CA2570822C - Branched polylactic acid polymers and method of preparing same - Google Patents
Branched polylactic acid polymers and method of preparing same Download PDFInfo
- Publication number
- CA2570822C CA2570822C CA2570822A CA2570822A CA2570822C CA 2570822 C CA2570822 C CA 2570822C CA 2570822 A CA2570822 A CA 2570822A CA 2570822 A CA2570822 A CA 2570822A CA 2570822 C CA2570822 C CA 2570822C
- Authority
- CA
- Canada
- Prior art keywords
- polylactide resin
- copolymer
- acrylate polymer
- resin
- molecule
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/912—Polymers modified by chemical after-treatment derived from hydroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
- C08L33/068—Copolymers with monomers not covered by C08L33/06 containing glycidyl groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyesters Or Polycarbonates (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Biological Depolymerization Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58215604P | 2004-06-23 | 2004-06-23 | |
| US60/582,156 | 2004-06-23 | ||
| PCT/US2005/022480 WO2006002372A2 (en) | 2004-06-23 | 2005-06-23 | Branched polylactic acid polymers and method of preparing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2570822A1 CA2570822A1 (en) | 2006-01-05 |
| CA2570822C true CA2570822C (en) | 2010-10-05 |
Family
ID=35782365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2570822A Expired - Lifetime CA2570822C (en) | 2004-06-23 | 2005-06-23 | Branched polylactic acid polymers and method of preparing same |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7566753B2 (enExample) |
| EP (1) | EP1773586B1 (enExample) |
| JP (1) | JP4798800B2 (enExample) |
| KR (1) | KR100854168B1 (enExample) |
| CN (1) | CN100564025C (enExample) |
| AU (1) | AU2005258271B2 (enExample) |
| BR (1) | BRPI0512370B1 (enExample) |
| CA (1) | CA2570822C (enExample) |
| ES (1) | ES2397898T3 (enExample) |
| NZ (1) | NZ552193A (enExample) |
| PL (1) | PL1773586T3 (enExample) |
| WO (1) | WO2006002372A2 (enExample) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8133558B2 (en) * | 2004-08-30 | 2012-03-13 | Plastics Suppliers, Inc. | Polylactic acid blown film and method of manufacturing same |
| DE102005007479A1 (de) * | 2005-02-17 | 2006-08-31 | Basf Ag | Verfahren zur Compoundierung von Polycondensaten |
| JP4672409B2 (ja) * | 2005-03-24 | 2011-04-20 | 東亞合成株式会社 | 脂肪族ポリエステル樹脂組成物 |
| EP1890862A4 (en) * | 2005-04-19 | 2008-09-03 | Plastic Suppliers Inc | RETRACTABLE FILM OF POLYLACTIC ACID AND METHOD OF MANUFACTURING THE SAME |
| PL1954571T3 (pl) | 2005-11-21 | 2019-08-30 | Plastic Suppliers, Inc. | Polilaktydowe folie kurczliwe i sposoby ich odlewania |
| JP4952252B2 (ja) * | 2005-11-30 | 2012-06-13 | 東レ株式会社 | ポリ乳酸系樹脂積層シートおよびそれからなる成形体 |
| AU2007239514B2 (en) * | 2006-04-14 | 2010-09-23 | Biotec Biologische Naturverpackungen Gmbh & Co. Kg | Multilayered film and method for manufacturing same |
| US9163141B2 (en) * | 2006-04-27 | 2015-10-20 | Cryovac, Inc. | Polymeric blend comprising polylactic acid |
| US8206796B2 (en) * | 2006-04-27 | 2012-06-26 | Cryovac, Inc. | Multilayer film comprising polylactic acid |
| US7604859B2 (en) * | 2006-08-30 | 2009-10-20 | Far Eastern Textile Ltd. | Heat adhesive biodegradable bicomponent fibers |
