BRPI0614075B1 - composição poliolefínica, artigo moldado, método para preparar uma composição - Google Patents
composição poliolefínica, artigo moldado, método para preparar uma composição Download PDFInfo
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- BRPI0614075B1 BRPI0614075B1 BRPI0614075A BRPI0614075A BRPI0614075B1 BR PI0614075 B1 BRPI0614075 B1 BR PI0614075B1 BR PI0614075 A BRPI0614075 A BR PI0614075A BR PI0614075 A BRPI0614075 A BR PI0614075A BR PI0614075 B1 BRPI0614075 B1 BR PI0614075B1
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- Brazil
- Prior art keywords
- ethylene
- olefin
- weight
- composition
- hdt
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 180
- 238000000034 method Methods 0.000 title claims description 25
- 229920000098 polyolefin Polymers 0.000 title claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 123
- 239000005977 Ethylene Substances 0.000 claims abstract description 123
- 239000004711 α-olefin Substances 0.000 claims abstract description 94
- 229920001384 propylene homopolymer Polymers 0.000 claims abstract description 53
- 239000000454 talc Substances 0.000 claims abstract description 53
- 229910052623 talc Inorganic materials 0.000 claims abstract description 53
- 239000000945 filler Substances 0.000 claims abstract description 22
- 239000004609 Impact Modifier Substances 0.000 claims abstract description 20
- 239000000654 additive Substances 0.000 claims description 27
- 229920001519 homopolymer Polymers 0.000 claims description 22
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 18
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 17
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 16
- 239000003063 flame retardant Substances 0.000 claims description 15
- 229920005629 polypropylene homopolymer Polymers 0.000 claims description 15
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 14
- 238000005299 abrasion Methods 0.000 claims description 14
- 230000000694 effects Effects 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 13
- 230000008018 melting Effects 0.000 claims description 13
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 11
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 230000003678 scratch resistant effect Effects 0.000 claims description 6
- 238000007707 calorimetry Methods 0.000 claims description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 5
- 239000004566 building material Substances 0.000 claims description 4
- -1 for example Substances 0.000 abstract description 95
- 230000003014 reinforcing effect Effects 0.000 abstract description 9
- 229920000642 polymer Polymers 0.000 description 83
- 239000004743 Polypropylene Substances 0.000 description 67
- 229920001155 polypropylene Polymers 0.000 description 67
- 235000012222 talc Nutrition 0.000 description 50
- 229920001971 elastomer Polymers 0.000 description 26
- 229920001577 copolymer Polymers 0.000 description 23
- 239000000806 elastomer Substances 0.000 description 21
- 239000000126 substance Substances 0.000 description 20
- 229920002397 thermoplastic olefin Polymers 0.000 description 19
- 150000001993 dienes Chemical class 0.000 description 18
- 229920000573 polyethylene Polymers 0.000 description 18
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 16
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 16
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 16
- 239000000178 monomer Substances 0.000 description 15
- 239000004698 Polyethylene Substances 0.000 description 14
- 239000003054 catalyst Substances 0.000 description 14
- 239000004205 dimethyl polysiloxane Substances 0.000 description 14
- 238000009472 formulation Methods 0.000 description 14
- 230000008569 process Effects 0.000 description 10
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- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
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- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 4
