CA2462348A1 - Metal complex compositions and their use as catalysts to produce polydienes - Google Patents

Metal complex compositions and their use as catalysts to produce polydienes Download PDF

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Publication number
CA2462348A1
CA2462348A1 CA002462348A CA2462348A CA2462348A1 CA 2462348 A1 CA2462348 A1 CA 2462348A1 CA 002462348 A CA002462348 A CA 002462348A CA 2462348 A CA2462348 A CA 2462348A CA 2462348 A1 CA2462348 A1 CA 2462348A1
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CA
Canada
Prior art keywords
polymerization
metal
phn
php
2nph
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002462348A
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English (en)
French (fr)
Inventor
Sven K. H. Thiele
Victor M. Monroy
David R. Wilson
Hartmut Stoye
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2462348A1 publication Critical patent/CA2462348A1/en
Abandoned legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
CA002462348A 2001-10-12 2002-10-07 Metal complex compositions and their use as catalysts to produce polydienes Abandoned CA2462348A1 (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US32893701P 2001-10-12 2001-10-12
US32893501P 2001-10-12 2001-10-12
US60/328,935 2001-10-12
US60/328,937 2001-10-12
US40486602P 2002-08-21 2002-08-21
US60/404,866 2002-08-21
PCT/US2002/031989 WO2003033545A2 (en) 2001-10-12 2002-10-07 Metal complex compositions and their use as catalysts to produce polydienes

Publications (1)

Publication Number Publication Date
CA2462348A1 true CA2462348A1 (en) 2003-04-24

Family

ID=27406641

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002462348A Abandoned CA2462348A1 (en) 2001-10-12 2002-10-07 Metal complex compositions and their use as catalysts to produce polydienes

Country Status (9)

