CH509240A - Verfahren zur Hydrierung von Benzol - Google Patents
Verfahren zur Hydrierung von BenzolInfo
- Publication number
- CH509240A CH509240A CH988966A CH988966A CH509240A CH 509240 A CH509240 A CH 509240A CH 988966 A CH988966 A CH 988966A CH 988966 A CH988966 A CH 988966A CH 509240 A CH509240 A CH 509240A
- Authority
- CH
- Switzerland
- Prior art keywords
- reaction vessel
- vol
- hydrogenation
- stage
- temperature
- Prior art date
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims description 75
- 238000005984 hydrogenation reaction Methods 0.000 title claims description 45
- 238000000034 method Methods 0.000 title claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 49
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 31
- 239000003054 catalyst Substances 0.000 claims description 29
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 28
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 22
- 229910052739 hydrogen Inorganic materials 0.000 claims description 22
- 239000001257 hydrogen Substances 0.000 claims description 22
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 20
- 229910052717 sulfur Inorganic materials 0.000 claims description 20
- 239000011593 sulfur Substances 0.000 claims description 20
- 239000007789 gas Substances 0.000 claims description 15
- 229910052759 nickel Inorganic materials 0.000 claims description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 10
- 239000004113 Sepiolite Substances 0.000 claims description 7
- 229910052624 sepiolite Inorganic materials 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000012071 phase Substances 0.000 claims description 4
- 235000019355 sepiolite Nutrition 0.000 claims description 4
- 230000007423 decrease Effects 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000012808 vapor phase Substances 0.000 claims description 3
- 239000003345 natural gas Substances 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 7
- 238000005336 cracking Methods 0.000 claims 1
- 230000036961 partial effect Effects 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 239000007858 starting material Substances 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- 238000005486 sulfidation Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/14—Silica and magnesia
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Tires In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB28767/65A GB1144495A (en) | 1965-07-07 | 1965-07-07 | Improvements relating to the hydrogenation of benzene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH509240A true CH509240A (de) | 1971-06-30 |
Family
ID=10280824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH988966A CH509240A (de) | 1965-07-07 | 1966-07-07 | Verfahren zur Hydrierung von Benzol |
Country Status (10)
| Country | Link |
|---|---|
| AT (1) | AT281790B (enrdf_load_stackoverflow) |
| BE (1) | BE683783A (enrdf_load_stackoverflow) |
| CH (1) | CH509240A (enrdf_load_stackoverflow) |
| DE (1) | DE1568140B2 (enrdf_load_stackoverflow) |
| ES (1) | ES329182A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1144495A (enrdf_load_stackoverflow) |
| IL (1) | IL26070A (enrdf_load_stackoverflow) |
| NL (1) | NL6609524A (enrdf_load_stackoverflow) |
| NO (1) | NO122419B (enrdf_load_stackoverflow) |
| SE (1) | SE334872B (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2139843C1 (ru) * | 1998-04-15 | 1999-10-20 | Закрытое акционерное общество "Максим Инжиниринг" | Способ получения циклогексана |
-
1965
- 1965-07-07 GB GB28767/65A patent/GB1144495A/en not_active Expired
-
1966
- 1966-06-30 IL IL26070A patent/IL26070A/xx unknown
- 1966-07-06 DE DE19661568140 patent/DE1568140B2/de active Granted
- 1966-07-06 ES ES0329182A patent/ES329182A1/es not_active Expired
- 1966-07-06 NO NO163821A patent/NO122419B/no unknown
- 1966-07-07 CH CH988966A patent/CH509240A/de not_active IP Right Cessation
- 1966-07-07 AT AT650266A patent/AT281790B/de not_active IP Right Cessation
- 1966-07-07 SE SE09305/66A patent/SE334872B/xx unknown
- 1966-07-07 BE BE683783D patent/BE683783A/xx unknown
- 1966-07-07 NL NL6609524A patent/NL6609524A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AT281790B (de) | 1970-06-10 |
| IL26070A (en) | 1970-04-20 |
| SE334872B (enrdf_load_stackoverflow) | 1971-05-10 |
| ES329182A1 (es) | 1967-05-01 |
| NL6609524A (enrdf_load_stackoverflow) | 1967-01-09 |
| NO122419B (enrdf_load_stackoverflow) | 1971-06-28 |
| BE683783A (enrdf_load_stackoverflow) | 1967-01-09 |
| DE1568140B2 (de) | 1973-07-05 |
| GB1144495A (en) | 1969-03-05 |
| DE1568140C3 (enrdf_load_stackoverflow) | 1974-02-14 |
| DE1568140A1 (de) | 1970-06-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased |