CA2546499C - Process for making nickel hydroxide - Google Patents
Process for making nickel hydroxide Download PDFInfo
- Publication number
- CA2546499C CA2546499C CA2546499A CA2546499A CA2546499C CA 2546499 C CA2546499 C CA 2546499C CA 2546499 A CA2546499 A CA 2546499A CA 2546499 A CA2546499 A CA 2546499A CA 2546499 C CA2546499 C CA 2546499C
- Authority
- CA
- Canada
- Prior art keywords
- nickel
- sulfuric acid
- nickel metal
- nickel sulfate
- bulk
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 63
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 title abstract description 53
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 230
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 148
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 110
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims abstract description 82
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims abstract description 82
- 229910052751 metal Inorganic materials 0.000 claims abstract description 49
- 239000002184 metal Substances 0.000 claims abstract description 49
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000001301 oxygen Substances 0.000 claims abstract description 40
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 40
- 238000006243 chemical reaction Methods 0.000 claims abstract description 37
- 239000007789 gas Substances 0.000 claims abstract description 27
- 239000002253 acid Substances 0.000 claims description 6
- 238000010924 continuous production Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 25
- 235000011149 sulphuric acid Nutrition 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 54
- 238000004519 manufacturing process Methods 0.000 description 17
- 239000002245 particle Substances 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- 238000010586 diagram Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000011149 active material Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000007774 positive electrode material Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- ZRUWFKRETRELPY-UHFFFAOYSA-N azane;nickel(2+) Chemical group N.[Ni+2] ZRUWFKRETRELPY-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 150000002815 nickel Chemical class 0.000 description 3
- 229910000480 nickel oxide Inorganic materials 0.000 description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000004801 Chlorinated PVC Substances 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 2
- 239000004035 construction material Substances 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- -1 nickel metal hydride Chemical class 0.000 description 2
- 229910021508 nickel(II) hydroxide Inorganic materials 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002449 FKM Polymers 0.000 description 1
- 229910003307 Ni-Cd Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/04—Oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/727,413 | 2003-12-04 | ||
| US10/727,413 US7364717B2 (en) | 2003-12-04 | 2003-12-04 | Process for converting nickel to nickel sulfate |
| PCT/US2004/039799 WO2005060523A2 (en) | 2003-12-04 | 2004-11-23 | Process for making nickel hydroxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2546499A1 CA2546499A1 (en) | 2005-07-07 |
| CA2546499C true CA2546499C (en) | 2013-04-30 |
Family
ID=34633481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2546499A Expired - Fee Related CA2546499C (en) | 2003-12-04 | 2004-11-23 | Process for making nickel hydroxide |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7364717B2 (enExample) |
| EP (1) | EP1689682B1 (enExample) |
| JP (1) | JP4996923B2 (enExample) |
| KR (1) | KR20060129199A (enExample) |
| CN (1) | CN100457638C (enExample) |
| BR (1) | BRPI0417163A (enExample) |
| CA (1) | CA2546499C (enExample) |
| MX (1) | MX284392B (enExample) |
| WO (1) | WO2005060523A2 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7799296B2 (en) * | 2003-12-04 | 2010-09-21 | Ovonic Battery Company, Inc. | Method of producing a nickel salt solution |
| KR100981366B1 (ko) | 2009-11-19 | 2010-09-10 | 인천화학 주식회사 | 황산니켈 결정의 제조 방법 |
