CA2315345A1 - Catalyseur a base de ferrierite/fer pour la reduction catalytique de la teneur de gaz en protoxyde d'azote, son procede d'obtention et son application - Google Patents

Catalyseur a base de ferrierite/fer pour la reduction catalytique de la teneur de gaz en protoxyde d'azote, son procede d'obtention et son application Download PDF

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Publication number
CA2315345A1
CA2315345A1 CA002315345A CA2315345A CA2315345A1 CA 2315345 A1 CA2315345 A1 CA 2315345A1 CA 002315345 A CA002315345 A CA 002315345A CA 2315345 A CA2315345 A CA 2315345A CA 2315345 A1 CA2315345 A1 CA 2315345A1
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CA
Canada
Prior art keywords
gases
iron
application
nitrous oxide
ferrierite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002315345A
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English (en)
Other versions
CA2315345C (fr
Inventor
Bernard Neveu (Decede)
Christian Hamon
Karine Malefant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Casale SA
Institut Regional des Materiaux Avances IRMA
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2315345A1 publication Critical patent/CA2315345A1/fr
Application granted granted Critical
Publication of CA2315345C publication Critical patent/CA2315345C/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/24—Nitric oxide (NO)
    • C01B21/26—Preparation by catalytic or non-catalytic oxidation of ammonia
    • C01B21/265—Preparation by catalytic or non-catalytic oxidation of ammonia characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/88—Ferrosilicates; Ferroaluminosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/402—Dinitrogen oxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Un catalyseur pour la réduction de la teneur de gaz en protoxyde d'azote fonctionnant à températures relativement basses, dont l'activité est peu sensible à la présence de vapeur d'eau et résistant bien à la dégradation hydrothermique est élaboré à partir de ferriérite échangée au fer. Application au traitement des gaz à faible teneur en N2O, tels les gaz issus des ateliers de fabrication d'acide nitrique comme des gaz à forte teneur en N2O qui sont émis au cours des oxydations de composés organiques par l'acide nitrique.
CA002315345A 1997-12-31 1998-12-16 Catalyseur a base de ferrierite/fer pour la reduction catalytique de la teneur de gaz en protoxyde d'azote, son procede d'obtention et son application Expired - Lifetime CA2315345C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR97/16803 1997-12-31
FR9716803A FR2773144B1 (fr) 1997-12-31 1997-12-31 Catalyseur a base de ferrierite/fer pour la reduction catalytique de la teneur de gaz en protoxyde d'azote. son procede d'obtention. application au traitement de gaz industriels
PCT/FR1998/002747 WO1999034901A1 (fr) 1997-12-31 1998-12-16 Catalyseur a base de ferrierite/fer pour la reduction catalytique de la teneur de gaz en protoxyde d'azote, son procede d'obtention et son application

Publications (2)

Publication Number Publication Date
CA2315345A1 true CA2315345A1 (fr) 1999-07-15
CA2315345C CA2315345C (fr) 2008-02-05

Family

ID=9515380

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002315345A Expired - Lifetime CA2315345C (fr) 1997-12-31 1998-12-16 Catalyseur a base de ferrierite/fer pour la reduction catalytique de la teneur de gaz en protoxyde d'azote, son procede d'obtention et son application

Country Status (21)

