CA1132963A - Billes d'alumine a double porosite, leur procede de preparation et leurs applications comme supports de catalyseurs - Google Patents

Billes d'alumine a double porosite, leur procede de preparation et leurs applications comme supports de catalyseurs

Info

Publication number
CA1132963A
CA1132963A CA346,371A CA346371A CA1132963A CA 1132963 A CA1132963 A CA 1132963A CA 346371 A CA346371 A CA 346371A CA 1132963 A CA1132963 A CA 1132963A
Authority
CA
Canada
Prior art keywords
alumina
boehmite
spheroidal
particles
ultra
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA346,371A
Other languages
English (en)
French (fr)
Inventor
Roland Jacques
Gilbert Bouge
Laurent Seigneurin
Regis Poisson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
Rhone Poulenc Industries SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9222440&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA1132963(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Rhone Poulenc Industries SA filed Critical Rhone Poulenc Industries SA
Application granted granted Critical
Publication of CA1132963A publication Critical patent/CA1132963A/fr
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/02—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops
    • B01J2/06—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops in a liquid medium
    • B01J2/08—Gelation of a colloidal solution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/14—Aluminium oxide or hydroxide from alkali metal aluminates
    • C01F7/141—Aluminium oxide or hydroxide from alkali metal aluminates from aqueous aluminate solutions by neutralisation with an acidic agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/02—Amorphous compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/60—Compounds characterised by their crystallite size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/32—Spheres
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C01P2006/13—Surface area thermal stability thereof at high temperatures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/21—Attrition-index or crushing strength of granulates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
    • Y10S502/50—Stabilized
    • Y10S502/503—Crush strength

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Catalysts (AREA)
CA346,371A 1979-02-26 1980-02-25 Billes d'alumine a double porosite, leur procede de preparation et leurs applications comme supports de catalyseurs Expired CA1132963A (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7904810A FR2449474A1 (fr) 1979-02-26 1979-02-26 Billes d'alumine a double porosite, leur procede de preparation et leurs applications comme supports de catalyseurs
FR79.04810 1979-02-26

Publications (1)

Publication Number Publication Date
CA1132963A true CA1132963A (fr) 1982-10-05

Family

ID=9222440

Family Applications (1)

Application Number Title Priority Date Filing Date
CA346,371A Expired CA1132963A (fr) 1979-02-26 1980-02-25 Billes d'alumine a double porosite, leur procede de preparation et leurs applications comme supports de catalyseurs

Country Status (9)

Country Link
US (1) US4315839A (en, 2012)
EP (1) EP0015801B2 (en, 2012)
JP (1) JPS6049135B2 (en, 2012)
BR (1) BR8001096A (en, 2012)
CA (1) CA1132963A (en, 2012)
DE (1) DE3064074D1 (en, 2012)
ES (1) ES488840A1 (en, 2012)
FR (1) FR2449474A1 (en, 2012)
MX (1) MX6359E (en, 2012)

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FR2527197B1 (fr) * 1982-05-19 1985-06-21 Rhone Poulenc Spec Chim Procede de fabrication de billes d'alumine mises en forme par coagulation en gouttes
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FR2537889B1 (fr) * 1982-12-20 1992-10-09 Pro Catalyse Procede de traitement d'hydrocarbures en presence d'un catalyseur a base de billes d'alumine mises en forme par coagulation en gouttes
JPS6027646A (ja) * 1983-07-25 1985-02-12 三菱重工業株式会社 アルミナ成形体の製造方法
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US8354091B2 (en) * 2006-10-31 2013-01-15 Denki Kagaku Kogyo Kabushiki Kaisha Alumina powder and method for preparing the same as well as use thereof
CN101172256B (zh) * 2006-10-31 2011-02-09 中国石油化工股份有限公司石油化工科学研究院 一种耐高温磁性氧化铝载体的制备方法
CN102365337B (zh) * 2009-03-31 2014-05-14 塞特克技术公司 用于结构粘接应用的水基非铬酸盐底漆
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CN104248986B (zh) * 2013-06-28 2016-06-29 中国石油化工股份有限公司 球形凹凸棒石介孔复合载体和负载型催化剂及其制备方法和应用以及乙酸乙酯的制备方法
CN104248991B (zh) * 2013-06-28 2016-06-29 中国石油化工股份有限公司 球形蒙脱石介孔复合载体和负载型催化剂及其制备方法和应用以及乙酸乙酯的制备方法
JP6236647B2 (ja) * 2014-02-26 2017-11-29 国立研究開発法人産業技術総合研究所 アルミナ粒子
CN105440168B (zh) * 2014-09-29 2018-03-02 中国石油化工股份有限公司 球形蒙脱石介孔复合载体和负载型聚乙烯催化剂及其制备方法和应用
CN108698975B (zh) * 2016-02-04 2021-10-08 罗地亚经营管理公司 用于制备脂肪胺的大孔催化剂
TR201812437T1 (tr) * 2016-09-20 2018-11-21 Highchem Tech Co Ltd Katali̇zör taşiyici ve bunu i̇çeren katali̇zör
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EP3915675A1 (en) * 2020-05-26 2021-12-01 SASOL Germany GmbH Stable shaped alumina carriers and method for producing same
JP7261888B2 (ja) * 2020-06-19 2023-04-20 エルジー・ケム・リミテッド 脱水反応触媒、その製造方法及びそれを用いたアルケンの製造方法
KR102584441B1 (ko) 2020-06-19 2023-10-05 주식회사 엘지화학 알루미나 촉매의 제조방법, 이로부터 제조된 알루미나 촉매 및 이를 이용한 프로필렌의 제조방법
CN113371746B (zh) * 2021-07-14 2023-02-21 中氢能源科技发展(内蒙古)有限公司 一种制备超细介孔氧化铝的方法及所得产物
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CN115490253B (zh) * 2022-10-08 2023-06-20 山东理工大学 一种氢氧化铝微球的制备方法
CN119869439B (zh) * 2025-03-24 2025-06-24 杭州嘉隆气体设备有限公司 一种活性氧化铝球及其制备方法和应用

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US4001144A (en) * 1975-12-19 1977-01-04 Kaiser Aluminum & Chemical Corporation Process for modifying the pore volume distribution of alumina base catalyst supports

Also Published As

Publication number Publication date
DE3064074D1 (en) 1983-08-18
MX6359E (es) 1985-05-09
JPS55116623A (en) 1980-09-08
FR2449474A1 (fr) 1980-09-19
EP0015801B2 (fr) 1988-03-30
US4315839A (en) 1982-02-16
BR8001096A (pt) 1980-10-29
EP0015801B1 (fr) 1983-07-13
FR2449474B1 (en, 2012) 1984-02-24
ES488840A1 (es) 1980-09-16
JPS6049135B2 (ja) 1985-10-31
EP0015801A1 (fr) 1980-09-17

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