| EP2872447B1 (de) * | 2012-07-10 | 2016-12-28 | Basf Se | Verfahren zur herstellung von wässrigen lösungen von kobaltsulfat |
| US9364890B2 (en) | 2013-03-11 | 2016-06-14 | Ati Properties, Inc. | Enhanced techniques for centrifugal casting of molten materials |
| KR101724690B1 (ko) | 2016-09-20 | 2017-04-10 | 서울대학교 산학협력단 | 양극산화를 통한 철-니켈 기반 물분해 촉매전극 제조방법 및 이에 따라 제조된 물 분해 촉매전극 |
| DE102018005586A1 (de) | 2018-07-17 | 2020-01-23 | Manfred Koch | Ein neuer integrierter Prozess für die Herstellung von Kathodenmaterial für Batterien |
| CN109336194A (zh) * | 2018-12-13 | 2019-02-15 | 怀化恒安石化有限公司 | 一种废硝酸镍溶液经除氯离子生产硝酸镍产品的工艺方法 |
| JP7183765B2 (ja) * | 2018-12-20 | 2022-12-06 | 住友金属鉱山株式会社 | 硫酸ニッケル溶液の製造方法および製造装置 |
| CN111439791A (zh) * | 2019-01-17 | 2020-07-24 | 江西核工业兴中新材料有限公司 | 一种气液乳化生产硫酸镍的方法 |
| KR102301974B1 (ko) | 2019-08-21 | 2021-09-16 | 서울대학교산학협력단 | 아크-멜팅법을 이용한 촉매전극의 제조방법 및 이에 따라 제조된 촉매전극 |
| JP7415221B2 (ja) * | 2019-11-18 | 2024-01-17 | 住友金属鉱山株式会社 | 硫酸ニッケル溶液の製造装置および製造方法 |
| CN111826523B (zh) * | 2020-06-28 | 2022-07-15 | 广东邦普循环科技有限公司 | 一种氢氧化镍钴精炼的方法 |
| ES2960719T3 (es) * | 2020-09-09 | 2024-03-06 | Northvolt Ab | Proceso para preparar soluciones de sulfato metálico de grado de batería |
| CN113003618A (zh) * | 2021-03-01 | 2021-06-22 | 杭州申柯新材料有限公司 | 一种金属镍直接氧化法生产高纯氧化亚镍生产线及其生产工艺 |
| KR102504964B1 (ko) * | 2021-10-06 | 2023-03-03 | (주)한청알에프 | 니켈도금의 NdFeB계 소결자석 폐스크랩으로부터 니켈성분을 회수하는 방법 |
| CA3191462A1 (en) | 2022-03-03 | 2023-09-03 | Umicore | Process for the oxidative leaching of ni |
| NO20220405A1 (en) * | 2022-04-01 | 2023-10-02 | Glencore Nikkelverk As | Continuous dissolution reactor |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1936829A (en) * | 1932-11-08 | 1933-11-28 | Grasselli Chemical Co | Process of making nickel sulphate |
| US3962051A (en) * | 1974-12-26 | 1976-06-08 | Amax Inc. | Atmospheric leaching of matte containing iron |
| CA1107678A (en) * | 1978-04-12 | 1981-08-25 | Kohur N. Subramanian | Nickel recovery from sulfur-deficient mattes |
| FI64188C (fi) * | 1979-06-29 | 1983-10-10 | Outokumpu Oy | Foerfarande foer selektiv lakning av nickel-kopparskaersten |
| US5281494A (en) * | 1990-05-04 | 1994-01-25 | Inco Limited | Nickel hydroxide |
| FI97154C (fi) * | 1994-11-15 | 1996-10-25 | Outokumpu Eng Contract | Menetelmä nikkelikuparikiven liuottamiseksi |
| US6444363B1 (en) * | 1998-08-17 | 2002-09-03 | Ovonic Battery Company, Inc. | Method of making a nickel hydroxide material |
| US6432580B1 (en) * | 1998-08-17 | 2002-08-13 | Ovonic Battery Company, Inc. | Method of making a nickel hydroxide material |
| KR100345743B1 (ko) * | 1999-12-22 | 2002-07-27 | 주식회사 포스코 | 고순도의 황산니켈 결정 제조방법 |
| JP2002050355A (ja) * | 2000-05-23 | 2002-02-15 | Sumitomo Metal Mining Co Ltd | アルカリ二次電池用被覆水酸化ニッケル粉末とその製造方法及び評価方法 |
-
2003
- 2003-12-04 US US10/727,413 patent/US7364717B2/en not_active Expired - Fee Related
-
2004
- 2004-11-23 WO PCT/US2004/039799 patent/WO2005060523A2/en not_active Ceased
- 2004-11-23 CN CNB2004800360001A patent/CN100457638C/zh not_active Expired - Lifetime
- 2004-11-23 EP EP04812338.4A patent/EP1689682B1/en not_active Expired - Lifetime
- 2004-11-23 BR BRPI0417163-2A patent/BRPI0417163A/pt not_active Application Discontinuation
- 2004-11-23 MX MXPA06006223 patent/MX284392B/es active IP Right Grant
- 2004-11-23 KR KR1020067010165A patent/KR20060129199A/ko not_active Ceased
- 2004-11-23 JP JP2006542638A patent/JP4996923B2/ja not_active Expired - Lifetime
- 2004-11-23 CA CA2546499A patent/CA2546499C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US7364717B2 (en) | 2008-04-29 |
| MXPA06006223A (es) | 2006-08-29 |
| MX284392B (es) | 2011-03-04 |
| JP4996923B2 (ja) | 2012-08-08 |
| CN100457638C (zh) | 2009-02-04 |
| KR20060129199A (ko) | 2006-12-15 |
| EP1689682A4 (en) | 2011-07-20 |
| JP2007513049A (ja) | 2007-05-24 |
| BRPI0417163A (pt) | 2007-03-06 |
| WO2005060523A3 (en) | 2006-01-05 |
| EP1689682B1 (en) | 2013-07-31 |
| WO2005060523A2 (en) | 2005-07-07 |
| CA2546499A1 (en) | 2005-07-07 |
| CN1890183A (zh) | 2007-01-03 |
| US20050123469A1 (en) | 2005-06-09 |
| EP1689682A2 (en) | 2006-08-16 |
| WO2005060523A8 (en) | 2007-01-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20191125 |