JP2005518928A - 分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 - Google Patents
分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 Download PDFInfo
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- JP2005518928A JP2005518928A JP2003572679A JP2003572679A JP2005518928A JP 2005518928 A JP2005518928 A JP 2005518928A JP 2003572679 A JP2003572679 A JP 2003572679A JP 2003572679 A JP2003572679 A JP 2003572679A JP 2005518928 A JP2005518928 A JP 2005518928A
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- Prior art keywords
- metal oxide
- catalyst composition
- molecular sieve
- acetone
- oxide
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 121
- 239000002808 molecular sieve Substances 0.000 title claims abstract description 117
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 239000003054 catalyst Substances 0.000 title claims abstract description 109
- 238000000034 method Methods 0.000 title claims abstract description 78
- 230000008569 process Effects 0.000 title claims abstract description 36
- 238000006243 chemical reaction Methods 0.000 title abstract description 33
- 238000004519 manufacturing process Methods 0.000 title description 8
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 116
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 113
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 86
- 150000001336 alkenes Chemical class 0.000 claims abstract description 50
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 40
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 40
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 96
- 239000011230 binding agent Substances 0.000 claims description 42
- 239000011159 matrix material Substances 0.000 claims description 40
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 34
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 19
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 17
- 239000001569 carbon dioxide Substances 0.000 claims description 17
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 16
- 239000004927 clay Substances 0.000 claims description 12
- 230000000737 periodic effect Effects 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 6
- 239000011148 porous material Substances 0.000 claims description 6
- 239000012018 catalyst precursor Substances 0.000 claims description 5
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical group O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 4
- HYXGAEYDKFCVMU-UHFFFAOYSA-N scandium oxide Chemical compound O=[Sc]O[Sc]=O HYXGAEYDKFCVMU-UHFFFAOYSA-N 0.000 claims description 3
- 238000013329 compounding Methods 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 14
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract description 14
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 14
- -1 magnesium oxide Chemical class 0.000 abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
- 229930195733 hydrocarbon Natural products 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
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- 239000012702 metal oxide precursor Substances 0.000 description 11
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
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- 238000001354 calcination Methods 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 239000010457 zeolite Substances 0.000 description 8
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- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 235000012211 aluminium silicate Nutrition 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 6
- 239000001307 helium Substances 0.000 description 6
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- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 6
- 239000008240 homogeneous mixture Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 239000005995 Aluminium silicate Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 229910052809 inorganic oxide Inorganic materials 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000011068 loading method Methods 0.000 description 5
