CA2522107C - Cathode active material comprising additive for improving overdischarge-performance and lithium secondary battery using the same - Google Patents

Cathode active material comprising additive for improving overdischarge-performance and lithium secondary battery using the same Download PDF

Info

Publication number
CA2522107C
CA2522107C CA2522107A CA2522107A CA2522107C CA 2522107 C CA2522107 C CA 2522107C CA 2522107 A CA2522107 A CA 2522107A CA 2522107 A CA2522107 A CA 2522107A CA 2522107 C CA2522107 C CA 2522107C
Authority
CA
Canada
Prior art keywords
lithium
transition metal
active material
cathode active
manganese oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA2522107A
Other languages
English (en)
French (fr)
Other versions
CA2522107A1 (en
Inventor
Jae-Hyun Lee
Min-Chul Jang
Duk-Hyun Ryu
Jun-Yong Jeong
Han-Ho Lee
Soon-Ho Ahn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Energy Solution Ltd
Original Assignee
LG Chem Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Publication of CA2522107A1 publication Critical patent/CA2522107A1/en
Application granted granted Critical
Publication of CA2522107C publication Critical patent/CA2522107C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/044—Activating, forming or electrochemical attack of the supporting material
    • H01M4/0445—Forming after manufacture of the electrode, e.g. first charge, cycling
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0028—Organic electrolyte characterised by the solvent
    • H01M2300/0037—Mixture of solvents
    • H01M2300/004—Three solvents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
CA2522107A 2003-04-09 2004-04-06 Cathode active material comprising additive for improving overdischarge-performance and lithium secondary battery using the same Expired - Lifetime CA2522107C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR10-2003-0022429A KR100533095B1 (ko) 2003-04-09 2003-04-09 과방전 방지제를 포함하는 양극 활물질 및 이를 이용한리튬 이차 전지
KR10-2003-0022429 2003-04-09
PCT/KR2004/000786 WO2004091016A1 (en) 2003-04-09 2004-04-06 Cathode active material comprising additive for improving overdischarge-performance and lithium secondary battery using the same

Publications (2)

Publication Number Publication Date
CA2522107A1 CA2522107A1 (en) 2004-10-21
CA2522107C true CA2522107C (en) 2013-04-02

Family

ID=36241085

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2522107A Expired - Lifetime CA2522107C (en) 2003-04-09 2004-04-06 Cathode active material comprising additive for improving overdischarge-performance and lithium secondary battery using the same

Country Status (10)

Country Link
US (1) US20070015055A1 (enExample)
EP (1) EP1609201A4 (enExample)
JP (1) JP2006512747A (enExample)
KR (1) KR100533095B1 (enExample)
CN (1) CN1771618A (enExample)
BR (1) BRPI0409759B8 (enExample)
CA (1) CA2522107C (enExample)
RU (1) RU2307431C2 (enExample)
TW (1) TWI269472B (enExample)
WO (1) WO2004091016A1 (enExample)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100612089B1 (ko) * 2003-09-26 2006-08-11 주식회사 엘지화학 과방전 시 양극 종료전압을 조절하는 방법 및 리튬 이차전지용 양극활물질
KR101150069B1 (ko) * 2004-12-13 2012-06-01 파나소닉 주식회사 활물질층과 고체 전해질층을 포함하는 적층체 및 이것을이용한 전고체 리튬 2차전지
WO2006108302A1 (en) * 2005-04-15 2006-10-19 Avestor Limited Partnership LITHIUM RECHARGEABLE CELL HAVING AN EXCESS OF LiFePO4 BASED CATHODE RELATIVE TO A Li4Ti5O12 BASED ANODE
KR20060111393A (ko) * 2005-04-22 2006-10-27 주식회사 엘지화학 대용량 비가역 물질을 포함하는 새로운 시스템의 리튬 이온전지
US7923150B2 (en) 2005-08-26 2011-04-12 Panasonic Corporation Non-aqueous electrolyte secondary battery
JP5016814B2 (ja) * 2005-12-14 2012-09-05 株式会社日立製作所 非水系二次電池
US7494744B2 (en) * 2006-03-08 2009-02-24 Changs-Ascending Enterprise Co. Cathode material for Li-ion battery applications
EP2171791A4 (en) * 2007-07-12 2014-09-10 A123 Systems Inc MULTIFUNCTIONAL MIXED METAL OLIVES FOR LITHIUM ION BATTERIES
KR100927244B1 (ko) * 2007-10-13 2009-11-16 주식회사 엘지화학 리튬 이차전지용 양극 활물질
KR100889622B1 (ko) * 2007-10-29 2009-03-20 대정이엠(주) 안전성이 우수한 리튬 이차전지용 양극 활물질 및 그제조방법과 이를 포함하는 리튬 이차전지
TWI466370B (zh) 2008-01-17 2014-12-21 A123 Systems Inc 鋰離子電池的混合式金屬橄欖石電極材料
CN102625959B (zh) 2009-08-25 2015-09-09 A123系统有限责任公司 用于锂离子电池的具有改良的比容量和能量密度的混合金属橄榄石电极材料
US9660267B2 (en) 2009-09-18 2017-05-23 A123 Systems, LLC High power electrode materials
WO2011035235A1 (en) * 2009-09-18 2011-03-24 A123 Systems, Inc. Ferric phosphate and methods of preparation thereof
US10305104B2 (en) 2010-04-02 2019-05-28 A123 Systems, LLC Li-ion battery cathode materials with over-discharge protection
RU2444815C1 (ru) * 2010-08-27 2012-03-10 Учреждение Российской академии наук Институт химии твердого тела и механохимии Сибирского отделения РАН (ИХТТМ СО РАН) СПОСОБ ПОЛУЧЕНИЯ ВЫСОКОДИСПЕРСНЫХ КАТОДНЫХ МАТЕРИАЛОВ LixFeyMzPO4/C СО СТРУКТУРОЙ ОЛИВИНА
RU2457585C1 (ru) * 2011-05-05 2012-07-27 Государственное образовательное учреждение высшего профессионального образования Саратовский государственный технический университет (ГОУ ВПО СГТУ) Катодный материал для литиевого источника тока
JP5970978B2 (ja) * 2011-07-04 2016-08-17 日産自動車株式会社 電気デバイス用正極活物質、電気デバイス用正極及び電気デバイス
RU2538605C2 (ru) * 2011-08-03 2015-01-10 Российская Федерация,от имени которой выступает Министерство образования и науки Российской Федерации Способ получения нитевидных кристаллов активного материала положительного электрода литий-воздушного аккумулятора
US9991566B2 (en) * 2011-11-03 2018-06-05 Johnson Controls Technology Company Cathode active material for overcharge protection in secondary lithium batteries
CN104067435B (zh) * 2012-01-20 2016-09-28 丰田自动车株式会社 非水电解质二次电池的制造方法和非水电解质二次电池
JP6156713B2 (ja) 2012-03-07 2017-07-05 日産自動車株式会社 正極活物質、電気デバイス用正極及び電気デバイス
JP6112380B2 (ja) 2012-03-07 2017-04-12 日産自動車株式会社 正極活物質、電気デバイス用正極及び電気デバイス
JP5999307B2 (ja) * 2012-03-07 2016-09-28 日産自動車株式会社 正極活物質、電気デバイス用正極及び電気デバイス
JP6085994B2 (ja) * 2012-04-27 2017-03-01 日産自動車株式会社 非水電解質二次電池の製造方法
CN102779998A (zh) * 2012-07-19 2012-11-14 东莞新能源科技有限公司 一种防止过放电的锂离子单体电池
EP2882029A4 (en) 2012-08-02 2015-07-29 Nissan Motor Nonaqueous organic electrolyte secondary cell
WO2015126932A1 (en) * 2014-02-18 2015-08-27 Brookhaven Science Associates, Llc Multifunctional cathode additives for battery technologies
US20160062984A1 (en) * 2014-09-03 2016-03-03 Lenovo (Singapore) Pte. Ltd. Devices and methods for determining a recipient for a message
JP6169246B2 (ja) * 2015-02-16 2017-07-26 株式会社東芝 非水電解質電池及び電池パック
CN105206868A (zh) * 2015-10-23 2015-12-30 东莞市致格电池科技有限公司 一种内燃机启动用锂离子二次电池
KR102268176B1 (ko) * 2017-08-28 2021-06-22 주식회사 엘지에너지솔루션 리튬 이차전지
HUE062067T2 (hu) 2017-11-17 2023-09-28 Lg Energy Solution Ltd Eljárás egy lítium szekunder akkumulátorhoz alkalmas katód anyagba foglalt irreverzibilis adalékanyag elõállítására, az azzal elõállított irreverzibilis adalékanyagot magába foglaló katód anyag, és a katód anyagot tartalmazó lítium szekunder akkumulátor
JP6988502B2 (ja) * 2018-01-17 2022-01-05 トヨタ自動車株式会社 全固体電池用正極合剤、全固体電池用正極、全固体電池及びこれらの製造方法
KR102791146B1 (ko) * 2018-06-21 2025-04-04 주식회사 엘지에너지솔루션 리튬 이차전지
RU2702785C1 (ru) * 2018-08-29 2019-10-14 Автономная некоммерческая образовательная организация высшего образования "Сколковский институт науки и технологий" Защитное шпинельное покрытие для ni-mn-co (nmc) катода с повышенным содержанием li для литий-ионных аккумуляторов, способ нанесения указанного покрытия на катод и катод с указанным покрытием
EP3985762B1 (en) * 2020-01-31 2023-08-09 LG Energy Solution, Ltd. Irreversible additive included in cathode material for secondary battery, cathode material comprising same, and secondary battery comprising cathode material
JP7365565B2 (ja) * 2020-03-18 2023-10-20 トヨタ自動車株式会社 正極活物質および該正極活物質を備える二次電池
JP2024536612A (ja) * 2021-10-25 2024-10-04 寧徳新能源科技有限公司 正極片及びそれを含むリチウムイオン二次電池
EP4421897A4 (en) 2021-10-25 2025-03-05 NingDe Amperex Technology Limited ELECTROCHEMICAL DEVICE AND ELECTRONIC DEVICE THEREOF
WO2023070287A1 (zh) * 2021-10-25 2023-05-04 宁德新能源科技有限公司 正极极片、电化学装置及电子装置
CN115602817B (zh) * 2022-11-01 2025-09-23 国联汽车动力电池研究院有限责任公司 补锂型复合正极材料及其制备方法和补锂方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2107360C1 (ru) * 1993-03-04 1998-03-20 Асахи Касеи Когио Кабусики Кайся Аккумуляторная батарея
US5609975A (en) * 1994-05-13 1997-03-11 Matsushita Electric Industrial Co., Ltd. Positive electrode for non-aqueous electrolyte lithium secondary battery and method of manufacturing the same
DE69631900T2 (de) * 1995-12-27 2004-08-05 Motorola, Inc., Schaumburg Elektrodenmaterial für elektrochemische lithiumeinlagerung
US5753202A (en) * 1996-04-08 1998-05-19 Duracell Inc. Method of preparation of lithium manganese oxide spinel
JP2974213B1 (ja) * 1998-11-13 1999-11-10 宇部興産株式会社 リチウム二次電池用正極活物質とその製造方法及びその用途
KR100326457B1 (ko) * 1999-03-10 2002-02-28 김순택 리튬 이차 전지용 양극 활물질 및 그 제조 방법
JP2001235312A (ja) * 2000-02-25 2001-08-31 Hitachi Koki Co Ltd 電子写真印刷装置の用紙厚検出方法
JP2001339774A (ja) * 2000-05-30 2001-12-07 Sony Corp 電子機器
JP4375642B2 (ja) * 2000-08-30 2009-12-02 東邦チタニウム株式会社 マンガン酸リチウムの製造方法、マンガン酸リチウム、これを正極活物質とするリチウムイオン二次電池用正極、及びリチウムイオン二次電池
JP4082855B2 (ja) * 2000-09-25 2008-04-30 Ａｇｃセイミケミカル株式会社 リチウム二次電池

Also Published As

Publication number Publication date
WO2004091016A1 (en) 2004-10-21
KR20040088292A (ko) 2004-10-16
TW200501472A (en) 2005-01-01
CN1771618A (zh) 2006-05-10
JP2006512747A (ja) 2006-04-13
CA2522107A1 (en) 2004-10-21
EP1609201A4 (en) 2009-11-11
EP1609201A1 (en) 2005-12-28
RU2005134662A (ru) 2006-04-10
BRPI0409759B8 (pt) 2023-01-17
KR100533095B1 (ko) 2005-12-01
BRPI0409759A (pt) 2006-05-09
US20070015055A1 (en) 2007-01-18
TWI269472B (en) 2006-12-21
RU2307431C2 (ru) 2007-09-27
BRPI0409759B1 (pt) 2015-12-29

Similar Documents

Publication Publication Date Title
CA2522107C (en) Cathode active material comprising additive for improving overdischarge-performance and lithium secondary battery using the same
EP2270901B1 (en) Method for regulating terminal voltage of cathode during overdischarge and cathode active matrial for lithium secondary battery
US9236610B2 (en) Cathode active material for lithium secondary battery
US9786904B2 (en) Positive electrode for lithium secondary battery and lithium secondary battery having the same
JP4101435B2 (ja) リチウム二次電池用正極活物質組成物及びそれを用いた正極の製造方法
JP5232631B2 (ja) 非水電解質電池
US7695867B2 (en) Method for regulating terminal voltage of cathode during overdischarge and cathode active material for lithium secondary battery
JP2005521220A (ja) 過放電防止剤を含むリチウム二次電池
KR20190098074A (ko) 리튬 이차전지용 비수전해액 및 이를 포함하는 리튬 이차전지
JP2007200865A (ja) 非水電解質二次電池
JPH07235291A (ja) 二次電池
JP2001243943A (ja) 非水電解液二次電池
KR20160091864A (ko) 비수 전해질 이차 전지
US20240322260A1 (en) Secondary battery and electrical apparatus containing the same
KR20030076153A (ko) 과방전 방지제를 포함하는 리튬 이차 전지
KR20070117826A (ko) 리튬 이차 전지용 양극, 및 그를 포함하는 리튬 이차 전지
KR20000071371A (ko) 비수성 전해질 전지
JPH11111291A (ja) 非水二次電池用正極材料及びこれを用いた電池
KR100624970B1 (ko) 리튬 이차 전지용 양극 활물질, 그 제조 방법 및 리튬이차 전지
JPH0541251A (ja) 非水電解質二次電池
KR100312689B1 (ko) 리튬 이차 전지용 양극 활물질 조성물 및 그를 포함하는 리튬이차 전지
JP2002110155A (ja) 非水電解液二次電池
KR100434547B1 (ko) 리튬양극및이를채용하는리튬2차전지
KR100424638B1 (ko) 리튬 이차전지용 양극 활물질 및 그의 제조방법
KR19990085713A (ko) 리튬 이온 이차 전지용 극판

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20240408