CA2689201A1 - Antimicrobial polyolefin and polyester compositions - Google Patents
Antimicrobial polyolefin and polyester compositions Download PDFInfo
- Publication number
- CA2689201A1 CA2689201A1 CA002689201A CA2689201A CA2689201A1 CA 2689201 A1 CA2689201 A1 CA 2689201A1 CA 002689201 A CA002689201 A CA 002689201A CA 2689201 A CA2689201 A CA 2689201A CA 2689201 A1 CA2689201 A1 CA 2689201A1
- Authority
- CA
- Canada
- Prior art keywords
- silver
- polyolefin
- composition according
- antimicrobial
- polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 51
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 45
- 229920000728 polyester Polymers 0.000 title claims abstract description 43
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 102
- 229910052709 silver Inorganic materials 0.000 claims abstract description 99
- 239000004332 silver Substances 0.000 claims abstract description 99
- 239000000654 additive Substances 0.000 claims abstract description 55
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 21
- 229910052751 metal Inorganic materials 0.000 claims abstract description 21
- 239000002184 metal Substances 0.000 claims abstract description 21
- 239000010457 zeolite Substances 0.000 claims abstract description 21
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 20
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 14
- 239000011521 glass Substances 0.000 claims abstract description 10
- 150000003871 sulfonates Chemical class 0.000 claims abstract description 10
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 7
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 5
- 229910021607 Silver chloride Inorganic materials 0.000 claims abstract description 3
- 229910052586 apatite Inorganic materials 0.000 claims abstract description 3
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 claims abstract description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims abstract description 3
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 3
- FJOLTQXXWSRAIX-UHFFFAOYSA-K silver phosphate Chemical compound [Ag+].[Ag+].[Ag+].[O-]P([O-])([O-])=O FJOLTQXXWSRAIX-UHFFFAOYSA-K 0.000 claims abstract description 3
- 229910000161 silver phosphate Inorganic materials 0.000 claims abstract description 3
- 229940019931 silver phosphate Drugs 0.000 claims abstract description 3
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 claims abstract description 3
- 229910000367 silver sulfate Inorganic materials 0.000 claims abstract description 3
- -1 polypropylene Polymers 0.000 claims description 59
- 239000004743 Polypropylene Substances 0.000 claims description 39
- 229920001155 polypropylene Polymers 0.000 claims description 39
- 230000000996 additive effect Effects 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 19
- 150000001298 alcohols Chemical class 0.000 claims description 18
- 239000004698 Polyethylene Substances 0.000 claims description 10
- 229920000573 polyethylene Polymers 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 7
- 150000001412 amines Chemical class 0.000 claims description 5
- 239000004745 nonwoven fabric Substances 0.000 claims description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- 239000004611 light stabiliser Substances 0.000 claims description 3
- 229940124543 ultraviolet light absorber Drugs 0.000 claims description 3
- 239000002759 woven fabric Substances 0.000 claims description 3
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 claims description 2
- ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 2
- ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical compound OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 claims description 2
- VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical compound OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 claims description 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 239000002530 phenolic antioxidant Substances 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims 2
- 239000000835 fiber Substances 0.000 abstract description 34
- 239000004599 antimicrobial Substances 0.000 abstract description 4
- 229910052744 lithium Inorganic materials 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 description 23
- 229920001577 copolymer Polymers 0.000 description 20
- 239000011734 sodium Substances 0.000 description 17
- 239000004744 fabric Substances 0.000 description 14
- 239000000523 sample Substances 0.000 description 14
- 230000001580 bacterial effect Effects 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
- 239000005977 Ethylene Substances 0.000 description 9
- 230000009467 reduction Effects 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000004700 high-density polyethylene Substances 0.000 description 8
- 229920001684 low density polyethylene Polymers 0.000 description 8
- 239000004702 low-density polyethylene Substances 0.000 description 8
- 229920001903 high density polyethylene Polymers 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229920001817 Agar Polymers 0.000 description 6
- 241000588724 Escherichia coli Species 0.000 description 6
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
- 239000008272 agar Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000009987 spinning Methods 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 4
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000011534 incubation Methods 0.000 description 4
- 239000002054 inoculum Substances 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000000787 lecithin Substances 0.000 description 4
- 235000010445 lecithin Nutrition 0.000 description 4
- 229940067606 lecithin Drugs 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 4
- 229920000053 polysorbate 80 Polymers 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 3
- 239000001888 Peptone Substances 0.000 description 3
- 108010080698 Peptones Proteins 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 235000010419 agar Nutrition 0.000 description 3
- 239000000872 buffer Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 150000001993 dienes Chemical class 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 3
- 230000002779 inactivation Effects 0.000 description 3
- 150000005673 monoalkenes Chemical class 0.000 description 3
- 235000019319 peptone Nutrition 0.000 description 3
- 239000008363 phosphate buffer Substances 0.000 description 3
- 239000002504 physiological saline solution Substances 0.000 description 3
- 239000001967 plate count agar Substances 0.000 description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000003466 anti-cipated effect Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000009960 carding Methods 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 230000035622 drinking Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 229960002885 histidine Drugs 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 229920001179 medium density polyethylene Polymers 0.000 description 2
- 239000004701 medium-density polyethylene Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000006150 trypticase soy agar Substances 0.000 description 2
- 229910001868 water Inorganic materials 0.000 description 2
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 description 1
- LINPIYWFGCPVIE-UHFFFAOYSA-N 2,4,6-trichlorophenol Chemical compound OC1=C(Cl)C=C(Cl)C=C1Cl LINPIYWFGCPVIE-UHFFFAOYSA-N 0.000 description 1
- YQPCHPBGAALCRT-UHFFFAOYSA-N 2-[1-(carboxymethyl)cyclohexyl]acetic acid Chemical compound OC(=O)CC1(CC(O)=O)CCCCC1 YQPCHPBGAALCRT-UHFFFAOYSA-N 0.000 description 1
- ICPXIRMAMWRMAD-UHFFFAOYSA-N 2-[3-[2-[3-(2-hydroxyethoxy)phenyl]propan-2-yl]phenoxy]ethanol Chemical compound C=1C=CC(OCCO)=CC=1C(C)(C)C1=CC=CC(OCCO)=C1 ICPXIRMAMWRMAD-UHFFFAOYSA-N 0.000 description 1
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 description 1
- HDCGAHPPUWORDU-UHFFFAOYSA-N 2-butyl-3h-1,2-benzothiazole Chemical compound C1=CC=C2SN(CCCC)CC2=C1 HDCGAHPPUWORDU-UHFFFAOYSA-N 0.000 description 1
- 125000003229 2-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- PNJNLCNHYSWUPT-UHFFFAOYSA-N 2-methylpentane-1,4-diol Chemical compound CC(O)CC(C)CO PNJNLCNHYSWUPT-UHFFFAOYSA-N 0.000 description 1
- 229940044120 2-n-octyl-4-isothiazolin-3-one Drugs 0.000 description 1
- 229940061334 2-phenylphenol Drugs 0.000 description 1
