CA2800868A1 - Graphene oxide and graphite oxide catalysts and systems - Google Patents

Graphene oxide and graphite oxide catalysts and systems Download PDF

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Publication number
CA2800868A1
CA2800868A1 CA2800868A CA2800868A CA2800868A1 CA 2800868 A1 CA2800868 A1 CA 2800868A1 CA 2800868 A CA2800868 A CA 2800868A CA 2800868 A CA2800868 A CA 2800868A CA 2800868 A1 CA2800868 A1 CA 2800868A1
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Canada
Prior art keywords
catalyst
group
carbocatalyst
carbon
oxide
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Abandoned
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CA2800868A
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English (en)
French (fr)
Inventor
Christopher W. Bielawski
Daniel R. Dreyer
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GRAPHEA Inc
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GRAPHEA Inc
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Publication of CA2800868A1 publication Critical patent/CA2800868A1/en
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B01J21/185—Carbon nanotubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2235/10—Infrared [IR]
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/12—Oxidising
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    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/349—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of flames, plasmas or lasers
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    • B01J8/382—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it with a rotatable device only
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    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
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  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
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CA2800868A 2010-05-28 2011-05-27 Graphene oxide and graphite oxide catalysts and systems Abandoned CA2800868A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US34937810P 2010-05-28 2010-05-28
US61/349,378 2010-05-28
US201161440574P 2011-02-08 2011-02-08
US61/440,574 2011-02-08
PCT/US2011/038327 WO2011150325A2 (en) 2010-05-28 2011-05-27 Graphene oxide and graphite oxide catalysts and systems

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CA2800868A1 true CA2800868A1 (en) 2011-12-01

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CA2800868A Abandoned CA2800868A1 (en) 2010-05-28 2011-05-27 Graphene oxide and graphite oxide catalysts and systems
CA2800874A Abandoned CA2800874A1 (en) 2010-05-28 2011-05-27 Carbocatalysts for chemical transformations

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CA2800874A Abandoned CA2800874A1 (en) 2010-05-28 2011-05-27 Carbocatalysts for chemical transformations

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US (2) US20130123514A1 (enExample)
EP (2) EP2576048A4 (enExample)
JP (1) JP2013533219A (enExample)
KR (2) KR20130021413A (enExample)
CN (2) CN103002983A (enExample)
AU (2) AU2011258067B2 (enExample)
BR (1) BR112012030292A2 (enExample)
CA (2) CA2800868A1 (enExample)
EA (2) EA201270809A1 (enExample)
GB (2) GB2480915B (enExample)
IL (2) IL223249A0 (enExample)
MX (2) MX2012013797A (enExample)
SG (1) SG186093A1 (enExample)
WO (2) WO2011150329A2 (enExample)
ZA (1) ZA201208928B (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014019089A1 (en) * 2012-07-30 2014-02-06 Zhongwei Chen Low cost synthesis of single material bifunctional nonprecious catalyst for electrochemical devices

Families Citing this family (72)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112012030292A2 (pt) * 2010-05-28 2017-06-20 Graphea Inc carbocatalisadores para transformações químicas
WO2012109212A2 (en) * 2011-02-08 2012-08-16 Graphea, Inc. Carbocatalysts for polymerization
JP5779721B2 (ja) 2011-09-16 2015-09-16 エンパイア テクノロジー ディベロップメント エルエルシー グラフェン欠陥を修正するための方法及びシステム
CN102491316B (zh) * 2011-12-13 2013-05-08 南京理工大学 一种热稳定性增强的石墨烯基超分子杂化材料及其制备方法
CN102578145A (zh) * 2012-01-19 2012-07-18 常州大学 一种载银氧化石墨烯抗菌材料的制备方法
US8979978B2 (en) 2012-01-26 2015-03-17 Empire Technology Development Llc Graphene membrane with regular angstrom-scale pores
CN102603446B (zh) * 2012-02-13 2014-08-06 湖南大学 一种以碳材料催化氧化有机酮制备有机内酯的方法
CN102746123B (zh) * 2012-06-30 2014-11-05 浙江工业大学 一种氧化石墨烯催化苯甲醇制备二苄醚的方法
US9156702B2 (en) 2012-07-25 2015-10-13 Empire Technology Development Llc Graphene membrane repair
WO2014018030A1 (en) 2012-07-25 2014-01-30 Empire Technology Development Llc Repairing graphene on a porous support
CN103112850B (zh) * 2013-03-13 2015-02-18 上海二工大资产经营有限公司 一种催化氧化多次插层制备高质量石墨烯的方法
CN103274883B (zh) * 2013-06-08 2016-04-13 中山大学 一种催化酮类化合物氧化制备内酯的方法
TW201500064A (zh) * 2013-06-28 2015-01-01 Nat Univ Tsing Hua 抗菌材料及其製備與使用方法
CN103408000B (zh) * 2013-07-25 2015-04-15 黑龙江科技大学 大片氧化石墨烯的制备方法
KR101465207B1 (ko) * 2013-10-25 2014-11-25 성균관대학교산학협력단 유기 반응용 상전이 촉매
CN103772177B (zh) * 2014-01-07 2016-03-02 郑州大学 一种对甲氧基苯乙酮的制备方法
CN103769051B (zh) * 2014-02-08 2015-08-19 南昌航空大学 一种改造氧化石墨以提高其吸附酸性染料性能的方法
CN103880717B (zh) * 2014-03-21 2015-11-04 江苏傲伦达科技实业股份有限公司 二（3-烯丙基-4-羟基苯基）砜及其衍生物的制备方法
CN103977835B (zh) * 2014-06-06 2016-08-24 上海师范大学 磺化石墨烯基Ru(bpy)32+纳米非均相催化剂及其制备方法
US20160087148A1 (en) * 2014-09-19 2016-03-24 National Cheng Kung University Non-metallic semiconductor quantum dot and method of carrying out chemical reaction or photoluminescence reaction by using the same
KR101724148B1 (ko) * 2014-12-03 2017-04-06 주식회사 에이시티 세라믹 하니컴 기반 저온환경용 탈취제
CN104496831B (zh) * 2014-12-30 2016-08-24 陕西师范大学 氧化石墨烯催化制备β-氨基羰基化合物的方法
CN105985212B (zh) * 2015-01-29 2018-02-23 中国科学院金属研究所 一种高比表面积石墨烯材料作为乙苯氧化脱氢反应催化剂的应用
CN104667869B (zh) * 2015-02-11 2016-10-05 四川大学 一种利用单过硫酸盐及负载钴铁双相复合氧化石墨烯去除水中内分泌干扰物的方法
CN105016330B (zh) * 2015-07-08 2017-12-22 常州市诚天电子有限公司 一种石墨烯的制备方法
CN106927444B (zh) * 2015-08-06 2019-11-26 成都中医药大学 一种具有烯酮结构的氧化石墨烯及其制备方法
CN105241571B (zh) * 2015-09-21 2018-03-20 长安大学 N和Mo用于提高氧化石墨烯温敏特性的方法
CN105289723A (zh) * 2015-10-20 2016-02-03 河南职业技术学院 使用碳催化剂的烃转化
CN107008481B (zh) * 2016-01-27 2020-09-22 中国石油化工股份有限公司 一种含杂原子纳米碳材料及其制备方法和应用以及一种烃脱氢反应方法
CN107216461B (zh) * 2016-03-22 2020-08-25 中国科学院理化技术研究所 一种以氧化石墨烯为引发剂引发环氧类单体聚合的方法
CN106467529B (zh) * 2016-08-24 2019-06-14 江苏三月光电科技有限公司 一种以9-芴酮为核心的有机电致发光材料及其应用
CN106279204B (zh) * 2016-09-19 2018-07-03 陕西国防工业职业技术学院 一种螺噁嗪光致变色基团修饰的氧化石墨烯及其制备方法
KR101804762B1 (ko) * 2017-02-16 2017-12-05 한국과학기술연구원 알킬렌 카보네이트 제조용 촉매, 그 제조 방법 및 상기 촉매를 이용한 알킬렌 카보네이트 제조 방법 및 장치
CN107418199B (zh) * 2017-06-26 2019-07-23 杭州师范大学 一种石墨烯改性的尼龙复合树脂及其粉末的制备方法与应用
CN107649112B (zh) * 2017-09-25 2019-08-02 山东大学 一种用于氟代磷腈及其衍生物工业化生产的催化剂
EP3694950A1 (en) * 2017-10-12 2020-08-19 Saudi Arabian Oil Company Polymer gel with nanocomposite crosslinker