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 4
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
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- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 3
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 3
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- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000012963 UV stabilizer Substances 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
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- 238000010438 heat treatment Methods 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
- 239000004702 low-density polyethylene Substances 0.000 description 3
- 229910000000 metal hydroxide Inorganic materials 0.000 description 3
- 150000004692 metal hydroxides Chemical class 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229920002959 polymer blend Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical group O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 description 3
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 2
- CJSBUWDGPXGFGA-UHFFFAOYSA-N 4-methylpenta-1,3-diene Chemical compound CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 description 2
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 2
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 2
- UCKITPBQPGXDHV-UHFFFAOYSA-N 7-methylocta-1,6-diene Chemical compound CC(C)=CCCCC=C UCKITPBQPGXDHV-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
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- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 description 2
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- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
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- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
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- 238000004132 cross linking Methods 0.000 description 2
- NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 description 2
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 2
- ZSFDBVJMDCMTBM-UHFFFAOYSA-N ethane-1,2-diamine;phosphoric acid Chemical compound NCCN.OP(O)(O)=O ZSFDBVJMDCMTBM-UHFFFAOYSA-N 0.000 description 2
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 2
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- 230000009477 glass transition Effects 0.000 description 2
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- 229910052757 nitrogen Inorganic materials 0.000 description 2
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- KEMUGHMYINTXKW-NQOXHWNZSA-N (1z,5z)-cyclododeca-1,5-diene Chemical compound C1CCC\C=C/CC\C=C/CC1 KEMUGHMYINTXKW-NQOXHWNZSA-N 0.000 description 1
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 1
- QEOSCXACXNFJCY-AKHDSKFASA-N (2R,3R,4S,5R)-6-benzyl-7-phenylheptane-1,2,3,4,5,6-hexol Chemical compound C(C1=CC=CC=C1)C(O)([C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO)CC1=CC=CC=C1 QEOSCXACXNFJCY-AKHDSKFASA-N 0.000 description 1
- ZGXMNEKDFYUNDQ-GQCTYLIASA-N (5e)-hepta-1,5-diene Chemical compound C\C=C\CCC=C ZGXMNEKDFYUNDQ-GQCTYLIASA-N 0.000 description 1
- RJUCIROUEDJQIB-GQCTYLIASA-N (6e)-octa-1,6-diene Chemical compound C\C=C\CCCC=C RJUCIROUEDJQIB-GQCTYLIASA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- SJFNJMCYFVSADL-UHFFFAOYSA-N 1,1,1,3-tetrabromononane Chemical compound CCCCCCC(Br)CC(Br)(Br)Br SJFNJMCYFVSADL-UHFFFAOYSA-N 0.000 description 1
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 description 1
- UZOSVZSBPTTWIG-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-chlorocyclohexane Chemical compound ClC1C(Br)C(Br)C(Br)C(Br)C1Br UZOSVZSBPTTWIG-UHFFFAOYSA-N 0.000 description 1
- YUAPUIKGYCAHGM-UHFFFAOYSA-N 1,2-dibromo-3-(2,3-dibromopropoxy)propane Chemical compound BrCC(Br)COCC(Br)CBr YUAPUIKGYCAHGM-UHFFFAOYSA-N 0.000 description 1
- PQRRSJBLKOPVJV-UHFFFAOYSA-N 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane Chemical compound BrCC(Br)C1CCC(Br)C(Br)C1 PQRRSJBLKOPVJV-UHFFFAOYSA-N 0.000 description 1
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical class O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 description 1
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- PPWUTZVGSFPZOC-UHFFFAOYSA-N 1-methyl-2,3,3a,4-tetrahydro-1h-indene Chemical compound C1C=CC=C2C(C)CCC21 PPWUTZVGSFPZOC-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- HKORUDUNMQUYRD-UHFFFAOYSA-N 2,4-dimethylocta-1,7-diene Chemical compound CC(=C)CC(C)CCC=C HKORUDUNMQUYRD-UHFFFAOYSA-N 0.000 description 1
- YXRZFCBXBJIBAP-UHFFFAOYSA-N 2,6-dimethylocta-1,7-diene Chemical compound C=CC(C)CCCC(C)=C YXRZFCBXBJIBAP-UHFFFAOYSA-N 0.000 description 1
- YHCGGLXPGFJNCO-UHFFFAOYSA-N 2-(2H-benzotriazol-4-yl)phenol Chemical compound OC1=CC=CC=C1C1=CC=CC2=C1N=NN2 YHCGGLXPGFJNCO-UHFFFAOYSA-N 0.000 description 1
- OWHSTLLOZWTNTQ-UHFFFAOYSA-N 2-ethylhexyl 2-sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS OWHSTLLOZWTNTQ-UHFFFAOYSA-N 0.000 description 1
- SLQMKNPIYMOEGB-UHFFFAOYSA-N 2-methylhexa-1,5-diene Chemical compound CC(=C)CCC=C SLQMKNPIYMOEGB-UHFFFAOYSA-N 0.000 description 1
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- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical class C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 1
- FPQQSJJWHUJYPU-UHFFFAOYSA-N 3-(dimethylamino)propyliminomethylidene-ethylazanium;chloride Chemical compound Cl.CCN=C=NCCCN(C)C FPQQSJJWHUJYPU-UHFFFAOYSA-N 0.000 description 1
- UFERIGCCDYCZLN-UHFFFAOYSA-N 3a,4,7,7a-tetrahydro-1h-indene Chemical compound C1C=CCC2CC=CC21 UFERIGCCDYCZLN-UHFFFAOYSA-N 0.000 description 1
- DYIZJUDNMOIZQO-UHFFFAOYSA-N 4,5,6,7-tetrabromo-2-[2-(4,5,6,7-tetrabromo-1,3-dioxoisoindol-2-yl)ethyl]isoindole-1,3-dione Chemical compound O=C1C(C(=C(Br)C(Br)=C2Br)Br)=C2C(=O)N1CCN1C(=O)C2=C(Br)C(Br)=C(Br)C(Br)=C2C1=O DYIZJUDNMOIZQO-UHFFFAOYSA-N 0.000 description 1
- IZLXZVWFPZWXMZ-UHFFFAOYSA-N 5-cyclohexylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1=CC2CC1CC2=C1CCCCC1 IZLXZVWFPZWXMZ-UHFFFAOYSA-N 0.000 description 1
- BDEXHIMNEUYKBS-UHFFFAOYSA-N 5-cyclopent-2-en-1-ylbicyclo[2.2.1]hept-2-ene Chemical compound C1=CCCC1C1C(C=C2)CC2C1 BDEXHIMNEUYKBS-UHFFFAOYSA-N 0.000 description 1
- VSQLAQKFRFTMNS-UHFFFAOYSA-N 5-methylhexa-1,4-diene Chemical compound CC(C)=CCC=C VSQLAQKFRFTMNS-UHFFFAOYSA-N 0.000 description 1
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- UGJBFMMPNVKBPX-UHFFFAOYSA-N 5-propan-2-ylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C(C)C)CC1C=C2 UGJBFMMPNVKBPX-UHFFFAOYSA-N 0.000 description 1
- KUFDSEQTHICIIF-UHFFFAOYSA-N 6-methylhepta-1,5-diene Chemical compound CC(C)=CCCC=C KUFDSEQTHICIIF-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
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- HPGAXSAGNBYYTH-UHFFFAOYSA-N C(CC(=O)O)(=O)O.C(C(=O)NC1=CC=CC=C1)(=O)NC1=CC=CC=C1 Chemical compound C(CC(=O)O)(=O)O.C(C(=O)NC1=CC=CC=C1)(=O)NC1=CC=CC=C1 HPGAXSAGNBYYTH-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Instrument Panels (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
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| US69415005P | 2005-06-24 | 2005-06-24 | |
| US60/694,150 | 2005-06-24 | ||
| PCT/US2006/024527 WO2007002436A1 (en) | 2005-06-24 | 2006-06-23 | Filled tpo compositions, methods of making the same, and articles prepared from the same |
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| BRPI0614075A2 BRPI0614075A2 (pt) | 2011-03-09 |
| BRPI0614075B1 true BRPI0614075B1 (pt) | 2017-04-11 |
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| BRPI0614075A BRPI0614075B1 (pt) | 2005-06-24 | 2006-06-23 | composição poliolefínica, artigo moldado, método para preparar uma composição |
