JP6716247B2 - 放射性アンチモン、放射性ヨウ素及び放射性ルテニウムの吸着剤、当該吸着剤を用いた放射性廃液の処理方法 - Google Patents

放射性アンチモン、放射性ヨウ素及び放射性ルテニウムの吸着剤、当該吸着剤を用いた放射性廃液の処理方法 Download PDF

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JP6716247B2
JP6716247B2 JP2015252082A JP2015252082A JP6716247B2 JP 6716247 B2 JP6716247 B2 JP 6716247B2 JP 2015252082 A JP2015252082 A JP 2015252082A JP 2015252082 A JP2015252082 A JP 2015252082A JP 6716247 B2 JP6716247 B2 JP 6716247B2
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radioactive
less
adsorbent
antimony
ruthenium
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JP2017116407A (ja
JP2017116407A5 (enExample
Inventor
貴志 佐久間
貴志 佐久間
小松　誠
誠 小松
出水　丈志
丈志 出水
慎介 宮部
慎介 宮部
木ノ瀬　豊
豊 木ノ瀬
佐藤　清
清 佐藤
健太 小指
健太 小指
茉里 徳武
茉里 徳武
坂本　剛
剛 坂本
かおり 杉原
かおり 杉原
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Ebara Corp
Nippon Chemical Industrial Co Ltd
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Ebara Corp
Nippon Chemical Industrial Co Ltd
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Priority to JP2015252082A priority Critical patent/JP6716247B2/ja
Priority to US16/065,386 priority patent/US11213799B2/en
Priority to EP16878377.7A priority patent/EP3396677A4/en
Priority to PCT/JP2016/086485 priority patent/WO2017110485A1/ja
Priority to CA3007617A priority patent/CA3007617C/en
Publication of JP2017116407A publication Critical patent/JP2017116407A/ja
Publication of JP2017116407A5 publication Critical patent/JP2017116407A5/ja
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0233—Compounds of Cu, Ag, Au
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0292—Phosphates of compounds other than those provided for in B01J20/048
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011—Other properties, e.g. density, crush strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28052—Several layers of identical or different sorbents stacked in a housing, e.g. in a column
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/20—Compounds containing only rare earth metals as the metal element
    • C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
    • C01F17/224—Oxides or hydroxides of lanthanides
    • C01F17/235—Cerium oxides or hydroxides
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G21F9/12—Processing by absorption; by adsorption; by ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00—Energy generation of nuclear origin
    • Y02E30/30—Nuclear fission reactors

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Geology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
JP2015252082A 2015-12-24 2015-12-24 放射性アンチモン、放射性ヨウ素及び放射性ルテニウムの吸着剤、当該吸着剤を用いた放射性廃液の処理方法 Expired - Fee Related JP6716247B2 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2015252082A JP6716247B2 (ja) 2015-12-24 2015-12-24 放射性アンチモン、放射性ヨウ素及び放射性ルテニウムの吸着剤、当該吸着剤を用いた放射性廃液の処理方法
US16/065,386 US11213799B2 (en) 2015-12-24 2016-12-08 Adsorbent for radioactive antimony, radioactive iodine and radioactive ruthenium, and treatment method of radioactive waste water using the adsorbent
EP16878377.7A EP3396677A4 (en) 2015-12-24 2016-12-08 ADSORPTION AGENT FOR RADIOACTIVE ANTIMON, RADIOACTIVE IOD AND RADIOACTIVE RUTHENIUM AND METHOD FOR PROCESSING RADIOACTIVE WASTE FLUID WITH USE OF THE ADSORPTION AGENT
PCT/JP2016/086485 WO2017110485A1 (ja) 2015-12-24 2016-12-08 放射性アンチモン、放射性ヨウ素及び放射性ルテニウムの吸着剤、当該吸着剤を用いた放射性廃液の処理方法
CA3007617A CA3007617C (en) 2015-12-24 2016-12-08 Adsorbent for radioactive antimony, radioactive iodine and radioactive ruthenium, and treatment method of radioactive waste water using the adsorbent

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Application Number Priority Date Filing Date Title
JP2015252082A JP6716247B2 (ja) 2015-12-24 2015-12-24 放射性アンチモン、放射性ヨウ素及び放射性ルテニウムの吸着剤、当該吸着剤を用いた放射性廃液の処理方法

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JP2017116407A JP2017116407A (ja) 2017-06-29
JP2017116407A5 JP2017116407A5 (enExample) 2018-08-02
JP6716247B2 true JP6716247B2 (ja) 2020-07-01

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US (1) US11213799B2 (enExample)
EP (1) EP3396677A4 (enExample)
JP (1) JP6716247B2 (enExample)
CA (1) CA3007617C (enExample)
WO (1) WO2017110485A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7313922B2 (ja) * 2019-06-20 2023-07-25 日本化学工業株式会社 ヨウ化物イオン吸着剤及びその製造方法
EP4094829A4 (en) * 2020-01-20 2024-04-17 The University of Tokyo Novel adsorbent
KR20210121562A (ko) * 2020-03-30 2021-10-08 한국원자력연구원 방사성 폐기물의 선택적 전처리 방법
US20230230717A1 (en) 2022-01-14 2023-07-20 Department Of Atomic Energy Government Of India Method for the removal of radionuclides from aqueous radioactive waste
CN119409264B (zh) * 2024-11-08 2025-10-03 杨凌核盛辐照技术有限公司 一种利用锆功能化吸附树脂去除锑的方法

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JPS5549719B2 (enExample) * 1974-04-30 1980-12-13
JPS6019035A (ja) * 1983-07-13 1985-01-31 Mitsui Mining & Smelting Co Ltd 放射性ルテニウム廃液の吸着剤
JPS60161598A (ja) 1983-12-15 1985-08-23 日本原子力研究所 放射性ルテニウムを含む放射性廃液の処理方法
JPS61187931A (ja) 1985-02-18 1986-08-21 Asahi Chem Ind Co Ltd 水溶液中の砒素の吸着剤
JP3119755B2 (ja) * 1993-01-18 2000-12-25 株式会社日立製作所 オフガス処理設備及びヨウ素吸着材とその製造方法
JP2001133594A (ja) * 1999-11-05 2001-05-18 Jgc Corp 原子炉冷却水からの放射性核種の除去方法
JP2007098362A (ja) * 2005-10-07 2007-04-19 Nippon Sheet Glass Co Ltd カチオン吸着材とその製造方法
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JP6053325B2 (ja) * 2012-05-22 2016-12-27 スリーエム イノベイティブ プロパティズ カンパニー 焼成物、金属イオン吸着材、金属イオンの除去方法、及び金属イオン除去設備
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JP5793230B1 (ja) 2014-09-05 2015-10-14 日本化学工業株式会社 ヨウ素酸イオン吸着剤及びその製造方法

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Publication number Publication date
WO2017110485A1 (ja) 2017-06-29
JP2017116407A (ja) 2017-06-29
CA3007617A1 (en) 2017-06-29
US11213799B2 (en) 2022-01-04
EP3396677A1 (en) 2018-10-31
US20190009245A1 (en) 2019-01-10
CA3007617C (en) 2022-03-01
EP3396677A4 (en) 2019-07-24

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