| FR2916203B1 (fr) * | 2007-05-14 | 2012-07-20 | Arkema | Liants de coextrusion sur base renouvelable/biodegradable |
| WO2009076541A1 (en) * | 2007-12-11 | 2009-06-18 | Toray Plastics (America), Inc. | Process to produce biaxially oriented polylactic acid film at high transverse orientation rates |
| CN102037053B (zh) * | 2008-04-30 | 2016-03-02 | 自然工作有限责任公司 | 由具有高分子量和高特性粘数的聚丙交酯制得的挤出泡沫 |
| US8137818B2 (en) * | 2008-07-28 | 2012-03-20 | Tate & Lyle Ingredients Americas Llc | Poly(lactic acid)-containing compositions for use in imparting oil, grease, or water resistance to paper |
| WO2010012688A1 (de) * | 2008-08-01 | 2010-02-04 | Basf Se | Erhöhung der hydrolysebeständigkeit von biologisch abbaubaren polyestern |
| US9314999B2 (en) * | 2008-08-15 | 2016-04-19 | Toray Plastics (America), Inc. | Biaxially oriented polylactic acid film with high barrier |
| CN101921371B (zh) * | 2009-06-09 | 2012-06-27 | 中国科学院化学研究所 | 一种长链支化聚乳酸树脂及其制备方法 |
| US9150004B2 (en) * | 2009-06-19 | 2015-10-06 | Toray Plastics (America), Inc. | Biaxially oriented polylactic acid film with improved heat seal properties |
| EP2480710B1 (en) | 2009-09-25 | 2018-01-24 | Toray Plastics (America) , Inc. | Multi-layer high moisture barrier polylactic acid film and its method of forming |
| US9221213B2 (en) * | 2009-09-25 | 2015-12-29 | Toray Plastics (America), Inc. | Multi-layer high moisture barrier polylactic acid film |
| WO2011085058A1 (en) | 2010-01-06 | 2011-07-14 | Nature Works Llc | Polylactide molding compositions and molding process |
| US9517612B2 (en) * | 2010-03-15 | 2016-12-13 | Lg Hausys, Ltd. | Floor material using PLA resin |
| WO2011123165A1 (en) | 2010-03-31 | 2011-10-06 | Toray Plastics (America), Inc. | Biaxially oriented polyactic acid film with reduced noise level |
| US9492962B2 (en) | 2010-03-31 | 2016-11-15 | Toray Plastics (America), Inc. | Biaxially oriented polylactic acid film with reduced noise level and improved moisture barrier |
| US10753023B2 (en) | 2010-08-13 | 2020-08-25 | Kimberly-Clark Worldwide, Inc. | Toughened polylactic acid fibers |
| US8936740B2 (en) * | 2010-08-13 | 2015-01-20 | Kimberly-Clark Worldwide, Inc. | Modified polylactic acid fibers |
| WO2012103208A2 (en) * | 2011-01-28 | 2012-08-02 | Anderson Development Company | Compositions of glycidyl methacrylate copolymer suitable as chain extender for poly(lactic acid) |
| US9045611B2 (en) | 2011-03-04 | 2015-06-02 | Cryovac, Inc. | Process for preparing a heat resistant polylactic acid foamed article |
| SK262011A3 (sk) | 2011-04-11 | 2012-11-05 | Ustav Polymerov Sav | Biologically degradable polymeric composition having improved properties |
| WO2013069726A1 (ja) * | 2011-11-11 | 2013-05-16 | 日本合成化学工業株式会社 | 生分解性積層体 |
| US10858762B2 (en) | 2012-02-10 | 2020-12-08 | Kimberly-Clark Worldwide, Inc. | Renewable polyester fibers having a low density |
| US8637130B2 (en) | 2012-02-10 | 2014-01-28 | Kimberly-Clark Worldwide, Inc. | Molded parts containing a polylactic acid composition |
| US8980964B2 (en) | 2012-02-10 | 2015-03-17 | Kimberly-Clark Worldwide, Inc. | Renewable polyester film having a low modulus and high tensile elongation |
| US9040598B2 (en) | 2012-02-10 | 2015-05-26 | Kimberly-Clark Worldwide, Inc. | Renewable polyester compositions having a low density |
