CH160653A - Process for the preparation of a high molecular weight sulfonic acid. - Google Patents

Process for the preparation of a high molecular weight sulfonic acid.

Info

Publication number
CH160653A
CH160653A CH160653DA CH160653A CH 160653 A CH160653 A CH 160653A CH 160653D A CH160653D A CH 160653DA CH 160653 A CH160653 A CH 160653A
Authority
CH
Switzerland
Prior art keywords
preparation
molecular weight
high molecular
sulfonic acid
wool
Prior art date
Application number
Other languages
German (de)
Inventor
A-G J R Geigy
Original Assignee
Geigy Ag J R
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Geigy Ag J R filed Critical Geigy Ag J R
Publication of CH160653A publication Critical patent/CH160653A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G14/00—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
    • C08G14/02—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
    • C08G14/04—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
    • C08G14/12—Chemically modified polycondensates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/56—Condensation products or precondensation products prepared with aldehydes

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Description

  

      Zusatzpatent    zum Hauptpatent     Nr.    158243.    Verfahren zur Darstellung einer hochmolekularen     Nulfosäure.       Es wurde gefunden, dass man zu neuen,  wasserlöslichen Kondensationsprodukten ge  langen kann, wenn man feste, sauer konden  sierte Kunstharze auf     Formaldehydbasis    einer  Behandlung mit Phenol, seinen Homologen  oder     Substitutionsprodukten    unterwirft und  die entstehende homogene Masse mit sulfo  nierenden Mitteln behandelt.  



  Vorliegende Erfindung bezieht sich nun  auf ein Verfahren zur Darstellung einer  hochmolekularen     Sulfosäure,    dadurch gekenn  zeichnet, dass man ein durch Kondensation  eines technischen Gemisches     isonrerer        Xylen-          ole    vom     Sdp.    209/220 0 C und     Harnstoff    mit  Formaldehyd unter     Mitverwendung    von sauren  Katalysatoren erhaltenes Kunstharz in Phe  nol löst und bis zur Wasserlöslichkeit mit  sulfonierenden Mitteln behandelt.  



  Der neue Körper stellt in Form seines       Alkalisalzes    eine schwach gefärbte, amorphe  Masse dar. Ausser als Gerbstoff kann das  Produkt als     Wollreservierungsmittel    in der       Halbwol)färberei    dienen.

      <I>Beispiel:</I>  75 Teile eines Harzes erhalten durch Kon  densation von 120 Teilen     Xylenol,    32 Teilen       Harnstoff,    125 Teilen     Formaldehydlösung          38        %        ig        und        25        Teilen        Schwefelsäure        4'/o     bei<B>780</B> werden mit 100 Teilen Phenol bei  <B>700</B>     solänge    gerührt, bis eine homogene  Lösung des Harzes entstanden ist.

   Man lässt  nun zwischen 40 0 und 110 0 125 Teile Schwefel  säure von 66 0     B6    zufliessen und rührt weiter,  bis eine Probe im gleichen Raumteil Wasser  auch in der Kälte klar löslich ist. Nach Ab  stumpfen der überschüssigen Säure mit Na  triunicarbonat lässt sich das lösliche Harz  durch     Aussalzen    mit     Natriumchlorid    oder  durch Eindampfen als schwach gefärbte;  amorphe Masse gewinnen; ihre     Lösungen     wirken auf basische Farbstoffe stark fällend,  besitzen stark leimfällende Eigenschaften und  färben sich mit     Ferrichlorid        rotstichig    blau.



      Additional patent to main patent No. 158243. Process for the preparation of a high molecular weight sulfonic acid. It has been found that new, water-soluble condensation products can be obtained if solid, acid-condensed synthetic resins based on formaldehyde are subjected to a treatment with phenol, its homologues or substitution products and the resulting homogeneous mass is treated with sulfonating agents.



  The present invention relates to a process for the preparation of a high molecular weight sulfonic acid, characterized in that a synthetic resin obtained by condensation of a technical mixture of isonereric xylenes with bp. 209/220 0 C and urea with formaldehyde is incorporated into Phenol dissolves and treated with sulfonating agents until it is water-soluble.



  In the form of its alkali salt, the new body represents a weakly colored, amorphous mass. In addition to being a tanning agent, the product can also serve as a wool reservation agent in semi-wool dyeing.

      <I> Example: </I> 75 parts of a resin obtained by condensation of 120 parts of xylenol, 32 parts of urea, 125 parts of 38% formaldehyde solution and 25 parts of sulfuric acid 4% at 780 stirred with 100 parts of phenol at <B> 700 </B> until a homogeneous solution of the resin has formed.

   It is now allowed to flow in between 40 0 and 110 0 125 parts of sulfuric acid of 66 0 B6 and stirring is continued until a sample in the same volume of water is clearly soluble even in the cold. After blunting the excess acid with sodium triunicarbonate, the soluble resin can be pale colored by salting out with sodium chloride or by evaporation; gain amorphous mass; Their solutions have a strong precipitating effect on basic dyes, have strong glue-precipitating properties and turn a reddish blue color with ferric chloride.

Claims (1)

PATENTANSPRUCH: Verfahren zur Darstellung einer hoch- molekulare.n Sulfosäure, dadurch gekennzeich- net, dass man ein durch Kondensation eines technischen Gemisches isomerer Xylenole vom Sdp. 209/220 C und Harnstoff mit For maldehyd unter Mitverwendung von sauren Katalysatoren erhaltenes Kunstharz in Phe nol löst und bis zur Wasserlöslichkeit mit sulfonierenden Mitteln behandelt. PATENT CLAIM: Process for the preparation of a high-molecular sulphonic acid, characterized in that a synthetic resin obtained by condensation of a technical mixture of isomeric xylenols with bp. 209/220 C and urea with formaldehyde using acidic catalysts is converted into phenol dissolves and treated with sulfonating agents until it is water-soluble. Der neue Körper stellt in Form seines Alkalisalzes eine schwach gefärbte, amorphe Masse dar, deren wässrige Lösung stark leimfällende Eigenschaften besitzt, auf ba sische Farbstoffe stark fällend wirkt und sich mit Ferrichlorid rotstichig blau färbt. Ausser als Gerbstoff kann das Produkt als Wollreservierungsmittel in der Halbwollfär- berei dienen. The new body in the form of its alkali salt is a weakly colored, amorphous mass, the aqueous solution of which has strong glue-precipitating properties, has a strong precipitating effect on basic dyes and turns reddish blue with ferric chloride. In addition to being a tanning agent, the product can also be used as a wool reservation agent in semi-wool dyeing.
CH160653D 1932-05-12 1932-05-12 Process for the preparation of a high molecular weight sulfonic acid. CH160653A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH158243T 1932-05-12
CH160653T 1932-05-12

Publications (1)

Publication Number Publication Date
CH160653A true CH160653A (en) 1933-03-15

Family

ID=25717064

Family Applications (1)

Application Number Title Priority Date Filing Date
CH160653D CH160653A (en) 1932-05-12 1932-05-12 Process for the preparation of a high molecular weight sulfonic acid.

Country Status (1)

Country Link
CH (1) CH160653A (en)

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