Country Link
US (1) US20050090383A1 (en20)
EP (1) EP1436332A2 (en20)
JP (1) JP2005506404A (en20)
KR (1) KR20050034609A (en20)
CN (1) CN1568332A (en20)
BR (1) BR0213639A (en20)
CA (1) CA2462348A1 (en20)
MX (1) MXPA04003409A (en20)
WO (1) WO2003033545A2 (en20)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2267046B1 (en) * 2003-02-21 2013-08-07 Styron Europe GmbH Process for homo- or copolymerization of conjugated olefines
JP4207814B2 (ja) * 2004-03-19 2009-01-14 宇部興産株式会社 トランス−１，４−ポリブタジエンの製造方法
CN1961011B (zh) * 2004-04-05 2013-09-11 株式会社普利司通 改性共轭二烯类聚合物、聚合引发剂及其制备方法和橡胶组合物
DE102004022676A1 (de) * 2004-05-07 2005-12-15 Bayer Ag Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen
US7297653B2 (en) 2005-07-21 2007-11-20 Exxonmobil Chemical Patents Inc. Fluorophenylborates and their use as activators in catalyst systems for olefin polymerization
JO3598B1 (ar) 2006-10-10 2020-07-05 Infinity Discovery Inc الاحماض والاسترات البورونية كمثبطات اميد هيدروليز الحامض الدهني
US7820580B2 (en) * 2007-11-15 2010-10-26 Bridgestone Corporation Nickel-based catalysts for preparing high cis 1,4-polydienes
CA2721060A1 (en) * 2008-04-09 2009-10-15 Infinity Pharmaceuticals, Inc. Inhibitors of fatty acid amide hydrolase
US8609574B2 (en) * 2008-04-25 2013-12-17 Promerus Llc In situ olefin polymerization catalyst system
EP2291415B1 (en) * 2008-06-20 2016-07-20 Bridgestone Corporation Catalysts for preparing cis 1,4-polydienes
JP2012523425A (ja) 2009-04-07 2012-10-04 インフイニトイ プハルマセウトイカルス インコーポレイテッド 脂肪酸アミドヒドロラーゼの阻害薬
EP2416660B1 (en) 2009-04-07 2014-07-02 Infinity Pharmaceuticals, Inc. Inhibitors of fatty acid amide hydrolase
FR2944800B1 (fr) 2009-04-28 2012-10-26 Michelin Soc Tech Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues
FR2946047B1 (fr) * 2009-06-02 2011-07-29 Michelin Soc Tech Nouveaux composes organometallique a base d'un metal appartenant a la 2eme colonne de la classification periodique et procede de preparation
FR2946048B1 (fr) 2009-06-02 2012-12-28 Michelin Soc Tech Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu
MX361011B (es) * 2010-02-03 2018-11-26 Infinity Pharmaceuticals Inc Inhibidores de amida hidrolasa de ácido graso.
CN102432702B (zh) * 2010-09-29 2013-11-06 中国石油化工股份有限公司 一种烯烃聚合催化剂组合物
CN105732401A (zh) * 2010-11-02 2016-07-06 宇部兴产株式会社 (酰胺氨基烷烃)金属化合物及使用所述金属化合物制备含金属的薄膜的方法
EP2641909A1 (en) 2012-03-19 2013-09-25 LANXESS Deutschland GmbH Transition metal P-N complexes as polymerization catalysts
EP2840095B1 (en) * 2012-04-18 2020-06-17 Bridgestone Corporation Method for producing polymerization catalyst composition, polymerization catalyst composition, method for producing polymer composition, and polymer composition
RU2590155C2 (ru) * 2012-05-30 2016-07-10 Бриджстоун Корпорейшн Композиция катализатора полимеризации, способ получения синтетического полиизопрена и синтетический полиизопрен
SG11201408828TA (en) 2012-07-04 2015-02-27 Bridgestone Corp Method for producing polybutadiene, polybutadiene, rubber composition and tire
JP6031375B2 (ja) * 2013-02-14 2016-11-24 株式会社ブリヂストン 重合触媒組成物、合成ポリイソプレンの製造方法、及び合成ポリイソプレン
SG11201705078TA (en) 2015-01-06 2017-07-28 Scg Chemicals Co Ltd SIO<sb>2</sb>-LAYERED DOUBLE HYDROXIDE MICROSPHERES AND METHODS OF MAKING THEM
CN105199028B (zh) * 2015-09-12 2021-11-16 青岛科技大学 一种微观结构可调节的高乙烯基聚丁二烯橡胶及其制备方法
ES2893100T3 (es) 2015-10-12 2022-02-08 Advanced Cell Diagnostics Inc Detección in situ de variantes de nucleótidos en muestras con un elevado nivel de ruido, y composiciones y métodos relacionados con ésta
CN106589239B (zh) * 2015-10-19 2019-04-19 中国石油化工股份有限公司 一种制备丁二烯/异戊二烯共聚物的方法
CN106589195B (zh) * 2015-10-19 2018-11-02 中国石油化工股份有限公司 一种制备聚异戊二烯的方法
CN106588962A (zh) * 2015-10-19 2017-04-26 中国石油化工股份有限公司 稀土金属有机化合物和稀土催化剂组合物及其制备方法和应用
EP3159346B1 (en) 2015-10-21 2018-07-04 Trinseo Europe GmbH Aminosilane-functionalized dienes for use in functionalization of elastomeric polymers
JP2017082137A (ja) * 2015-10-29 2017-05-18 株式会社ブリヂストン 変性共役ジエン重合体の製造方法、変性共役ジエン重合体、ゴム組成物、及びタイヤ
GB201607989D0 (en) * 2016-05-06 2016-06-22 Scg Chemicals Co Ltd Catalytic support and the uses thereof
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
CN108164646B (zh) * 2016-12-08 2020-09-15 中国石油化工股份有限公司 一种由蒸汽裂化c5石脑油馏分制备聚异戊二烯的方法
KR102363032B1 (ko) 2018-03-21 2022-02-16 주식회사 엘지화학 전이금속 복합체의 제조 방법
CN112642428B (zh) * 2019-10-12 2023-05-02 中国石油化工股份有限公司 催化剂及其制备方法和应用以及废气的处理方法
CN110628010B (zh) * 2019-10-18 2022-09-27 辽宁奥克医药辅料股份有限公司 一种催化剂组合物及其应用于制备中等分子量聚乙二醇的方法
CN113735686B (zh) * 2020-05-29 2023-10-10 中国石油化工股份有限公司 一种环烷烃的催化氧化方法
CN113402637B (zh) * 2021-05-25 2022-07-05 中国石油天然气股份有限公司 稀土催化剂及其制备方法、包含其的稀土催化剂组合物及应用
KR102569201B1 (ko) * 2021-06-04 2023-08-23 주식회사 한솔케미칼 유기 금속 화합물 제조방법 및 이를 이용하여 박막을 형성하는 방법
FR3123917B1 (fr) * 2021-06-10 2024-04-19 Cie Generale Des Etablissements Michelin Système catalytique pour la polymérisation stéréospécifique de diènes et leur utilisation en procédé de synthèse de polymères diéniques
CN115260367B (zh) * 2022-08-26 2023-10-10 中国科学院长春应用化学研究所 稀土金属配合物在乙烯和1,3-丁二烯制备乙烯/丁二烯共聚物过程中的应用

