CA1236620A - High shearing of polymer blends to elastoplastics - Google Patents
High shearing of polymer blends to elastoplasticsInfo
- Publication number
- CA1236620A CA1236620A CA000435089A CA435089A CA1236620A CA 1236620 A CA1236620 A CA 1236620A CA 000435089 A CA000435089 A CA 000435089A CA 435089 A CA435089 A CA 435089A CA 1236620 A CA1236620 A CA 1236620A
- Authority
- CA
- Canada
- Prior art keywords
- rubber
- blend
- parts
- plastic
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002959 polymer blend Polymers 0.000 title 1
- 238000010008 shearing Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 60
- 229920001971 elastomer Polymers 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 37
- 239000005060 rubber Substances 0.000 claims abstract description 36
- 238000004073 vulcanization Methods 0.000 claims abstract description 30
- 239000004033 plastic Substances 0.000 claims abstract description 29
- 229920003023 plastic Polymers 0.000 claims abstract description 29
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 4
- 229920002943 EPDM rubber Polymers 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 8
- 239000004606 Fillers/Extenders Substances 0.000 claims description 7
- 239000004743 Polypropylene Substances 0.000 claims description 7
- -1 polypropylene Polymers 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 239000012190 activator Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 229920001568 phenolic resin Polymers 0.000 claims 1
- 239000005011 phenolic resin Substances 0.000 claims 1
- 239000007965 rubber solvent Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 3
- 238000004898 kneading Methods 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 6
- 101100313164 Caenorhabditis elegans sea-1 gene Proteins 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000002361 compost Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000331231 Amorphocerini gen. n. 1 DAD-2008 Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008380 degradant Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/80—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
- B29C48/83—Heating or cooling the cylinders
- B29C48/832—Heating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US410,196 | 1982-08-23 | ||
| US06/410,196 US4594390A (en) | 1982-08-23 | 1982-08-23 | Process for the preparation of thermoplastic elastomers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1236620A true CA1236620A (en) | 1988-05-10 |
Family
ID=23623670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000435089A Expired CA1236620A (en) | 1982-08-23 | 1983-08-22 | High shearing of polymer blends to elastoplastics |
Country Status (11)
Families Citing this family (112)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1187779A (en) * | 1982-03-15 | 1985-05-28 | Eric G. Kent | Process for adhering a rubber layer to a substrate |
| US4639487A (en) * | 1984-07-11 | 1987-01-27 | Exxon Research & Engineering Co. | Heat shrinkable thermoplastic olefin composition |
| JPS61195144A (ja) * | 1985-02-26 | 1986-08-29 | Mitsubishi Monsanto Chem Co | 塩化ビニル樹脂系熱可塑性エラストマ−の製法 |
| IT1207498B (it) * | 1985-05-31 | 1989-05-25 | Himont Inc | Procedimento per la preparazione di composizioni plasto-elastomeriche poliolefiniche, mediante vulcanizzazione dinamica. |
| IT1223262B (it) * | 1987-12-11 | 1990-09-19 | Himont Inc | Composizioni elasto plastiche e procedimento per la loro preparazione |
| US4981908A (en) * | 1988-02-02 | 1991-01-01 | E. I. Du Pont De Nemours And Company | Thermoplastic elastomer blends |
| US4910245A (en) * | 1988-04-07 | 1990-03-20 | The Dow Chemical Company | Thermoplastic elastomers based upon chlorinated polyethylene and a crystalline olefin polymer |
| US5102958A (en) * | 1989-12-22 | 1992-04-07 | Exxon Chemical Patents Inc. | Partially crosslinked elastomeric polymers and process for producing the same |
| US5075387A (en) * | 1989-12-22 | 1991-12-24 | Exxon Chemical Patents Inc. | Partially crosslinked elastomeric polymers and process for producing the same |
| DE4113063A1 (de) | 1991-04-22 | 1992-10-29 | Continental Ag | Thermoplastische elastomere und verfahren zu deren herstellung |
| JP3031022B2 (ja) * | 1991-12-19 | 2000-04-10 | 住友化学工業株式会社 | 熱可塑性エラストマー組成物の製造方法 |
