CA2910680A1 - Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides - Google Patents
Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides Download PDFInfo
- Publication number
- CA2910680A1 CA2910680A1 CA2910680A CA2910680A CA2910680A1 CA 2910680 A1 CA2910680 A1 CA 2910680A1 CA 2910680 A CA2910680 A CA 2910680A CA 2910680 A CA2910680 A CA 2910680A CA 2910680 A1 CA2910680 A1 CA 2910680A1
- Authority
- CA
- Canada
- Prior art keywords
- monomer
- oil
- thermoplastic
- block
- block copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F122/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F122/10—Esters
- C08F122/12—Esters of phenols or saturated alcohols
- C08F122/20—Esters containing oxygen in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F242/00—Copolymers of drying oils with other monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L35/06—Copolymers with vinyl aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J135/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J135/06—Copolymers with vinyl aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2555/00—Characteristics of bituminous mixtures
- C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
- C08L2555/80—Macromolecular constituents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2555/00—Characteristics of bituminous mixtures
- C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
- C08L2555/80—Macromolecular constituents
- C08L2555/82—Macromolecular constituents from natural renewable resources, e.g. starch, cellulose, saw dust, straw, hair or shells
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361825241P | 2013-05-20 | 2013-05-20 | |
| US61/825,241 | 2013-05-20 | ||
| PCT/US2014/038799 WO2014189939A2 (en) | 2013-05-20 | 2014-05-20 | Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2910680A1 true CA2910680A1 (en) | 2014-11-27 |
Family
ID=50983166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2910680A Abandoned CA2910680A1 (en) | 2013-05-20 | 2014-05-20 | Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides |
Country Status (14)
| Country | Link |
|---|---|
| US (5) | US9650463B2 (OSRAM) |
| EP (3) | EP2999727B1 (OSRAM) |
| JP (1) | JP2016528306A (OSRAM) |
| KR (1) | KR20160009583A (OSRAM) |
| CN (3) | CN108641053B (OSRAM) |
| AU (1) | AU2014268692B2 (OSRAM) |
| BR (2) | BR122017010545B1 (OSRAM) |
| CA (1) | CA2910680A1 (OSRAM) |
| CL (1) | CL2015003375A1 (OSRAM) |
| EA (1) | EA201592176A1 (OSRAM) |
| HK (1) | HK1220219A1 (OSRAM) |
| PH (1) | PH12015502467A1 (OSRAM) |
| SG (3) | SG11201509408UA (OSRAM) |
| WO (1) | WO2014189939A2 (OSRAM) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112014017476B1 (pt) | 2012-01-18 | 2021-03-30 | Iowa State University Research Foundation, Inc | Copolímero em bloco, composições elastomérica, asfáltica e adesiva, pneu de veículo, métodos para preparar um polímero ou copolímero em bloco termoplástico, e polímero termoplástico |
| AU2014268692B2 (en) | 2013-05-20 | 2018-02-01 | Iowa State University Research Foundation, Inc. | Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides |
| US10253132B2 (en) * | 2015-02-09 | 2019-04-09 | Archer Daniels Midland Company | Renewable source-derived polymer oil macroinitiators and thermoplastic block copolymers derived therefrom |
| EP3262082B1 (en) | 2015-02-27 | 2020-10-21 | Cargill, Incorporated | Polymerized oils and methods of manufacturing the same |
| DE102015208810A1 (de) | 2015-05-12 | 2016-11-17 | Continental Reifen Deutschland Gmbh | RAFT-Agens, Verfahren zur Polymerisation, Polymer und Kautschukmischung sowie deren Verwendung |
| HK1249897A1 (zh) * | 2015-06-02 | 2018-11-16 | 内斯托尔株式会社 | 新型甘油三酯及其用途 |
| US10323148B1 (en) | 2016-05-26 | 2019-06-18 | Marathon Petroleum Company Lp | Method of making an asphalt composition containing ester bottoms |
| US10968173B2 (en) * | 2016-07-07 | 2021-04-06 | Iowa State University Research Foundation, Inc. | Thiocarbonylthio compounds as chain transfer agents suitable for raft polymerization |
| WO2018009753A1 (en) * | 2016-07-07 | 2018-01-11 | Iowa State University Research Foundaton, Inc. | Multiblock copolymer and method of making thereof |
| CN106433158B (zh) * | 2016-07-07 | 2018-12-04 | 交通运输部科学研究院 | 改性生物沥青的制备方法和改性生物沥青及其用途 |
| WO2018031373A1 (en) | 2016-08-12 | 2018-02-15 | Iowa State University Research Foundation, Inc. | Acrylated and acylated or acetalized polyol as a biobased substitute for hard, rigid thermoplastic and thermoplastic and thermoset materials |
| FR3058729A1 (fr) * | 2016-11-17 | 2018-05-18 | Compagnie Generale Des Etablissements Michelin | Pneumatique comprenant une bande de roulement comprenant un elastomere thermoplastique et un systeme de reticulation a base de soufre |
| FR3060588A1 (fr) * | 2016-12-20 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant une poudrette de caoutchouc specifique |
| WO2018183261A1 (en) * | 2017-03-27 | 2018-10-04 | Iowa State University Research Foundation, Inc. | Macro-raft chain transfer agents as anionic polymerization terminators |
| US10316192B2 (en) | 2017-08-25 | 2019-06-11 | Cargill, Incorporated | Emulsions with polymerized oils and methods of manufacturing the same |
| CN108084071B (zh) * | 2017-12-29 | 2019-11-22 | 云南铁峰矿业化工新技术有限公司 | 一种黄药真空制备装置 |
| CN108503276A (zh) * | 2018-04-20 | 2018-09-07 | 万玉梅 | 一种功能型路面养护材料及其制备方法 |
| CN112384581A (zh) | 2018-06-11 | 2021-02-19 | 宣伟投资管理有限公司 | 包含水分散性丙烯酸类嵌段共聚物的包装涂层 |
| CA3103339A1 (en) | 2018-06-18 | 2019-12-26 | Cornell University | Systems and methods for n-halamine-dopamine copolymers for high-performance, low-cost, and easy-to-apply antimicrobial coatings |
| CN109679001A (zh) * | 2018-12-29 | 2019-04-26 | 锦州英诺威科技服务有限公司 | 一种用于聚丙烯生产的杀活剂 |
| US11814506B2 (en) | 2019-07-02 | 2023-11-14 | Marathon Petroleum Company Lp | Modified asphalts with enhanced rheological properties and associated methods |
| CA3088894C (en) | 2020-05-21 | 2024-04-30 | Marathon Petroleum Company Lp | Systems and methods for venting asphalt transport tanks |
| CN112175555A (zh) * | 2020-09-29 | 2021-01-05 | 杭州英创新材料有限公司 | 一种极性热熔胶及其制备方法 |
| CA3214142A1 (en) * | 2021-04-02 | 2022-10-06 | Iowa State University Research Foundation, Inc. | Thermoplastic graft elastomers via reactive compatibilization of polyacrylated epoxidized high oleic soybean oil and polydiene-containing copolymers |
| WO2022212880A1 (en) * | 2021-04-02 | 2022-10-06 | Iowa State University Research Foundation, Inc. | Impact modification of polyesters via reactive extrusion with polyacrylated epoxidized high oleic soybean oil |
| CN113214575B (zh) * | 2021-04-24 | 2022-03-25 | 温州市剑利鞋业有限公司 | 一种pvc鞋底及其制备工艺 |
| CN114605653B (zh) * | 2022-04-19 | 2023-07-04 | 东南大学 | 一种代替sbs的生物热塑性弹性体的制备方法及其应用 |
| CN115160467B (zh) * | 2022-06-22 | 2023-10-03 | 东南大学 | 一种新型生物基液体改性剂的制备方法及其应用 |
| CN115738133B (zh) * | 2022-11-10 | 2023-09-29 | 国网浙江省电力有限公司湖州供电公司 | 一种应用于电化学储能系统的自动灭火器材 |
| CN116144165B (zh) * | 2022-12-27 | 2024-04-02 | 四川大学 | 可回收、可修复的热固性聚氨酯改性沥青材料及其制法 |
| KR20250060701A (ko) * | 2023-10-26 | 2025-05-07 | 롯데케미칼 주식회사 | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
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| KR101614978B1 (ko) * | 2008-12-31 | 2016-04-22 | 가부시키가이샤 브리지스톤 | 코어-우선 나노입자 형성 방법, 나노입자 및 조성물 |
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