| US8975305B2 (en) | 2012-02-10 | 2015-03-10 | Kimberly-Clark Worldwide, Inc. | Rigid renewable polyester compositions having a high impact strength and tensile elongation |
| WO2013184014A1 (en) | 2012-06-06 | 2013-12-12 | Universidade De Coimbra | Process for preparing high molecular weight poly(lactic acid) by melt polycondensation |
| WO2014184057A1 (en) | 2013-05-14 | 2014-11-20 | Basf Se | Process for production of polymer powders |
| JP6206711B2 (ja) * | 2013-09-27 | 2017-10-04 | Dic株式会社 | スチレン系樹脂組成物及びその製造方法 |
| EP3252103B1 (en) | 2015-01-30 | 2020-09-09 | Toyobo Co., Ltd. | Polylactic acid-containing aqueous dispersion |
| US10843372B1 (en) | 2015-06-22 | 2020-11-24 | Purdue Research Foundation | Methods and compositions for preparing particle boards |
| CN106317338B (zh) * | 2015-06-23 | 2018-09-21 | 中国石油化工股份有限公司 | 长链支化聚乳酸树脂及其制备方法 |
| US10711097B2 (en) | 2015-08-21 | 2020-07-14 | National University Corporation NARA Institute of Science and Technology | Polylactide derivative, method for producing same, and polylactide stereocomplex |
| KR102219992B1 (ko) | 2016-04-28 | 2021-02-25 | 네이쳐웍스 엘엘씨 | 내열성 폴리머 층 및 폴리락티드 수지 층을 포함하는 다층 시트의 외장을 갖는 폴리머 발포체 단열 구조물 |
| JP6961615B2 (ja) | 2016-04-28 | 2021-11-10 | ネイチャーワークス・エル・エル・シー | ポリラクチド樹脂の化粧面層を有するポリマーフォーム断熱材構造 |
| KR102604796B1 (ko) * | 2017-12-03 | 2023-11-21 | 네이쳐웍스 엘엘씨 | 판지 코팅용 폴리락티드 수지 조성물 및 그 조성물을 사용하는 판지 코팅 방법 |
| AU2019213590B2 (en) | 2018-02-02 | 2024-02-01 | Natureworks Llc | Hyperbranched polylactide resin compositions |
| CN110577648B (zh) * | 2018-04-19 | 2021-09-28 | 苏州大学 | 一种疏水型聚己内酯的制备方法 |
| SI3820941T1 (sl) * | 2018-07-13 | 2024-02-29 | Byk-Chemie Gmbh | Cepljena polimlečna kislina |
| WO2020074445A1 (en) | 2018-10-09 | 2020-04-16 | Byk-Chemie Gmbh | A composition comprising a grafted polylactic acid |
| US12275842B2 (en) | 2019-06-13 | 2025-04-15 | Natureworks Llc | Fast-hydrolyzing polylactide resin compositions |
| CN113265029A (zh) * | 2020-11-26 | 2021-08-17 | 汕头市三马塑胶制品有限公司 | 一种兼具高熔体强度及优异加工流动性的长链支化聚乳酸及其制备方法 |
| KR20240017340A (ko) | 2021-03-31 | 2024-02-07 | 네이쳐웍스 엘엘씨 | 아인산염 에스테르를 함유하는 용융 안정성 폴리락타이드 수지 조성물 |
| CN113512181B (zh) * | 2021-08-09 | 2022-08-12 | 重庆大学 | 一种可低温加工的聚乳酸及其制备方法 |
| US20250171585A1 (en) | 2022-03-30 | 2025-05-29 | Natureworks Llc | Hyperbranched poly(meso-lactide) resin compositions |
| CN114940745B (zh) * | 2022-06-09 | 2024-06-25 | 万华化学集团股份有限公司 | 一种分子量可控的聚乳酸的制备方法 |
| HRP20250823T1 (hr) | 2022-10-27 | 2025-09-12 | Basf Se | Biorazgradivi polimerni pripravak |
| WO2024145130A1 (en) | 2022-12-28 | 2024-07-04 | Natureworks Llc | Polylactide resin compositions and biaxial stretching process for the polylactide resin compositions |
| CN119421915A (zh) * | 2023-01-05 | 2025-02-11 | 株式会社Lg化学 | 支化聚乳酸聚合物及其制备方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3845016A (en) * | 1971-12-17 | 1974-10-29 | Ford Motor Co | Thermoset molding powders employing glycidyl methacrylate-functional polymers and polymeric polyanhydride crosslinking agents and moldings thereof |
| JPS61163952A (ja) * | 1985-01-16 | 1986-07-24 | Showa Denko Kk | 熱可塑性樹脂組成物 |
| JPH0578556A (ja) | 1991-09-18 | 1993-03-30 | Mitsubishi Kasei Corp | 熱可塑性樹脂組成物および電子部品封止成形品 |