WO2019090323A1 (en) * 2017-11-06 2019-05-09 Massachusetts Institute Of Technology High functionalization density graphene
CN108003031B (zh) * 2017-11-23 2021-02-02 南京偌赛医药科技有限公司 一种应用石墨烯催化二氧化氮制备硝基化合物的方法
CN108003029B (zh) * 2017-11-23 2020-11-13 南京偌赛医药科技有限公司 一种应用石墨烯催化一氧化氮制备硝基化合物的方法
CN108620095B (zh) * 2018-05-16 2020-09-29 扬州工业职业技术学院 一种复合催化剂及其在合成甘油醛中的应用
CN112638823B (zh) * 2018-08-24 2023-11-28 上海特瑞思材料科技有限公司 水过滤膜装置和制备方法
CN111100046B (zh) * 2018-10-29 2021-10-08 中国石油化工股份有限公司 一种硫醚氧化方法
CN109289937B (zh) * 2018-11-07 2021-03-26 浙江海洋大学 一种高分散负载型金属催化剂的制备方法
CN111606789B (zh) * 2019-02-26 2022-10-21 中国石油化工股份有限公司 环烷烃的催化氧化方法
CN109897512B (zh) * 2019-03-27 2021-03-23 浙江中科应化科技有限公司 一种改性聚脲涂料
CN109943058B (zh) * 2019-03-27 2021-05-04 浙江中科应化科技有限公司 一种改性聚氨酯材料
CN111763161B (zh) * 2019-04-01 2022-04-08 中国石油化工股份有限公司 氧化硫醚的方法
CN110078064A (zh) * 2019-05-07 2019-08-02 青岛科技大学 一种可导电氧化石墨烯及其制备方法和应用
CN112441958B (zh) * 2019-08-30 2022-10-21 中国石油化工股份有限公司 一种氧化叔丁醇的方法
US11220581B2 (en) 2019-11-05 2022-01-11 Saudi Arabian Oil Company Polymer gel with crosslinker and filler
CN111239111A (zh) * 2020-02-14 2020-06-05 西北师范大学 g-C3N4纳米片在检测VB12中的应用
CN111299607B (zh) * 2020-04-13 2022-06-07 紫金矿业集团黄金冶炼有限公司 一种5n级微米导电金球制备方法
US20230241245A1 (en) * 2020-06-08 2023-08-03 The Texas A&M University System Therapeutic Carbon Nanomaterial H2S Oxidants for Biological Polysulfide Synthesis
CN111790423A (zh) * 2020-06-30 2020-10-20 江苏大学 非金属官能团边缘修饰的复合光催化剂及其制备方法和应用
CN111744469B (zh) * 2020-07-30 2023-03-10 太原工业学院 一种用于去除废水中甲醛的催化剂及其制备方法和去除废水中甲醛的方法
CN114436914B (zh) * 2020-10-30 2024-07-09 中国石油化工股份有限公司 一种制备亚砜的方法
CN112812754B (zh) * 2021-02-07 2021-07-16 广西师范大学 一种苯乙炔功能化石墨烯/铜复合导热材料及其制备方法
US11802232B2 (en) 2021-03-10 2023-10-31 Saudi Arabian Oil Company Polymer-nanofiller hydrogels
CN113045976B (zh) * 2021-03-16 2022-03-25 广东绿色大地化工有限公司 一种纳米陶瓷防腐水性涂料
CN113731495B (zh) * 2021-08-23 2024-01-26 扬州帮杰新材料有限公司 一种催化剂、其制备方法和应用
CN113651734B (zh) * 2021-09-17 2023-02-14 成都理工大学 一种催化氧化硫醚成砜的方法
US12158053B2 (en) 2021-12-14 2024-12-03 Saudi Arabian Oil Company Selective zonal isolation
US11708521B2 (en) 2021-12-14 2023-07-25 Saudi Arabian Oil Company Rigless method for selective zonal isolation in subterranean formations using polymer gels
US11572761B1 (en) 2021-12-14 2023-02-07 Saudi Arabian Oil Company Rigless method for selective zonal isolation in subterranean formations using colloidal silica
WO2023114163A1 (en) * 2021-12-15 2023-06-22 Electric Hydrogen Co. Durable, low loading oxygen evolution reaction catalysts and methods of forming such catalysts
CN114345388B (zh) * 2022-01-11 2023-11-28 广州亦盛环保科技有限公司 一种类石墨相氮化碳的改性方法
CN114394922B (zh) * 2022-01-26 2024-06-11 河南农业大学 一种n取代吡咯基芳基丙烯酮类化合物的制备方法
CN114853107B (zh) * 2022-04-13 2023-08-22 锦洋高新材料股份有限公司 一种含氟废水的深度除氟工艺及铝源除氟剂
CN115106094B (zh) * 2022-08-26 2022-11-29 北京石油化工学院 一种用于催化醇类脱氢的催化剂及其制备方法和应用
PL247281B1 (pl) * 2022-12-22 2025-06-09 Univ Ostrawski Sposoby syntezy pochodnych 1,3-dioksolanów na bazie materiałów węglowych
CN118142579B (zh) * 2024-02-18 2025-06-06 中国科学院理化技术研究所 一种用于在室温下高效催化羟醛缩合反应的膜催化材料
CN118638297B (zh) * 2024-08-16 2024-10-29 山东安博瑞工程科技有限公司 一种改性聚脲树脂组合物及其制备方法

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB993921A (en) * 1963-03-28 1965-06-02 Distillers Co Yeast Ltd Improvements in or relating to the production of unsaturated aliphatic aldehydes
JPS4936642A (enExample) * 1972-08-11 1974-04-05
GB1565074A (en) * 1976-11-03 1980-04-16 British Petroleum Co Process for the production of ammonia
DE2738269C3 (de) * 1977-08-25 1980-02-21 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Herstellung von Aceton aus Isobutyraldehyd
US5876687A (en) * 1997-04-04 1999-03-02 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Elemental metals or oxides distributed on a carbon substrate or self-supported and the manufacturing process using graphite oxide as template
DE10046957A1 (de) * 2000-09-21 2002-04-11 Basf Ag Verfahren zur Herstellung eines Multimetalloxid-Katalysators, Verfahren zur Herstellung ungesättigter Aldehyde und/oder Carbonsäuren und Bandcalziniervorrichtung
JP3882072B2 (ja) * 2001-12-25 2007-02-14 独立行政法人産業技術総合研究所 多孔質グラファイト複合材料及びその製造方法
JP2003238131A (ja) * 2002-02-08 2003-08-27 Mitsubishi Gas Chem Co Inc 炭素からなる骨格を持つ薄膜状粒子のランダム凝集体
US7550611B2 (en) * 2002-11-14 2009-06-23 Catalytic Materials, Llc Carbon nanochips as catalyst supports for metals and metal oxides
TWI267219B (en) * 2005-08-29 2006-11-21 Ind Tech Res Inst Composition, complex and method for enhancing catalysts utilization
WO2008048295A2 (en) * 2005-11-18 2008-04-24 Northwestern University Stable dispersions of polymer-coated graphitic nanoplatelets
JP5156399B2 (ja) * 2006-02-03 2013-03-06 ダイキン工業株式会社 −ｓｏ３ｈ基含有フルオロポリマー製造方法及び−ｓｏ３ｈ基含有フルオロポリマー
CN101385978B (zh) * 2007-09-12 2011-04-20 上海华谊丙烯酸有限公司 一种合成甲基丙烯醛的催化剂及其制备方法
KR20100117570A (ko) * 2008-01-03 2010-11-03 내셔널 유니버시티 오브 싱가포르 기능성화된 그래핀 옥사이드
EP2240405A4 (en) * 2008-02-05 2011-06-15 John M Crain COATINGS WITH FUNCTIONALIZED GRAPH LAYERS AND ITEMS COATED WITH IT
US9546092B2 (en) * 2008-02-05 2017-01-17 The Trustees Of Princeton University Functionalized graphene sheets having high carbon to oxygen ratios
JP5077795B2 (ja) * 2008-03-10 2012-11-21 独立行政法人科学技術振興機構 カルボニル化合物の製造方法
US20110186789A1 (en) * 2008-05-22 2011-08-04 The University Of North Carolina At Chapel Hill Synthesis of graphene sheets and nanoparticle composites comprising same
JP5661618B2 (ja) * 2008-07-02 2015-01-28 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 幾何学的酸化物成形体の製造方法
CN102112424A (zh) * 2008-08-05 2011-06-29 陶氏技术投资有限公司 用于制备烷撑二醇的两级气相方法
CN101337878B (zh) * 2008-08-13 2011-04-06 华南理工大学 一种催化氧化环己烷直接生产己二酸的方法
JP5549067B2 (ja) * 2008-10-22 2014-07-16 株式会社豊田中央研究所 糖又はその誘導体の製造方法
CN101670269B (zh) * 2009-09-18 2011-05-11 淮阴师范学院 负载型氧化石墨/羟基硝酸氧铋复合材料的合成方法
JP2011224499A (ja) * 2010-04-21 2011-11-10 Toyota Central R&D Labs Inc 糖又はその誘導体の製造方法
BR112012030292A2 (pt) * 2010-05-28 2017-06-20 Graphea Inc carbocatalisadores para transformações químicas

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014019089A1 (en) * 2012-07-30 2014-02-06 Zhongwei Chen Low cost synthesis of single material bifunctional nonprecious catalyst for electrochemical devices
US9419287B2 (en) 2012-07-30 2016-08-16 Zhongwei Chen Low cost synthesis of single material bifunctional nonprecious catalyst for electrochemical devices

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