CA2232737C - Solid electrolytes as well as fuel cells, hydrogen pumps, oxygen concentration sensors, and steam concentration sensors using the solid electrolytes - Google Patents

Solid electrolytes as well as fuel cells, hydrogen pumps, oxygen concentration sensors, and steam concentration sensors using the solid electrolytes Download PDF

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Publication number
CA2232737C
CA2232737C CA002232737A CA2232737A CA2232737C CA 2232737 C CA2232737 C CA 2232737C CA 002232737 A CA002232737 A CA 002232737A CA 2232737 A CA2232737 A CA 2232737A CA 2232737 C CA2232737 C CA 2232737C
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CA
Canada
Prior art keywords
hydrogen
fuel
solid electrolyte
rare earth
electrolyte layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002232737A
Other languages
English (en)
French (fr)
Other versions
CA2232737A1 (en
Inventor
Shigeyuki Kawatsu
Takehisa Fukui
Satoshi Ohara
Mitsue Ogawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Motor Corp
Original Assignee
Toyota Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyota Motor Corp filed Critical Toyota Motor Corp
Publication of CA2232737A1 publication Critical patent/CA2232737A1/en
Application granted granted Critical
Publication of CA2232737C publication Critical patent/CA2232737C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • B01D53/326Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 in electrochemical cells
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403Cells and electrode assemblies
    • G01N27/406Cells and probes with solid electrolytes
    • G01N27/407Cells and probes with solid electrolytes for investigating or analysing gases
    • G01N27/4073Composition or fabrication of the solid electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/1231Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with both reactants being gaseous or vaporised
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/124Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
    • H01M8/1246Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293Fuel cells with solid oxide electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • H01M2300/0071Oxides
    • H01M2300/0074Ion conductive at high temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Fuel Cell (AREA)
  • Molecular Biology (AREA)
  • Physics & Mathematics (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Conductive Materials (AREA)
  • Measuring Oxygen Concentration In Cells (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Compositions Of Oxide Ceramics (AREA)
CA002232737A 1997-03-31 1998-03-19 Solid electrolytes as well as fuel cells, hydrogen pumps, oxygen concentration sensors, and steam concentration sensors using the solid electrolytes Expired - Fee Related CA2232737C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP09807297A JP3680232B2 (ja) 1997-03-31 1997-03-31 固体電解質と、これを用いた燃料電池、水素ポンプ、酸素濃度センサおよび水蒸気濃度センサ
JP9-98072 1997-03-31

Publications (2)

Publication Number Publication Date
CA2232737A1 CA2232737A1 (en) 1998-09-30
CA2232737C true CA2232737C (en) 2005-06-14

Family

ID=14210152

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002232737A Expired - Fee Related CA2232737C (en) 1997-03-31 1998-03-19 Solid electrolytes as well as fuel cells, hydrogen pumps, oxygen concentration sensors, and steam concentration sensors using the solid electrolytes

Country Status (3)