| US5225521A (en) * | 1991-12-31 | 1993-07-06 | E. I. Du Pont De Nemours And Company | Star-shaped hydroxyacid polymers |
| US5210108A (en) * | 1992-07-29 | 1993-05-11 | E. I. Du Pont De Nemours And Company | Degradable foam materials |
| US5359026A (en) * | 1993-07-30 | 1994-10-25 | Cargill, Incorporated | Poly(lactide) copolymer and process for manufacture thereof |
| US5498650A (en) * | 1995-02-24 | 1996-03-12 | Ecological Chemical Products | Poly(lactic acid) composition having improved physical properties |
| JP3693756B2 (ja) * | 1996-05-27 | 2005-09-07 | カネボウ株式会社 | ポリ乳酸樹脂組成物 |
| US5910545A (en) * | 1997-10-31 | 1999-06-08 | Kimberly-Clark Worldwide, Inc. | Biodegradable thermoplastic composition |
| JP2001123055A (ja) * | 1999-10-27 | 2001-05-08 | Shimadzu Corp | ポリ乳酸系樹脂組成物 |
| EP1406947A4 (en) | 2001-06-08 | 2010-08-04 | Cargill Dow Llc | COPOLYMERS OF MONOCYCLIC ESTERS AND CARBONATES AND METHODS OF PRODUCING THE SAME |
| JP3824547B2 (ja) * | 2001-08-10 | 2006-09-20 | ユニチカ株式会社 | 生分解性ポリエステル樹脂組成物、その製造方法、及びそれより得られる発泡体、成形体 |
| US20030105231A1 (en) * | 2001-11-28 | 2003-06-05 | Hitech Polymers Inc. | Polyester composition |
| JP4476804B2 (ja) * | 2002-05-29 | 2010-06-09 | 株式会社クレハ | 生分解性耐熱性硬質樹脂成形容器 |
| JP4311916B2 (ja) * | 2002-06-05 | 2009-08-12 | アキレス株式会社 | 耐加水分解性に優れた生分解性樹脂製フィルムまたはシート |
| US7354973B2 (en) * | 2003-12-12 | 2008-04-08 | E.I. Du Pont De Nemours And Company | Toughened poly(lactic acid) compositions |
| JP2005343970A (ja) * | 2004-06-01 | 2005-12-15 | Okura Ind Co Ltd | ポリ乳酸系樹脂組成物 |
-
2005
- 2005-06-23 ES ES05788614T patent/ES2397898T3/es not_active Expired - Lifetime
- 2005-06-23 AU AU2005258271A patent/AU2005258271B2/en not_active Ceased
- 2005-06-23 KR KR1020077001447A patent/KR100854168B1/ko not_active Expired - Fee Related
- 2005-06-23 US US11/629,798 patent/US7566753B2/en active Active
- 2005-06-23 JP JP2007518309A patent/JP4798800B2/ja not_active Expired - Fee Related
- 2005-06-23 EP EP20050788614 patent/EP1773586B1/en not_active Expired - Lifetime
- 2005-06-23 CN CNB2005800269801A patent/CN100564025C/zh not_active Expired - Fee Related
- 2005-06-23 CA CA2570822A patent/CA2570822C/en not_active Expired - Lifetime
- 2005-06-23 BR BRPI0512370-4A patent/BRPI0512370B1/pt not_active IP Right Cessation
- 2005-06-23 NZ NZ552193A patent/NZ552193A/en not_active IP Right Cessation
- 2005-06-23 PL PL05788614T patent/PL1773586T3/pl unknown
- 2005-06-23 WO PCT/US2005/022480 patent/WO2006002372A2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JP4798800B2 (ja) | 2011-10-19 |
| CN100564025C (zh) | 2009-12-02 |
| EP1773586A2 (en) | 2007-04-18 |
| KR20070049140A (ko) | 2007-05-10 |
| HK1110273A1 (zh) | 2008-07-11 |
| ES2397898T3 (es) | 2013-03-12 |
| EP1773586B1 (en) | 2012-08-08 |
| AU2005258271B2 (en) | 2010-02-18 |
| US7566753B2 (en) | 2009-07-28 |
| US20080050603A1 (en) | 2008-02-28 |
| AU2005258271A1 (en) | 2006-01-05 |
| BRPI0512370B1 (pt) | 2018-01-30 |
| JP2008504404A (ja) | 2008-02-14 |
| CA2570822A1 (en) | 2006-01-05 |
| PL1773586T3 (pl) | 2013-01-31 |
| BRPI0512370A (pt) | 2008-03-11 |
| CN101018668A (zh) | 2007-08-15 |
| WO2006002372A3 (en) | 2006-06-22 |
| EP1773586A4 (en) | 2009-11-11 |
| NZ552193A (en) | 2010-04-30 |
| WO2006002372A2 (en) | 2006-01-05 |
| KR100854168B1 (ko) | 2008-08-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |