CA1278148C - Modified polyethylene, process for preparing modified polyethylene, and products produced from modified polyethylene - Google Patents
Modified polyethylene, process for preparing modified polyethylene, and products produced from modified polyethyleneInfo
- Publication number
- CA1278148C CA1278148C CA000519949A CA519949A CA1278148C CA 1278148 C CA1278148 C CA 1278148C CA 000519949 A CA000519949 A CA 000519949A CA 519949 A CA519949 A CA 519949A CA 1278148 C CA1278148 C CA 1278148C
- Authority
- CA
- Canada
- Prior art keywords
- polymer
- poly
- mole
- amount
- unsaturated compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- -1 polyethylene Polymers 0.000 title description 7
- 239000004698 Polyethylene Substances 0.000 title description 6
- 229920000573 polyethylene Polymers 0.000 title description 6
- 229920000642 polymer Polymers 0.000 claims abstract description 71
- 150000001875 compounds Chemical class 0.000 claims abstract description 39
- 239000003054 catalyst Substances 0.000 claims abstract description 24
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000005977 Ethylene Substances 0.000 claims abstract description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 18
- 230000004913 activation Effects 0.000 claims abstract description 10
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 8
- 150000003624 transition metals Chemical class 0.000 claims abstract description 8
- 150000001993 dienes Chemical class 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 230000003287 optical effect Effects 0.000 claims description 8
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 claims description 6
- VJHGSLHHMIELQD-UHFFFAOYSA-N nona-1,8-diene Chemical compound C=CCCCCCC=C VJHGSLHHMIELQD-UHFFFAOYSA-N 0.000 claims description 6
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 4
- NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- GEAWFZNTIFJMHR-UHFFFAOYSA-N hepta-1,6-diene Chemical compound C=CCCCC=C GEAWFZNTIFJMHR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims 2
- TVEFFNLPYIEDLS-VQHVLOKHSA-N (4e)-deca-1,4,9-triene Chemical compound C=CCCC\C=C\CC=C TVEFFNLPYIEDLS-VQHVLOKHSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 15
- 239000004707 linear low-density polyethylene Substances 0.000 description 15
- 239000000155 melt Substances 0.000 description 8
- 229920001903 high density polyethylene Polymers 0.000 description 7
- 239000004700 high-density polyethylene Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- ADTDLWOIUYJQNC-GLVZAGOZSA-N (3e,5e)-deca-1,3,5-triene Chemical compound CCCC\C=C\C=C\C=C ADTDLWOIUYJQNC-GLVZAGOZSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- MVECFARLYQAUNR-UHFFFAOYSA-N CCCC[Mg]CC Chemical compound CCCC[Mg]CC MVECFARLYQAUNR-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
- Y10T428/1345—Single layer [continuous layer]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8502747 | 1985-10-09 | ||
| NL8502747A NL8502747A (nl) | 1985-10-09 | 1985-10-09 | Gemodificeerd polyetheen, werkwijze voor het bereiden van gemodificeerd polyetheen, en produkten vervaardigd uit gemodificeerd polyetheen. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1278148C true CA1278148C (en) | 1990-12-18 |
Family
ID=19846681
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000519949A Expired - Lifetime CA1278148C (en) | 1985-10-09 | 1986-10-07 | Modified polyethylene, process for preparing modified polyethylene, and products produced from modified polyethylene |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US4868264A (https=) |
| EP (1) | EP0219166B1 (https=) |
| JP (1) | JPS6291511A (https=) |
| KR (1) | KR900000569B1 (https=) |
| CN (1) | CN1007894B (https=) |
| AT (1) | ATE59659T1 (https=) |
| BR (1) | BR8604915A (https=) |
| CA (1) | CA1278148C (https=) |
| DE (1) | DE3676417D1 (https=) |
| ES (1) | ES2020659B3 (https=) |
| IN (1) | IN168421B (https=) |
| NL (1) | NL8502747A (https=) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6468512A (en) * | 1987-09-05 | 1989-03-14 | Mitsui Petrochemical Ind | Molecular oriented formed article of ethylene-polyene copolymer having ultra-high molecular weight |
| JP2538625B2 (ja) * | 1987-11-13 | 1996-09-25 | 三井石油化学工業株式会社 | 分枝α−オレフイン系ランダム共重合体およびその製法 |
| JP2762482B2 (ja) * | 1988-10-07 | 1998-06-04 | 三井化学株式会社 | 高級α−オレフィン系共重合体の製造方法 |
| JP2738562B2 (ja) * | 1989-05-25 | 1998-04-08 | 三菱化学株式会社 | 不飽和共重合体の製造法 |
| WO1991017194A1 (en) * | 1990-05-07 | 1991-11-14 | Exxon Chemical Patents Inc. | UNSATURATED α-OLEFIN COPOLYMERS AND METHOD FOR PREPARATION THEREOF |
| GB9010887D0 (en) * | 1990-05-15 | 1990-07-04 | Ici Plc | Olefin copolymers |
| JP2930371B2 (ja) * | 1990-06-08 | 1999-08-03 | 東燃株式会社 | 両末端修飾エチレン重合体及びその製造法 |
| CN1090195C (zh) * | 1994-03-14 | 2002-09-04 | 三井化学株式会社 | 乙烯不饱和共聚物及其制备方法 |
| US5405915A (en) * | 1994-06-27 | 1995-04-11 | Phillips Petroleum Company | Ethylene polymer compositions |
| CA2194178C (en) * | 1994-07-01 | 2006-02-07 | Nicolaas Hendrika Friederichs | Catalyst system for the polymerization of ethylene |
| TW344746B (en) * | 1994-07-06 | 1998-11-11 | Mitsui Petroleum Chemicals Ind | Unsaturated copolymer of ethylene and process for preparing the same |
| US5814714A (en) * | 1995-11-30 | 1998-09-29 | The Dow Chemical Company | Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof |
| TW331569B (en) * | 1995-12-29 | 1998-05-11 | Mitsui Petroleum Chemicals Ind | Unsaturated copolymer based on olefin and production and use |
| US6699955B1 (en) * | 1999-11-19 | 2004-03-02 | E. I. Du Pont De Nemours And Company | Copolymerization of ethylene and dienes |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR778691A (fr) * | 1933-12-07 | 1935-03-22 | Perfectionnements aux liaisons et joints élastiques | |
| US3435020A (en) * | 1958-03-07 | 1969-03-25 | Hercules Inc | Crystalline polymers of alpha,omega-diolefins |
| NL126769C (https=) * | 1962-03-02 | |||
| US3351621A (en) * | 1964-02-06 | 1967-11-07 | Chevron Res | Copolymerization with alpha, omega-dienes |
| NL7008302A (https=) * | 1969-06-11 | 1970-12-15 | ||
| FR2087213A5 (https=) * | 1970-05-11 | 1971-12-31 | Aquitaine Petrole | |
| US3819591A (en) * | 1970-05-19 | 1974-06-25 | J Campbell | Branched-chain hydrocarbon elastomers |
| FR2124299B1 (https=) * | 1971-02-03 | 1977-04-01 | Snam Progetti | |
| CA980498A (en) * | 1971-04-16 | 1975-12-23 | Du Pont Of Canada Limited | Ethylene polymers with long chain branching |
| US4028284A (en) * | 1973-01-23 | 1977-06-07 | Unitika Ltd. | Phenolic chelate resin |
| JPS5117291A (ja) * | 1974-08-01 | 1976-02-12 | Mitsui Petrochemical Ind | Tainetsuseinosugureta kakyonanshitsujushino seizohoho |
| FR2322883A1 (fr) * | 1975-09-02 | 1977-04-01 | Michelin & Cie | Elastomeres du type e p t, et articles comportant de tels elastomeres |
| JPS52141888A (en) * | 1976-05-21 | 1977-11-26 | Nippon I P Rubber Kk | Ethyleneepropylene copolymers rubber |
| US4189553A (en) * | 1976-12-01 | 1980-02-19 | The Dow Chemical Company | High efficiency catalyst for polymerizing olefins |
| US4551503A (en) * | 1977-12-19 | 1985-11-05 | The Goodyear Tire & Rubber Company | Preparation of interpolymers of alpha-olefins and nonconjugated alpha, omega-dienes |
| GB2047254B (en) * | 1979-04-13 | 1983-03-09 | Mitsui Petrochemical Ind | Rubbery ethylene/1-butene/polyene copolymers and process for production thereof |
| DE3021273A1 (de) * | 1979-06-12 | 1981-01-08 | Mitsubishi Petrochemical Co | Ungesaettigte mischpolymerisate |
| JPS5630413A (en) * | 1979-08-21 | 1981-03-27 | Mitsubishi Petrochem Co Ltd | Unsaturated copolymer |
| DE3007725A1 (de) * | 1980-02-29 | 1981-09-17 | Hansjörg Prof. Dr. 2000 Hamburg Sinn | Verfahren zur herstellung von polyethylen, polypropylen und copolymeren |
| JPS5956412A (ja) * | 1982-09-22 | 1984-03-31 | Mitsubishi Chem Ind Ltd | 不飽和共重合体の製造方法 |
| JPS61148211A (ja) * | 1984-12-21 | 1986-07-05 | Idemitsu Petrochem Co Ltd | エチレン系不飽和共重合体組成物 |
-
1985
- 1985-10-09 NL NL8502747A patent/NL8502747A/nl not_active Application Discontinuation
-
1986
- 1986-09-30 IN IN775/MAS/86A patent/IN168421B/en unknown
- 1986-10-07 KR KR1019860008466A patent/KR900000569B1/ko not_active Expired
- 1986-10-07 CA CA000519949A patent/CA1278148C/en not_active Expired - Lifetime
- 1986-10-08 CN CN86106849A patent/CN1007894B/zh not_active Expired
- 1986-10-08 DE DE8686201745T patent/DE3676417D1/de not_active Expired - Lifetime
- 1986-10-08 JP JP61238174A patent/JPS6291511A/ja active Pending
- 1986-10-08 BR BR8604915A patent/BR8604915A/pt unknown
- 1986-10-08 ES ES86201745T patent/ES2020659B3/es not_active Expired - Lifetime
- 1986-10-08 AT AT86201745T patent/ATE59659T1/de not_active IP Right Cessation
- 1986-10-08 EP EP86201745A patent/EP0219166B1/en not_active Expired - Lifetime
-
1987
- 1987-05-15 US US07/050,032 patent/US4868264A/en not_active Expired - Fee Related
-
1989
- 1989-06-02 US US07/360,308 patent/US5096986A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BR8604915A (pt) | 1987-07-07 |
| IN168421B (https=) | 1991-03-30 |
| US4868264A (en) | 1989-09-19 |
| DE3676417D1 (de) | 1991-02-07 |
| ATE59659T1 (de) | 1991-01-15 |
| KR900000569B1 (ko) | 1990-01-31 |
| NL8502747A (nl) | 1987-05-04 |
| CN86106849A (zh) | 1987-04-08 |
| KR870004061A (ko) | 1987-05-07 |
| EP0219166A1 (en) | 1987-04-22 |
| EP0219166B1 (en) | 1991-01-02 |
| ES2020659B3 (es) | 1991-09-01 |
| CN1007894B (zh) | 1990-05-09 |
| JPS6291511A (ja) | 1987-04-27 |
| US5096986A (en) | 1992-03-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |