CA2327427C - Polymeric materials formed using blends of electron donors - Google Patents
Polymeric materials formed using blends of electron donors Download PDFInfo
- Publication number
- CA2327427C CA2327427C CA002327427A CA2327427A CA2327427C CA 2327427 C CA2327427 C CA 2327427C CA 002327427 A CA002327427 A CA 002327427A CA 2327427 A CA2327427 A CA 2327427A CA 2327427 C CA2327427 C CA 2327427C
- Authority
- CA
- Canada
- Prior art keywords
- mfr
- electron donor
- ziegler
- dcpms
- ptes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000000463 material Substances 0.000 title description 15
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 claims abstract description 48
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 claims abstract description 46
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 22
- 239000011954 Ziegler–Natta catalyst Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 17
- 229920001519 homopolymer Polymers 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims abstract description 12
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 12
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 9
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 8
- 239000003426 co-catalyst Substances 0.000 claims description 8
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 6
- 239000011949 solid catalyst Substances 0.000 claims description 5
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 claims 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 18
- 241000352333 Amegilla alpha Species 0.000 abstract 2
- -1 polypropylenes Polymers 0.000 description 31
- 239000004743 Polypropylene Substances 0.000 description 29
- 239000003054 catalyst Substances 0.000 description 28
- 229910052739 hydrogen Inorganic materials 0.000 description 28
- 239000001257 hydrogen Substances 0.000 description 28
- 229920001155 polypropylene Polymers 0.000 description 28
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 27
- 230000004044 response Effects 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 8
- 238000011065 in-situ storage Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 5
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 229920005629 polypropylene homopolymer Polymers 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- 229920001580 isotactic polymer Polymers 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229920005606 polypropylene copolymer Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229920000576 tactic polymer Polymers 0.000 description 3
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical group 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- 101100378709 Arabidopsis thaliana AIR3 gene Proteins 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical class [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 1
- 229920001585 atactic polymer Polymers 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 150000008039 phosphoramides Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229920006301 statistical copolymer Polymers 0.000 description 1
- 150000001629 stilbenes Chemical class 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 230000026676 system process Effects 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8549898P | 1998-05-14 | 1998-05-14 | |
| US09/079,425 US6087459A (en) | 1998-05-14 | 1998-05-14 | Polymeric materials formed using blends of electron donors |
| US09/079,425 | 1998-05-14 | ||
| US60/085,498 | 1998-05-14 | ||
| PCT/US1999/010307 WO1999058585A1 (en) | 1998-05-14 | 1999-05-11 | Polymeric materials formed using blends of electron donors |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2327427A1 CA2327427A1 (en) | 1999-11-18 |
| CA2327427C true CA2327427C (en) | 2008-09-02 |
Family
ID=26761990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002327427A Expired - Fee Related CA2327427C (en) | 1998-05-14 | 1999-05-11 | Polymeric materials formed using blends of electron donors |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP1080122B1 (enExample) |
| JP (1) | JP2002514666A (enExample) |
| CN (1) | CN1138794C (enExample) |
| CA (1) | CA2327427C (enExample) |
| DE (1) | DE69914076T2 (enExample) |
| ES (1) | ES2211087T3 (enExample) |
| WO (1) | WO1999058585A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1662564A (zh) | 2002-06-14 | 2005-08-31 | 联合碳化化学及塑料技术公司 | 催化剂组合物及使用电子供体混合物的聚合方法 |
