CA2477428A1 - Compositions de tamis moleculaire, catalyseur obtenu a partir de celles-ci, leur production et leur utilisation dans des procedes de conversion - Google Patents
Compositions de tamis moleculaire, catalyseur obtenu a partir de celles-ci, leur production et leur utilisation dans des procedes de conversion Download PDFInfo
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- CA2477428A1 CA2477428A1 CA002477428A CA2477428A CA2477428A1 CA 2477428 A1 CA2477428 A1 CA 2477428A1 CA 002477428 A CA002477428 A CA 002477428A CA 2477428 A CA2477428 A CA 2477428A CA 2477428 A1 CA2477428 A1 CA 2477428A1
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- Prior art keywords
- oxide
- catalyst composition
- metal oxide
- molecular sieve
- elements
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- 239000000203 mixture Substances 0.000 title claims abstract 18
- 239000003054 catalyst Substances 0.000 title claims abstract 17
- 239000002808 molecular sieve Substances 0.000 title claims abstract 13
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract 13
- 238000000034 method Methods 0.000 title claims 11
- 238000006243 chemical reaction Methods 0.000 title abstract 2
- 229910052768 actinide Inorganic materials 0.000 claims abstract 5
- 150000001255 actinides Chemical class 0.000 claims abstract 5
- 229910052747 lanthanoid Inorganic materials 0.000 claims abstract 5
- 150000002602 lanthanoids Chemical class 0.000 claims abstract 5
- 229910052751 metal Inorganic materials 0.000 claims abstract 5
- 239000002184 metal Substances 0.000 claims abstract 5
- 230000000737 periodic effect Effects 0.000 claims abstract 4
- 150000001336 alkenes Chemical class 0.000 claims abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910044991 metal oxide Inorganic materials 0.000 claims 16
- 150000004706 metal oxides Chemical class 0.000 claims 16
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 10
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 5
- 239000001569 carbon dioxide Substances 0.000 claims 5
- 239000002245 particle Substances 0.000 claims 5
- 239000011230 binding agent Substances 0.000 claims 4
- 239000011159 matrix material Substances 0.000 claims 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- 239000002243 precursor Substances 0.000 claims 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 239000004927 clay Substances 0.000 claims 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical group [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims 2
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims 2
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims 2
- 238000001354 calcination Methods 0.000 claims 1
- 229910000420 cerium oxide Inorganic materials 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims 1
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 claims 1
- 229910003447 praseodymium oxide Inorganic materials 0.000 claims 1
- 229910001954 samarium oxide Inorganic materials 0.000 claims 1
- 229940075630 samarium oxide Drugs 0.000 claims 1
- FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 claims 1
- HYXGAEYDKFCVMU-UHFFFAOYSA-N scandium oxide Chemical compound O=[Sc]O[Sc]=O HYXGAEYDKFCVMU-UHFFFAOYSA-N 0.000 claims 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 claims 1
- 229910003452 thorium oxide Inorganic materials 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
L'nvention concerne une composition catalytique, un procédé de préparation de celle-ci et son utilisation dans la conversion d'une charge, de préférence une charge oxygénée, en une ou plusieurs oléfine(s), de préférence de l'éthylène et/ou du propylène. Cette composition catalytique comprend un tamis moléculaire et au moins un oxyde d'un métal choisi dans le Groupe 3 du tableau périodique des éléments, à savoir les lanthanides et les actinides.
Applications Claiming Priority (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36096302P | 2002-02-28 | 2002-02-28 | |
US60/360,963 | 2002-02-28 | ||
US36601202P | 2002-03-20 | 2002-03-20 | |
US60/366,012 | 2002-03-20 | ||
US37469702P | 2002-04-22 | 2002-04-22 | |
US60/374,697 | 2002-04-22 | ||
US10/215,511 US6906232B2 (en) | 2002-08-09 | 2002-08-09 | Molecular sieve compositions, catalysts thereof, their making and use in conversion processes |
US10/215,511 | 2002-08-09 | ||
PCT/US2003/004169 WO2003074177A2 (fr) | 2002-02-28 | 2003-02-10 | Compositions de tamis moleculaires, catalyseur de celles-ci, leur preparation et utilisation dans des procedes de conversion |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2477428A1 true CA2477428A1 (fr) | 2003-09-12 |
CA2477428C CA2477428C (fr) | 2011-03-22 |
Family
ID=27792286
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2477428A Expired - Fee Related CA2477428C (fr) | 2002-02-28 | 2003-02-10 | Compositions de tamis moleculaire, catalyseur obtenu a partir de celles-ci, leur production et leur utilisation dans des procedes de conversion |
CA002477432A Abandoned CA2477432A1 (fr) | 2002-02-28 | 2003-02-10 | Compositions de tamis moleculaire, catalyseur de ces compositions, leur fabrication et leur utilisation dans des procedes de conversion |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002477432A Abandoned CA2477432A1 (fr) | 2002-02-28 | 2003-02-10 | Compositions de tamis moleculaire, catalyseur de ces compositions, leur fabrication et leur utilisation dans des procedes de conversion |
Country Status (11)
Country | Link |
---|---|
EP (3) | EP1478461A2 (fr) |
JP (3) | JP2005518928A (fr) |
KR (3) | KR20040089679A (fr) |
CN (3) | CN1298427C (fr) |
AU (3) | AU2003225560B2 (fr) |
BR (1) | BR0308011A (fr) |
CA (2) | CA2477428C (fr) |
EA (3) | EA007873B1 (fr) |
MY (2) | MY140018A (fr) |
TW (3) | TWI265824B (fr) |
WO (3) | WO2003074176A2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008098343A1 (fr) * | 2007-02-14 | 2008-08-21 | Nova Chemicals (International) S.A. | Craquage catalytique d'éthers en 1-oléfines |
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EA007873B1 (ru) * | 2002-02-28 | 2007-02-27 | Эксонмобил Кемикэл Пейтентс Инк. | Каталитические композиции, включающие молекулярные сита, их приготовление и применение в процессах превращения |
US7074739B2 (en) | 2002-11-19 | 2006-07-11 | Exxonmobil Chemical Patents Inc. | Multi-component molecular sieve catalyst compositions and their use in aromatics reactions |
US6951830B2 (en) | 2003-08-05 | 2005-10-04 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst compositions, their production and use in conversion processes |
US7404891B2 (en) * | 2004-03-29 | 2008-07-29 | Exxonmobil Chemical Patents Inc. | Heat recovery technique for catalyst regenerator flue gas |
US7166757B2 (en) * | 2004-07-30 | 2007-01-23 | Exxonmobil Chemical Patents Inc. | Conversion of oxygenates to olefins |
WO2007021394A2 (fr) * | 2005-08-18 | 2007-02-22 | Exxonmobil Chemical Patents Inc. | Conversion catalytique d'oxygenates en olefines |
CN101003018A (zh) * | 2006-01-20 | 2007-07-25 | 中国石油天然气股份有限公司 | 一种多相催化固体碱催化剂及其制备方法和应用 |
US7335621B2 (en) | 2006-04-19 | 2008-02-26 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and preparation thereof |
JP4710744B2 (ja) | 2006-07-18 | 2011-06-29 | トヨタ自動車株式会社 | 複合金属酸化物の製造方法 |
US7595275B2 (en) | 2006-08-15 | 2009-09-29 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and their synthesis |
CN101239866B (zh) * | 2007-02-07 | 2010-12-01 | 中国石油化工股份有限公司 | 含氧化合物生产乙烯、丙烯的方法 |
CN101239878B (zh) * | 2007-02-07 | 2010-05-19 | 中国石油化工股份有限公司 | 碳四及其以上烯烃增产乙烯、丙烯的方法 |
EP2022565A1 (fr) * | 2007-07-06 | 2009-02-11 | Casale Chemicals S.A. | Procédé pour la préparation de tamis moléculaires en silicoaluminoposphate (SAPO), catalyseurs contenant lesdits tamis et procédés de déshydratation catalytique utilisant lesdits catalyseurs |
EP2183203A1 (fr) * | 2007-08-13 | 2010-05-12 | Saudi Basic Industries Corporation | Procédé de conversion de composés oxygénés aliphatiques en produits aromatiques |
DE102007059129A1 (de) * | 2007-12-07 | 2009-06-10 | Süd-Chemie AG | Katalysator mit erhöhter Olefinselektivität zur Umsetzung von Oxygenaten zu Olefinen |
CA2719905A1 (fr) * | 2008-04-04 | 2009-10-08 | Petr Vasiliev | Structure secondaire de zeolite pour catalyseur zeolite |
JP5818133B2 (ja) * | 2011-05-20 | 2015-11-18 | 国立大学法人東京工業大学 | オレフィン製造用触媒及びオレフィンの製造方法 |
CN102344328B (zh) * | 2011-07-25 | 2014-03-12 | 浙江大学 | 一种使用移动床技术将甲醇转化为丙烯的半连续方法 |
WO2014061569A1 (fr) * | 2012-10-15 | 2014-04-24 | 三菱瓦斯化学株式会社 | Procédé de production d'un catalyseur pouvant être utilisé dans la production d'un composé de méthylamine, et procédé de production dudit composé de méthylamine |
EP2994229B1 (fr) * | 2013-05-07 | 2016-10-19 | Synthos S.A. | Procédé pour la production de 1,3-butadiène |
CN107661774B (zh) * | 2016-07-27 | 2020-11-03 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制低碳烯烃的方法 |
CN107661773B (zh) * | 2016-07-29 | 2020-08-04 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制液体燃料联产低碳烯烃的方法 |
CN108568311B (zh) * | 2017-03-07 | 2021-03-23 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制乙烯的方法 |
WO2018195865A1 (fr) * | 2017-04-27 | 2018-11-01 | 中国科学院大连化学物理研究所 | Procédé de préparation in-situ pour catalyseur pour la préparation de toluène, de p-xylène et/ou d'oléfine à faible teneur en carbone, et processus de réaction |
CN109939667B (zh) * | 2018-01-26 | 2021-01-05 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制低碳烯烃的方法 |
CN109939722B (zh) * | 2018-01-26 | 2021-05-25 | 中国科学院大连化学物理研究所 | 一种有机碱修饰的复合催化剂及一氧化碳加氢制乙烯的方法 |
EP3873878A4 (fr) * | 2018-10-30 | 2022-08-03 | ExxonMobil Chemical Patents Inc. | Teneur en ions métalliques du groupe 1 de catalyseurs à tamis moléculaire microporeux |
CN111346664B (zh) * | 2018-12-24 | 2022-11-15 | 中国石油化工股份有限公司 | 改性钒硅分子筛及其制备方法以及硫醚氧化方法 |
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US4465889A (en) * | 1982-07-02 | 1984-08-14 | Summit Gas Systems Pte. Ltd. | Catalytic conversion of methanol, dimethyl ether and mixtures thereof to a hydrocarbon product rich in iso-C4 compounds and new catalysts therefor |
US4781816A (en) | 1987-10-19 | 1988-11-01 | Phillips Petroleum Company | Cracking process |
US6040264A (en) * | 1996-04-04 | 2000-03-21 | Exxon Chemical Patents Inc. | Use of alkaline earth metal containing small pore non-zeolitic molecular sieve catalysts in oxygenate conversion |
TW412510B (en) | 1996-12-31 | 2000-11-21 | Exxon Chemical Patents Inc | Oxygenate conversions using small pore non-zeolitic molecular sieve catalysts |
US6423879B1 (en) * | 1997-10-02 | 2002-07-23 | Exxonmobil Oil Corporation | Selective para-xylene production by toluene methylation |
JP4221532B2 (ja) * | 1998-06-26 | 2009-02-12 | 三菱瓦斯化学株式会社 | メチルアミン製造用触媒及び該触媒を用いたメチルアミン類の製造方法 |
US6388156B1 (en) * | 1999-05-14 | 2002-05-14 | Exxonmobil Chemical Patents Inc. | Direct selective synthesis of para-xylene by reacting an aromatic compound with a methylating agent formed from CO, Co2 and H2 |
AU2001236984A1 (en) * | 2000-03-01 | 2001-09-12 | Exxonmobil Chemical Patents Inc | Thorium-containing sapo molecular sieve for producing olefins |
US6448197B1 (en) * | 2000-07-13 | 2002-09-10 | Exxonmobil Chemical Patents Inc. | Method for making a metal containing small pore molecular sieve catalyst |
AU2001275901A1 (en) * | 2000-07-13 | 2002-01-30 | Uop Llc | Attrition resistant catalyst for light olefin production |
CA2369318A1 (fr) * | 2002-01-28 | 2003-07-28 | Universite Concordia | Catalyseurs hybrides utilises pour le craquage catalytique avance d'essences lourdes et d'autres matieres premieres a base d'hydrocarbures dans la production selective d'olefines legeres |
EA007873B1 (ru) * | 2002-02-28 | 2007-02-27 | Эксонмобил Кемикэл Пейтентс Инк. | Каталитические композиции, включающие молекулярные сита, их приготовление и применение в процессах превращения |
-
2003
- 2003-02-10 EA EA200401102A patent/EA007873B1/ru not_active IP Right Cessation
- 2003-02-10 EP EP03709038A patent/EP1478461A2/fr not_active Withdrawn
- 2003-02-10 WO PCT/US2003/004153 patent/WO2003074176A2/fr active Application Filing
- 2003-02-10 AU AU2003225560A patent/AU2003225560B2/en not_active Ceased
- 2003-02-10 CA CA2477428A patent/CA2477428C/fr not_active Expired - Fee Related
- 2003-02-10 JP JP2003572679A patent/JP2005518928A/ja not_active Withdrawn
- 2003-02-10 KR KR10-2004-7013378A patent/KR20040089679A/ko not_active Application Discontinuation
- 2003-02-10 JP JP2003572681A patent/JP2005518930A/ja active Pending
- 2003-02-10 CN CNB038047616A patent/CN1298427C/zh not_active Expired - Fee Related
- 2003-02-10 EA EA200401101A patent/EA007872B1/ru not_active IP Right Cessation
- 2003-02-10 BR BR0308011-0A patent/BR0308011A/pt not_active IP Right Cessation
- 2003-02-10 WO PCT/US2003/003951 patent/WO2003074175A2/fr active Application Filing
- 2003-02-10 EP EP03743673A patent/EP1478464A2/fr not_active Withdrawn
- 2003-02-10 CN CNB038082659A patent/CN100335172C/zh not_active Expired - Fee Related
- 2003-02-10 AU AU2003216248A patent/AU2003216248B2/en not_active Ceased
- 2003-02-10 KR KR10-2004-7013384A patent/KR20040089680A/ko not_active Application Discontinuation
- 2003-02-10 EA EA200401061A patent/EA007871B1/ru not_active IP Right Cessation
- 2003-02-10 AU AU2003212993A patent/AU2003212993A1/en not_active Abandoned
- 2003-02-10 EP EP03743671A patent/EP1478462A2/fr not_active Withdrawn
- 2003-02-10 WO PCT/US2003/004169 patent/WO2003074177A2/fr active Application Filing
- 2003-02-10 CA CA002477432A patent/CA2477432A1/fr not_active Abandoned
- 2003-02-10 JP JP2003572680A patent/JP2005518929A/ja not_active Withdrawn
- 2003-02-10 CN CNB038068079A patent/CN1327964C/zh not_active Expired - Fee Related
- 2003-02-10 KR KR10-2004-7013377A patent/KR20040091080A/ko active IP Right Grant
- 2003-02-14 TW TW092103148A patent/TWI265824B/zh not_active IP Right Cessation
- 2003-02-14 TW TW092103154A patent/TWI265825B/zh not_active IP Right Cessation
- 2003-02-14 TW TW092103144A patent/TWI306780B/zh not_active IP Right Cessation
- 2003-02-21 MY MYPI20030609A patent/MY140018A/en unknown
- 2003-02-21 MY MYPI20030610A patent/MY139847A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008098343A1 (fr) * | 2007-02-14 | 2008-08-21 | Nova Chemicals (International) S.A. | Craquage catalytique d'éthers en 1-oléfines |
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