| TW273561B (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html) * | 1993-10-21 | 1996-04-01 | Sumitomo Bakelite Co | |
| JPH07148471A (ja) * | 1993-11-29 | 1995-06-13 | Sansha Electric Mfg Co Ltd | 洗浄装置 |
| BR9509510A (pt) | 1994-10-11 | 1997-12-30 | Milliken Res Corp | Tapete e processo contínuo para a produção do mesmo |
| JP3168450B2 (ja) * | 1995-09-29 | 2001-05-21 | 住友化学工業株式会社 | 熱可塑性エラストマー組成物の製造方法 |
| US5791278A (en) * | 1995-12-19 | 1998-08-11 | Duramax, Inc. | Fender protective structure |
| EP0938522B1 (de) | 1996-11-14 | 2002-03-13 | Phoenix Aktiengesellschaft | Verfahren zur herstellung einer thermoplastischen elastomermasse |
| US5936039A (en) * | 1997-11-10 | 1999-08-10 | Wang; Kang-Bo | Processes for producing thermoplastic elastomers having improved engineering performance |
| AU7278598A (en) | 1998-01-09 | 1999-07-26 | Minnesota Mining And Manufacturing Company | Insulation protection tape |
| JP2002537432A (ja) * | 1999-02-15 | 2002-11-05 | フェニックス アクチエンゲゼルシャフト | 熱可塑性加硫ゴムおよびその製造方法 |
| US6440492B1 (en) | 2000-05-10 | 2002-08-27 | Gencorp, Inc. | Methods of coating rubber with solventless crystalline polyolefin coatings |
| DE10049804A1 (de) * | 2000-10-09 | 2002-04-18 | Bayer Ag | Wirkstoffkombinationen mit fungiziden und akariziden Eigenschaften |
| CN1227290C (zh) * | 2000-10-11 | 2005-11-16 | 埃克森美孚化学专利公司 | 卤化弹性体的热塑性组合物 |
| US7019058B2 (en) * | 2000-10-11 | 2006-03-28 | Exxonmobil Chemical Patents, Inc. | Halogenated elastomeric compositions having enhanced viscosity |
| US6552108B1 (en) | 2000-10-11 | 2003-04-22 | Exxonmobil Chemical Patents Inc. | Rubber blends having improved stability and green strength |
| US6451915B1 (en) | 2000-12-29 | 2002-09-17 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved processing and physical property balance |
| CA2449072A1 (en) * | 2001-06-07 | 2002-12-19 | Exxonmobil Chemical Patents Inc. | Halogenated isobutylene-based copolymers having enhanced viscosity and thermoplastic compositions thereof |
| WO2002100940A1 (en) * | 2001-06-08 | 2002-12-19 | Thermoplastic Rubber Systems, Inc. | Thermoplastic vulcanizates |
| JP3977038B2 (ja) * | 2001-08-27 | 2007-09-19 | 株式会社半導体エネルギー研究所 | レーザ照射装置およびレーザ照射方法 |
| EP1436135B1 (en) | 2001-10-11 | 2006-03-29 | DSM IP Assets B.V. | Process for the preparation of a dynamically vulcanized thermoplastic elastomer |
| ATE405594T1 (de) | 2002-01-15 | 2008-09-15 | Advanced Elastomer Systems | Thermoplastische elastomere |
| JP3835313B2 (ja) | 2002-03-08 | 2006-10-18 | 住友電装株式会社 | オレフィン系熱可塑性エラストマー組成物および被覆電線 |
| US6790911B2 (en) * | 2002-12-26 | 2004-09-14 | Advanvced Elastomer Systems, L.P. | Thermoplastic elastomers having improved adhesive proterties |
| US6797779B1 (en) | 2003-03-28 | 2004-09-28 | The Goodyear Tire & Rubber Company | Thermoplastic composition |
| EP1652873A4 (en) * | 2003-08-05 | 2009-11-11 | Bridgestone Corp | RUBBER MASTERBATCH AND MANUFACTURING METHOD THEREFOR |
| US20070010641A1 (en) * | 2003-08-07 | 2007-01-11 | Ashok Adur | Catalyst systems for elastomeric compositions |
| WO2005028556A1 (en) * | 2003-09-17 | 2005-03-31 | Advanced Elastomer Systems | Thermoplastic vulcanizates and process for making the same |
| US7439304B2 (en) * | 2004-06-03 | 2008-10-21 | Advanced Elastomer Systems, L.P. | Thermoplastic vulcanizates and process for making the same |
| WO2005028555A1 (en) * | 2003-09-17 | 2005-03-31 | Advanced Elastomer Systems, L.P. | Improved thermoplastic vulcanizates and processes for making the same |
| US7015284B2 (en) * | 2004-01-06 | 2006-03-21 | The Goodyear Tire & Rubber Company | Thermoplastic elastomer composition |
| US7340280B2 (en) * | 2004-02-26 | 2008-03-04 | Nokia Corporation | Method of configuring base station, and base station |
| US7326748B2 (en) * | 2004-06-14 | 2008-02-05 | The Goodyear Tire & Rubber Company | Thermoplastic composition |
| US20060052540A1 (en) | 2004-09-09 | 2006-03-09 | Maria Ellul | Thermoplastic vulcanizates |
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| DE102005049571A1 (de) * | 2004-10-26 | 2006-05-04 | Sumitomo Chemical Co., Ltd. | Verfahren zur Herstellung einer thermoplastischen Elastomerzusammensetzung |
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| US7951316B2 (en) * | 2005-04-05 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Process for pipe seal manufacture |
