BRPI0514779A - processo de oxidação em fase lìquida, e, reator de coluna de bolhas - Google Patents

processo de oxidação em fase lìquida, e, reator de coluna de bolhas

Info

Publication number
BRPI0514779A
BRPI0514779A BRPI0514779-4A BRPI0514779A BRPI0514779A BR PI0514779 A BRPI0514779 A BR PI0514779A BR PI0514779 A BRPI0514779 A BR PI0514779A BR PI0514779 A BRPI0514779 A BR PI0514779A
Authority
BR
Brazil
Prior art keywords
liquid phase
phase oxidation
bubble column
column reactor
cta
Prior art date
Application number
BRPI0514779-4A
Other languages
English (en)
Inventor
Alan George Wonders
Puneet Gupta
Lee Reynolds Partin
Wayne Scott Strasser
Marcel De Vreede
Original Assignee
Eastman Chem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chem Co filed Critical Eastman Chem Co
Priority to BR122015022124A priority Critical patent/BR122015022124B8/pt
Publication of BRPI0514779A publication Critical patent/BRPI0514779A/pt
Publication of BRPI0514779B1 publication Critical patent/BRPI0514779B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/003—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor in a downward flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872—Details of the fluidised bed reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/222—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid in the presence of a rotating device only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/14—Monocyclic dicarboxylic acids
    • C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
    • C07C63/26—1,4 - Benzenedicarboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00292—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids
    • B01J2208/003—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids involving reactant slurries
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00761—Discharging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00831—Stationary elements
    • B01J2208/0084—Stationary elements inside the bed, e.g. baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00858—Moving elements
    • B01J2208/00867—Moving elements inside the bed, e.g. rotary mixer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCESSO DE OXIDAçãO EM FASE LìQUIDA, E, REATOR DE COLUNA DE BOLHAS. São revelados um processo e aparelho otimizados para realizar de forma mais eficiente e económica a oxidação em fase líquida de um composto oxidável. Tal oxidação em fase líquida é realizada em um reator de coluna de bolhas que permite uma reação altamente eficiente a temperaturas relativamente baixas. Quando o composto oxidado é para-xileno e o produto da reação de oxidação é ácido tereftálico bruto (CTA), tal produto CTA pode ser purificado e separado por técnicas mais económicas do que as que poderiam ser empregadas se o CTA fosse formado por um processo convencional de oxidação a alta temperatura.
BRPI0514779-4A 2004-09-02 2005-08-29 processo de oxidação em fase líquida BRPI0514779B1 (pt)

Priority Applications (1)

Application Number Priority Date Filing Date Title
BR122015022124A BR122015022124B8 (pt) 2004-09-02 2005-08-29 Reator de coluna de bolhas

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US60665304P 2004-09-02 2004-09-02
US60/606,653 2004-09-02
US63155904P 2004-11-29 2004-11-29
US60/631,559 2004-11-29
US11/153,994 2005-06-16
US11/153,994 US7910769B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation
PCT/US2005/030659 WO2006028771A2 (en) 2004-09-02 2005-08-29 Optimized liquid-phase oxidation

Publications (2)

Publication Number Publication Date
BRPI0514779A true BRPI0514779A (pt) 2008-06-24
BRPI0514779B1 BRPI0514779B1 (pt) 2020-12-08

Family

ID=35781255

Family Applications (2)

Application Number Title Priority Date Filing Date
BR122015022124A BR122015022124B8 (pt) 2004-09-02 2005-08-29 Reator de coluna de bolhas
BRPI0514779-4A BRPI0514779B1 (pt) 2004-09-02 2005-08-29 processo de oxidação em fase líquida

Family Applications Before (1)

Application Number Title Priority Date Filing Date
BR122015022124A BR122015022124B8 (pt) 2004-09-02 2005-08-29 Reator de coluna de bolhas

Country Status (13)

Country Link
US (2) US7910769B2 (pt)
EP (1) EP1786556B1 (pt)
JP (1) JP2008511649A (pt)
KR (2) KR101281442B1 (pt)
CN (1) CN101010134B (pt)
BR (2) BR122015022124B8 (pt)
CA (1) CA2576795A1 (pt)
ES (1) ES2617727T3 (pt)
LT (1) LT1786556T (pt)
MX (1) MX2007002515A (pt)
PL (1) PL1786556T3 (pt)
PT (1) PT1786556T (pt)
WO (1) WO2006028771A2 (pt)

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US7692036B2 (en) 2004-11-29 2010-04-06 Eastman Chemical Company Optimized liquid-phase oxidation
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US7910769B2 (en) 2004-09-02 2011-03-22 Eastman Chemical Company Optimized liquid-phase oxidation
US7987613B2 (en) * 2004-10-12 2011-08-02 Great River Energy Control system for particulate material drying apparatus and process
US20070155987A1 (en) * 2006-01-04 2007-07-05 O'meadhra Ruairi S Oxidative digestion with optimized agitation
US7326808B2 (en) * 2006-03-01 2008-02-05 Eastman Chemical Company Polycarboxylic acid production system employing cooled mother liquor from oxidative digestion as feed to impurity purge system
US7816556B2 (en) * 2006-03-01 2010-10-19 Eastman Chemical Company Polycarboxylic acid production system employing enhanced multistage oxidative digestion
US7326807B2 (en) * 2006-03-01 2008-02-05 Eastman Chemical Company Polycarboxylic acid production system with enhanced heating for oxidative digestion
US7420082B2 (en) * 2006-03-01 2008-09-02 Eastman Chemical Company Polycarboxylic acid production system employing hot liquor removal downstream of oxidative digestion
US7501537B2 (en) * 2006-03-01 2009-03-10 Eastman Chemical Company Polycarboxylic acid production system employing oxidative digestion with reduced or eliminated upstream liquor exchange
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US8936767B2 (en) * 2010-01-29 2015-01-20 Grupo Petrotemex. S.A. de C.V. Oxidation system with sidedraw secondary reactor
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CN101010134B (zh) 2012-03-07
ES2617727T3 (es) 2017-06-19
LT1786556T (lt) 2017-02-27
CA2576795A1 (en) 2006-03-16
US20110256037A1 (en) 2011-10-20
US8685334B2 (en) 2014-04-01
BR122015022124B1 (pt) 2021-05-04
BR122015022124B8 (pt) 2021-10-05
BRPI0514779B1 (pt) 2020-12-08
US20060047143A1 (en) 2006-03-02
CN101010134A (zh) 2007-08-01
WO2006028771A3 (en) 2006-08-10
PL1786556T3 (pl) 2017-08-31
MX2007002515A (es) 2007-05-04
US7910769B2 (en) 2011-03-22
KR101363742B1 (ko) 2014-02-14
JP2008511649A (ja) 2008-04-17
WO2006028771A2 (en) 2006-03-16
EP1786556B1 (en) 2016-11-30
KR20070054699A (ko) 2007-05-29
PT1786556T (pt) 2017-03-14
EP1786556A2 (en) 2007-05-23
KR101281442B1 (ko) 2013-07-02
KR20130028750A (ko) 2013-03-19

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