| DE602004024994D1 (de) | 2003-06-24 | 2010-02-25 | Union Carbide Chem Plastic | Katalysatorzusammensetzung und Polymerisationsverfahren mit einer Mischung von Silane Elektrondonoren |
| RU2345094C2 (ru) | 2003-09-23 | 2009-01-27 | Дау Глобал Текнолоджиз Инк. | Композиция катализатора с самоограничением реакции, включающая внутренний донор в виде сложного эфира дикарбоновой кислоты, и способ полимеризации пропилена |
| US7420021B2 (en) | 2003-09-23 | 2008-09-02 | Union Carbide Chemicals & Plastics Technology Llc | Self-extinguishing catalyst composition with monocarboxylic acid ester internal door and propylene polymerization process |
| US7491670B2 (en) | 2003-09-23 | 2009-02-17 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
| EP1668045B1 (en) | 2003-09-23 | 2012-10-03 | Dow Global Technologies LLC | Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process |
| MX351199B (es) | 2007-08-24 | 2017-10-05 | Grace W R & Co | Sistema de catalizador auto-limitante con proporción de aluminio a sca controlada y método. |
| MX2011001970A (es) | 2008-08-21 | 2011-08-12 | Dow Global Technologies Llc | Composicion de catalizador con agente de control de selectividad mezclado y metodo de polimerizacion que la usa. |
| CN102453163B (zh) * | 2010-10-21 | 2014-02-05 | 中国石油化工股份有限公司 | 丙烯聚合物的制备方法及由该方法制备的丙烯聚合物 |
| CN103382234B (zh) * | 2012-05-04 | 2016-04-06 | 中国石油天然气股份有限公司 | 聚丙烯的制备方法 |
| CN104650268A (zh) * | 2013-11-22 | 2015-05-27 | 中国石油天然气股份有限公司 | 一种高熔融指数聚1-丁烯的制备方法 |
| US10759883B2 (en) | 2015-08-07 | 2020-09-01 | Sabin Global Technologies B.V. | Process for the polymerization of olefins |
| US10745499B2 (en) * | 2015-08-07 | 2020-08-18 | Sabic Global Technologies B.V. | Process for the polymerization of olefins |
| US10696756B2 (en) | 2015-08-07 | 2020-06-30 | Sabic Global Technologies B.V. | Process for the polymerization of olefins |
| KR102415349B1 (ko) * | 2021-11-18 | 2022-07-01 | 대한유화 주식회사 | 초고분자량 폴리프로필렌의 제조방법 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE122060T1 (de) * | 1989-03-02 | 1995-05-15 | Mitsui Petrochemical Ind | Verfahren zur polymerisation von olefinen und katalysator für olefinpolymerisation. |
| JP2825909B2 (ja) * | 1989-03-02 | 1998-11-18 | 三井化学株式会社 | オレフィンの重合方法およびオレフィン重合用触媒 |
| TW300235B (enExample) * | 1992-12-04 | 1997-03-11 | Mitsui Petroleum Chemicals Ind | |
| JPH06248019A (ja) * | 1993-02-24 | 1994-09-06 | Mitsui Petrochem Ind Ltd | オレフィン重合用触媒およびオレフィンの重合方法 |
| EP0657477B1 (en) * | 1993-12-07 | 2001-03-14 | Sumitomo Chemical Company Limited | Process for producing olefin polymers for biaxially oriented film and olefin-polymerizing catalyst |
| JP3095177B2 (ja) * | 1994-02-04 | 2000-10-03 | エクソン・ケミカル・パテンツ・インク | オレフィンの重合用の二重供与体触媒系 |
| JPH07309913A (ja) * | 1994-05-19 | 1995-11-28 | Tokuyama Corp | ポリプロピレン |
| EP0717053B1 (en) * | 1994-11-25 | 2001-03-14 | Japan Polyolefins Co., Ltd. | Catalyst for olefin polymerization and process for producing polyolefin using the same |
| WO1997008218A1 (en) * | 1995-08-31 | 1997-03-06 | Chisso Corporation | Propylene-ethylene copolymer compositions and process for the production thereof |
| JPH09241318A (ja) * | 1996-03-04 | 1997-09-16 | Tonen Corp | 広い分子量分布を有するポリオレフィンの製造方法 |
| FI104080B1 (fi) * | 1996-05-15 | 1999-11-15 | Borealis As | Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi ja monivaiheiset polymerointiprosessit, joissa tätä systeemiä käytetään |
| JP3580639B2 (ja) * | 1996-06-04 | 2004-10-27 | 出光石油化学株式会社 | ポリプロピレン樹脂 |
-
1999
- 1999-05-11 JP JP2000548387A patent/JP2002514666A/ja active Pending
- 1999-05-11 WO PCT/US1999/010307 patent/WO1999058585A1/en not_active Ceased
- 1999-05-11 CA CA002327427A patent/CA2327427C/en not_active Expired - Fee Related
- 1999-05-11 ES ES99922932T patent/ES2211087T3/es not_active Expired - Lifetime
- 1999-05-11 EP EP99922932A patent/EP1080122B1/en not_active Expired - Lifetime
- 1999-05-11 DE DE69914076T patent/DE69914076T2/de not_active Expired - Lifetime
- 1999-05-11 CN CNB998059943A patent/CN1138794C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2211087T3 (es) | 2004-07-01 |
| CN1138794C (zh) | 2004-02-18 |
| JP2002514666A (ja) | 2002-05-21 |
| CA2327427A1 (en) | 1999-11-18 |
| DE69914076T2 (de) | 2004-08-26 |
| EP1080122A1 (en) | 2001-03-07 |
| CN1300299A (zh) | 2001-06-20 |
| DE69914076D1 (de) | 2004-02-12 |
| EP1080122B1 (en) | 2004-01-07 |
| WO1999058585A1 (en) | 1999-11-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |