CA3007617C - Adsorbent for radioactive antimony, radioactive iodine and radioactive ruthenium, and treatment method of radioactive waste water using the adsorbent - Google Patents

Adsorbent for radioactive antimony, radioactive iodine and radioactive ruthenium, and treatment method of radioactive waste water using the adsorbent Download PDF

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Publication number
CA3007617C
CA3007617C CA3007617A CA3007617A CA3007617C CA 3007617 C CA3007617 C CA 3007617C CA 3007617 A CA3007617 A CA 3007617A CA 3007617 A CA3007617 A CA 3007617A CA 3007617 C CA3007617 C CA 3007617C
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CA
Canada
Prior art keywords
radioactive
adsorbent
ruthenium
less
antimony
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA3007617A
Other languages
English (en)
French (fr)
Other versions
CA3007617A1 (en
Inventor
Takashi Sakuma
Makoto Komatsu
Takeshi Izumi
Shinsuke Miyabe
Yutaka Kinose
Kiyoshi Satou
Kenta Kozasu
Mari Tokutake
Takeshi Sakamoto
Kaori Sugihara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Chemical Industrial Co Ltd
Original Assignee
Ebara Corp
Nippon Chemical Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ebara Corp, Nippon Chemical Industrial Co Ltd filed Critical Ebara Corp
Publication of CA3007617A1 publication Critical patent/CA3007617A1/en
Application granted granted Critical
Publication of CA3007617C publication Critical patent/CA3007617C/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0233—Compounds of Cu, Ag, Au
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0292—Phosphates of compounds other than those provided for in B01J20/048
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011—Other properties, e.g. density, crush strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28052—Several layers of identical or different sorbents stacked in a housing, e.g. in a column
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/20—Compounds containing only rare earth metals as the metal element
    • C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
    • C01F17/224—Oxides or hydroxides of lanthanides
    • C01F17/235—Cerium oxides or hydroxides
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G21F9/12—Processing by absorption; by adsorption; by ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00—Energy generation of nuclear origin
    • Y02E30/30—Nuclear fission reactors

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Geology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
CA3007617A 2015-12-24 2016-12-08 Adsorbent for radioactive antimony, radioactive iodine and radioactive ruthenium, and treatment method of radioactive waste water using the adsorbent Active CA3007617C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2015-252082 2015-12-24
JP2015252082A JP6716247B2 (ja) 2015-12-24 2015-12-24 放射性アンチモン、放射性ヨウ素及び放射性ルテニウムの吸着剤、当該吸着剤を用いた放射性廃液の処理方法
PCT/JP2016/086485 WO2017110485A1 (ja) 2015-12-24 2016-12-08 放射性アンチモン、放射性ヨウ素及び放射性ルテニウムの吸着剤、当該吸着剤を用いた放射性廃液の処理方法

Publications (2)

Publication Number Publication Date
CA3007617A1 CA3007617A1 (en) 2017-06-29
CA3007617C true CA3007617C (en) 2022-03-01

Family

ID=59090011

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3007617A Active CA3007617C (en) 2015-12-24 2016-12-08 Adsorbent for radioactive antimony, radioactive iodine and radioactive ruthenium, and treatment method of radioactive waste water using the adsorbent

Country Status (5)

Country Link
US (1) US11213799B2 (enExample)
EP (1) EP3396677A4 (enExample)
JP (1) JP6716247B2 (enExample)
CA (1) CA3007617C (enExample)
WO (1) WO2017110485A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7313922B2 (ja) * 2019-06-20 2023-07-25 日本化学工業株式会社 ヨウ化物イオン吸着剤及びその製造方法
EP4094829A4 (en) * 2020-01-20 2024-04-17 The University of Tokyo Novel adsorbent
KR20210121562A (ko) * 2020-03-30 2021-10-08 한국원자력연구원 방사성 폐기물의 선택적 전처리 방법
US20230230717A1 (en) 2022-01-14 2023-07-20 Department Of Atomic Energy Government Of India Method for the removal of radionuclides from aqueous radioactive waste
CN119409264B (zh) * 2024-11-08 2025-10-03 杨凌核盛辐照技术有限公司 一种利用锆功能化吸附树脂去除锑的方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5549719B2 (enExample) * 1974-04-30 1980-12-13
JPS6019035A (ja) * 1983-07-13 1985-01-31 Mitsui Mining & Smelting Co Ltd 放射性ルテニウム廃液の吸着剤
JPS60161598A (ja) 1983-12-15 1985-08-23 日本原子力研究所 放射性ルテニウムを含む放射性廃液の処理方法
JPS61187931A (ja) 1985-02-18 1986-08-21 Asahi Chem Ind Co Ltd 水溶液中の砒素の吸着剤
JP3119755B2 (ja) * 1993-01-18 2000-12-25 株式会社日立製作所 オフガス処理設備及びヨウ素吸着材とその製造方法
JP2001133594A (ja) * 1999-11-05 2001-05-18 Jgc Corp 原子炉冷却水からの放射性核種の除去方法
JP2007098362A (ja) * 2005-10-07 2007-04-19 Nippon Sheet Glass Co Ltd カチオン吸着材とその製造方法
EP2243547A1 (en) 2009-04-20 2010-10-27 Fortum OYJ Novel sorbent, method of producing the same and the use thereof
US8436052B2 (en) * 2010-01-07 2013-05-07 Jack L. Collins Formulation and method for preparing gels comprising hydrous cerium oxide
US9233863B2 (en) * 2011-04-13 2016-01-12 Molycorp Minerals, Llc Rare earth removal of hydrated and hydroxyl species
JP5873302B2 (ja) 2011-11-11 2016-03-01 日立Ｇｅニュークリア・エナジー株式会社 原子力設備の廃水処理装置及び廃水処理方法
DE102012006542A1 (de) * 2012-04-02 2013-10-02 Clariant Produkte (Deutschland) Gmbh Methyliodidadsorber, Verwendung desselben und Verfahren zur Adsorption von Methyliodid
JP6053325B2 (ja) * 2012-05-22 2016-12-27 スリーエム イノベイティブ プロパティズ カンパニー 焼成物、金属イオン吸着材、金属イオンの除去方法、及び金属イオン除去設備
GB2533497B (en) 2013-08-23 2017-12-20 Hitachi Ge Nuclear Energy Ltd Method of treating radioactive liquid waste and radioactive liquid waste treatment apparatus
JP6125960B2 (ja) 2013-09-19 2017-05-10 日立Ｇｅニュークリア・エナジー株式会社 放射性廃液の処理方法及び放射性廃液処理装置
JP6046582B2 (ja) * 2013-09-19 2016-12-21 日立Ｇｅニュークリア・エナジー株式会社 放射性廃液の処理方法及び放射性廃液処理装置
JP6276945B2 (ja) * 2013-08-29 2018-02-07 水ｉｎｇ株式会社 放射性物質吸着剤の除染処理方法及び放射能汚染水の除染処理装置
JP6379382B2 (ja) * 2014-03-20 2018-08-29 株式会社化研 水溶液からヨウ素を除去するヨウ素除去剤、除去装置および除去方法
JP5793231B1 (ja) * 2014-09-05 2015-10-14 日本化学工業株式会社 ヨウ素酸イオン吸着剤及びその製造方法
JP5793230B1 (ja) 2014-09-05 2015-10-14 日本化学工業株式会社 ヨウ素酸イオン吸着剤及びその製造方法

Also Published As

Publication number Publication date
WO2017110485A1 (ja) 2017-06-29
JP2017116407A (ja) 2017-06-29
CA3007617A1 (en) 2017-06-29
US11213799B2 (en) 2022-01-04
JP6716247B2 (ja) 2020-07-01
EP3396677A1 (en) 2018-10-31
US20190009245A1 (en) 2019-01-10
EP3396677A4 (en) 2019-07-24

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