- UEDISDQWZXBSKK-UHFFFAOYSA-N 3-[4-[1-[4-(3-hydroxypropoxy)phenyl]ethyl]phenoxy]propan-1-ol Chemical compound C=1C=C(OCCCO)C=CC=1C(C)C1=CC=C(OCCCO)C=C1 UEDISDQWZXBSKK-UHFFFAOYSA-N 0.000 description 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- RBQLGIKHSXQZTB-UHFFFAOYSA-N 3-methylpentane-2,4-diol Chemical compound CC(O)C(C)C(C)O RBQLGIKHSXQZTB-UHFFFAOYSA-N 0.000 description 1
- CKVHXAPZCATURN-UHFFFAOYSA-N 4-(2-tert-butyl-5-methylphenoxy)phenol Chemical compound CC1=CC=C(C(C)(C)C)C(OC=2C=CC(O)=CC=2)=C1 CKVHXAPZCATURN-UHFFFAOYSA-N 0.000 description 1
- CDBAMNGURPMUTG-UHFFFAOYSA-N 4-[2-(4-hydroxycyclohexyl)propan-2-yl]cyclohexan-1-ol Chemical compound C1CC(O)CCC1C(C)(C)C1CCC(O)CC1 CDBAMNGURPMUTG-UHFFFAOYSA-N 0.000 description 1
- LANFMNFQTUQWEF-UHFFFAOYSA-N 4-methylpent-1-ene Chemical compound C[C](C)CC=C LANFMNFQTUQWEF-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
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- 229920001634 Copolyester Polymers 0.000 description 1
- MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophen Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 description 1
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- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
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- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004146 Propane-1,2-diol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
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- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 1
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- WPZSJJJTNREFSV-UHFFFAOYSA-N [Zn].[O-][N+]1=CC=CC=C1S Chemical compound [Zn].[O-][N+]1=CC=CC=C1S WPZSJJJTNREFSV-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
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- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 230000000704 physical effect Effects 0.000 description 1
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- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
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- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- BSWGGJHLVUUXTL-UHFFFAOYSA-N silver zinc Chemical compound [Zn].[Ag] BSWGGJHLVUUXTL-UHFFFAOYSA-N 0.000 description 1
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0058—Biocides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/015—Biocides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
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| US93414007P | 2007-06-11 | 2007-06-11 | |
| US60/934,140 | 2007-06-11 | ||
| PCT/EP2008/056694 WO2008151948A2 (en) | 2007-06-11 | 2008-05-30 | Antimicrobial polyolefin and polyester compositions |
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| CA2689201A1 true CA2689201A1 (en) | 2008-12-18 |
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| EP (1) | EP2155815B1 (enExample) |
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| BR (1) | BRPI0812471A2 (enExample) |
| CA (1) | CA2689201A1 (enExample) |
| ES (1) | ES2522616T3 (enExample) |
| TW (1) | TWI448499B (enExample) |
| WO (1) | WO2008151948A2 (enExample) |
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| JP2782719B2 (ja) | 1988-04-28 | 1998-08-06 | トヨタ自動車株式会社 | 素材切断機における素材回転装置 |
| DE102007054132A1 (de) * | 2007-11-14 | 2009-05-20 | Mitsubishi Polyester Film Gmbh | Antimikrobiell ausgerüstete, biaxial orientierte Polyesterfolie |
| US20110171321A1 (en) * | 2008-09-11 | 2011-07-14 | Luchsinger Benjamin P | Elastomeric article having a broad spectrum antimicrobial agent and method of making |
| JP5474443B2 (ja) * | 2009-08-10 | 2014-04-16 | 株式会社セラフト | 添加粒子及び添加粒子連結体 |
| CN102040828A (zh) | 2009-10-26 | 2011-05-04 | 杜邦兴达（无锡）单丝有限公司 | 抗菌组合物、抗菌刷丝及它们的制备方法 |
| GB201006076D0 (en) | 2010-04-12 | 2010-05-26 | Xeros Ltd | Novel cleaning apparatus and method |
| FR2962348B1 (fr) * | 2010-07-12 | 2012-09-07 | Ind Du Ponant L | Filtre microbicide et cartouche filtrante incorporant un tel filtre |
| GB201015277D0 (en) | 2010-09-14 | 2010-10-27 | Xeros Ltd | Novel cleaning method |
| WO2012074153A1 (ko) * | 2010-12-03 | 2012-06-07 | 주식회사 엔피텍 | 항균성이 우수한 폴리에스테르 마스터배치 및 그 제조방법 |
| GB201100627D0 (en) | 2011-01-14 | 2011-03-02 | Xeros Ltd | Improved cleaning method |
| GB201100918D0 (en) | 2011-01-19 | 2011-03-02 | Xeros Ltd | Improved drying method |
| WO2012123273A1 (en) | 2011-03-11 | 2012-09-20 | Basf Se | Antimicrobial coating |
| WO2012128406A1 (ko) * | 2011-03-24 | 2012-09-27 | 주식회사 엔피텍 | 은-실리카 나노복합체를 포함하는 폴리에스테르 마스터배치 및 그 제조방법 |
| US20120312840A1 (en) * | 2011-05-13 | 2012-12-13 | Ayako Hasegawa | Container closure system with integral antimicrobial additives |
| CN102512879B (zh) * | 2011-12-02 | 2014-11-26 | 杭州帝凡过滤技术有限公司 | 耐高温高压过滤芯的制造方法 |
| GB201212098D0 (en) | 2012-07-06 | 2012-08-22 | Xeros Ltd | New cleaning material |
| US20140154335A1 (en) * | 2012-12-04 | 2014-06-05 | Whitehall Products, Llc | Antimicrobial packaing |
| WO2014152586A1 (en) * | 2013-03-14 | 2014-09-25 | Aspen Research Corporation | Polymeric materials containing anti-microbial additive |
| BR112016006528B1 (pt) | 2013-09-27 | 2021-07-27 | Basf Se | Artigo extrudado compreendendo uma composição de poliolefina |
| GB201319782D0 (en) | 2013-11-08 | 2013-12-25 | Xeros Ltd | Cleaning method and apparatus |
| GB201320784D0 (en) | 2013-11-25 | 2014-01-08 | Xeros Ltd | Improved cleaning Apparatus and method |
| KR101478942B1 (ko) | 2014-01-23 | 2015-01-02 | 해성엔터프라이즈 주식회사 | 항균성 원사의 제조방법 및 항균성 원사 |
| GB201410514D0 (en) * | 2014-06-12 | 2014-07-30 | Fantex Ltd | Polymer antimicrobial composition |
| US20170136140A1 (en) * | 2014-06-26 | 2017-05-18 | Avent, Inc. | Antimicrobial Compositions Utilizing Silver and Oxygen, Process for Making, and Method of Using the Same |
| US20190053556A1 (en) * | 2017-08-18 | 2019-02-21 | Gregory G. Judah | Textiles Treated with Composition Inhibiting Sustainability and Growth of Pathogenic Microbes |
| BR112020019892A2 (pt) * | 2018-03-29 | 2021-01-05 | Dow Global Technologies Llc | Composições antimicrobianas de revestimento de selagem a quente |
| CN108619556B (zh) * | 2018-06-21 | 2021-07-06 | 江西省科学院应用化学研究所 | 一种多孔纤维复合止血材料的制备方法 |
| FR3085105B1 (fr) * | 2018-08-22 | 2021-02-12 | Commissariat Energie Atomique | Nouvel agent antimicrobien a base de materiau polymerique particulaire poreux dope |
| CN109898175B (zh) * | 2019-02-28 | 2021-06-29 | 东莞易昌塑胶布业有限公司 | 一种环保衬布及其制作方法 |
| JP6579462B1 (ja) * | 2019-06-07 | 2019-09-25 | 株式会社アイセル | コーティング液貯蔵体の製造方法 |
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|---|---|---|---|---|
| JPS59133235A (ja) * | 1983-01-21 | 1984-07-31 | Kanebo Ltd | 殺菌性ポリマー組成物及びその製造法 |
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| JP2006335913A (ja) * | 2005-06-03 | 2006-12-14 | Daicel Polymer Ltd | 洗浄用樹脂組成物 |
-
2008
- 2008-05-30 WO PCT/EP2008/056694 patent/WO2008151948A2/en not_active Ceased
- 2008-05-30 ES ES08760282.7T patent/ES2522616T3/es active Active
- 2008-05-30 CA CA002689201A patent/CA2689201A1/en not_active Abandoned
- 2008-05-30 EP EP08760282.7A patent/EP2155815B1/en not_active Not-in-force
- 2008-05-30 JP JP2010511576A patent/JP5631205B2/ja not_active Expired - Fee Related
- 2008-05-30 CN CN2008800199588A patent/CN101688028B/zh not_active Expired - Fee Related
- 2008-05-30 AU AU2008264057A patent/AU2008264057B2/en not_active Ceased
- 2008-05-30 BR BRPI0812471A patent/BRPI0812471A2/pt not_active IP Right Cessation
- 2008-06-09 US US12/157,278 patent/US20080306183A1/en not_active Abandoned
- 2008-06-10 TW TW097121495A patent/TWI448499B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| WO2008151948A2 (en) | 2008-12-18 |
| AU2008264057B2 (en) | 2013-07-04 |
| ES2522616T3 (es) | 2014-11-17 |
| TWI448499B (zh) | 2014-08-11 |
| EP2155815A2 (en) | 2010-02-24 |
| EP2155815B1 (en) | 2014-09-03 |
| WO2008151948A3 (en) | 2009-02-19 |
| US20080306183A1 (en) | 2008-12-11 |
| TW200904880A (en) | 2009-02-01 |
| CN101688028A (zh) | 2010-03-31 |
| JP5631205B2 (ja) | 2014-11-26 |
| JP2010530016A (ja) | 2010-09-02 |
| AU2008264057A1 (en) | 2008-12-18 |
| CN101688028B (zh) | 2012-07-18 |
| BRPI0812471A2 (pt) | 2017-06-13 |
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Legal Events
| Date | Code | Title | Description |
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| EEER | Examination request |
Effective date: 20130515 |
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| FZDE | Discontinued |
Effective date: 20160527 |