Country Link
US (2) US6682710B1 (fr)
CN (1) CN100377764C (fr)
AU (1) AU755129B2 (fr)
BG (1) BG64728B1 (fr)
BR (1) BR9814593B1 (fr)
CA (1) CA2315345C (fr)
CO (1) CO5050382A1 (fr)
CZ (1) CZ300579B6 (fr)
DZ (1) DZ2694A1 (fr)
EA (1) EA001894B1 (fr)
FR (1) FR2773144B1 (fr)
HR (1) HRP20000512B1 (fr)
HU (1) HU230552B1 (fr)
IL (1) IL136198A0 (fr)
MA (1) MA24731A1 (fr)
PL (1) PL194755B1 (fr)
RO (1) RO119864B1 (fr)
TN (1) TNSN98233A1 (fr)
TR (1) TR200001841T2 (fr)
WO (1) WO1999034901A1 (fr)
ZA (1) ZA9811945B (fr)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2773144B1 (fr) * 1997-12-31 2000-02-04 Grande Paroisse Sa Catalyseur a base de ferrierite/fer pour la reduction catalytique de la teneur de gaz en protoxyde d'azote. son procede d'obtention. application au traitement de gaz industriels
DE10001539B4 (de) 2000-01-14 2006-01-19 Uhde Gmbh Verfahren zur Beseitigung von NOx und N2O
DE10001541B4 (de) * 2000-01-14 2005-04-28 Uhde Gmbh Verfahren zur Beseitigung von NOx und N¶2¶O aus dem Restgas der Salpetersäureproduktion
DE10123402A1 (de) * 2001-05-14 2002-11-28 Fraunhofer Ges Forschung Verfahren zum Behandeln von ammoniakhaltigen Rauchgasen
DE10226461A1 (de) * 2002-06-13 2004-01-22 Uhde Gmbh Verfahren und Vorrichtung zur Verringerung des Gehaltes an NOx und N2O in Gasen
NL1026207C2 (nl) 2004-05-17 2005-11-21 Stichting Energie Werkwijze voor de decompositie van N2O, katalysator daarvoor en bereiding van deze katalysator.
EP1918016B1 (fr) * 2006-10-24 2012-03-21 Gpn Catalyseur a base de zéolithe de type ferriérite / fer pour la décomposition de N20 et réduction catalytique NOx et N20
FR2913610A1 (fr) 2007-03-16 2008-09-19 Air Liquide Procede pour eliminer le n2o d'un flux gazeux
CN101875015B (zh) * 2009-04-29 2012-06-13 高等技术研究院研究组合 用于消除一氧化二氮的催化剂制备方法
DE102010022775A1 (de) 2010-06-04 2011-12-08 Uhde Gmbh Verfahren und Vorrichtung zur Beseitigung von NOx und N2O
CN102295299B (zh) * 2010-06-23 2013-01-02 中国科学院大连化学物理研究所 一种高含量骨架铁zsm-35分子筛的分步晶化合成法
FR2962923B1 (fr) * 2010-07-22 2015-01-02 Peugeot Citroen Automobiles Sa Composition catalytique et dispositif de traitement des gaz comprenant une telle composition
FR2964043B1 (fr) * 2010-08-26 2013-03-22 Irma Procede de decomposition catalytique du n2o a haute temperature
DE102011121188A1 (de) 2011-12-16 2013-06-20 Thyssen Krupp Uhde Gmbh Vorrichtung und Verfahren zur Beseitigung von NOx und N20
US8945392B2 (en) * 2012-09-19 2015-02-03 Red Lion Chem Tech, Llc Composite for phosphate and ammonium ion removal
CN103203159B (zh) * 2013-04-08 2015-04-01 浙江师范大学 一种利用类沸石分子筛骨架材料分离氧化亚氮和二氧化碳的方法
CN106029228A (zh) 2014-02-28 2016-10-12 庄信万丰股份有限公司 具有改进的低温性能的scr催化剂，及其制造和使用方法
FR3058413A1 (fr) * 2016-11-08 2018-05-11 IFP Energies Nouvelles Procede de deshydratation isomerisante d'une charge d'un monoalcool primaire non lineaire sur un catalyseur comprenant une zeolithe de type fer et un alcalin
CN108793189A (zh) * 2018-07-25 2018-11-13 中国石油大学(北京) 分层纳米薄片镁碱沸石分子筛及其制备方法和用途
CZ2018398A3 (cs) 2018-08-07 2019-10-02 Vysoká Škola Báňská - Technická Univerzita Ostrava Způsob přípravy katalyzátoru pro odstranění oxidu dusného z odpadních průmyslových plynů a katalyzátor připravený tímto způsobem
EP3689441A1 (fr) * 2019-02-01 2020-08-05 Casale Sa Procédé pour l'élimination d'oxydes d'azote dans un gaz
CN111229035B (zh) * 2020-01-21 2022-05-10 鞍钢股份有限公司 一种适用于烧结烟气的脱硝方法
FI20205806A1 (en) * 2020-08-19 2022-02-20 Teknologian Tutkimuskeskus Vtt Oy Process for the selective catalytic reduction of nitrous oxide, process for the extraction of carbon dioxide, process for the detection of carbon dioxide, apparatus and use

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US625369A (en) * 1899-05-23 Centrifugal separator
US3899441A (en) * 1971-08-10 1975-08-12 Union Oil Co Rejuvenation of damaged zeolite-supported metal catalysts
US4002575A (en) * 1975-08-14 1977-01-11 Union Oil Company Of California Rejuvenation of supported group VIII metal catalysts
NL7812162A (nl) * 1978-12-14 1980-06-17 Shell Int Research Werkwijze voor de bereiding van ferrieriet.
JPS6172621A (ja) * 1984-09-14 1986-04-14 Toa Nenryo Kogyo Kk バインダ−レスゼオライト成型物及びその製造方法
US5024981A (en) * 1989-04-20 1991-06-18 Engelhard Corporation Staged metal-promoted zeolite catalysts and method for catalytic reduction of nitrogen oxides using the same
CA2024154C (fr) * 1989-08-31 1995-02-14 Senshi Kasahara Catalyseur pour la reduction des oxydes d'azote dans le gaz d'echappement
JPH07106300B2 (ja) * 1989-12-08 1995-11-15 財団法人産業創造研究所 燃焼排ガス中の窒素酸化物除去法
JPH0478444A (ja) * 1990-07-23 1992-03-12 Tosoh Corp 排ガス浄化用触媒及びその使用方法
RU2071817C1 (ru) * 1992-02-04 1997-01-20 Институт катализа СО РАН Способ очистки отходящих газов от оксида азота (i)
FR2705036B1 (fr) * 1993-05-10 1995-06-16 Paroisse Sa Grande Procédé pour abaisser la teneur en protoxyde d'azote dans les effluents gazeux, en particulier dans ceux qui sont issus de synthèses par oxydation nitrique.
WO1994027709A1 (fr) * 1993-05-28 1994-12-08 Engelhard Corporation Catalyseur utilise dans la decomposition de l'oxyde azote
DE4413404C2 (de) * 1994-04-18 1999-01-14 Degussa Verfahren zur katalytischen Zersetzung von in Gasen enthaltenem Distickstoffmonoxid in die Elemente
US5520895A (en) * 1994-07-07 1996-05-28 Mobil Oil Corporation Method for the reduction of nitrogen oxides using iron impregnated zeolites
US5589147A (en) * 1994-07-07 1996-12-31 Mobil Oil Corporation Catalytic system for the reducton of nitrogen oxides
FR2773144B1 (fr) 1997-12-31 2000-02-04 Grande Paroisse Sa Catalyseur a base de ferrierite/fer pour la reduction catalytique de la teneur de gaz en protoxyde d'azote. son procede d'obtention. application au traitement de gaz industriels

Also Published As

Publication number Publication date
IL136198A0 (en) 2001-05-20
AU755129B2 (en) 2002-12-05
AU1764299A (en) 1999-07-26
PL194755B1 (pl) 2007-07-31
US20040192538A1 (en) 2004-09-30
EA001894B1 (ru) 2001-10-22
FR2773144B1 (fr) 2000-02-04
CN100377764C (zh) 2008-04-02
HRP20000512A2 (en) 2001-12-31
CA2315345C (fr) 2008-02-05
CO5050382A1 (es) 2001-06-27
HU230552B1 (hu) 2016-11-28
CZ300579B6 (cs) 2009-06-17
PL341287A1 (en) 2001-04-09
BG104637A (en) 2001-03-30
ZA9811945B (en) 1999-10-22
US7238641B2 (en) 2007-07-03
BR9814593B1 (pt) 2010-03-09
CZ20002483A3 (cs) 2001-03-14
HUP0100604A2 (hu) 2001-06-28
DZ2694A1 (fr) 2003-03-29
BR9814593A (pt) 2000-10-17
BG64728B1 (bg) 2006-01-31
HUP0100604A3 (en) 2010-01-28
CN1283132A (zh) 2001-02-07
WO1999034901A1 (fr) 1999-07-15
FR2773144A1 (fr) 1999-07-02
TR200001841T2 (tr) 2000-11-21
RO119864B1 (ro) 2005-05-30
HRP20000512B1 (en) 2009-03-31
US6682710B1 (en) 2004-01-27
TNSN98233A1 (fr) 2000-12-29
MA24731A1 (fr) 1999-07-01
EA200000727A1 (ru) 2001-02-26

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Effective date: 20181217