- 239000010453 quartz Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 4
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- 229910004283 SiO 4 Inorganic materials 0.000 description 4
- CSCPPACGZOOCGX-LBPDFUHNSA-N acetone-2-13c Chemical compound C[13C](C)=O CSCPPACGZOOCGX-LBPDFUHNSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 241000894007 species Species 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
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- 238000000975 co-precipitation Methods 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910052746 lanthanum Inorganic materials 0.000 description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
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- 238000002360 preparation method Methods 0.000 description 3
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- 238000004922 13C solid-state nuclear magnetic resonance spectroscopy Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LTPBRCUWZOMYOC-UHFFFAOYSA-N Beryllium oxide Chemical compound O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 2
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- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
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- 229940094800 barium oxalate Drugs 0.000 description 1
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- 210000000988 bone and bone Anatomy 0.000 description 1
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Classifications
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/83—Aluminophosphates (APO compounds)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
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US36096302P | 2002-02-28 | 2002-02-28 | |
US36601202P | 2002-03-20 | 2002-03-20 | |
US37469702P | 2002-04-22 | 2002-04-22 | |
US10/215,511 US6906232B2 (en) | 2002-08-09 | 2002-08-09 | Molecular sieve compositions, catalysts thereof, their making and use in conversion processes |
PCT/US2003/003951 WO2003074175A2 (fr) | 2002-02-28 | 2003-02-10 | Compostions de tamis moleculaires, catalyseur associe et fabrication et utilisation dans des procedes de conversion |
Publications (2)
Publication Number | Publication Date |
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JP2005518928A true JP2005518928A (ja) | 2005-06-30 |
JP2005518928A5 JP2005518928A5 (fr) | 2006-03-30 |
Family
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Application Number | Title | Priority Date | Filing Date |
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JP2003572680A Withdrawn JP2005518929A (ja) | 2002-02-28 | 2003-02-10 | 分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 |
JP2003572681A Pending JP2005518930A (ja) | 2002-02-28 | 2003-02-10 | 分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 |
JP2003572679A Withdrawn JP2005518928A (ja) | 2002-02-28 | 2003-02-10 | 分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
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JP2003572680A Withdrawn JP2005518929A (ja) | 2002-02-28 | 2003-02-10 | 分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 |
JP2003572681A Pending JP2005518930A (ja) | 2002-02-28 | 2003-02-10 | 分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 |
Country Status (11)
Country | Link |
---|---|
EP (3) | EP1478464A2 (fr) |
JP (3) | JP2005518929A (fr) |
KR (3) | KR20040089680A (fr) |
CN (3) | CN100335172C (fr) |
AU (3) | AU2003225560B2 (fr) |
BR (1) | BR0308011A (fr) |
CA (2) | CA2477432A1 (fr) |
EA (3) | EA007871B1 (fr) |
MY (2) | MY140018A (fr) |
TW (3) | TWI265824B (fr) |
WO (3) | WO2003074177A2 (fr) |
Families Citing this family (29)
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KR20040089680A (ko) * | 2002-02-28 | 2004-10-21 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 분자 체를 포함하는 촉매 조성물, 이들의 제조 방법 및전환 공정에서의 이들의 용도 |