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1068433B (it) * 1976-10-28 1985-03-21 Snam Progetti Procedimento per l'lachilazione di ammine secondarie alifatiche
CA1212932A (en) * 1982-04-01 1986-10-21 Derek K. Jenkins Polymerisation of conjugated dienes
FR2567135B1 (fr) * 1984-07-03 1989-01-13 Asahi Chemical Ind Polymere ou copolymere de butadiene et procede de preparation
US4575538A (en) * 1984-12-20 1986-03-11 Phillips Petroleum Company Olefin polymerization
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
ZA94612B (en) * 1993-01-29 1995-07-28 Dow Chemical Co Ethylene interpolymerization
US5625087A (en) * 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
DE4436059A1 (de) * 1994-10-10 1996-04-11 Bayer Ag Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch
HUP9801224A3 (en) * 1995-03-10 1998-11-30 Dow Chemical Co Supported catalyst component, supported catalyst, preparation process, polymerization process, complex compounds, and their preparation
DE19512116A1 (de) * 1995-04-04 1996-10-10 Bayer Ag Gasphasenpolymerisation von konjugierten Dienen in Gegenwart von Allylverbindungen der seltenen Erden
US5914377A (en) * 1995-04-04 1999-06-22 Bayer Ag Method for the production of diene rubbers in the gas phase
US5610115A (en) * 1995-07-20 1997-03-11 Samsung General Chemicals Co., Ltd. Organic carrier supported metallocene catalyst for olefin polymerization
FI102476B (fi) * 1996-05-31 1998-12-15 Borealis As Uudet siirtymämetallikompleksit ja menetelmä niiden valmistamiseksi
DE69722902T2 (de) * 1996-12-09 2004-05-19 Mitsubishi Chemical Corp. Katalysator für Alpha-Olefinpolymerisation
DE19720171A1 (de) * 1997-05-14 1998-11-19 Bayer Ag Verbindungen der Seltenen Erden und ihre Verwendung als Polymerisationskatalysatoren für ungesättigte Verbindungen
US6001478A (en) * 1997-08-08 1999-12-14 Union Carbide Chemicals & Plastics Technology Corporation Resin particle produced by diene polymerization with rare earth and transition metal catalysts
US5879805A (en) * 1997-09-09 1999-03-09 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization of vinylpolybutadiene
US6018007A (en) * 1997-09-22 2000-01-25 Bridgestone Corporation Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
DE19746266A1 (de) * 1997-10-20 1999-04-22 Bayer Ag Katalysator auf Basis von Verbindungen der seltenen Erdmetalle für die Polymerisation von ungesättigten organischen Verbindungen
US6197713B1 (en) * 1997-12-19 2001-03-06 Bridgestone Corporation Use of Lewis acids for the breakdown of gelatinous rare earth compounds in hydrocarbon solutions
US20030134999A1 (en) * 1998-07-18 2003-07-17 Heike Windisch Method for polymerizing conjugated diolefins (dienes) with rare earth catalysts in the presence of vinylaromatic solvents
US6403773B1 (en) * 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
KR100365581B1 (ko) * 1999-02-25 2003-01-15 금호석유화학 주식회사 높은 1,4-시스 함량을 갖는 폴리부타디엔의 제조방법
EP1086957A4 (en) * 1999-03-04 2005-08-31 Riken CATALYST COMPOSITION
US6825297B1 (en) * 1999-05-14 2004-11-30 The Dow Chemical Company Transition metal complexes and olefin polymerization process
US6887824B1 (en) * 1999-09-21 2005-05-03 The Regents Of The University Of California Divalent lanthanide reduction catalysts
JP2004532320A (ja) * 2001-05-04 2004-10-21 ダウ グローバル テクノロジーズ インコーポレイティド 金属錯体触媒の使用により製造されたランダムまたはブロック共重合体または三元重合体
DE10140202A1 (de) * 2001-08-16 2003-03-06 Bayer Ag Vanadium-Imido-Phosphoraniminato für die Olefinpolymerisation
AU2003277808A1 (en) * 2002-06-21 2004-01-06 Exxonmobil Chemical Patents Inc. Yttrium-based ethylene polymerization catalysts with bulky amidinate ancillary ligands

Also Published As

Publication number Publication date
CN1568332A (zh) 2005-01-19
MXPA04003409A (es) 2004-07-30
JP2005506404A (ja) 2005-03-03
WO2003033545A2 (en) 2003-04-24
KR20050034609A (ko) 2005-04-14
WO2003033545A3 (en) 2003-11-27
BR0213639A (pt) 2004-09-14
US20050090383A1 (en) 2005-04-28
EP1436332A2 (en) 2004-07-14

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FZDE Discontinued