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| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| KR101113341B1 (ko) | 2002-10-15 | 2012-09-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체 |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7968180B2 (en) * | 2005-04-27 | 2011-06-28 | Prime Polymer Co., Ltd. | Extruded propylene-resin composite foam |
| US7714057B2 (en) * | 2005-06-24 | 2010-05-11 | Dow Global Technologies Inc. | Automotive articles prepared from filled TPO compositions, and methods of making the same |
| US8080607B2 (en) | 2006-08-16 | 2011-12-20 | Dow Global Technologies Llc | Polymeric material and process for forming and using same |
| WO2008059616A1 (en) | 2006-11-14 | 2008-05-22 | Medical Therapies Limited | Antibody recognizing c-domain of midkine |
| CN101558116B (zh) * | 2006-12-15 | 2012-02-01 | 住友化学株式会社 | 聚丙烯树脂组合物 |
| JP5363339B2 (ja) * | 2006-12-21 | 2013-12-11 | ダウ グローバル テクノロジーズ エルエルシー | 充填されたｔｐｏ組成物、それを作成する方法、およびそれから調製された物品 |
| US7862671B2 (en) | 2007-01-11 | 2011-01-04 | Dow Global Technologies Inc. | Welding of a polymeric material and structures formed thereby |
| JP5390194B2 (ja) * | 2007-01-18 | 2014-01-15 | 株式会社プライムポリマー | 応力耐久成形体用のプロピレン単独重合体、および該重合体を含む組成物、並びにこれらから得られる応力耐久成形体 |
| WO2008109093A1 (en) * | 2007-03-06 | 2008-09-12 | Exxonmobil Research And Engineering Company | Fiber reinforced polypropylene composite front end modules |
| EP1988122A1 (en) * | 2007-05-04 | 2008-11-05 | Total Petrochemicals Research Feluy | Blend for use in automobile application |
| JP5364095B2 (ja) | 2007-08-24 | 2013-12-11 | トタル リサーチ アンド テクノロジー フエリユイ | シングルサイト触媒を用いて製造されたポリプロピレンとポリ（ヒドロキシカルボン酸）とのブレンド |
| WO2009035850A1 (en) * | 2007-09-07 | 2009-03-19 | Dow Global Technologies Inc. | Filled tpo compositions with good low temperature ductility |
| US20090095096A1 (en) * | 2007-10-10 | 2009-04-16 | Charles Edwin Dean | Hazardous materials sensing robot |
| EP2055738A1 (en) * | 2007-10-31 | 2009-05-06 | Borealis Technology Oy | Impact-modified polypropylene |
| EP2108679A1 (en) * | 2008-04-10 | 2009-10-14 | Borealis Technology Oy | Low emission polymer composition |
| CN102089370A (zh) * | 2008-07-14 | 2011-06-08 | 北欧化工公司 | 具有低clte的聚烯烃组合物 |
| CN102300922B (zh) | 2009-01-30 | 2013-07-31 | 陶氏环球技术有限责任公司 | 聚合物组合物和具有改善美感的填充tpo制品 |
| US9018310B2 (en) * | 2009-04-06 | 2015-04-28 | Polyone Designed Structures And Solutions Llc | Polymer blend composition for automotive flooring applications |
| EP2275476A1 (en) * | 2009-06-09 | 2011-01-19 | Borealis AG | Automotive material with excellent flow, high stiffness, excellent ductility and low CLTE |
| JP2011099091A (ja) * | 2009-09-30 | 2011-05-19 | Sumitomo Chemical Co Ltd | エチレン系重合体の製造方法 |
| JP5331754B2 (ja) * | 2010-06-08 | 2013-10-30 | 日本ポリプロ株式会社 | 押出成形用ポリプロピレン樹脂組成物およびその塗装樹脂成形体 |
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2006
- 2006-06-23 US US11/473,706 patent/US7714057B2/en active Active
- 2006-06-23 WO PCT/US2006/024526 patent/WO2007002435A1/en not_active Ceased
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| EP1896538A1 (en) | 2008-03-12 |
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| EP1896538B1 (en) | 2012-05-23 |
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| US7714057B2 (en) | 2010-05-11 |
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| US20070037914A1 (en) | 2007-02-15 |
| MX2007016391A (es) | 2008-03-07 |
| WO2007002435A1 (en) | 2007-01-04 |
| EP1896539A1 (en) | 2008-03-12 |
| AU2006261996A1 (en) | 2007-01-04 |
| AU2006261995B2 (en) | 2011-12-08 |
| CN101365748A (zh) | 2009-02-11 |
| US20070037913A1 (en) | 2007-02-15 |
| JP5118030B2 (ja) | 2013-01-16 |
| CA2612228A1 (en) | 2007-01-04 |
| JP2008544071A (ja) | 2008-12-04 |
| ATE491746T1 (de) | 2011-01-15 |
| WO2007002436A1 (en) | 2007-01-04 |
| CN101223226A (zh) | 2008-07-16 |
| BRPI0614075A2 (pt) | 2011-03-09 |
| EP1896539B1 (en) | 2010-12-15 |
| KR20080040636A (ko) | 2008-05-08 |
| US7741398B2 (en) | 2010-06-22 |
| DE602006018914D1 (de) | 2011-01-27 |
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