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| US20100119855A1 (en) * | 2008-11-10 | 2010-05-13 | Trazollah Ouhadi | Thermoplastic Elastomer with Excellent Adhesion to EPDM Thermoset Rubber and Low Coefficient of Friction |
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| US8557906B2 (en) | 2010-09-03 | 2013-10-15 | Exxonmobil Chemical Patents Inc. | Flame resistant polyolefin compositions and methods for making the same |
| CN103403086B (zh) | 2010-12-30 | 2016-12-07 | 陶氏环球技术有限责任公司 | 热塑性硫化橡胶组合物、其制备方法和由其制备的制品 |
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| EP2935409B1 (en) | 2012-12-20 | 2023-12-20 | ExxonMobil Chemical Patents Inc. | Process for preparing dynamically vulcanized alloys |
| US9309114B2 (en) * | 2013-01-14 | 2016-04-12 | Xerox Corporation | Porous nanoparticles produced by solvent-free emulsification |
| US9822231B2 (en) | 2013-12-24 | 2017-11-21 | Exxonmobil Chemical Patents Inc. | Compositions comprising thermoplastic vulcanizate, foamed material and articles made therefrom |
| WO2016064479A1 (en) | 2014-10-24 | 2016-04-28 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions |
| WO2016085457A1 (en) | 2014-11-25 | 2016-06-02 | Exxonmobil Chemical Patents Inc. | Method of making thermoplastic vulcanizates and thermoplastic vulcanizates made therefrom |
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Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3037954A (en) * | 1958-12-15 | 1962-06-05 | Exxon Research Engineering Co | Process for preparing a vulcanized blend of crystalline polypropylene and chlorinated butyl rubber |
| NL271957A (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html) * | 1960-11-30 | |||
| DE1520152A1 (de) * | 1963-05-29 | 1969-07-17 | Roemmler Gmbh H | Veraenderung der Struktur von hochmolekularen thermoplastischen Kunststoffen |
| US3806558A (en) * | 1971-08-12 | 1974-04-23 | Uniroyal Inc | Dynamically partially cured thermoplastic blend of monoolefin copolymer rubber and polyolefin plastic |
| US4130535A (en) * | 1975-07-21 | 1978-12-19 | Monsanto Company | Thermoplastic vulcanizates of olefin rubber and polyolefin resin |
| CA1124917A (en) * | 1977-11-09 | 1982-06-01 | Michael A. Fath | Elastoplastic blends of cured olefin rubber and polyolefin resin |
| US4311628A (en) * | 1977-11-09 | 1982-01-19 | Monsanto Company | Thermoplastic elastomeric blends of olefin rubber and polyolefin resin |
| US4271049A (en) * | 1979-09-10 | 1981-06-02 | Monsanto Company | Elastoplastic compositions of cured diene rubber and polypropylene |
| US4299931A (en) * | 1980-03-10 | 1981-11-10 | Monsanto Company | Compatibilized polymer blends |
| JPS5825340A (ja) * | 1981-08-07 | 1983-02-15 | Mitsui Petrochem Ind Ltd | 部分架橋ゴム−樹脂組成物の製造法 |
-
1982
- 1982-08-23 US US06/410,196 patent/US4594390A/en not_active Expired - Lifetime
-
1983
- 1983-08-19 DE DE8383870081T patent/DE3373794D1/de not_active Expired
- 1983-08-19 EP EP83870081A patent/EP0107635B2/en not_active Expired - Lifetime
- 1983-08-22 BR BR8304511A patent/BR8304511A/pt not_active IP Right Cessation
- 1983-08-22 AR AR83293968A patent/AR242407A1/es active
- 1983-08-22 CA CA000435089A patent/CA1236620A/en not_active Expired
- 1983-08-22 AU AU18178/83A patent/AU555125B2/en not_active Expired
- 1983-08-22 KR KR1019830003910A patent/KR880000830B1/ko not_active Expired
- 1983-08-22 JP JP58152994A patent/JPS5958043A/ja active Granted
- 1983-08-22 IN IN1030/CAL/83A patent/IN159092B/en unknown
- 1983-08-22 ZA ZA836190A patent/ZA836190B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US4594390A (en) | 1986-06-10 |
| EP0107635B1 (en) | 1987-09-23 |
| JPS5958043A (ja) | 1984-04-03 |
| EP0107635A1 (en) | 1984-05-02 |
| AR242407A1 (es) | 1993-03-31 |
| BR8304511A (pt) | 1984-04-03 |
| KR880000830B1 (ko) | 1988-05-14 |
| DE3373794D1 (en) | 1987-10-29 |
| ZA836190B (en) | 1984-04-25 |
| JPH0587529B2 (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html) | 1993-12-17 |
| IN159092B (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html) | 1987-03-21 |
| AU1817883A (en) | 1984-03-01 |
| KR840005833A (ko) | 1984-11-19 |
| EP0107635B2 (en) | 1993-03-17 |
| AU555125B2 (en) | 1986-09-11 |
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