CA2853154C - Catalyst composition and method for use in selective catalytic reduction of nitrogen oxides - Google Patents

Catalyst composition and method for use in selective catalytic reduction of nitrogen oxides Download PDF

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Publication number
CA2853154C
CA2853154C CA2853154A CA2853154A CA2853154C CA 2853154 C CA2853154 C CA 2853154C CA 2853154 A CA2853154 A CA 2853154A CA 2853154 A CA2853154 A CA 2853154A CA 2853154 C CA2853154 C CA 2853154C
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Canada
Prior art keywords
zeolite
catalyst composition
components
catalyst
beta
Prior art date
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Expired - Fee Related
Application number
CA2853154A
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English (en)
French (fr)
Other versions
CA2853154A1 (en
Inventor
Alexandr Yu Stakheev
Marie GRILL
Arkady Kustov
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Umicore AG and Co KG
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Umicore AG and Co KG
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Publication of CA2853154A1 publication Critical patent/CA2853154A1/en
Application granted granted Critical
Publication of CA2853154C publication Critical patent/CA2853154C/en
Expired - Fee Related legal-status Critical Current
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B01D2255/2065—Cerium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/2073—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/209—Other metals
    • B01D2255/2092—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/40—Mixed oxides
    • B01D2255/407—Zr-Ce mixed oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B01D2255/502—Beta zeolites

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
CA2853154A 2011-10-24 2012-05-02 Catalyst composition and method for use in selective catalytic reduction of nitrogen oxides Expired - Fee Related CA2853154C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PCT/EP2011/005344 WO2013060341A1 (en) 2011-10-24 2011-10-24 Catalyst composition for use in selective catalytic reduction of nitrogen oxides
EPPCT/EP2011/005344 2011-10-24
PCT/EP2012/058003 WO2013060487A1 (en) 2011-10-24 2012-05-02 Catalyst composition and method for use in selective catalytic reduction of nitrogen oxides

Publications (2)

Publication Number Publication Date
CA2853154A1 CA2853154A1 (en) 2013-05-02
CA2853154C true CA2853154C (en) 2018-04-03

Family

ID=46085901

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2853154A Expired - Fee Related CA2853154C (en) 2011-10-24 2012-05-02 Catalyst composition and method for use in selective catalytic reduction of nitrogen oxides

Country Status (11)

Country Link
JP (1) JP6112734B2 (ja)
KR (1) KR101789114B1 (ja)
CN (1) CN103889569B (ja)
AU (1) AU2012327482A1 (ja)
BR (1) BR112014008669B1 (ja)
CA (1) CA2853154C (ja)
CL (1) CL2014000993A1 (ja)
IN (1) IN2014CN02950A (ja)
MX (1) MX2014004494A (ja)
RU (1) RU2608616C2 (ja)
WO (2) WO2013060341A1 (ja)

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CN104014324B (zh) * 2014-05-14 2016-08-17 华东理工大学 氧化铈基负载型烟气脱硝催化剂及其制备方法
CN105435789A (zh) * 2014-09-09 2016-03-30 中国石油化工股份有限公司 一种Cu基甲醇合成催化剂大比表面载体的制备方法
CN104525216B (zh) * 2014-12-11 2017-01-04 清华大学 用于宽温度窗口高硫条件下的脱硝催化剂及其制备方法
CN104437540A (zh) * 2014-12-31 2015-03-25 安徽省元琛环保科技有限公司 一种抗磷低温scr脱硝催化剂及其制备方法
CN108472636B (zh) * 2015-08-21 2021-08-06 巴斯夫公司 排气处理催化剂
EP3356019A1 (en) * 2015-09-29 2018-08-08 Johnson Matthey Public Limited Company Catalytic filter having a soot catalyst and an scr catalyst
CA3182231A1 (en) 2015-10-30 2017-05-04 Blueshift Materials, Inc. Highly branched non-crosslinked aerogel, methods of making, and uses thereof
WO2017212424A1 (en) 2016-06-08 2017-12-14 Blueshift International Materials, Inc. Polymer aerogel with improved mechanical and thermal properties
EP3281698A1 (de) 2016-08-11 2018-02-14 Umicore AG & Co. KG Scr-aktives material
EP3496854A1 (de) 2016-08-11 2019-06-19 Umicore AG & Co. KG Scr-aktives material mit erhöhter thermischer stabilität
TW201838708A (zh) * 2017-03-02 2018-11-01 丹麥商托普索公司 用於移除來自工廠的廢氣所含有的硫氧化物和氮氧化物的方法
JP7383628B2 (ja) 2017-12-05 2023-11-20 ブルーシフト マテリアルズ インコーポレイテッド 熱処理されたポリアミック酸アミドエアロゲル
DE102018100833A1 (de) 2018-01-16 2019-07-18 Umicore Ag & Co. Kg Verfahren zur Herstellung eines SCR-Katalysators
DE102018100834A1 (de) 2018-01-16 2019-07-18 Umicore Ag & Co. Kg Verfahren zur Herstellung eines SCR-Katalysators
CN111742121B (zh) * 2018-02-19 2022-08-16 巴斯夫公司 具有上游scr催化剂的排气处理系统
CN109126817B (zh) * 2018-11-07 2021-07-16 东北大学 一种铁、钨、锌改良氧化铈/氧化锰scr脱硝催化剂及其制备方法
EP3791955A1 (de) 2019-09-10 2021-03-17 Umicore Ag & Co. Kg Kupfer-zeolith- und kupfer/alumina-haltiges katalytisches material für die scr, abgasreinigungsverfahren mit diesem material und verfahren zur herstellung dieses materials
CN110586176B (zh) * 2019-09-27 2020-11-17 中国环境科学研究院 一种电解锰渣基微介孔zsm-5催化剂及制备方法
CN110917829A (zh) * 2019-12-13 2020-03-27 西安润川环保科技有限公司 一种脱硫脱硝的烟气深度处理方法
CN111111429A (zh) * 2019-12-16 2020-05-08 山东金城柯瑞化学有限公司 一种利用单活性中心多相催化剂技术治理乙酰呋喃氧化尾气的方法
CN111389454B (zh) * 2020-04-29 2022-09-20 陕西延长石油（集团）有限责任公司 一种合成气与甲苯制备对甲基苯甲醛的催化剂及方法
US11989661B1 (en) * 2023-07-24 2024-05-21 Morgan Stanley Services Group Inc. Dynamic rules for rules engines

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JPH0557196A (ja) * 1991-08-29 1993-03-09 Toyota Motor Corp 排気ガス浄化用触媒の製造方法
AU1461201A (en) * 1999-12-28 2001-07-09 Corning Incorporated Zeolite/alumina catalyst support compositions and method of making the same
DE60122243T2 (de) * 2000-06-28 2007-06-28 Ict Co. Ltd. Abgasreinigungskatalysator
JP3917541B2 (ja) * 2003-03-20 2007-05-23 日産ディーゼル工業株式会社 ディーゼルエンジンの排気浄化装置
JP2006136776A (ja) * 2004-11-10 2006-06-01 Toyota Central Res & Dev Lab Inc ＮＯｘ選択還元触媒
FR2898887B1 (fr) * 2006-03-21 2008-05-02 Rhodia Recherches & Tech Composition a base d'oxyde de zirconium et d'oxyde de cerium a reductibilite elevee et a surface specifique stable procede de preparation et utilisation dans le traitement des gaz d'echappement
JP2008100152A (ja) * 2006-10-18 2008-05-01 Cataler Corp 排ガス浄化用触媒
US7527776B2 (en) * 2007-01-09 2009-05-05 Catalytic Solutions, Inc. Ammonia SCR catalyst and method of using the catalyst
US8802582B2 (en) * 2007-01-09 2014-08-12 Catalytic Solutions, Inc. High temperature ammonia SCR catalyst and method of using the catalyst
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Also Published As

Publication number Publication date
BR112014008669A2 (pt) 2017-04-18
KR20140095512A (ko) 2014-08-01
CN103889569A (zh) 2014-06-25
JP6112734B2 (ja) 2017-04-12
IN2014CN02950A (ja) 2015-07-03
KR101789114B1 (ko) 2017-10-23
MX2014004494A (es) 2014-07-11
RU2014120917A (ru) 2015-12-10
CN103889569B (zh) 2017-02-15
WO2013060487A1 (en) 2013-05-02
AU2012327482A1 (en) 2014-05-15
WO2013060341A1 (en) 2013-05-02
CL2014000993A1 (es) 2014-08-22
CA2853154A1 (en) 2013-05-02
RU2608616C2 (ru) 2017-01-23
JP2015501210A (ja) 2015-01-15
BR112014008669B1 (pt) 2019-07-02

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