US7074739B2 (en) | 2002-11-19 | 2006-07-11 | Exxonmobil Chemical Patents Inc. | Multi-component molecular sieve catalyst compositions and their use in aromatics reactions |
US6951830B2 (en) | 2003-08-05 | 2005-10-04 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst compositions, their production and use in conversion processes |
US7404891B2 (en) * | 2004-03-29 | 2008-07-29 | Exxonmobil Chemical Patents Inc. | Heat recovery technique for catalyst regenerator flue gas |
US7166757B2 (en) * | 2004-07-30 | 2007-01-23 | Exxonmobil Chemical Patents Inc. | Conversion of oxygenates to olefins |
WO2007021394A2 (fr) * | 2005-08-18 | 2007-02-22 | Exxonmobil Chemical Patents Inc. | Conversion catalytique d'oxygenates en olefines |
CN101003018A (zh) * | 2006-01-20 | 2007-07-25 | 中国石油天然气股份有限公司 | 一种多相催化固体碱催化剂及其制备方法和应用 |
US7335621B2 (en) | 2006-04-19 | 2008-02-26 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and preparation thereof |
JP4710744B2 (ja) * | 2006-07-18 | 2011-06-29 | トヨタ自動車株式会社 | 複合金属酸化物の製造方法 |
US7595275B2 (en) | 2006-08-15 | 2009-09-29 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and their synthesis |
CN101239878B (zh) * | 2007-02-07 | 2010-05-19 | 中国石油化工股份有限公司 | 碳四及其以上烯烃增产乙烯、丙烯的方法 |
CN101239866B (zh) * | 2007-02-07 | 2010-12-01 | 中国石油化工股份有限公司 | 含氧化合物生产乙烯、丙烯的方法 |
CA2578494A1 (fr) * | 2007-02-14 | 2008-08-14 | Nova Chemicals Corporation | Craquage catalytique d'ethers en 1-olefines |
EP2022565A1 (fr) * | 2007-07-06 | 2009-02-11 | Casale Chemicals S.A. | Procédé pour la préparation de tamis moléculaires en silicoaluminoposphate (SAPO), catalyseurs contenant lesdits tamis et procédés de déshydratation catalytique utilisant lesdits catalyseurs |
JP5543347B2 (ja) * | 2007-08-13 | 2014-07-09 | サウディ ベーシック インダストリーズ コーポレイション | 脂肪族燃料促進物質を芳香族化合物に転化するプロセス |
DE102007059129A1 (de) * | 2007-12-07 | 2009-06-10 | Süd-Chemie AG | Katalysator mit erhöhter Olefinselektivität zur Umsetzung von Oxygenaten zu Olefinen |
WO2009123556A1 (fr) * | 2008-04-04 | 2009-10-08 | Petr Vasiliev | Structure secondaire de zéolite pour catalyseur zéolite |
JP5818133B2 (ja) * | 2011-05-20 | 2015-11-18 | 国立大学法人東京工業大学 | オレフィン製造用触媒及びオレフィンの製造方法 |
CN102344328B (zh) * | 2011-07-25 | 2014-03-12 | 浙江大学 | 一种使用移动床技术将甲醇转化为丙烯的半连续方法 |
WO2014061569A1 (fr) * | 2012-10-15 | 2014-04-24 | 三菱瓦斯化学株式会社 | Procédé de production d'un catalyseur pouvant être utilisé dans la production d'un composé de méthylamine, et procédé de production dudit composé de méthylamine |
KR101803051B1 (ko) * | 2013-05-07 | 2017-11-29 | 신도스 에스.에이. | 1,3-부타디엔의 제조방법 |
CN107661774B (zh) * | 2016-07-27 | 2020-11-03 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制低碳烯烃的方法 |
CN107661773B (zh) * | 2016-07-29 | 2020-08-04 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制液体燃料联产低碳烯烃的方法 |
CN108568311B (zh) * | 2017-03-07 | 2021-03-23 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制乙烯的方法 |
KR102326358B1 (ko) * | 2017-04-27 | 2021-11-12 | 달리안 인스티튜트 오브 케미컬 피직스, 차이니즈 아카데미 오브 사이언시즈 | 톨루엔, p-크실렌 및 경질 올레핀 중 적어도 하나를 제조하기 위한 촉매의 원위치 제조 방법 및 반응 공정 |
CN109939722B (zh) * | 2018-01-26 | 2021-05-25 | 中国科学院大连化学物理研究所 | 一种有机碱修饰的复合催化剂及一氧化碳加氢制乙烯的方法 |
CN109939667B (zh) * | 2018-01-26 | 2021-01-05 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制低碳烯烃的方法 |
WO2020091969A1 (fr) * | 2018-10-30 | 2020-05-07 | Exxonmobil Chemical Patents Inc. | Teneur en ions métalliques du groupe 1 de catalyseurs à tamis moléculaire microporeux |
CN111346664B (zh) * | 2018-12-24 | 2022-11-15 | 中国石油化工股份有限公司 | 改性钒硅分子筛及其制备方法以及硫醚氧化方法 |
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US4465889A (en) * | 1982-07-02 | 1984-08-14 | Summit Gas Systems Pte. Ltd. | Catalytic conversion of methanol, dimethyl ether and mixtures thereof to a hydrocarbon product rich in iso-C4 compounds and new catalysts therefor |
US4781816A (en) | 1987-10-19 | 1988-11-01 | Phillips Petroleum Company | Cracking process |
US6040264A (en) * | 1996-04-04 | 2000-03-21 | Exxon Chemical Patents Inc. | Use of alkaline earth metal containing small pore non-zeolitic molecular sieve catalysts in oxygenate conversion |
TW412510B (en) * | 1996-12-31 | 2000-11-21 | Exxon Chemical Patents Inc | Oxygenate conversions using small pore non-zeolitic molecular sieve catalysts |
US6423879B1 (en) * | 1997-10-02 | 2002-07-23 | Exxonmobil Oil Corporation | Selective para-xylene production by toluene methylation |
JP4221532B2 (ja) * | 1998-06-26 | 2009-02-12 | 三菱瓦斯化学株式会社 | メチルアミン製造用触媒及び該触媒を用いたメチルアミン類の製造方法 |
US6388156B1 (en) * | 1999-05-14 | 2002-05-14 | Exxonmobil Chemical Patents Inc. | Direct selective synthesis of para-xylene by reacting an aromatic compound with a methylating agent formed from CO, Co2 and H2 |
WO2001064340A1 (fr) * | 2000-03-01 | 2001-09-07 | Exxonmobil Chemical Patents Inc. | Tamis moleculaire de silico-aluminophosphates contenant du thorium destine a la production d'olefines |
US6448197B1 (en) * | 2000-07-13 | 2002-09-10 | Exxonmobil Chemical Patents Inc. | Method for making a metal containing small pore molecular sieve catalyst |
WO2002005952A2 (fr) * | 2000-07-13 | 2002-01-24 | Uop Llc | Catalyseur resistant a l'attrition pour production d'olefines legeres |
CA2369318A1 (fr) * | 2002-01-28 | 2003-07-28 | Universite Concordia | Catalyseurs hybrides utilises pour le craquage catalytique avance d'essences lourdes et d'autres matieres premieres a base d'hydrocarbures dans la production selective d'olefines legeres |
KR20040089680A (ko) * | 2002-02-28 | 2004-10-21 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 분자 체를 포함하는 촉매 조성물, 이들의 제조 방법 및전환 공정에서의 이들의 용도 |
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2003
- 2003-02-10 KR KR10-2004-7013384A patent/KR20040089680A/ko not_active Application Discontinuation
- 2003-02-10 JP JP2003572680A patent/JP2005518929A/ja not_active Withdrawn
- 2003-02-10 BR BR0308011-0A patent/BR0308011A/pt not_active IP Right Cessation
- 2003-02-10 WO PCT/US2003/004169 patent/WO2003074177A2/fr active Application Filing
- 2003-02-10 EP EP03743673A patent/EP1478464A2/fr not_active Withdrawn
- 2003-02-10 WO PCT/US2003/004153 patent/WO2003074176A2/fr active Application Filing
- 2003-02-10 KR KR10-2004-7013378A patent/KR20040089679A/ko not_active Application Discontinuation
- 2003-02-10 CA CA002477432A patent/CA2477432A1/fr not_active Abandoned
- 2003-02-10 CN CNB038082659A patent/CN100335172C/zh not_active Expired - Fee Related
- 2003-02-10 JP JP2003572681A patent/JP2005518930A/ja active Pending
- 2003-02-10 EA EA200401061A patent/EA007871B1/ru not_active IP Right Cessation
- 2003-02-10 EP EP03709038A patent/EP1478461A2/fr not_active Withdrawn
- 2003-02-10 WO PCT/US2003/003951 patent/WO2003074175A2/fr active Application Filing
- 2003-02-10 AU AU2003225560A patent/AU2003225560B2/en not_active Ceased
- 2003-02-10 KR KR10-2004-7013377A patent/KR20040091080A/ko active IP Right Grant
- 2003-02-10 CN CNB038068079A patent/CN1327964C/zh not_active Expired - Fee Related
- 2003-02-10 EA EA200401101A patent/EA007872B1/ru not_active IP Right Cessation
- 2003-02-10 CA CA2477428A patent/CA2477428C/fr not_active Expired - Fee Related
- 2003-02-10 JP JP2003572679A patent/JP2005518928A/ja not_active Withdrawn
- 2003-02-10 AU AU2003212993A patent/AU2003212993A1/en not_active Abandoned
- 2003-02-10 EA EA200401102A patent/EA007873B1/ru not_active IP Right Cessation
- 2003-02-10 CN CNB038047616A patent/CN1298427C/zh not_active Expired - Fee Related
- 2003-02-10 EP EP03743671A patent/EP1478462A2/fr not_active Withdrawn
- 2003-02-10 AU AU2003216248A patent/AU2003216248B2/en not_active Ceased
- 2003-02-14 TW TW092103148A patent/TWI265824B/zh not_active IP Right Cessation
- 2003-02-14 TW TW092103154A patent/TWI265825B/zh not_active IP Right Cessation
- 2003-02-14 TW TW092103144A patent/TWI306780B/zh not_active IP Right Cessation
- 2003-02-21 MY MYPI20030609A patent/MY140018A/en unknown
- 2003-02-21 MY MYPI20030610A patent/MY139847A/en unknown
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