Country Link
JP (1) JP3680232B2 (de)
CA (1) CA2232737C (de)
DE (1) DE19814106B4 (de)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0931762B1 (de) * 1998-01-21 2005-05-04 Haldor Topsoe A/S Verfahren zur Herstellung von wasserstoffreichem Gas
DE19945668B4 (de) * 1999-09-23 2004-10-07 Siemens Ag Verfahren zum Starten einer PEM-Brennstoffzellenanlage sowie PEM-Brennstoffzellenanlage zur Durchführung des Verfahrens
JP4817476B2 (ja) * 1999-09-29 2011-11-16 京セラ株式会社 固体酸化物形燃料電池
DE19963008B4 (de) * 1999-12-24 2009-07-02 Robert Bosch Gmbh Sensorelement eines Gassensors zur Bestimmung von Gaskomponenten
JP2001185190A (ja) * 1999-12-28 2001-07-06 Mitsubishi Gas Chem Co Inc 燃料電池用水素の製造方法
JP4763870B2 (ja) * 1999-12-28 2011-08-31 三菱瓦斯化学株式会社 燃料電池用水素の製造法
JP2001185191A (ja) * 1999-12-28 2001-07-06 Mitsubishi Gas Chem Co Inc 燃料電池用水素の製造方法
JP2001185192A (ja) * 1999-12-28 2001-07-06 Mitsubishi Gas Chem Co Inc 燃料電池用水素の製造方法
JP4688263B2 (ja) * 2000-08-30 2011-05-25 京セラ株式会社 固体電解質形燃料電池セルおよびその起動方法
DE10053986A1 (de) * 2000-10-31 2002-05-08 Forschungszentrum Juelich Gmbh Verfahren zur Wasserstoffdosierung
JP4730635B2 (ja) * 2001-03-21 2011-07-20 独立行政法人産業技術総合研究所 炭化水素ガスセンサ及び炭化水素ガス濃度測定方法
JP2003031255A (ja) * 2001-07-18 2003-01-31 Matsushita Electric Ind Co Ltd 燃料電池発電装置、及び凝縮水の貯水タンクへの供給方法
JP5200312B2 (ja) 2001-09-03 2013-06-05 富士通株式会社 電子機器
JP4743375B2 (ja) * 2001-09-12 2011-08-10 独立行政法人産業技術総合研究所 可燃性ガス濃度測定方法
JP5088996B2 (ja) * 2001-09-27 2012-12-05 中国電力株式会社 リバーシブル・コージェネシステム
JP4695826B2 (ja) * 2002-06-06 2011-06-08 パナソニック株式会社 固体電解質型燃料電池
US6977121B2 (en) * 2003-04-03 2005-12-20 Utc Fuel Cells, Llc Fuel cell power plant having a fuel concentration sensor cell
KR20060023582A (ko) * 2003-06-30 2006-03-14 가부시키가이샤 저펜에너지 개질기 부착 연료 전지
US7252900B2 (en) * 2003-09-09 2007-08-07 Plug Power Inc. Combination fuel cell and ion pump, and methods and infrastructure systems employing same
GB2411043B (en) * 2004-02-10 2007-09-19 Ceres Power Ltd A method and apparatus for operating an intermediate-temperature solid-oxide fuel cell stack
JP2005268056A (ja) * 2004-03-18 2005-09-29 Central Japan Railway Co 水素供給システムおよび燃料電池システム
US8158286B2 (en) 2005-08-17 2012-04-17 Honda Motor Co., Ltd. Energy stations
WO2007105291A1 (ja) * 2006-03-13 2007-09-20 Fujitsu Limited 燃料電池
JP5491284B2 (ja) * 2010-05-28 2014-05-14 日本電信電話株式会社 燃料電池システムおよび燃料電池システムの運転方法
JP5652602B2 (ja) * 2010-09-24 2015-01-14 独立行政法人物質・材料研究機構 固体燃料電池用電解質材料及びその製造方法
JP5525463B2 (ja) * 2011-01-18 2014-06-18 日本電信電話株式会社 固体酸化物型燃料電池用空気極材料および固体酸化物型燃料電池
DE102011054803B4 (de) * 2011-10-25 2014-07-24 Günther Heisskanaltechnik Gmbh Heißkanaldüse mit einer Heizung und mit einem Thermoelement
JP2013008689A (ja) * 2012-08-29 2013-01-10 Ngk Spark Plug Co Ltd 燃料電池
RU2543071C1 (ru) * 2014-03-19 2015-02-27 Федеральное государственное бюджетное учреждение науки Институт высокотемпературной электрохимии Уральского отделения Российской Академии наук Способ изготовления электродов электрохимических устройств с твердым электролитом
US10722841B2 (en) * 2017-07-05 2020-07-28 Panasonic Intellectual Property Management Co., Ltd. Hydrogen supply system
JP6709974B2 (ja) * 2018-05-15 2020-06-17 パナソニックIpマネジメント株式会社 電気化学装置および水素システム
EP3978651A4 (de) * 2019-05-27 2022-12-21 Panasonic Intellectual Property Management Co., Ltd. Elektrochemische vorrichtung und verfahren zur erzeugung von wasserstoff
DE102021203538A1 (de) 2021-04-09 2022-10-13 Robert Bosch Gesellschaft mit beschränkter Haftung Brennstoffzellensystem und Verfahren zum Betrieb des Brennstoffzellensystems
CN114509472B (zh) * 2022-04-19 2022-07-19 佛山速敏智能仪器科技有限公司 气体检测系统、检测方法及变压器油中气体检测装置

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DE19634645C2 (de) * 1996-08-27 1999-11-11 Forschungszentrum Juelich Gmbh Schichtenfolge mit einem hochtemperatursupraleitenden Material und deren Verwendung

Also Published As

Publication number Publication date
DE19814106A1 (de) 1998-10-22
JP3680232B2 (ja) 2005-08-10
DE19814106B4 (de) 2004-08-05
JPH10284108A (ja) 1998-10-23
CA2232737A1 (en) 1998-09-30

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