophenyl phenol Substances 0.000 description 1
- IJRHDFLHUATAOS-DPMBMXLASA-M sodium ricinoleate Chemical compound [Na+].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O IJRHDFLHUATAOS-DPMBMXLASA-M 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 125000003003 spiro group Chemical group 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OLBWDGJTEXRJLY-UHFFFAOYSA-N tetradecyl 3-(2,2,4,4-tetramethyl-21-oxo-7-oxa-3,20-diazadispiro[5.1.11^{8}.2^{6}]henicosan-20-yl)propanoate Chemical compound O1C2(CCCCCCCCCCC2)N(CCC(=O)OCCCCCCCCCCCCCC)C(=O)C21CC(C)(C)NC(C)(C)C2 OLBWDGJTEXRJLY-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- 125000001680 trimethoxyphenyl group Chemical group 0.000 description 1
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229940070710 valerate Drugs 0.000 description 1
- 125000003774 valeryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 239000002446 δ-tocopherol Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3462—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3462—Six-membered rings
- C08K5/3465—Six-membered rings condensed with carbocyclic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Protection Of Plants (AREA)
- Nonwoven Fabrics (AREA)
- Greenhouses (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405904 | 2002-10-22 | ||
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020118933A1 (zh) | 2018-12-10 | 2020-06-18 | 优缔新材料科技(苏州)有限公司 | 一种新型多环化合物 |
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| ITMI20051202A1 (it) * | 2005-06-24 | 2006-12-25 | Alcantara Spa | Tessuto non tessuto microfibroso scamosciato ad elevata solidita' alla luce e procedimento per la sua preparazione |
| KR20080050503A (ko) * | 2005-10-12 | 2008-06-05 | 시바 홀딩 인코포레이티드 | 캡슐화된 발광 안료 |
| DE102005061954A1 (de) | 2005-12-23 | 2007-07-05 | Basf Ag | Verfahren zur Wiedergewinnung von Ruthenium aus gebrauchten Rutheniumoxid-haltigen Katalysatoren |
| MX277096B (es) | 2006-01-13 | 2010-07-06 | Basf Se | Mezcla de estabilizador. |
| WO2007088114A1 (en) * | 2006-02-01 | 2007-08-09 | Ciba Holding Inc. | Stabilizer composition for polymers |
| ATE532797T1 (de) * | 2006-05-31 | 2011-11-15 | 3M Innovative Properties Co | Polymerisierbare zusammensetzungen enthaltend salze aus barbitursäure-derivaten |
| GB0708692D0 (en) | 2007-05-04 | 2007-06-13 | Innovia Films Ltd | Seelable, pealable film |
| EP2147044B1 (en) | 2007-05-24 | 2013-08-07 | Innovia Films Limited | Low emissivity film |
| GB0714418D0 (en) | 2007-07-24 | 2007-09-05 | Innovia Films Ltd | UV barrier film |
| US20090056209A1 (en) * | 2007-08-28 | 2009-03-05 | Epi Environmental Technologies (Nevada) Inc. | Biodegradable agricultural film |
| WO2009080548A1 (en) * | 2007-12-21 | 2009-07-02 | Basf Se | Nano structured uv absorbers |
| USD619477S1 (en) | 2008-10-03 | 2010-07-13 | Innovia Films Limited | Outer wrapper for packaging of CDs/DVDs |
| WO2010081104A1 (en) * | 2009-01-10 | 2010-07-15 | Medical College Of Georgia Research Institute, Inc. | Use of polymeri zable quaternary ammonium compounds to inhibit endogenous mmps in tooth dentin |
| JP2012097198A (ja) * | 2010-11-02 | 2012-05-24 | Japan Polyethylene Corp | 機能性フィルムおよびその製造方法 |
| JP2012095601A (ja) * | 2010-11-02 | 2012-05-24 | Japan Polyethylene Corp | 農業用フィルム及びその製造方法 |
| GB201106677D0 (en) | 2011-04-20 | 2011-06-01 | Kritis Plastika | Multilayer plastic film with separable layers for covering of inflated greenhouse |
| US8889769B2 (en) * | 2011-06-27 | 2014-11-18 | Basf Se | Weathering-resistant polyester molding compositions with styrene copolymers |
| GB201204579D0 (en) * | 2012-03-15 | 2012-05-02 | Univ Nottingham Trent | Coating metal oxide particles |
| CN103450882A (zh) * | 2012-05-30 | 2013-12-18 | 财团法人工业技术研究院 | 荧光粉 |
| US9204598B2 (en) | 2013-05-27 | 2015-12-08 | Saudi Basic Indsutries Corporation | Solar energy funneling using thermoplastics for agricultural applications |
| EP3514204B1 (en) * | 2016-09-13 | 2021-03-17 | Kuraray Co., Ltd. | Resin composition and use of same |
| JP7005938B2 (ja) * | 2017-05-24 | 2022-02-10 | 大日本印刷株式会社 | 農業シート |
| KR102687097B1 (ko) | 2017-07-17 | 2024-07-19 | 에이비 루드빅 스벤쏜 | 온실 스크린 |
| CN111286133A (zh) * | 2018-12-06 | 2020-06-16 | 中国科学院苏州纳米技术与纳米仿生研究所 | 一种光转换膜及其制作方法 |
| JP2022551141A (ja) * | 2019-10-11 | 2022-12-07 | ソルヴェイ（ソシエテ アノニム） | 植物の花の発達を増加させるためのグリーンハウスフィルム中でのシリケートの使用 |
| KR102294987B1 (ko) * | 2020-03-27 | 2021-08-30 | 도레이첨단소재 주식회사 | 내후성이 강화된 부직포와 그의 적층체, 및 물품 |
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| EP0704560A1 (en) * | 1994-09-30 | 1996-04-03 | Ciba-Geigy Ag | Stabilization of pigmented fiber with a synergistic mixture of hindered amine and UV absorber |
| JP2701371B2 (ja) * | 1988-08-02 | 1998-01-21 | 三菱化学エムケーブイ株式会社 | 農業用塩化ビニル系樹脂蛍光フィルム |
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| US2803640A (en) * | 1954-11-12 | 1957-08-20 | Du Pont | Alpha-cyanovinyl-substituted aryl amines and their preparation |
| US3331687A (en) * | 1962-09-24 | 1967-07-18 | Render Belipa G M B H Fa | Electrophotographic material |
| PL103086B1 (pl) * | 1976-05-06 | 1979-05-31 | Ciba Geigy Ag | Srodek owadobojczy |
| SU695635A1 (ru) * | 1977-12-01 | 1979-11-05 | Северо-Кавказский научно-исследовательский институт фитопатологии | Стимул тор роста растений |
| US4707297A (en) * | 1986-04-29 | 1987-11-17 | Bell & Howell Company | Removable guidepath for automated guidance vehicles |
| JPH04144618A (ja) * | 1990-10-05 | 1992-05-19 | Mitsubishi Kasei Vinyl Co | 農業用塩化ビニル系樹脂蛍光フィルム |
| JPH11116556A (ja) * | 1997-10-13 | 1999-04-27 | Chemiprokasei Kaisha Ltd | アミノメチレンピリミジン誘導体、その製造方法および用途 |
| JP2000136270A (ja) | 1998-10-30 | 2000-05-16 | Dainippon Ink & Chem Inc | 樹脂組成物およびその成形体 |
| CO5231248A1 (es) | 2000-07-26 | 2002-12-27 | Ciba Sc Holding Ag | Articulos transparentes de polimero de baja consistencia |
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- 2003-10-10 MY MYPI20033871A patent/MY130651A/en unknown
- 2003-10-14 ES ES03405736T patent/ES2277053T3/es not_active Expired - Lifetime
- 2003-10-14 PT PT03405736T patent/PT1413599E/pt unknown
- 2003-10-14 DE DE60310500T patent/DE60310500T2/de not_active Expired - Lifetime
- 2003-10-14 EP EP03405736A patent/EP1413599B1/en not_active Expired - Lifetime
- 2003-10-14 AT AT03405736T patent/ATE348858T1/de active
- 2003-10-17 EC EC2003004812A patent/ECSP034812A/es unknown
- 2003-10-17 ZA ZA200308091A patent/ZA200308091B/xx unknown
- 2003-10-20 KR KR1020030072954A patent/KR100963983B1/ko not_active Expired - Fee Related
- 2003-10-20 AR ARP030103809A patent/AR041667A1/es active IP Right Grant
- 2003-10-20 US US10/690,120 patent/US7037962B2/en not_active Expired - Fee Related
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- 2003-10-20 CA CA2445617A patent/CA2445617C/en not_active Expired - Fee Related
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- 2003-10-20 IL IL158505A patent/IL158505A/en not_active IP Right Cessation
- 2003-10-21 CN CNB2003101138805A patent/CN100500754C/zh not_active Expired - Fee Related
- 2003-10-21 MX MXPA03009621A patent/MXPA03009621A/es active IP Right Grant
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- 2003-10-22 JP JP2003362083A patent/JP4461319B2/ja not_active Expired - Fee Related
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2701371B2 (ja) * | 1988-08-02 | 1998-01-21 | 三菱化学エムケーブイ株式会社 | 農業用塩化ビニル系樹脂蛍光フィルム |
| EP0704560A1 (en) * | 1994-09-30 | 1996-04-03 | Ciba-Geigy Ag | Stabilization of pigmented fiber with a synergistic mixture of hindered amine and UV absorber |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2020118933A1 (zh) | 2018-12-10 | 2020-06-18 | 优缔新材料科技(苏州)有限公司 | 一种新型多环化合物 |
Also Published As
| Publication number | Publication date |
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| CA2445617A1 (en) | 2004-04-22 |
| ATE348858T1 (de) | 2007-01-15 |
| SA03240422B1 (ar) | 2007-05-06 |
| DE60310500D1 (de) | 2007-02-01 |
| MXPA03009621A (es) | 2005-04-19 |
| IL158505A0 (en) | 2004-09-27 |
| ECSP034812A (es) | 2004-02-26 |
| JP2004143457A (ja) | 2004-05-20 |
| JP4461319B2 (ja) | 2010-05-12 |
| IL158505A (en) | 2007-06-17 |
| KR100963983B1 (ko) | 2010-06-15 |
| SG112002A1 (en) | 2005-06-29 |
| DE60310500T2 (de) | 2007-09-27 |
| PT1413599E (pt) | 2007-03-30 |
| BR0304632A (pt) | 2004-08-31 |
| AR041667A1 (es) | 2005-05-26 |
| MY130651A (en) | 2007-07-31 |
| TWI323270B (en) | 2010-04-11 |
| CO5410180A1 (es) | 2004-06-30 |
| CA2445617C (en) | 2011-12-06 |
| ZA200308091B (en) | 2004-04-22 |
| EP1413599B1 (en) | 2006-12-20 |
| US20040087446A1 (en) | 2004-05-06 |
| ES2277053T3 (es) | 2007-07-01 |
| BR0304632B1 (pt) | 2012-12-25 |
| EP1413599A1 (en) | 2004-04-28 |
| KR20040035561A (ko) | 2004-04-29 |
| CN1497012A (zh) | 2004-05-19 |
| TW200418920A (en) | 2004-10-01 |
| US7037962B2 (en) | 2006-05-02 |
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